Development of space-stable thermal-control coatings Triannual report, 1 Aug. - 31 Oct. 1967
Preparation of zinc oxide pigmented methyl silicone coating for thermal protection of space flight structures
Noble, G.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Development of improved zinc electrodes for secondary batteries Final report, Jul. 1968 - Jul. 1969
Performance of sintered zinc oxide electrodes for secondary batteries
Himy, A.↗
Thin film devices used as oxygen partial pressure sensors
Electrical conductivity of zinc oxide films to be used in an oxygen partial pressure sensor is measured as a function of temperature, oxygen partial pressure, and other atmospheric constituents. Time response following partial pressure changes is studied as a function of temperature and environmental changes.
Canady, K. S.↗
The development of a miniaturized heater for thin film oxygen partial pressure sensors
Miniature heater for zinc oxide thin film oxygen partial pressure sensor
Pearson, C. R.↗
Improved thermal paint formulation
Potassium silicate-treated zinc oxide paint stabilizes pigment against ultraviolet-induced, bleachable degradation in infrared region, and permits use of ZnO as pigment in ultraviolet-stable coatings based upon polymethyl siloxane elastomers and resins. Material has low absorptance/emittance ratio.
Gates, D. W.↗
Feasibility of miniaturizing a heater for a thin-film oxygen partial-pressure sensor
Feasibility of miniaturized heater for zinc oxide thin film oxygen partial pressure sensor
Pearson, C. R.↗
Investigation of environmental effects on coatings for thermal control
Accomplishments made during study of coatings are reported. Development of structure/property theory for selecting most appropriate pigments for space vehicle paints is discussed along with improvements made in zinc-oxide pigmented potassium silicate paint.
Ashford, N. A.↗
Development of a space stable thermal control coatings for use in large space vehicles
The preparation and evaluation of zinc orthotitanate and of several new pigments and the environmental testing and evaluation of these pigments and of coatings made from them constitute the bulk of the work accomplished. New pigments were prepared and EPR spectra of pigments and their precursor compounds studied. Results of extensive testing of commercially-available, strippable, protective coatings are reported; Owens-Illinois 650 glass resin has been stabilized against progressive mechanical failures; and definite improvements have been noted. A zinc oxide pigmented lithium silicate paint has demonstrated very good ultraviolet stability.
Gilligan, J. E.↗
Electron spin resonance of ultraviolet radiation induced defects in ZnO thermal control coating pigment.
Electron spin resonance measurements on variously treated zinc oxide powders reveal that the resonance signal at g = 1.956 is due to one electron trapped oxygen ion vacancy level, at a depth of (0.31 plus or minus 0.02) eV below the conduction band. The electrons at this level are delocalized. Schottky barrier influences nearly the entire bulk of the powder sample, and the bending of the bands caused by chemisorbed oxygen puts the vacancy level above the Fermi level almost through the entire bulk.
Mookherji, T.↗
Formulation procedures, rationale, and preliminary IMP-H flight data for silicone paints with improved stability
Results are given of a class of silicone paints undergoing space qualification on IMP-H. In addition to ultraviolet irradiation, samples are presently reclining about 10 to the 16th power solar wind protons per year. Preliminary data, covering the time span of the first anniversary, give incremental solar absorptances of 0.03 for two white paints, and 0.01 for leafing aluminum and a green tinted white paint. Complementing these data are complete descriptions of techniques used in making these paints, stabilizing the zinc oxide pigment, and choosing a solvent. Outgassing characteristics of finished coatings are also included. An attempt toward unification of these various aspects of the aerospace paint problem is provided through documented photochemical reactions, and a generalized band representation of the problem and its solutions.
Schutt, J. B.↗
Radiative property investigation
A detailed formulation of radiative heat transfer problems involving the use of bidirectional reflectance is discussed. Except for very simple systems this formulation is very intricate. For this reason and the fact that bidirectional data are scarce, such a formulation is not in common use. However, with the development of the digital computer there have been numerical methods developed for detailed radiative investigations using the bidirectional reflectance. Since computations using bidirectional reflectance are coming into use for spacecraft radiative studies, it is necessary to have reflectance data on the materials involved. Materials that are frequently studied are coatings which are used in controlling the thermal environment of spacecrafts. This study is primarily concerned with the bidirectional reflectance of zinc oxide which is one constituent commonly used for coatings.
Scott, R. L., Jr.↗
Investigation of conductive thermal control coatings by a contactless method in vacuo
A technique for determining the conductance per unit area of thermal control coatings for electrostatically clean spacecraft is described. In order to simulate orbital conditions more closely, current-density-voltage (j-V) curves are obtained by a contactless method in which the paint on an aluminum substrate is the anode of a vacuum diode configuration with a tungsten filament cathode. Conductances per unit area which satisfy the International Sun Earth Explorer (ISEE) requirement were observed on black paints containing carbon and in white and green paints filled with zinc oxide which were fired in order to induce defect conductivity. Because of surface effects and the nonhomogeneous nature of paints, large discrepancies were found between measurements with the contactless method and measurements employing metallic contacts, particularly at low current densities. Therefore, measurements with metallic contacts are considered to be of questionable value in deciding the suitability of coatings for electrostatic charge control.
Viehmann, W.↗
The study of surface acoustic wave charge transfer device
A surface acoustic wave-charge transfer device, consisting of an n-type silicon substrate, a thermally grown silicon dioxide layer, and a sputtered film of piezoelectric zinc oxide is proposed as a means of circumventing problems associated with charge-coupled device (CCD) applications in memory, signal processing, and imaging. The proposed device creates traveling longitudinal electric fields in the silicon and replaces the multiphase clocks in CCD's. The traveling electric fields create potential wells which carry along charges stored there. These charges may be injected into the wells by light or by using a p-n junction as in conventional CCD's.
Papanicolaou, N.↗
Development of Silane Hydrolysate Binder for Thermal-Control Coatings
Technical report describes theoretical and experimental development of methyltriethoxysilane (MTES) hydrolysate binder for white, titanium dioxidepigmented thermal-control coatings often needed on satellites. New coating is tougher and more abrasion-resistant than conventional coating, S-13G, which comprises zinc oxide in hydroxyl-therminated dimethylsiloxane binder.
Patterson, W. J.↗
Cross-linked polyvinyl alcohol films as alkaline battery separators
Cross-linking methods were investigated to determine their effect on the performance of polyvinyl alcohol (PVA) films as alkaline battery separators. The following types of cross-linked PVA films are discussed: (1) PVA-dialdehyde blends post-treated with an acid or acid periodate solution (two-step method) and (2) PVA-dialdehyde blends cross-linked during film formation (drying) by using a reagent with both aldehyde and acid functionality (one-step method). Laboratory samples of each cross-linked type of film were prepared and evaluated in standard separator screening tests. The pilot-plant batches of films were prepared and compared to measure differences due to the cross-linking method. The pilot-plant materials were then tested in nickel oxide - zinc cells to compare the two methods with respect to performance characteristics and cycle life. Cell test results are compared with those from tests with Celgard.
Sheibley, D. W.↗
Cross-linked polyvinyl alcohol films as alkaline battery separators
Cross-linking methods have been investigated to determine their effect on the performance of polyvinyl alcohol (PVA) films as alkaline battery separators. The following types of cross-linked PVA films are discussed: (1) PVA-dialdehyde blends post-treated with an acid or acid periodate solution (two-step method) and (2) PVA-dialdehyde blends cross-linked during film formation (drying) by using a reagent with both aldehyde and acid functionality (one-step method). Laboratory samples of each cross-linked type of film were prepared and evaluated in standard separator screening tests. Then pilot-plant batches of films were prepared and compared to measure differences due to the cross-linking method. The pilot-plant materials were then tested in nickel oxide-zinc cells to compare the two methods with respect to performance characteristics and cycle life. Cell test results are compared with those from tests with Celgard.
Sheibley, D. W.↗
Size-specific composition of aerosols in the El Chichon volcanic cloud
A NASA U-2 research aircraft flew sampling missions in April, May, July, November, and December 1982 aimed at obtaining in situ data in the stratospheric cloud produced from the March-April 1982 El Chichon eruptions. Post flight analyses provided information on the aerosol composition and morphology. The particles ranged in size from smaller than 0.05 m to larger than 20 m diameter and were quite complex in composition. In the April, May, and July samples the aerosol mass was dominated by magmatic and lithic particles larger than about 3 m. The submicron particles consisted largely of sulfuric acid. Halite particles, believed to be related to a salt dome beneath El Chichon, were collected in the stratosphere in April and May. On the July 23 flight, copper-zinc oxide particles were collected. In July, November, and December, in addition to the volcanic ash and acid particles, carbon-rich particles smaller than about 0.1 m aerodynamic diameter were abundant.
Woods, D. C.↗
Electrically conductive, black thermal control coatings for spacecraft application. I - Silicate matrix formulation
The formulation of the graphite silicate paints MH-11 and MH-11Z, which will serve as electrically conductive, heat-resistant thermal control coatings for the Galileo spacecraft's 400 Newton engine plume shield, 10 Newton thruster plume shields, and external shunt radiators, is described, and performance results for these paints are reported. The MH-11 is produced by combining a certain grade of graphite powder with a silicate base to produce a black, inorganic, electrically conductive, room temperature cure thermal control paint having high temperature capability. Zinc oxide is added to the MH-11 formulation to produce the blister resistant painta MH-11Z. The mechanical, chemical, thermal, optical, and radiation characteristics of the coatings are reported. The formulation, mixing, application, and surface preparation of the substrates are described, and a method of determining the electrical resistance of the coatings is demonstrated.
Bauer, J. L.↗