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At least 289 records · Page 16

Nitric oxide delta band emission in the earth's atmosphere - Comparison of a measurement and a theory

Attention is given to the altitude dependent emission rate in the delta-bands of nitric oxide as measured in the earth's atmosphere at night by a scanning ultraviolet spectrometer. It is noted that the reaction responsible is the two-body association of nitrogen and oxygen atoms. The measurements show a vertical intensity beneath the layer for the delta-band system of 19 R. The horizontal emission rate is found to increase from 70 R at 117 km to 140 R at 150 km. The data are analyzed with a one-dimensional, time-dependent, vertical-transport model of odd nitrogen photochemistry. The calculated and measured intensities agree so long as the quenching of N(2D) by atomic oxygen is near 5 x 10 to the -13 cu cm/sec.

Rusch, D. W.↗

Emission of nitric oxide (NO) from tropical forest soils and exchange of NO between the forest canopy and atmospheric boundary layers

Emissions of NO from soils in the Amazon rain forest were measured at 66 locations using an enclosure technique, and continuous vertical profiles of NO and O3 were measured between the ground and 41-m altitude. Fluxes of NO averaged 8.9 (+ or - 1.5) x 10 to the 9th molecules/sq cm per sec from the dominant (yellow clay) soils of the region, with larger fluxes observed from adjacent white sand soils. Fluxes from clay soils were lower by more than a factor of 5 than fluxes observed during the dry season at a nearby site. Low soil emission rates were reflected in lower concentrations of NO at the top of the forest canopy in the wet season, only 30-50 parts per trillion by volume during the daytime. The measured fluxes are consistent with chemical mass balances for NO within the forest canopy, calculated from the NO and O3 profiles taken at night, and with observations of NO between 150 and 5000 m altitude. Measurements of NO emission rates from soil plots fertilized using NaNO3, NH4Cl, or sucrose indicated that a reductive pathway (denitrification) may have been primarily responsible for production of the NO released by both clay and sand soils.

Bakwin, Peter S.↗

X-ray Emission from Magnetized Neutron Star Atmospheres at Low Mass Accretion Rates

Recent observations of X-ray pulsars at low luminosities allow, for the first time, to compare theoretical models for the emission from highly magnetized neutron star atmospheres at low mass accretion rates ( M ≲ 10(exp 15) g s(exp -1)) with the broadband X-ray data. The purpose of this paper is to investigate the spectral formation in the neutron star atmosphere at low M and to conduct a parameter study of physical properties of the emitting region. We obtain the structure of the static atmosphere, assuming that Coulomb collisions are the dominant deceleration process. The upper part of the atmosphere is strongly heated by the braking plasma, reaching temperatures of 30–40 keV, while its denser isothermal interior is much cooler (~2 keV). We numerically solve the polarized radiative transfer in the atmosphere with magnetic Compton scattering, free-free processes, and non-thermal cyclotron emission due to possible collisional excitations of electrons. The strongly polarized emitted spectrum has a double-hump shape that is observed in low-luminosity X-ray pulsars. A low-energy “thermal” component is dominated by extraordinary photons that can leave the atmosphere from deeper layers due to their long mean free path at soft energies. We find that a high-energy component is formed due to resonant Comptonization in the heated non-isothermal part of the atmosphere even in the absence of collisional excitations. The latter, however, affect the ratio of the two components. A strong cyclotron line originates from the optically thin, uppermost zone. A fit of the model to NuSTAR and Swift/XRT observations of GX304􀀀1 provides an accurate description of the data with reasonable parameters. The model can thus reproduce the characteristic double-hump spectrum observed in low-luminosity X-ray pulsars and provides insights into spectral formation.

X-Ray binaries↗

Mineralogy and Spectroscopy of Mount Etna Lava Flows as an Analogue to Venus

Reports of geologically recent volcanism at Venus [1–3] raise the question of whether Venus is actively resurfacing. Observing the venusian surface is difficult due to the planet’s thick, relatively opaque atmosphere, but emission from the surface is detectable via a few atmospheric windows in the near-infrared (NIR) around 1 μm [4]. Spectroscopy of rocks at these wavelengths varies due to its primary composition and the presence of secondary weathering products [2, 5, 6]. If degree of alteration can be tied to the spectroscopic response, then the weathering of the venusian surface can reveal its age and extent of recent volcanism [2, 7]. Mount Etna on Earth is a potential analogue to Venus that can aid our understanding. The composite volcano is currently active and exhibits a progression of dated lava flows with a range of textures (‘a‘¯a versus p¯ahoehoe flows) and degrees of alteration [8]. While not a perfect analogue due to differing weathering environments, Mount Etna represents a natural age progression of altered basaltic rock [8] that can provide a useful comparison to volcanic structures on Venus. Here we will determine if spectroscopy can determine the alteration state of these flows as a proxy for their age. Future missions to Venus such as VERITAS, En- Vision, and DAVINCI will observe the surface in NIR emissivity. Kirchhoff’s Law holds that e = 1−r, where e is the emissivity and r is the reflectance. NIR emissivity can be reliably calculated from reflectance measurements of rocks [9], so laboratory reflectance spectroscopy is useful to rapidly test potential Venus analogue materials.

Gabriel L. Eggers↗

Pioneer 10 ultraviolet photometer observations at Jupiter encounter

A two-channel extreme ultraviolet photometer on Pioneer 10 was used to investigate hydrogen and helium emissions from the atmosphere of Jupiter and emissions associated with the Galilean satellites. The hydrogen Lyman alpha signal observed from Jupiter corresponded to 400 R in brightness. By using the results of Wallace and Hunten (1973), the eddy diffusion coefficient is found to be K = 3 x 10 to the (8 plus or minus 1) power. The He I 584-A emission rate was found to be 5.1 R. The radiative transfer problem for the resonantly scattered He I emissions was investigated in the coherent approximation. With these results, the observed brightness, and the derived eddy diffusion coefficient the He/H2 ratio in the mixing region of the atmosphere was found to be equal to 0.18 minus 0.12 or plus 0.46. Emissions attributed to H I Lyman alpha were found at the orbital radius of Io and appear to be due to resonance scattering by a toroidal cloud of H in orbit around Jupiter.

Carlson, R. W.↗

Powering Negative-Emissions Technologies with Marine Renewable Energy

The majority of modeled emissions scenarios that meet the climate change goals outlined in the 2015 Paris Agreement require not only significant reductions in anthropogenic carbon dioxide emissions, but also removal of carbon dioxide from the atmosphere ("negative emissions"). To date, research and development efforts have largely focused on land-based negative emissions technologies, such as bioenergy with carbon capture and storage. However, ocean-based technologies also have significant potential, and avoid competition for land use and fresh water with agriculture and human development. Marine carbon dioxide removal approaches include biological solutions that seek to increase carbon fixation through photosynthesis and chemical solutions that aim to increase the absorption of carbon dioxide in seawater. Most of these approaches have significant power requirements, especially when implemented at the scale necessary to meet negative-emissions goals. Marine renewable energy is uniquely poised to power marine carbon dioxide removal given its ability to provide carbon-free power at sea. In this work, the power requirements of marine carbon dioxide removal systems and the potential of marine renewable energy to power them are investigated, culminating in recommendations for future research and development to enable such developments.

marine renewable energy, carbon dioxide, climate c↗

Millisecond time scale atmospheric light pulses associated with solar and magnetospheric activity.

By using a wide-angle photomultiplier system a class of millisecond time scale diffuse atmospheric light emission of terrestrial origin has been discovered. These fast atmospheric pulsation events also show damped oscillations around 10-kHz frequency, which distinguishes them from ordinary lightning-type events. Evidence is presented for the enhancement in the rate of these events induced by solar flare activity.

Ogelman, H.↗

Heterodyne detection of CO2 emission lines and wind velocities in the atmosphere of Venus

Strong 10 micrometer line emission from (C-12)(O-16)2 in the upper atmosphere of Venus was detected by heterodyne techniques. Observations of the absolute Doppler shift of the emission features indicate mean zonal wind velocities less than 10 m/sec in the upper atmosphere near the equator. No evidence was found of the 100 m/sec wind velocity implied by the apparent 4-day rotation period of ultraviolet cloud features.

Betz, A. L.↗

Heterodyne detection of CO2 emission lines and wind velocities in the atmosphere of Venus

Strong 10 micrometer line emission from (c-12)(o-16)2 in the upper atmosphere of Venus was detected by heterodyne techniques. Observations of the absolute Doppler shift of the emission features indicate mean zonal wind velocities less than 10 m/sec in the upper atmosphere near the equator. No evidence was found of the 100 m/sec wind velocity implied by the apparent 4-day rotation period of ultraviolet cloud features.

Betz, A. L.↗

Modification in Applying Appendix D of 40 CFR Part 61 to Heated Solid Radionuclide Materials With High Melting and Boiling Points

Appendix D of Title 40 Part 61 of the US Code of Federal Regulations (CFR) provides a procedure that US Department of Energy (US DOE) facility owners and operators can use to estimate radionuclide emissions to the atmosphere for dose calculations instead of measuring emissions for minor sources under the 40 CFR Part 61, Subpart H, National Emission Standards for Emissions of Radionuclides Other Than Radon From Department of Energy Facilities, regulation. The procedure assumes that any radioactive material heated above 100 °C is completely vaporized and emitted to the atmosphere. In 1991, the US DOE Oak Ridge Reservation (ORR) requested approval to use different release fractions (RFs) for uranium because of its high melting and boiling points. In response to the request, the US Environmental Protection Agency (US EPA) Region IV approved the use of modified RFs for elemental uranium provided no reaction had taken place to alter its chemical form. In 2015, the ORR requested approval to use different RFs for tungsten, again because of its high melting and boiling points. EPA Region IV approved the use of modified RFs for heated radioactive tungsten metal. In accordance with the two precedents set for heating uranium and radioactive tungsten metals, in 2016, the ORR requested approval to use modified RFs in a similar fashion for other radioactive solid metals and compounds with melting and boiling points above 500 °C that might be heated above 100 °C in future research projects and experiments. EPA Region IV again granted approval to use modified RFs for the list of compounds. This note discusses the proposed modified RFs and their development.

36 MATERIALS SCIENCE↗

Heterodyne detection of CO2 emission lines and wind velocities in the atmosphere of Venus

Strong 10-micron line emission from (C-12)(O-16)2 in the upper atmosphere of Venus has been detected by heterodyne techniques. Observations of the absolute Doppler shift of the emission features indicated mean zonal wind velocities less than 10 m/s in the upper atmosphere near the equator. No evidence was found for the 100-m/s wind velocity implied by the apparent four-day rotation period of ultraviolet cloud features.

Betz, A. L.↗

Correlation Between Soil Moisture and Dust Emissions: An Investigation for Global Climate Modeling

This work is using the newly available NASA SMAP soil moisture measurement data to evaluate its impact on the atmospheric dust emissions. Dust is an important component of atmospheric aerosols, which affects both climate and air quality. In this work, we focused on semi-desert regions, where dust emissions show seasonal variations due to soil moisture changes, i.e. in Sahel of Africa. We first identified three Aerosol Robotic Network (AERONET) sites in the Sahel (IER_Cinzana, Banizoumbou, and Zinder_Airport). We then utilized measurements of aerosol optical depth (AOD), fine mode fraction, size distribution, and single-scattering albedo and its wave-length dependence to select dust plumes from the available measurements We matched the latitude and longitude of the AERONET station to the corresponding SMAP data cell in the years 2015 and 2016, and calculated their correlation coefficient. Additionally, we looked at the correlation coefficient with a three-day and a five-day shift to check the impact of soil moisture on dust plumes with some time delay. Due to the arid nature of Banizoumbou and Zinder_Airport, no correlation was found to exist between local soil moisture and dust aerosol load. While IER_Cinzana had soil moisture levels above the satellite threshold of 0.02cm3/cm3, R-value approaching zero indicated no presence of a correlation. On the other hand, Ilorin demonstrated a significant negative correlation between aerosol optical depth and soil moisture. When isolating the analysis to Ilorin's dry season, a negative correlation of -0.593 was the largest dust-isolated R-value recorded, suggesting that soil moisture is driven the dust emission in this semi-desert region during transitional season.

climate↗

Atmospheric structure of the outer planets from thermal emission data

Methods for determining atmospheric structure exploit the opacities provided by the collision induced H2 dipole and the nu4 fundamental of CH4. In addition to earth-based observations, useful measurements of thermal emission from Jupiter and Saturn have been or soon will be made by several spacecraft, with results cross-checked with independent radio occultaion results. For Uranus and Neptune, only a limited set of whole-disk earth-based data exists. All the outer planets show evidence for stratospheric temperature inversions; temperature minima range from about 105 K for Jupiter and 87 K for Saturn, to roughly 55 K for Uranus and Neptune. Remaining problems may be resolved by better quantitative understanding of gas and aerosol absorption and scattering properties, chemical composition, and non-LTE source functions. Ultimately, temperature structure results must be supplemented by quantitative energy equilibrium models which will allow some meaning to be given to the relationships between such characteristics as temperature, clouds, incident solar and planetary radiation, and chemical composition.

Orton, G. S.↗

Emission, absorption and group delay of microwaves in the atmosphere in relation to water vapour content over the Indian subcontinent

The advent of satellite communication for global coverage has apparently indicated a renewed interest in the studies of radio wave propagation through the atmosphere, in the VHF, UHF and microwave bands. The extensive measurements of atmosphere constituents, dynamics and radio meterological parameters during the Middle Atmosphere Program (MAP) have opened up further the possibilities of studying tropospheric radio wave propagation parameters, relevant to Earth/space link design. The three basic parameters of significance to radio propagation are thermal emission, absorption and group delay of the atmosphere, all of which are controlled largely by the water vapor content in the atmosphere, particular at microwave bands. As good emitters are also good absorbers, the atmospheric emission as well as the absorption attains a maximum at the frequency of 22.235 GHz, which is the peak of the water vapor line. The group delay is practically independent of frequency in the VHF, UHF and microwave bands. However, all three parameters exhibit a similar seasonal dependence originating presumably from the seasonal dependence of the water vapor content. Some of the interesting results obtained from analyses of radiosonde data over the Indian subcontinent collected by the India Meteorological Department is presented.

Sen, A. K.↗