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At least 289 records · Page 16

Decoupling Surface Topography from Gravitational Acceleration in Cryogenic Pool Boiling

Boiling heat transfer is governed by a complex interplay between surface conditions and gravitational acceleration. To isolate the sole effects of gravity, we investigated the pool boiling characteristics of liquid nitrogen on atomically smooth silicon dioxide (SiO 2 ) surfaces under terrestrial (1-g) and reduced gravity (0±0.02 g) conditions achieved via parabolic flight. Our results quantify a drastic reduction in the critical heat flux (CHF) in reduced gravity, decreasing from 16.15 W/cm 2 at 1-g to 5−6 W/cm 2 at μ-g due to the suppression of buoyancy. Conversely, we observed a distinct increase in the heat transfer coefficient (HTC) in the reduced gravity condition prior to CHF. By utilizing a surface with a maximum peak-to-valley height of ≈36.7 nm and low contact angle hysteresis (<10°), we confirm this HTC enhancement is an intrinsic response to the gravitational environment, decoupled from surface-defect-induced nucleation. These findings demonstrate that the influence of surface topography is significantly more prominent in reduced gravity than in terrestrial conditions, providing a critical baseline for rationalizing the design of cryogenic thermal management systems in space and quantum applications.

Liquid nitrogen↗

Time-resolved measurement of subchannel void distribution for boiling two-phase flow in 5 x 5 rod bundle at high-pressure and high-temperature

A subchannel void sensor (SCVS) was improved to acquire time-resolve boiling two-phase flow in a 5-by-5 heated rod bundle at high-pressure and high-temperature. The SCVS consists of 6-by-6 wire electrodes and 5-by-5 rod electrodes. The SCVS can acquire a time series data of local void fraction at 32 points of central subchannel region in addition to 100 points of rod surface regions between rods. The devised sensors are installed in the heated rod bundle at eight height levels to acquire two-phase flow dynamics and its development. The axial and radial power profile of the heated rod bundle are uniform, and eight pairs of sheath thermocouples are embedded on the heated rod to monitor its surface temperature distribution. The paper addresses the axial and cross-sectional distributions of void fraction at various pressure and rod bundle power conditions, which simulates an accidental condition in reactor core and in a spent fuel pool of a boiling water reactor (BWR). The experimental data are suitable to validate the computational multi-fluid dynamics (CMFD) and subchannel codes. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A new model for active nucleation site density in boiling systems

A new model for active nucleation site density in boiling systems has been developed. The model is based on parametric analysis of existing experimental data and is a function of wall superheat, pressure, and contact angle. The model is applicable for a wide pressure range - from 0.101 MPa to 19.8 MPa. Preliminary studies of temperature dependency of the contact angle have also been performed. The new model is intended to improve the predictions of the interfacial area concentration in two-fluid models and the wall temperature in subcooled boiling simulations. Validation activities have shown that the active nucleation site density predicted by the new model is in a good agreement with various published experimental data, and have demonstrated the achieved improvements as compared to existing models. (authors)

42 ENGINEERING↗

The Effect of Support Rod on Film Boiling Heat Transfer for Hot Metal Sphere in Subcooled Water

In fuel-coolant interaction (FCI), the heat transfer of corium has been conventionally evaluated by the correlations with a sphere developed in boiling region for subcooled film. However, these correlations do not give significant consideration on the support rod for the sphere from their developments, although Nishio et al. pointed out that the heat transfer and the vapor film collapsing mode would depend on H/D ratio. In this study, we performed experimental tests with the SS316 sphere (10 mm) and found the noticeable increase on the heat transfer in subcooled film boiling region with the deeper immersion depth and larger diameter of support rod. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Pool Boiling Reliability Tests and Degradation Mechanisms of Microporous Copper Inverse Opal (CuIOs) Structures: Preprint

The rising power density in electronic systems requires thermal management solutions that are both high-performing and reliable. Porous materials such as Copper Inverse Opals (CuIOs) have unique structural features, including high permeability and high thermal conductivity, to enhance pool boiling performance. However, there is little understanding of the degradation mechanism of such porous materials under pool boiling conditions. In this study, samples of 10-micrometer-thick CuIOs with 4.8-micrometer diameter, covering silicon substrate of area 11-mm by 11-mm, with various heated areas ranging from 2.5-mm by 2.5-mm to 10-mm by 10-mm, were tested in 100 degrees C deionized water at a constant heat flux of 110 watts per square cm for 3-7 days. The combined effect of erosion and corrosion caused structural degradation of the CuIOs. The directly heated area had the most severe degradation while the edge of the heater and the unheated area showed progressively less degradation, maintaining some CuIOs structure even after the 7-day reliability test. Among all the tested samples with various heater sizes, the 2.5-mm by 2.5-mm heater sample - in which the heater size was designed to be comparable to the water bubble characteristic length - had the largest critical heat flux (CHF) up to 300 watts per square cm with a superheat of approximately 13 degrees C. Additionally, CuIOs with a smaller heated area performed better in terms of reliability. This study offers preliminary insights into CuIOs degradation mechanisms, contributing to the development of more robust thermal management solutions. We expect that electroless plating of CuIOs with gold (Au), nickel (Ni), and atomic layer deposition of aluminum oxide in combination with appropriate application-specific coolants will further improve the reliability and lifetime of the CuIOs.

boiling-induced degradation↗

Heterogeneous Nucleating Agent for High‐Boiling‐Point Nonhalogenated Solvent‐Processed Organic Solar Cells and Modules

Abstract High‐boiling‐point nonhalogenated solvents are superior solvents to produce large‐area organic solar cells (OSCs) in industry because of their wide processing window and low toxicity; while, these solvents with slow evaporation kinetics will lead excessive aggregation of state‐of‐the‐art small molecule acceptors (e.g. L8‐BO), delivering serious efficiency losses. Here, a heterogeneous nucleating agent strategy is developed by grafting oligo (ethylene glycol) side‐chains on L8‐BO (BTO‐BO). The formation energy of the obtained BTO‐BO; while, changing from liquid in a solvent to a crystalline phase, is lower than that of L8‐BO irrespective of the solvent type. When BTO‐BO is added as the third component into the active layer (e.g. PM6:L8‐BO), it easily assembles to form numerous seed crystals, which serve as nucleation sites to trigger heterogeneous nucleation and increase nucleation density of L8‐BO through strong hydrogen bonding interactions even in high‐boiling‐point nonhalogenated solvents. Therefore, it can effectively suppress excessive aggregation during growth, achieving ideal phase‐separation active layer with small domain sizes and high crystallinity. The resultant toluene‐processed OSCs exhibit a record power conversion efficiency (PCE) of 19.42% (certificated 19.12%) with excellent operational stability. The strategy also has superior advantages in large‐scale devices, showing a 15.03‐cm 2 module with a record PCE of 16.35% (certificated 15.97%).

Chemistry↗

Flow boiling transient critical heat flux tests with stainless steel and FeCrAl: Transient correlation implementation, model calibration, and sensitivity analysis

In this study, steady-state and transient internal-flow critical heat flux (CHF) experiments were carried out under two flow conditions, at atmospheric pressure, on 316 stainless steel (316-SS) and iron-chromium-aluminum (FeCrAl) tubes. Slow power transients at a low mass flow (300 kg/m 2 - s) with very low subcooling (X e =-0.0054) generated premature CHFs, which were prevented by faster power transients and high mass flow (1000 kg/m 2 - s). The measured transient CHFs increased linearly with increasing power transients, compared with the steady-state CHF. Yet, the wall superheat at the CHFs decreased with faster power transients. Transient CHF correlations highlighting heterogeneous spontaneous nucleation were calibrated to the measured CHFs and compared with other existing correlations. Transient CHF multipliers were acquired from pool and flow boiling empirical CHF correlations that were generated. The multipliers were applied to the RELAP5-3D nuclear system code to analyze the discrepancies between the measured data and the predicted CHF and post-CHF behavior, which improved peak cladding temperature predictions by 24.6%. A variance-based global sensitivity study perturbing the experimental uncertainties and cladding material thermal properties showed the diminishing influence of flow boiling heat transfer with increasing power transients, highlighting the significance of the volumetric heat capacity for the cladding integrity during transients. Transient CHF correlations were applied to the most limiting design basis accident: a hot-zero-power reactivity-initiated accident on a generic pressurized water reactor RELAP5-3D model.

36 MATERIALS SCIENCE↗

A non-fueled nuclear-heated rod for in-pile transient boiling studies

Separate-effects boiling experiments have recently been conducted in the Transient Reactor Test Facility at Idaho National Laboratory to investigate transient heating and irradiation effects on cladding-to-coolant heat transfer. Specifically, transient critical heat flux (CHF) remains an important area of research, and better understanding of this phenomenon has potential for improving predictive models related to operational and safety limits. Consequently, this knowledge is expected to improve efficiency of light-water reactor operations. A novel borated nuclear-heated rodlet (BNHR) was designed to enable observation of transient cladding-to-coolant heat transfer phenomena. The final BNHR design takes a surrogate approach, wherein nuclear heating is induced by 10 B(n, α) reactions rather than derived from fissions in a fueled specimen. The structure of the BNHR consists of a hollowed out borated (B nat ~ 2.05 wt %) stainless steel tube with an hourglass-shaped outer surface, capped at both ends with non-borated stainless steel. This geometry allows for inner-rodlet instrumentation and generation of the highest nuclear heating rates near the center of the rodlet to ensure onset of boiling near instrumentation for real-time observation. A novel approach to measuring the nuclear energy deposition rate in the BNHR separate and apart from the influence of the coolant, termed the n-a thermometer, is also detailed in this paper. This device has demonstrated excellent repeatability, and measurements indicate predictive modeling results for energy deposition in the BNHR rod agree within a 10% margin of the experiment measurements. In conclusion, these results give confidence that the BNHR design has successfully met experiment objectives.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Simulation of Boiling Two-Phase Flow in a Helical Coil Steam Generator Using the Spectral Element Code Nek-2P

To enable the design of a light water small modular reactor, the boiling flow inside a helical coil steam generator has been simulated with the two-fluid model in Nek-2P. Nek-2P is the multiphase branch of the spectral element code Nek5000. Details of the implementation of the two-fluid model and the included closure models are discussed. The presented closure models include interactions for momentum, heat, and mass transfer between phases. Models for the drag, lift, and turbulent dispersion forces are included. The complete model is fully consistent in the limits of both phasic volume fractions approaching zero and is able to simulate flows of dispersed vapor, continuous liquid, dispersed liquid, continuous vapor, or any combination thereof. The closure models and their implementation in Nek-2P have been validated by comparing to experimental data for a boiling flow, demonstrating excellent agreement. Results from the simulation of the helical coil indicate strong phasic separation driven by the effects of buoyancy and inertia. Finally, significant differences were observed in the results compared to simulations performed using Star-CCM+, although these differences were somewhat expected.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Experimental and Numerical Investigation of Flow Boiling in Additive Manufactured Foam Structures With Vapor Pathways

Abstract The unique properties of metal foams make them potential candidates for a range of applications, including microsystem thermal management. Using additive manufacturing to create foam-type structures can improve upon prior thermal solutions by eliminating thermal interface materials and allowing for customization/local control of parameters. In the present investigation, flow boiling in additive-manufactured metal foams is investigated both experimentally and numerically. Two test samples, one with uniform structure and the other with pathways for vapor removal, are compared both experimentally and numerically. A conjugate computational fluid dynamics and heat transfer (CFD-HT) model utilizing a three-dimensional volume of fluid (VOF) model with accompanying evaporation/condensation model provided in-depth visualization of the boiling flow phenomena. The experiments generated the thermohydraulic performance over a range of heat fluxes, demonstrating that the sample incorporating dedicated vapor pathways performed better in both pressure and heat transfer performance metrics compared to the uniform foam. Additionally, negative system-level effects (i.e., hydraulic oscillations) were shown to be abated using the vapor removal structures. The numerical model yielded further insight into the factors contributing to the improved performance. Results indicated the pathways functioned as vapor removal channels, allowing the generated vapor to vent from the foam structure into the lanes. Further computational investigations demonstrated changes in flow regimes, where the addition of vapor channels caused the flow to change from churn to annular. Bubble behavior unique to the vapor pathway structure was studied, showing stagnant regions that eject vapor into the channel.

Engineering↗

Predicting departure from nucleate boiling with advanced data- and physics-driven approaches

The subcooled and low-quality saturated flow boiling critical heat flux (CHF) corresponding to the departure from nucleate boiling (DNB) is one of the major limiting factors in the design and operation of pressurized water reactors (PWRs). Due to lack of agreement on its physical mechanisms, development of an accurate DNB-type CHF model has been elusive. The various steady-state (SS) predictive tools that have been proposed can be grouped into two categories: (1) data-driven methods—namely best-fit empirical correlations and look-up tables that result in relatively good agreement with specific experimental datasets but often fail to extend beyond their ranges of validity, and (2) the physics-based mechanistic models that rely on reasonable yet limited understanding of the underlying physics and apply constitutive relations to close the conservation equations. On one hand, with recent advances in computational capabilities and optimization techniques, machine learning (ML)-based methods constitute an alternative and a more advanced, data-driven approach. With enough data, they can be particularly useful in engineering fields where the physical phenomena are complex and challenging to model. On the other hand, a state-of-the-art physics-driven approach would not only provide more accurate prediction of SS CHF, but it would also help better understand and model transient applications. The data-driven regression models use deep feed-forward neural networks (NNs) and random forests to cross-validate with 1,865 CHF test cases, covering a wide range of flow conditions and channel geometries. The best-estimate ML-based predictors compare favorably with the widely used look-up table for annulus and plate, and sensitivity analysis has confirmed their effectiveness. The key advantage of ML-based methods is their online extensibility of applicability domain. The proposed physics-driven approach combines key assumptions and parameters in the relatively well-accepted theories of liquid sublayer dryout and near-wall bubble crowding. A more realistic understanding of local mechanisms has been modeled. The new model has been optimized and validated against 1,439 tube data, and it shows considerably improved performance when compared to a recent mechanistic model, demonstrating unbiased close agreement with measurements over a wide range of operating conditions. Future work will extend the improved physics-driven model to non-tube geometry applications and will couple the model with ML via a hybrid approach. The mechanistic SS work will also serve to improve understanding and to model transient CHF scenarios.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Calculation of Spent Fuel Pool Time-to-Boil using Polaris/ORIGAMI [Slides]

The goal of this experiment was to calculate time-to-boil (TTB) for a Spent Fuel Pool (SFP). TTB is important for SFP management that represents the amount of time available to address loss of forced cooling. Researchers calculated and compared TTB for two cases using SCALE: SFP containing representative LEU fuel (≤ 5 wt %) and SFP containing representative LEU+ fuel (5 – 8 wt %). There were approximately 2300 fuel assemblies in the SFP for each case. Researchers concluded that the impact of LEU+ core on time-to-boil is very small. At such low cooling times, the impact of increased decay heat is not significant. Decay heat of SFP assemblies is small compared to discharge core decay heat.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reassessment of Boiling Water Reactor Rod Cusping Capability of VERA-MPACT

This technical report assesses the current modeling capabilities of the Virtual Environment for Reactor Applications (VERA) for minimizing control rod cusping in boiling water reactors. Assessment is performed on a 10 × 10 General Electric (GE)-14 assembly as well as a simplified version of the same assembly. Runs were performed using VERA for three available cusping treatments in the Michigan PArallel Characteristics Transport (MPACT) code: no treatment, subplane treatment, and fitted polynomial correction treatment. Subplane treatment is discussed, but specific results are not provided because of failures in the method of implementation for boiling water reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Reassessment of Boiling Water Reactor Rod Cusping Capability of VERA-MPACT

This technical report assesses the current modeling capabilities of the Virtual Environment for Reactor Applications (VERA) for minimizing control rod cusping in boiling water reactors. Assessment is performed on a 10 × 10 General Electric (GE)-14 assembly as well as a simplified version of the same assembly. Runs were performed using VERA for three available cusping treatments in the Michigan PArallel Characteristics Transport (MPACT) code: no treatment, subplane treatment, and fitted polynomial correction treatment. Subplane treatment is discussed, but specific results are not provided because of failures in the method of implementation for boiling water reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

STABILITY OF FILM BOILING TWO-PHASE FLOW IN CRYOGENIC SYSTEMS

The stability of film boiling two phase flow is investigated referring in particular to saturated cryogenic liquids. This type of fluid motion is unstable, such that a range of wave numbers will always be present in which disturbances are amplified. Further the mode of operation of the energy supply system may favour temperature fluctuations of large amplitude if the circuit does not provide feed-back compensation. The theoretically predicted stabilization due to capillarity is reduced considerably in liquefied gases with low surface tension, such as hydrogen. This effect causes the transition to turbulent flow to occur at low Reynolds numbers, and increases the heat transport in the turbulent regime. A comparison with experimental data, (horizontal cylinder), shows that the "critical" film Reynolds number ūδ/𝜈, at which instabilities become effective, is lowered from approximately 200, (O2), to about 30, (H2). Similar results have been found with other configurations. Therefore application of laminar film boiling solutions is restricted to small objects, entrance regions, or stagnation points. Turbulent correlations given so far are valid only for a certain group of substances with similar behavior.

LIQUID FLOW↗