On the eastward shift of winter surface chlorophyll‐a bloom peak in the B ay of B engal
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M. V. Martin↗
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Materials Data on B by Materials Project
B is T-50 Boron structured and crystallizes in the tetragonal P4_2/nnm space group. The structure is three-dimensional. there are five inequivalent B sites. In the first B site, B is bonded in a distorted trigonal pyramidal geometry to four equivalent B atoms. All B–B bond lengths are 1.70 Å. In the second B site, B is bonded in a 6-coordinate geometry to six B atoms. There are a spread of B–B bond distances ranging from 1.72–1.83 Å. In the third B site, B is bonded in a 6-coordinate geometry to six B atoms. There are a spread of B–B bond distances ranging from 1.71–1.82 Å. In the fourth B site, B is bonded in a 6-coordinate geometry to six B atoms. There is one shorter (1.74 Å) and two longer (1.80 Å) B–B bond length. In the fifth B site, B is bonded in a 6-coordinate geometry to six B atoms. There is one shorter (1.78 Å) and one longer (1.86 Å) B–B bond length.
36 MATERIALS SCIENCE↗
Materials Data on B by Materials Project
B is alpha boron-like structured and crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. there are five inequivalent B sites. In the first B site, B is bonded in a 7-coordinate geometry to seven B atoms. There are a spread of B–B bond distances ranging from 1.76–2.05 Å. In the second B site, B is bonded in a 6-coordinate geometry to six B atoms. There are a spread of B–B bond distances ranging from 1.67–1.81 Å. In the third B site, B is bonded in a 6-coordinate geometry to six B atoms. There is one shorter (1.66 Å) and two longer (1.78 Å) B–B bond length. In the fourth B site, B is bonded in a 7-coordinate geometry to seven B atoms. There is one shorter (1.74 Å) and one longer (1.90 Å) B–B bond length. In the fifth B site, B is bonded in a 6-coordinate geometry to six B atoms. The B–B bond length is 1.73 Å.
36 MATERIALS SCIENCE↗
Materials Data on B by Materials Project
B crystallizes in the tetragonal P4_2/nnm space group. The structure is three-dimensional. there are five inequivalent B sites. In the first B site, B is bonded in a 5-coordinate geometry to five B atoms. There is three shorter (1.75 Å) and two longer (1.77 Å) B–B bond length. In the second B site, B is bonded in a 6-coordinate geometry to six B atoms. There are a spread of B–B bond distances ranging from 1.72–1.90 Å. In the third B site, B is bonded in a 7-coordinate geometry to seven B atoms. There are a spread of B–B bond distances ranging from 1.69–2.13 Å. In the fourth B site, B is bonded in a 6-coordinate geometry to six B atoms. The B–B bond length is 1.68 Å. In the fifth B site, B is bonded in a 8-coordinate geometry to eight equivalent B atoms.
36 MATERIALS SCIENCE↗
First observation of Λ b 0 → Σ c ( * ) + + D ( * ) − K − decays
The four decays, Λ b 0 → Σ c ( * ) + + D ( * ) − K − , are observed for the first time using proton-proton collision data collected with the LHCb detector at a center-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 6 fb − 1 . By considering the Λ b 0 → Λ c + D ¯ 0 K − decay as reference channel, the following branching fraction ratios are measured to be B ( Λ b 0 → Σ c + + D − K − ) B ( Λ b 0 → Λ c + D ¯ 0 K − ) = 0.282 ± 0.016 ± 0.016 ± 0.005 , B ( Λ b 0 → Σ c * + + D − K − ) B ( Λ b 0 → Σ c + + D − K − ) = 0.460 ± 0.052 ± 0.028 , B ( Λ b 0 → Σ c + + D * − K − ) B ( Λ b 0 → Σ c + + D − K − ) = 2.261 ± 0.202 ± 0.129 ± 0.046 , B ( Λ b 0 → Σ c * + + D * − K − ) B ( Λ b 0 → Σ c + + D − K − ) = 0.896 ± 0.137 ± 0.066 ± 0.018 , where the first uncertainties are statistical, the second are systematic, and the third are due to uncertainties in the branching fractions of intermediate particle decays. These initial observations mark the beginning of pentaquark searches in these modes, with more datasets to become available following the LHCb upgrade. © 2024 CERN, for the LHCb Collaboration 2024 CERN
Aaij, R. (ORCID:0000000305331952)↗
Martian B Storm Genesis and Evolution: Initial Analysis of Thermal Datasets.
Introduction: Dust lifting on Mars likely occurs primarily as a result of the exchange of momentum between the atmosphere and the surface via saltation. During saltation, sand-sized particles are mobilized but do not enter into suspension. When these larger particles fall back to the surface, kinetic energy is transferred to smaller dust particles which are then lofted into suspension in the atmosphere. Depending on the altitude to which dust is lofted, it can have a significant effect on atmospheric temperatures. As a strong absorber and emitter in the infrared, dust can influence atmospheric heating and modify the global circulation and weather on Mars [1,2]. Although dust is present in Mars’ atmosphere throughout the year, the atmosphere is generally dustier during the second half of the year when Mars is near perihelion. Observations reveal that episodic global-scale dust storms and fairly regular regional-scale dust storms are superimposed on a well-defined and highly repeatable seasonal cycle of dust opacity and associated mid-level atmospheric temperature responses. Kass et al. (2016) used 50 Pa temperature observations from MRO/MCS to identify three highly repeatable time periods during which regional dust storms occur, and designated them the “A”, “B” and “C” storms. While “A” and “C” storms have been studied a fair amount to-date, “B” storms have not yet been investigated in detail. This study explores the generation and evolution of the annually recurring regional dust storm known as the “B” storm, which was identified and categorized by Kass et al. (2016) based on 25 km (50 Pa) temperature observations. The B storm is a southern-hemisphere (SH) phenomenon that originates at the cap edge just after perihelion and which reaches peak intensity during the SH summer solstice, Ls 270. It may originate from the cap edge storms that spawn near the edge of the seasonal CO2 cap during retreat, but the mechanisms for B storm genesis have yet to be determined definitively [1]. Methods: We will use observational data sets and a global climate model (GCM) to investigate “B” regional storms. The data analysis component will include the analysis of imagery from MGS/MOC and MRO/MARCI, and spectroscopic data sets of dust and temperatures from MGS/TES and MRO/MCS with the goal of fully characterizing the behavior of these storms. Both MGS and TES provide data well-suited for temperature analysis at 25 km. MCS measures atmospheric temperature, dust extinction, and water ice extinction at 5 km intervals from the surface to about 80 km. TES measured atmospheric temperatures, column dust and water ice opacities, and column water vapor abundances. Measurements made by TES extended from the surface to about 40 km [1]. At the 50 Pa (25 km) level, local dust events usually confined to shallower depths are effectively filtered out of the analysis leaving the regional dust events identifiable by their temperature signatures [1]. Our preliminary analysis makes use of the fact that the brightness temperature at 15 microns (T15 temperature) is a close approximation to observed temperature at 25 km. We first reproduce the zonal mean 50 Pa level temperature plots for MY 29-32 to establish a baseline for our procedures moving forward [1]. Expanding on Kass et al. (2016), we include recent MCS data from MY 33 and 34 as well. Preliminary Analysis: The daytime (3PM) T15 temperatures in Figure 1 indicate: in MY 29, a strong A storm at Ls 240, a B storm at high southern latitudes just after Ls 270, and a C storm at Ls 320; in MY 30, a B storm at Ls 270; in MY 31 & MY 32, a B storm just before Ls 270; in MY 33, a B storm at Ls 270; and in MY 34, a strong A storm in the northern hemisphere at Ls 210, and a B storm around Ls 270 although there is a data gap. For the B storms, each is indicative of lofted dust and resultant warming. The daytime temperature structure illustrates that the B storm occurs annually around Ls 270 and is confined to high southern latitudes. It reaches its peak intensity around SH summer solstice, Ls 270, consistently for all six MY assessed. Since direct solar heating is absent overnight, the nighttime T15 temperatures (Figure 2) are often useful for differentiating the heat signature of direct solar heating from the dynamical response to that heating. However, in the southern polar latitudes at perihelion the sun does not set and direct solar heating remains present throughout the night. Importantly for our study, dust lofted in the B storm experiences this direct heating day and night for the entirety of its lifetime. The B storm expands as far north as -60 latitude and decays in latitudinal extent more gradually than it grows. This feature is less obvious in the nighttime (3AM) T15 temperatures (Figure 2). The temperature signal is stronger at night for MY 30-33. The warm pool is larger in area relative to the background at night in these four cases. This more uniform warming masks the “tail” feature somewhat, such that it is barely noticeable during these years. Unfortunately, gaps in MCS data in MY 29 and 34 prevent confirmation of the tail feature during those years, however, the B storm temperature signature follows a very different pattern than that described for MY 30-33. MY 29 and 34 appear to show smaller centers of warming at night and larger centers of warming during the day. This is in opposition to that previously described for MY 30-33. Conclusions and Future Work: We will continue investigating the heat signatures of B storms by looking at the total column heating as recorded by TES. We will also look at lower altitudes for patterns that may describe the relationship between B storms and the cap edge storms that develop while the seasonal cap is retreating. In the future, we will use GCM simulations to determine the atmospheric and thermo-dynamic conditions associated with these storms.
Courtney Marylou Batterson↗
Search for the dark photon in B 0 → A'A', A' → e + e – , μ + μ – , and π + π – decays at Belle
We present a search for the dark photon A' in the B 0 → A'A' decays, where A' subsequently decays to e + e – , μ + μ – , and π + π – . The search is performed by analyzing 772 × 10 6 $B$$\overline{B}$ events collected by the Belle detector at the KEKB e + e – energy-asymmetric collider at the Υ(4S) resonance. No signal is found in the dark photon mass range 0.01 GeV/c 2 ≤ m A' ≤ 2.62 GeV/c 2 , and we set upper limits of the branching fraction of B0 → A'A' at the 90% confidence level. The products of branching fractions, B(B 0 →A'A')×B(A'→e + e – ) 2 and B(B 0 →A'A')×B(A'→μ + μ – ) 2 , have limits of the order of 10 –8 depending on the A' mass. Furthermore, considering A' decay rate to each pair of charged particles, the upper limits of B(B 0 →A'A') are of the order of 10 –8 –10 –5 . From the upper limits of B(B 0 →A'A'), we obtain the Higgs portal coupling for each assumed dark photon and dark Higgs mass. The Higgs portal couplings are of the order of 10 –2 –10 –1 at m h' ≃m B 0 ± 40 MeV/c 2 and 10 –1 –1 at m h' ≃m B 0 ± 3 GeV/c 2 .
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Dipolar Heteronuclear Correlation Solid-State NMR Experiments between Half-Integer Quadrupolar Nuclei: The Case of 11 B– 17 O
With 73% of all NMR-active nuclei being quadrupolar, there is great interest in the development of NMR experiments that can probe the proximity of quadrupolar spins. Here, pulse sequences for magic-angle spinning (MAS) 11 B– 17 O resonance-echo saturation-pulse double-resonance (RESPDOR) and dipolar heteronuclear multiple quantum correlation (D-HMQC) solid-state NMR experiments were investigated. In these pulse sequences, rotational-echo double-resonance (REDOR) recoupling was used with central transition (CT)-selective π-pulses applied to either the 11 B or 17 O spins to recouple 11 B– 17 O dipolar interactions. 11 B{ 17 O} RESPDOR experiments on 17 O-enriched boric acid and benzene diboronic acid showed that application of dipolar recoupling on the 11 B channel yielded more signal dephasing than when recoupling is applied on the 17 O channel; however, short effective 11 B transverse relaxation time constants (T 2 ') hinder the acquisition of dephasing curves out to long recoupling durations. Application of REDOR recoupling to 17 O spins was found to produce significant dephasing without compromising the 11 B T 2 '. Comparison of experimental 11 B{ 17 O} RESPDOR curves to those of numerical simulations enabled the 17 O isotopic enrichment to be estimated. 2D 11 B{ 17 O} D-HMQC spectra were recorded with either 11 B or 17 O REDOR recoupling under a variety of radio frequency field conditions. Lastly, 2D 11 B{ 17 O} and 23 Na{ 17 O} D-HMQC spectra of an 17 O-enriched sodium borate glass were acquired to demonstrate the practical application of these heteronuclear correlation experiments to probe structural connectivity between two quadrupolar spins. Importantly, the high-field 2D 11 B– 17 O D-HMQC NMR spectrum revealed two unique 17 O sites correlating to 4-coordinate BO 4 ( [4] B), which were attributed to the [3] B–O– [4] B and [4] B–O– [4] B bridging O atoms. Furthermore, the heteronuclear correlation experiments outlined here should be applicable to a variety of quadrupolar spin pairs.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Observation of the ${B}_s^0$ → D* + D* - decay
The first observation of the $B^{0}_{s}$ → D* + D* - decay and the measurement of its branching ratio relative to the B 0 → D* + D* - decay are presented. The data sample used corresponds to an integrated luminosit y of 9 fb -1 of proton-proton collisions recorded by the LHCb experiment at centre-of-mass energies of 7, 8 and 13 TeV between 2011 and 2018. The decay is observed with more than 10 standard deviations and the time-integrated ratio of branching fractions is determined to be $\frac{\mathcal{B}(B^{0}_{s} → D*^+D*^-)}{\mathcal{B}(B^0 → D*^+D*^-)}$ = 0.269 ± 0.032 ± 0.011 ± 0.008, where the first uncertainty is statistical, the second systematic and the third due to the uncertainty of the fragmentation fraction ratio f s /f d . The $B^{0}_{s}$ → D* + D* - branching fraction is calculated to be $\mathcal{B}$ ($B^{0}_{s} → D*^+D*^-)$ = (2.15 ± 0.26 ± 0.09 ± 0.06 ± 0.16) X 10 -4 , where the fourth uncertainty is due to the B 0 → D* + D* - branching fraction. These results are calculated using the average $B^{0}_{s}$ meson lifetime in simulation. Correction factors are reported for scenarios where either a purely heavy or a purely light $B^{0}_{s}$ eigenstate is considered.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Study of the lineshape of X ( 3872 ) using B decays to D 0 D ¯ * 0 K
We present a study of the X(3872) lineshape in the decay B →X(3872)K →D 0 $\overline{D}$ *0 K using a data sample of 772 ×10 6 B$\overline{B}$ pairs collected at the Y(4S) resonance with the Belle detector at the KEKB asymmetric-energy e + e - collider. The peak near the threshold in the D 0 $\overline{D}$ *0 invariant mass spectrum is fitted using a relativistic Breit-Wigner lineshape. We determine the mass and width parameters to be m BW =3873.71$^{+0.56}_{-0.50}$(stat) ±0.13(syst) MeV/c 2 and Γ BW =5.2$^{+2.2}_{-1.5}$(stat) ±0.4(syst) MeV, respectively. The branching fraction is found to be $\mathscr{B}$(B + → X(3872)K + ) × $\mathscr{B}$(X(3872) → D 0 $\overline{D}$ *0 ) = (0.97$^{+0.21}_{-0.18}$(stat) ± 0.10(syst)) ×10 -4 . The signal from B 0 decays is observed for the first time with 5.2σ significance, and the ratio of branching fractions between charged and neutral B decays is measured to be $\mathscr{B}$(B 0 → X(3872)K 0 )/$\mathscr{B}$(B + →X(3872)K + ) =1.34$^{+0.47}_{-0.40}$(stat) $^{+0.10}_{-0.12}$(syst). The peak is also studied using a Flatté lineshape. We determine the lower limit on the D 0 $\overline{D}$ * coupling constant g to be 0.075 at 95% credibility in the parameter region where the ratio of g to the mass difference from the D 0 $\overline{D}$ *0 threshold is equal to -15.11 GeV -1 , as measured by LHCb.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Measurement of branching fractions, C P asymmetry, and isospin asymmetry for B → ρ γ decays using Belle and Belle II data
We present measurements of B + → ρ + γ and B 0 → ρ 0 γ decays using a combined data sample of 772 × 10 6 B B ¯ pairs collected by the Belle experiment and 387 × 10 6 B B ¯ pairs collected by the Belle II experiment in e + e − collisions at the ϒ ( 4 S ) resonance. After an optimized selection, a simultaneous fit to the Belle and Belle II datasets yields 114 ± 12 B + → ρ + γ and 99 ± 12 B 0 → ρ 0 γ decays. The measured branching fractions are ( 13.1 − 1.9 − 1.2 + 2.0 + 1.3 ) × 10 − 7 and ( 7.6 ± 1.3 − 0.8 + 1.0 ) × 10 − 7 for B + → ρ + γ and B 0 → ρ 0 γ decays, respectively, where the first uncertainty is statistical and the second is systematic. We also measure the isospin asymmetry A I ( B → ρ γ ) = ( 10.9 − 11.7 − 7.3 + 11.2 + 7.8 ) % and the direct C P asymmetry A C P ( B + → ρ + γ ) = ( − 8.2 ± 15.2 − 1.3 + 2.0 ) % . Published by the American Physical Society 2025
Adachi, I. (ORCID:0000000322870173)↗
Analysis of Neutral B -Meson Decays into Two Muons
Branching fraction and effective lifetime measurements of the rare decay B s 0 → μ + μ - and searches for the decays B 0 → μ + μ - and B s 0 → μ + μ - γ are reported using proton-proton collision data collected with the LHCb detector at center-of-mass energies of 7, 8, and 13 TeV, corresponding to a luminosity of 9 fb - 1 . The branching fraction B ( B s 0 → μ + μ - ) = ( 3.0 9 - 0.43 - 0.11 + 0.46 + 0.15 ) × 10 - 9 and the effective lifetime τ ( B s 0 → μ + μ - ) = 2.07 ± 0.29 ± 0.03 ps are measured, where the first uncertainty is statistical and the second systematic. No significant signal for B 0 → μ + μ - and B s 0 → μ + μ - γ decays is found and upper limits B ( B 0 → μ + μ - ) < 2.6 × 10 - 10 and B ( B s 0 → μ + μ - γ ) < 2.0 × 10 - 9 at the 95% C.L. are determined, where the latter is limited to the range m μ μ > 4.9 GeV / c 2 . The results are in agreement with the standard model expectations.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Search for the lepton-flavour violating decays B0 → K *0 μ ± e ∓ and ${B}_s^0$ → Φμ ± e ∓
A search for the lepton-flavour violating decays B 0 → K *0 μ ± e ∓ and \( {B}_s^0 \) → Φμ ± e ∓ is presented, using proton-proton collision data collected by the LHCb detector at the LHC, corresponding to an integrated luminosity of 9 fb - 1 . No significant signals are observed and upper limits of $$ {\displaystyle \begin{array}{c}\mathcal{B}\left({B}^0\to {K}^{\ast 0}{\mu}^{+}{e}^{-}\right)<5.7\times {10}^{-9}\left(6.9\times {10}^{-9}\right),\\ {}\mathcal{B}\left({B}^0\to {K}^{\ast 0}{\mu}^{-}{e}^{+}\right)<6.8\times {10}^{-9}\left(7.9\times {10}^{-9}\right),\\ {}\mathcal{B}\left({B}^0\to {K}^{\ast 0}{\mu}^{\pm }{e}^{\mp}\right)<10.1\times {10}^{-9}\left(11.7\times {10}^{-9}\right),\\ {}\mathcal{B}\left({B}_s^0\to \phi {\mu}^{\pm }{e}^{\mp}\right)<16.0\times {10}^{-9}\left(19.8\times {10}^{-9}\right)\end{array}} $$ are set at 90% (95%) confidence level. These results constitute the world’s most stringent limits to date, with the limit on the decay \( {B}_s^0 \) → Φμ ± e ∓ the first being set. In addition, limits are reported for scalar and left-handed lepton-flavour violating New Physics scenarios.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Venturing into Unexplored Phase Space: Synthesis, Structure, and Properties of MgCo 3 B 2 Featuring a Rumpled Kagomé Network
MgCo 3 B 2 , a novel ternary boride in a previously unexplored phase space, was synthesized using the hydride route. In situ powder X-ray diffraction and DFT calculations aided in the discovery of this compound, whose structure was then determined by single-crystal X-ray diffraction. Like the closely related CeCo 3 B 2 , MgCo 3 B 2 crystallizes in centrosymmetric space group P6/mmm (a = 4.883(2) Å, c = 2.926(2) Å at 210 K, Z = 1). Unlike CeCo 3 B 2 , however, it adopts a disordered structure that features a rumpled Kagomé network of Co atoms, and Mg atoms fill the channels of a Co–B framework. Although the structural disorder leads to motifs that are similar to those observed in MgNi 3 B 2 and other related ternary borides, no evidence of an ordered superstructure was found by single-crystal X-ray diffraction or high-resolution powder X-ray diffraction. In the case of CeCo 3 B 2 , boron atoms occupy the center of regular Co 6 trigonal prisms; in MgCo 3 B 2 , boron atoms are shifted from the center of the prism to form B–B dimers with roughly the same length as those found in MgNi 3 B 2 . Magnetic susceptibility data exhibit an unusual temperature dependence that cannot be convincingly modeled by the modified Curie–Weiss equation, consistent with DFT calculations predicting a nonmagnetic ground state. Intrinsic susceptibility at 300 K is 1.42 × 10 –3 emu/mol Oe, which is comparable to that of paramagnetic YCo 3 B 2 and CeCo 3 B 2 with a similar structure and composition. Here, this study showcases the efficacy of combining several methodologies to discover new solids in unexplored phase spaces. This approach includes in situ PXRD data to monitor reactions of precursors upon heating, a diffusion-enhanced synthesis method, and DFT assessment of compound stability.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Role of E × B Drift in Divertor Detachment Control via Boron Powder Injection on EAST
Here, the effects of B powder injection on plasma detachment about EAST discharge were studied by using SOLPS-ITER code package with the effects of E × B drifts considered. The simulation results show that plasma detachment occurs at the inner target in favourable toroidal magnetic field (B t ) direction at a relatively low B powder flow rate, one order of magnitude lower than that at the outer target. In a similar scenario with unfavourable B t , it is found that the detachment thresholds of B flow rate for both the inner and outer targets are close and of the same order as that for the outer target with favourable Bt. In favourable B t direction at B powder flow rate of 1.2 × 10 21 atoms/s, a localized, broadened high-density region is formed near the inner target benefitted by the injection location and the E × B drift, and a radiation-intensified zone, mostly contributed by B 1+ and B 2+ , occurs there. The E × B drift facilitates plasma detachment at the inner target and simultaneously amplifies the in–out divertor asymmetry. In addition, the simulation results with three different injection locations show that the injection from outer strike point leads to the lowest Z eff inside the separatrix and has an intermediate flow rate for detachment at the outer target, comparing with the X-point and upstream locations.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Search for direct CP violation in charged charmless B→PV decays
Measurements of C P asymmetry in charmless B → P V decays are presented, where P and V denote a pseudoscalar and a vector meson, respectively. Five different B → P V decays from four final states, B ± → π ± π + π - , B ± → K ± π + π - , B ± → K ± K + K - and B ± → π ± K + K - are analyzed. The measurements are based on a method that does not require full amplitude analyses, and are performed using proton-proton collision data at a center-of-mass energy of 13 TeV collected by LHCb between 2015 and 2018, corresponding to an integrated luminosity of 5.9 fb - 1 . In the π + π - P -wave, in the region dominated by the B ± → ρ ( 770 ) 0 K ± decay, a C P asymmetry of A C P = + 0.150 ± 0.019 ± 0.011 is measured, where the first uncertainty is statistical and the second is systematic. This is the first observation of C P violation in this process. For the other four decay channels, in regions dominated by the B ± → ρ ( 770 ) 0 π ± , B ± → K ( ¯ ) * ( 892 ) 0 π ± , B ± → K ( ¯ ) * ( 892 ) 0 K ± and B ± → Φ ( 1020 ) K ± decays, C P asymmetries in the P -wave compatible with zero are measured.
79 ASTRONOMY AND ASTROPHYSICS↗
Materials Data on B by Materials Project
B is alpha boron structured and crystallizes in the trigonal R-3m space group. The structure is three-dimensional. there are two inequivalent B sites. In the first B site, B is bonded in a 6-coordinate geometry to six B atoms. There are a spread of B–B bond distances ranging from 1.67–1.80 Å. In the second B site, B is bonded in a 7-coordinate geometry to seven B atoms. There is two shorter (1.78 Å) and two longer (2.01 Å) B–B bond length.
36 MATERIALS SCIENCE↗
Materials Data on B by Materials Project
B is BCT5-like structured and crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. there are two inequivalent B sites. In the first B site, B is bonded in a 5-coordinate geometry to five B atoms. There are a spread of B–B bond distances ranging from 1.69–1.78 Å. In the second B site, B is bonded in a 5-coordinate geometry to five B atoms. Both B–B bond lengths are 1.77 Å.
36 MATERIALS SCIENCE↗