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At least 271 records · Page 15

High-fidelity entanglement and coherent multi-qubit mapping in an atom array

Neutral atoms in optical tweezer arrays possess broad applicability for quantum technologies, such as computing, analogue simulation and metrology. The atomic species ytterbium-171 is able to host multiple types of qubits, making it a strong candidate for bridging various applications of tweezer arrays. Realizing this potential requires high-fidelity generation and transfer of many-body entanglement between these distinct qubit degrees of freedom. Here, in this study, we demonstrate the creation and coherent mapping of entangled quantum states across multiple qubits in ytterbium-171 tweezer arrays. We map entangled states onto the optical clock qubit from the nuclear spin qubit or the Rydberg qubit. We coherently transfer Z 2 -ordered Greenberger–Horne–Zeilinger states of up to 20 atoms from the interacting Rydberg manifold to the metastable nuclear spin manifold. Furthermore, we find that clock-qubit-based spin detection, when applied to Rydberg and nuclear spin qubits, facilitates atom-loss-detectable qubit measurements and Rydberg decay detection. This enables delayed-erasure detection, yielding an error-detected two-qubit gate fidelity of 99.78(4)% in metastable qubits. These results establish a versatile architecture that advances multiple fields of quantum information science while also establishing bridges between them.

Senoo, Aruku [University of Colorado, Boulder, CO ↗

Theoretical estimates of flammability bounds for thin condensed fuel diffusion flames in microgravity using detailed models of chemistry and radiation

Recently, U-shape flammability maps have been constructed showing minimal oxygen vs. flame strain for opposed flame spread in micro-gravity by Olson and Ferkul. The U-shape defines the limiting flammability bounds from radiative extinction and flame blow-off. Here, the minimum of the U corresponds to the minimum possible oxidizer concentration where burning can occur, and is an important quantity of interest for fire safety. While high strain extinction bounds have been well analyzed, low strain radiative extinction has not. To estimate low strain extinction, in this study an analytical theory is developed based on thin flame theory coupled with a heat and mass transfer model for solid fuels. A reaction progress variable based on the Damköhler number is adapted in the theory to account for incomplete combustion at high strain rates and enable the capturing of the full flammability map. The analytical model is compared to a one dimensional numerical model w/ detailed chemical kinetics and coupled radiation heat transfer in planar and spherical geometries. The flammability maps are then qualitatively compared to experimental extinguishment data compiled by Olson and Ferkul for cylindrical rods of PMMA showing similar trends. The results show the newly developed analytics capture the radiative extinction bound compared to the numerical model and qualitatively agrees with microgravity data.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Thermal Analysis of Wireless Power Transfer Coils for Dynamic Wireless Electric Vehicle Charging

In this paper, safe operating conditions of a wireless power transfer coil were identified and road infrastructure for a dynamic wireless electric vehicle charging system was studied. Magneto-thermal simulations were used to map the power loss directly into the computed fluid dynamics solver. This method allowed the authors to analyze the heating pattern of the enclosed wireless power transfer coil in the road structure, as well as for the vehicle coil. Thermal heating patterns for three types of rectangular coil structures were analyzed. Heating patterns were analyzed for 200 kW coils and different magnetic field densities in the magnetic core.

Wojda, Rafal↗

Toxin-Antitoxin Systems Reflect Community Interactions Through Horizontal Gene Transfer

Bacterial evolution through horizontal gene transfer (HGT) reflects their community interactions. In this way, HGT networks do well at mapping community interactions, but offer little toward controlling them—an important step in the translation of synthetic strains into natural contexts. Toxin–antitoxin (TA) systems serve as ubiquitous and diverse agents of selection; however, their utility is limited by their erratic distribution in hosts. Here we examine the heterogeneous distribution of TAs as a consequence of their mobility. By systematically mapping TA systems across a 10,000 plasmid network, we find HGT communities have unique and predictable TA signatures. We propose these TA signatures arise from plasmid competition and have further potential to signal the degree to which plasmids, hosts, and phage interact. To emphasize these relationships, we construct an HGT network based solely on TA similarity, framing specific selection markers in the broader context of bacterial communities. This work both clarifies the evolution of TA systems and unlocks a common framework for manipulating community interactions through TA compatibility.

59 BASIC BIOLOGICAL SCIENCES↗

Spatially Resolved Persistent Photoconductivity in MoS2–WS2 Lateral Heterostructures

The optical and electronic properties of 2D semiconductors are intrinsically linked via the strong interactions between optically excited bound species and free carriers. Here we use near-field scanning microwave microscopy (SMM) to image spatial variations in photoconductivity in MoS 2 –WS 2 lateral multijunction heterostructures using photon energy-resolved narrowband illumination. We find that the onset of photoconductivity in individual domains corresponds to the optical absorption onset, confirming that the tightly bound excitons in transition metal dichalcogenides can nonetheless dissociate into free carriers. These photogenerated carriers are most likely n-type and are seen to persist for up to days. Informed by finite element modeling we reveal that they can increase the carrier density by up to 200 times. This persistent photoconductivity appears to be dominated by contributions from the multilayer MoS 2 domains, and we attribute the flake-wide response in part to charge transfer across the heterointerface. Spatial correlation of our SMM imaging with photoluminescence (PL) mapping confirms the strong link between PL peak emission photon energy, PL intensity, and the local accumulated charge. This work reveals the spatially and temporally complex optoelectronic response of these systems and cautions that properties measured during or after illumination may not reflect the true dark state of these materials but rather a metastable charged state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

OH Roaming and Beyond in the Unimolecular Decay of the Methyl-Ethyl-Substituted Criegee Intermediate: Observations and Predictions

Alkene ozonolysis generates short-lived Criegee intermediates that are a significant source of hydroxyl (OH) radicals. Here this study demonstrates that roaming of the separating OH radicals can yield alternate hydroxycarbonyl products, thereby reducing the OH yield. Specifically, hydroxybutanone has been detected as a stable product arising from roaming in the unimolecular decay of the methyl-ethyl-substituted Criegee intermediate (MECI) under thermal flow cell conditions. The dynamical features of this novel multistage dissociation plus a roaming unimolecular decay process have also been examined with ab initio kinetics calculations. Experimentally, hydroxybutanone isomers are distinguished from the isomeric MECI by their higher ionization threshold and distinctive photoionization spectra. Moreover, the exponential rise of the hydroxybutanone kinetic time profile matches that for the unimolecular decay of MECI. A weaker methyl vinyl ketone (MVK) photoionization signal is also attributed to OH roaming. Complementary multireference electronic structure calculations have been utilized to map the unimolecular decay pathways for MECI, starting with 1,4 H atom transfer from a methyl or methylene group to the terminal oxygen, followed by roaming of the separating OH and butanonyl radicals in the long-range region of the potential. Roaming via reorientation and the addition of OH to the vinyl group of butanonyl is shown to yield hydroxybutanone, and subsequent C–O elongation and H-transfer can lead to MVK. A comprehensive theoretical kinetic analysis has been conducted to evaluate rate constants and branching yields (ca. 10–11%) for thermal unimolecular decay of MECI to conventional and roaming products under laboratory and atmospheric conditions, consistent with the estimated experimental yield (ca. 7%).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Performance of a supercharged direct-injection stratified-charge rotary combustion engine

A zero-dimensional thermodynamic performance computer model for direct-injection stratified-charge rotary combustion engines was modified and run for a single rotor supercharged engine. Operating conditions for the computer runs were a single boost pressure and a matrix of speeds, loads and engine materials. A representative engine map is presented showing the predicted range of efficient operation. After discussion of the engine map, a number of engine features are analyzed individually. These features are: heat transfer and the influence insulating materials have on engine performance and exhaust energy; intake manifold pressure oscillations and interactions with the combustion chamber; and performance losses and seal friction. Finally, code running times and convergence data are presented.

Bartrand, Timothy A.↗

Subnanometer Scale Mapping of Hydrogen Doping in Vanadium Dioxide

Hydrogen donor doping of correlated electron systems such as vanadium dioxide (VO 2 ) profoundly modifies the ground state properties. The electrical behavior of H x VO 2 is strongly dependent on the hydrogen concentration; hence, atomic scale control of the doping process is necessary. It is however a nontrivial problem to quantitatively probe the hydrogen distribution in a solid matrix. As hydrogen transfers its sole electron to the material, the ionization mechanism is suppressed. Here in this study, a methodology mapping the doping distribution at subnanometer length scale is demonstrated across a H x VO 2 thin film focusing on the oxygen-hydrogen bonds using electron energy loss spectroscopy (EELS) coupled with first-principles EELS calculations. The hydrogen distribution was revealed to be nonuniform along the growth direction and between different VO 2 grains, calling for intricate hydrogenation mechanisms. Our study points to a powerful approach to quantitatively map dopant distribution in quantum materials relevant to energy and information science

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Trajectory design for the Deep Space Program Science Experiment (DSPSE) mission

In 1994, the Deep Space Program Science Experiment (DSPSE) spacecraft will become the first spacecraft to perform, in succession, both a lunar orbiting mission and a deep-space asteroid encounter mission. The primary mission objective is to perform a long-duration flight-test of various new-technology lightweight components, such as sensors, in a deep-space environment. The mission has two secondary science objectives: to provide high-resolution imaging of the entire lunar surface for mapping purposes and flyby imaging of the asteroid 1620 Geographos. The DSPSE mission is sponsored by the Strategic Defense Initiative Organization (SDIO). As prime contractor, the Naval Research Laboratory (NRL) is building the spacecraft and will conduct mission operations. The Goddard Space Flight Center's (GSFC) Flight Dynamics Division is supporting NRL in the areas of The Deep Space Network (DSN) will provide tracking support. The DSPSE mission will begin with a launch from the Western Test Range in late January 1994. Following a minimum 1.5-day stay in a low-Earth parking orbit, a solid kick motor burn will boost DSPSE into an 18-day, 2.5-revolution phasing orbit transfer trajectory to the Moon. Two burns to insert DSPSE into a lunar polar orbit suitable for the mapping mission will be followed by mapping orbit maintenance and adjustment operations over a period of 2 sidereal months. In May 1994, a lunar orbit departure maneuver, in conjunction with a lunar swingby 26 days later, will propel DSPSE onto a heliocentric transfer that will intercept Geographos on September 1, 1994. This paper presents the characteristics, deterministic delta-Vs, and design details of each trajectory phase of this unique mission, together with the requirements, constraints, and design considerations to which each phase is subject. Numerous trajectory plots and tables of significant trajectory events are included. Following a discussion of the results of a preliminary launch window analysis, a summary of the deterministic impulsive delta-V budget required to establish the baseline mission trajectory design is presented.

Carrington, D.↗

Measurements and Modeling of Soot Formation and Radiation in Microgravity Jet Diffusion Flames

This is a computational and experimental study for soot formation and radiative heat transfer in jet diffusion flames under normal gravity (1-g) and microgravity (0-g) conditions. Instantaneous soot volume fraction maps are measured using a full-field imaging absorption technique developed by the authors. A compact, self-contained drop rig is used for microgravity experiments in the 2.2-second drop tower facility at NASA Lewis Research Center. On modeling, we have coupled flame structure and soot formation models with detailed radiation transfer calculations. Favre-averaged boundary layer equations with a k-e-g turbulence model are used to predict the flow field, and a conserved scalar approach with an assumed Beta-pdf are used to predict gaseous species mole fraction. Scalar transport equations are used to describe soot volume fraction and number density distributions, with formation and oxidation terms modeled by one-step rate equations and thermophoretic effects included. An energy equation is included to couple flame structure and radiation analyses through iterations, neglecting turbulence-radiation interactions. The YIX solution for a finite cylindrical enclosure is used for radiative heat transfer calculations. The spectral absorption coefficient for soot aggregates is calculated from the Rayleigh solution using complex refractive index data from a Drude- Lorentz model. The exponential-wide-band model is used to calculate the spectral absorption coefficient for H20 and C02. It is shown that when compared to results from true spectral integration, the Rosseland mean absorption coefficient can provide reasonably accurate predictions for the type of flames studied. The soot formation model proposed by Moss, Syed, and Stewart seems to produce better fits to experimental data and more physically sound than the simpler model by Khan et al. Predicted soot volume fraction and temperature results agree well with published data for a normal gravity co-flow laminar flames and turbulent jet flames. Predicted soot volume fraction results also agree with our data for 1-g and 0-g laminar jet names as well as 1-g turbulent jet flames.

Ku, Jerry C.↗

Intensified reactive extraction for the acid-catalyzed conversion of fructose to 5-hydroxymethyl furfural

Here we conduct an experimental study of fructose dehydration to 5-hydroxymethyl furfural (HMF) in a biphasic microreactor as a function of residence time, temperature, and sugar loading using methyl butyl iso-ketone (MIBK) and 2-pentanol as extracting solvents. We demonstrate stable operation with maximum HMF yields of 93% and 87% in the two solvents, respectively, at 200 °C and a residence time of 2 s for a 5 wt% fructose aqueous feed. We report the highest optimal HMF space–time yield of 60 kg/L-hr at 200 °C (10 – 2,500-fold higher than published reports). Unexpectedly, an optimum organic-to-water ratio exists that depends on the solvent. Notably, we observe experimentally an increased fructose rate and HMF yield well above the extraction thermodynamic limit and hypothesize that the solvent plays a dual role, that of an extractant to protect HMF from degradation and a modifier of the fundamental chemistry. We expose mass transfer limitations of microreactors at longer residence times and higher temperatures and provide reactivity maps for their design. We show that batch reactors are unfit for high throughput and distributed manufacturing where small, farm-based systems are necessary.

42 ENGINEERING↗

BiCuI 4 (Pyridine) 5 a neutral ligand-supported compound of BiI 3 and CuI

Reaction of equimolar pyridine (Py) solutions BiI 3 and CuI produces the Py-supported 1:1 bimetallic complex BiCuI 4 (Py) 5 in quantitative yield. The title complex is only the second neutral complex to feature Cu–I–Bi bridging and shows an octahedral trans-[BiI 4 (Py) 2 ] unit joined to a distorted tetrahedral CuI(Py) 3 unit by an iodide bridge. The complex shows low thermal stability, decomposing under modest heating or vacuum to produce a mixture of BiI 3 and CuI. Thus, it is a potential entry/precursor to BiI 3 /CuI chemistry. Natural Localized Molecular Orbital (NLMO) calculations were performed to analyze the nature of the Cu–I–Bi bonds, revealing that the title compound lies on the cusp of being [Cu(Py) 3 ] + [BiI 4 (Py) 2 ] – . Diffuse reflectance spectroscopy measurements show a strong absorption band with an optical bandgap energy of 1.94 eV. Theoretical density of states (DOS) and time-dependent density functional theory (TD-DFT) experiments to map the electronic structure assign the primary electronic transition as a mixed halide/metal-to-ligand charge transfer between Cu–I–Bi donor orbitals and Py π* acceptor orbitals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Data-Driven Modeling and Correction of Vehicle Dynamics

We develop a data-driven framework for learning and correcting nonautonomous vehicle dynamics. Physics-based vehicle models are often simplified for tractability and therefore exhibit inherent model-form uncertainty, motivating the need for data-driven correction. Moreover, nonautonomous dynamics are governed by time-dependent control inputs, which pose challenges in learning predictive models directly from temporal snapshot data. To address these, we reformulate the vehicle dynamics via a local parameterization of the time-dependent inputs, yielding a modified system composed ofa sequence of local parametric dynamical systems. Here, we approximate these parametric systems using two complementary approaches. First, we employ the dimension reduction and interpolation in parameter space (DRIPS) methodology to construct efficient linear surrogate models, equipped with lifted observable spaces and manifold-based operator interpolation. This enables data-efficient learning of vehicle models whose dynamics admit accurate linear representations in the lifted spaces. Second, for more strongly nonlinear systems, we employ flow map learning (FML), a deep neural network (DNN) approach that approximates the parametric evolution map without requiring special treatment of nonlinearities. We further extend FML with a transfer-learning-based model correction procedure, enabling the correction of misspecified prior models using only a sparse set of high-fidelity or experimental measurements, without assuming a prescribed form for the correction term. Through a suite of numerical experiments on unicycle, simplified bicycle, and slip-based bicycle models, we demonstrate that DRIPS offers robust and highly data-efficient learning of nonautonomous vehicle dynamics, while FML provides expressive nonlinear modeling and effective correction of model-form errors under severe data scarcity.

data-driven modeling↗

Echo mapping the Balmer-emission region in NGC 3516

We use a maximum-entropy method to show that the transfer function (TF) of the broad-line region (BLR) in the Seyfert-1 galaxy NGC 3516 is time-varying. The TF decreased by nearly a factor of two over a time scale less than half a year during a monitoring campaign in 1990. We conclude that the observed time dependency is likely to be either due to variations of the spectral index of the ionizing continuum spectrum; due to a change in the number or covering fraction of broad-line clouds; due to nonlinear line response; or due to nonstationary anisotropy of the continuum source on time scales of several weeks to months. An extended continuum source could also explain the observed time-dependency. The symmetry of the time lag for variations in the red and blue wings of H-alpha indicates that the BLR kinematics is not dominated by organized radial inflow or outflow. If we assume circular orbits, the observed time lag 14 days at velocity v = 4000 km/s suggests a mass of the central object of approximately 2 x 10(exp 7) solar mass. The H-alpha TF peaks away from zero delay, indicating that the H-alpa BLR is either non-spherical or inwardly emitting.

Wanders, I.↗

Modeling UV-B Effects on Primary Production Throughout the Southern Ocean Using Multi-Sensor Satellite Data

This study has used a combination of ocean color, backscattered ultraviolet, and passive microwave satellite data to investigate the impact of the springtime Antarctic ozone depletion on the base of the Antarctic marine food web - primary production by phytoplankton. Spectral ultraviolet (UV) radiation fields derived from the satellite data are propagated into the water column where they force physiologically-based numerical models of phytoplankton growth. This large-scale study has been divided into two components: (1) the use of Total Ozone Mapping Spectrometer (TOMS) and Special Sensor Microwave Imager (SSM/I) data in conjunction with radiative transfer theory to derive the surface spectral UV irradiance throughout the Southern Ocean; and (2) the merging of these UV irradiances with the climatology of chlorophyll derived from SeaWiFS data to specify the input data for the physiological models.

Lubin, Dan↗

Inferring Cloud Properties from Passive Solar Sensors

The most common approach for retrieving cloud optical depth from ground-based observations uses downwelling fluxes measured by pyranometers and Multi-Filter Rotating Shadowband Radiometers (MFRSR). The key element in both retrieval techniques is the one-to-one mapping of the "observed" fluxes into cloud optical depth through plane-parallel radiative transfer. Both methods are expected to work well only for completely overcast clouds giving an effective optical depth for the whole sky. To infer cloud optical depth locally one can assume to use a narrow-field-of view radiometer that measures radiances instead of fluxes. However, lack of one-to-one relationships between radiance and cloud optical depth, prevents the direct use of radiances either. Here we discuss a new method for retrieving cloud optical depth from ground-based measurements of zenith radiance in the RED and near infrared (NIR) spectral regions. In addition to an algebraic combinations of spectral radiances such as Normalized Difference Cloud Index (NDCI) that largely removes nonuniqueness and the radiative effects of cloud inhomogeneity but can result in poor retrievals due to its insensitivity to cloud fraction, both RED and NIR radiances as points on the "RED vs. NIR" plane are proposed to be used for retrieval. The proposed retrieval method is applied to a multi- channel sunphotometer (as a part of AERONET) measurements at the ARM site in Oklahoma. The results of retrieval are compared with the ones from Microwave Radiometer (MWR) and MFRSR. In addition to cloud optical depth, the new retrieval method also infers a "radiatively effective" cloud fraction.

Marshak, A.↗

Lunar and Planetary Science XXXVI, Part 4

Contents include the following: High-Resolution Electron Energy-Loss Spectroscopy (HREELS) Using a Monochromated TEM/STEM. Dynamical Evolution of Planets in Open Clusters. Experimental Petrology of the Basaltic Shergottite Yamato 980459: Implications for the Thermal Structure of the Martian Mantle. Cryogenic Reflectance Spectroscopy of Highly Hydrated Sulfur-bearing Salts. Implications for Core Formation of the Earth from High Pressure-Temperature Au Partitioning Experiments. Uranium-Thorium Cosmochronology. Protracted Core Differentiation in Asteroids from 182Hf-182W Systematics in the Eagle Station Pallasite. Maximizing Mission Science Return Through Use of Spacecraft Autonomy: Active Volcanism and the Autonomous Sciencecraft Experiment. Classification of Volcanic Eruptions on Io and Earth Using Low-Resolution Remote Sensing Data. Isotopic Mass Fractionation Laws and the Initial Solar System (sup26)Al/(sup27)Al Ratio. Catastrophic Disruption of Porous and Solid Ice Bodies (sup187)Re-(sup187)Os Isotope Disturbance in LaPaz Mare Basalt Meteorites. Comparative Petrology and Geochemistry of the LaPaz Mare Basalt Meteorites. A Comparison of the Structure and Bonding of Carbon in Apex Chert Kerogenous Material and Fischer-Tropsch-Type Carbons. Broad Spectrum Characterization of Returned Samples: Orientation Constraints of Small Samples on X-Ray and Other Spectroscopies. Apollo 14 High-Ti Picritic Glass: Oxidation/Reduction by Condensation of Alkali Metals. New Lunar Meteorites from Oman: Dhofar 925, 960 and 961. The First Six Months of Iapetus Observations by the Cassini ISS Camera. First Imaging Results from the Iapetus B/C Flyby of the Cassini Spacecraft. Radiative Transfer Calculations for the Atmosphere of Mars in the 200-900 nm Range. Geomorphologic Map of the Atlantis Basin, Terra Sirenum, Mars. The Meaning of Iron 60: A Nearby Supernova Injected Short-lived Radionuclides into Our Protoplanetary Disk.

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