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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Local measurement of thermal conductivity and diffusivity

Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness for extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representatives of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agreed closely with the literature values. A distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Intrinsic anharmonicity and thermal properties of ultralow thermal conductivity Ba 6 Sn 6 Se 13

Ultralow thermal conductivity materials continue to be of great interest for technologically important applications such as thermal insulators and thermoelectrics. Often, such materials possess constituents with extensive dynamic disorder, or “rattlers,” or structural disorder such as metallic glasses. Nevertheless, targeted crystalline bonding order and anharmonicity can provide effective means for the scattering of the phonons in certain materials. Our combined experimental and theoretical investigation of Ba 6 Sn 6 Se 13 reveals such a material, with ultralow thermal conductivity measured over a large temperature range. Optic phonon modes hybridize with acoustic modes at relatively low energies resulting in strong acoustic-optic scattering and limited phonon lifetimes. Moreover, our investigations reveal various avoided crossings at low energies that contribute to phonon scattering. These are derived from chiral phase symmetries and may result in nontrivial topological behaviors for phonon band crossings in this chiral material. This work contributes to the ongoing research on low thermal conductivity materials and the underlying mechanisms that affect their thermal behaviors. Manipulation of these effects may provide pathways for enhancement of material properties for targeted thermal applications using similar materials.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Observation of non-thermal electron formation during the thermal quench of shattered pellet injection shutdowns in DIII-D

Formation of non-thermal (hot) electrons is studied during the thermal quench of shattered pellet injection (SPI) discharge shutdowns in the DIII-D tokamak. Both pure neon and mixed neon/deuterium shutdowns are studied. High-energy radiation (SXR and EUV) brightness levels show indications of non-thermal electron formation during the TQ. The non-thermal densities are of order 10 18 m –3 and non-thermal temperatures are estimated to be of order 10 keV. The non-thermal electrons appear to be mostly lost during the subsequent current quench, as no signal of relativistic runaway electrons is typically seen at the end of the current quench. In conclusion, the non-thermals appear to have an effect on the deposition profile of the SPI pellets, especially at the end of the TQ, due to increased pellet ablation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Intrinsic thermal expansion and tunability of thermal expansion coefficient in Ni-substituted Co 2 V 2 O 7

Abstract Framework oxide materials are well-known for exhibiting not only negative thermal expansion (NTE), but also demonstrating thermal expansion that can be controlled using composition as a tuning parameter. In this work, we study the intrinsic thermal expansion properties of Co 2 V 2 O 7 , which has shown bulk linear NTE, and attempt to understand how substituting Ni 2+ for Co 2+ will affect the thermal expansion. The isomorphic solid solution is synthesized through solid-state methods and characterized using x-ray diffraction (XRD), diffuse reflectance spectroscopy, and neutron diffraction. The size difference between Ni 2+ and Co 2+ as well as the polyhedral volume of each Co 2+ metal coordination environment in the crystal structure allows Ni 2+ to partially be directed toward one crystallographic site over the other. Variable temperature synchrotron XRD data are employed to understand intrinsic thermal expansion. Across the solid solution, no intrinsic NTE is observed at the microscopic level, yet a degree of tunability in the thermal expansion coefficient with Ni substitution is demonstrated. The disparities between the intrinsic and bulk thermal expansion properties suggest that a morphological mechanism may have resulted in NTE in the bulk.

Materials Science↗
DOE OSTI2021

Computational Evaluation of Thermal Response of Open-Cell Foam With Circular Pore (Computional Evaluation of Thermal Response of Open-Cell Foam with Circular Pore)

The evaluation of effective material properties in heterogeneous materials (e.g., composites or multicomponent structures) critically relevant to a wide spectrum of applications, including nuclear power, electronic packaging, flame retardants, hypersonics, and gas turbine power. The work described in this paper is centered around the numerical assessment of the thermal behavior of porous materials obtained from finite element thermal modeling and simulation. Here, two-dimensional, steady state analyses were performed on unit cells with centered, circular pores using a second order accurate Galerkin finite element method (FEM). The effective thermal conductivities of the porous systems were examined, encompassing a range of porosities from 4.9% to 60.1%. The geometries of the models were generated based on ordered circular pores for each modeled porosity level. The system response quantity (SRQ) under investigation was the dimensionless effective thermal conductivity across the unit cell. The dimensionless effective thermal conductivity was compared across all simulated cases, producing a trend between porosity and effective thermal conductivity. In the presented investigation, the method of manufactured solutions (MMS) was used to perform code verification, and the grid convergence index (GCI) was employed to estimate discretization uncertainty as solution verification. Code verification concluded an approximately second order accurate Galerkin FEM solver. It was found that the introduction of porosity to the unit cell material structure reduces effective thermal conductivity, as anticipated. Numerical results obtained in this study are compared to an analytical solution and to a sample of empirical data.

36 MATERIALS SCIENCE↗
DOE OSTI2025

2024 Stor4Build Annual Meeting: Exploring Challenges and Opportunities in Thermal Energy Storage for Buildings

In late August 2024, Stor4Build brought nearly 80 stakeholders from the thermal energy storage industry to Oak Ridge National Laboratory (ORNL), including researchers, startups, electric utilities, nonprofits, implementers, state energy efficiency offices, and original equipment manufacturers. During the two-day Stor4Build Annual Meeting, participants engaged in vital discussions about the current challenges and opportunities for scaling thermal energy storage solutions in buildings. The event featured panel discussions led by leading technology experts and industry practitioners, as well as updates on Stor4Build–funded projects from national laboratories, highlighting advancements in the thermal energy storage field crucial to achieving the consortium’s mission.

25 ENERGY STORAGE↗
DOE OSTI2024

A Planar-Cavity Receiver Configuration for High-Temperature Solar Thermal Processes: Preprint

Next generation concentrating solar thermal power (CSP) and novel solar thermochemical systems using concentrating solar thermal (CST) energy require high operating temperatures exceeding those of traditional nitrate-salt CSP systems. Particle-based systems are attractive for next-generation CSP and CST applications owing to high-temperature stability of inert silica- or alumina-based particulate materials, the lack of low-temperature freezing concerns that limit molten salt and/or molten metal heat transfer media, and cost-effective thermal storage using low-cost particulate and containment materials. Open-cavity falling particle receivers have many potential advantages, but face challenges pertaining to scalability, thermal loss, and particle loss through the open aperture, and are infeasible for chemical processes that require a low-oxygen ambient environment. Enclosed receiver configurations can be scalable, avoid particle loss when heating particles, and have potential for future chemical processes; however, particle-based heat transfer media provide substantially lower heat transfer rates than liquid media, and thus enclosed particle receiver designs require novel configurations to limit surface temperatures under the high incident solar flux concentrations necessary for high receiver thermal efficiency at high temperature. This paper introduces the novel planar-cavity enclosed particle receiver configuration in which arrays of planar surfaces are arranged into sub-vertical cavities. Large angles between the panel surface normal vectors and the aperture surface normal allow the incoming solar beam to distribute along the panel walls. Correspondingly, a high incident solar flux concentration at the cavity aperture produces substantially lower absorbed solar flux concentration on any panel wall. Sets of individual vertical cavities can be arranged to form a scalable receiver configuration.

cavity receiver↗
NASA NTRS1981

Degradation of a two-layer thermal barrier coating under thermal cycling

A two-layer plasma-sprayed thermal barrier coating on a directionally solidified nickel-base eutectic alloy substrate was characterized prior to and after thermal cycling to 1095 C in an accelerated furnace test. The coating was comprised of an inner layer of Ni-16.4Cr-5.1Al-0.15Y (wt%) bond coat and an outer layer of ZrO2-7.9Y2O3 (wt%) thermal barrier. Characterization of the bond coat revealed that substantial amounts of yttrium and aluminum were oxidized during plasma-spraying in air. The oxidation of these elements reduced the protective capacity of the bond coat so that, on thermal exposure, severe degradation of the bond coat resulted and large amounts of nickel oxide formed. This nickel oxide was demonstrated to grow outward into the thermal barrier, which appears to have increased the stresses in the thermal barrier and contributed to its failure near the thermal barrier-bond coat interface.

Maier, R. D.↗
NASA NTRS1984

The thermal structure and thermal evolution of the continental lithosphere

The thermal structure and evolution of the continental lithosphere are examined. Surface heat flow data and the factors which modify them are addressed, and the diversity of thermal phenomena in the lithosphere is discussed in the framework of plate interactions. The lithosphere is divided into three sections for the purposes of discussion. In the upper, near-surface zone, temperatures can be strongly affected by near-surface processes, which must be taken into account in the measurement and evaluation of surface heat flow. The thermal structure of the middle, internal zone of the lithosphere responds to the heat balance and thermal properties of the lithosphere, which define its steady state thermal structure. Internal deformation and magmatic intrusion within this zone, and interaction between the lithosphere and the asthenosphere in the lower boundary zone of the lithosphere cause transient thermal disturbances in the lithosphere. The criteria for defining the base of the thermal lithosphere are briefly discussed.

Morgan, P.↗
NASA NTRS1990

Applications of high thermal conductivity composites to electronics and spacecraft thermal design

Recently, high thermal conductivity continuous graphite fiber reinforced metal matrix composites (MMC's) have become available that can save much weight over present methods of heat conduction. These materials have two or three times higher thermal conductivity in the fiber direction than the pure metals when compared on a thermal conductivity to weight basis. Use of these materials for heat conduction purposes can result in weight savings of from 50 to 70 percent over structural aluminum. Another significant advantage is that these materials can be used without the plumbing and testing complexities that accompany the use of liquid heat pipes. A spinoff of this research was the development of other MMC's as electronic device heat sinks. These use particulates rather than fibers and are formulated to match the coefficient of thermal expansion of electronic substrates in order to alleviate thermally induced stresses. The development of both types of these materials as viable weight saving substitutes for traditional methods of thermal control for electronics packaging and also for spacecraft thermal control applications are the subject of this report.

Sharp, G. Richard↗
NASA NTRS1994

Atmospheric effects on the mapping of Martian thermal inertia and thermally derived albedo

The most widely used thermal inertia data for Mars assumes the atmospheric contribution is constant and equal to 2 percent of the maximum solar insolation. Haberle and Jakosky investigated the effect of including a dusty CO2 atmosphere and sensible heat exchange with the surface on thermal inertia. We recently utilized Haberle and Jakosky's coupled surface-atmosphere model to investigate the effects of such an atmosphere on the thermally derived albedo. The thermally derived albedo is the albedo which, together with the thermal inertia, provides model surface temperatures which best match the observed temperatures. New maps are presented of thermal inertia and thermally derived albedo which incorporate dust opacities derived from IRTM data.

Hayashi, J. N.↗
NASA NTRS2004

Thermal Vacuum/Balance Test Results of Swift BAT with Loop Heat Pipe Thermal System

The Swift Burst Alert Telescope (BAT) Detector Array is thermally well coupled to eight constant conductance heat pipes (CCHPs) embedded in the Detector Array Plate PAP), and two loop heat pipes (LHPs) transport heat from the CCHPs to a radiator. The CCHPs have ammonia as the working fluid and the LHPs have propylene as the working fluid. Precision heater controllers, which have adjustable set points in flight, are used to control the LHP compensation chamber and Detector Array xA1 ASIC temperatures. The radiator has AZ-Tek's AZW-LA-II low solar absorptance white paint as the thermal coating, and is located on the anti-sun side of the spacecraft. A thermal balance (T/B) test on the BAT was successfully completed. It validated that the thermal design satisfies the temperature requirements of the BAT in the flight thermal environments. Instrument level and observatory level thermal vacuum (TN) cycling tests of the BAT Detector Array by using the LHP thermal system were successfully completed. This paper presents the results of the T/B test and T N cycling tests.

Choi, Michael K.↗
NASA NTRS1999

Thermal Mechanical Stability of Single-Crystal-Oxide Refractive Concentrators Evaluated for High-Temperature Solar-Thermal Propulsion

Recently, refractive secondary solar concentrator systems were developed for solar thermal power and propulsion (ref. 1). Single-crystal oxides-such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO), and sapphire (Al2O3)-are candidate refractive secondary concentrator materials. However, the refractive concentrator system will experience high-temperature thermal cycling in the solar thermal engine during the sun/shade transition of a space mission. The thermal mechanical reliability of these components in severe thermal environments is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions. In this research at the NASA Lewis Research Center, a controlled heat flux test approach was developed for investigating the thermal mechanical stability of the candidate oxide. This approach used a 3.0-kW continuous-wave (wavelength, 10.6 mm) carbon dioxide (CO2) laser (ref. 2). The CO2 laser is especially well-suited for single-crystal thermal shock tests because it can directly deliver well-characterized heat energy to the oxide surfaces. Since the oxides are opaque at the 10.6-mm wavelength of the laser beam, the light energy is absorbed at the surfaces rather than transmitting into the crystals, and thus generates the required temperature gradients within the specimens. The following figure is a schematic diagram of the test rig.

Jacobson, Nathan S.↗
NASA NTRS2006

Effects of Doping on Thermal Conductivity of Pyrochlore Oxides for Advanced Thermal Barrier Coatings

Pyrochlore oxides of general composition, A2B2O7, where A is a 3(+) cation (La to Lu) and B is a 4(+) cation (Zr, Hf, Ti, etc.) have high melting point, relatively high coefficient of thermal expansion, and low thermal conductivity which make them suitable for applications as high-temperature thermal barrier coatings. The effect of doping at the A site on the thermal conductivity of a pyrochlore oxide La2Zr2O7, has been investigated. Oxide powders of various compositions La2Zr2O7, La(1.7)Gd(0.3)Zr2O7, La(1.7)Yb(0.3)Zr2O7 and La(1.7)Gd(0.15)Yb(0.15)Zr2O7 were synthesized by the citric acid sol-gel method. These powders were hot pressed into discs and used for thermal conductivity measurements using a steady-state laser heat flux test technique. The rare earth oxide doped pyrochlores La(1.7)Gd(0.3)Zr2O7, La(1.7)Yb(0.3)Zr2O7 and La(1.7)Gd(0.15)Yb(0.15)Zr2O7 had lower thermal conductivity than the un-doped La2Zr2O7. The Gd2O3 and Yb2O3 co-doped composition showed the lowest thermal conductivity.

Bansal, Narottam P.↗
NASA NTRS2016

Temperature-Staged Thermal Energy Storage Enabling Low Thermal Exergy Loss Reflux Boiling in Full Spectrum Solar Systems

Hybrid full spectrum solar systems (FSSS) designed to capture and convert the full solar wavelength spectrum use hybrid solar photovoltaic/thermodynamic cycles that require low thermal exergy loss systems capable of transferring high thermal energy rates and fluxes with very low temperature differentials and losses. One approach to achieving this capability are high-heat-flux reflux boiling systems that take advantage of high heat transfer boiling and condensation mechanisms. Advanced solar systems are also intermittent by their nature and their electrical generation is often out-of-phase with electric utility power demand, and their required power system cycling reduces efficiency, performance (dispatch ability), lifetime, and reliability. High temperature thermal energy storage (TES) at 300-600°C enables these reflux boiling systems to simultaneously store thermal energy internally to increase the energy dispatch ability of the associated solar system, as this can increase the power generation profile by several hours (up to 6-10 hours) per day. Many TES phase change materials (PCM’s) exist including KNO3, NaNO3, LiBr/KBr, MgCl2/NaCl/KCl, Zn/Mg, and CuCl/NaCl, which have various operating melting points and different latent heats of fusion. Common, cost effective TES PCM's are FeCl2/NaCl/KCl mixtures, whose phase change temperature can be varied and controlled by simple composition adjustments. This paper presents and discusses unique "temperature-staged" thermal energy storage configurations using these TES materials and analysis of such systems integrated into high-heat-flux reflux boiling systems. In this specific application, the TES materials are designed to operate at staged temperatures surrounding an operating design point near 350°C, while providing 18 kW of source heat transfer to operate a thermoacoustic power system during off-sun conditions (e.g., temporary cloud conditions, after sun-down). This work discusses relevant configurations, and critical thermal and entropy models of the TES configurations, which show the inherent minimization of thermal exergy during critical heat transfers within the configurations and systems envisioned.

Hendricks, Terry J.↗
NASA NTRS2017

Thermal Control System of the ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS)

The ECOSystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) is a thermal infrared imaging multispectral scanner science mission. ECOSTRESS is designed and built by the NASA Jet Propulsion Laboratory and will be deployed on the International Space Station (ISS). ECOSTRESS will measure the water loss from growing leaves and the evaporation from the soil by measuring the temperature of plants and will gather data on the health of the agriculture system on Earth. The ISS orbit will allow ECOSTRESS to take observations at different times during each day over the seasons to provide coverage over the contiguous United States. The ECOSTRESS Thermal Control System (TCS) consists of a combination of active and passive components to maintain the ECOSTRESS components within the allowable flight temperature (AFT) limits. The active thermal control systems include mechanical cryocoolers, heaters and a single-phase pumped fluid loop for Instrument and Payload. The focal plane detector is cooled to 65K by a pair of mechanical cryocoolers and a third mechanical cryocooler cools an intermediate cold shield to 130K. The pumped fluid loop transfers the instrument waste heat to JAXA’s Japanese Exposed Module External Facility (JEM-EF) provided external fluid loop before rejection to space from the ISS radiators. The passive TCS includes multi-layer and single layer insulations, flexible thermal links and coatings on the radiometer. This paper describes the ECOSTRESS instrument TCS architecture, instrument thermal requirements and key design drivers, the top level thermal design and analysis approach, and reports preliminary test results.

Carroll, Brian↗