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At least 271 records · Page 15

Fabrication of IrSi(3)/p-Si Schottky diodes by a molecular beam epitaxy technique

IrSi(3)/p-Si Schottky diodes have been fabricated by a molecular beam epitaxy technique at 630 C. Good surface morphology was observed for IrSi(3) layers grown at temperatures below 680 C, and an increasing tendency to form islands is observed in samples grown at higher temperatures. Good diode current-voltage characteristics were observed and Schottky barrier heights of 0.14-0.18 eV were determined by activation energy analysis and spectral response measurement.

Lin, T. L.↗

Recent flood lavas in the Elysium region of Mars

A volcanic origin is presently suggested for the 'Cerberus Formation' region of smooth plains in the southeastern Elysium region of Mars, on the basis of its surface morphology, lobate edges, vents, and an embayment relation of the unit with adjacent, older units. The low viscosity lavas that filled a topographic depression in southeastern Elysium subsequently flowed into western Amazonic Planitia via channels formed by an earlier fluvial episode. A young, upper Amazonian dating is indicated by crater frequencies and stratigraphic relations, implying that large-scale eruptions of low-viscosity lava were still possible late in Martian history.

Plescia, J. B.↗

Substrate effects on the epitaxial growth of ZnGeP2 thin films by open tube organometallic chemical vapor deposition

Epitaxial ZnGeP2-Ge films have been grown on (111)GaP substrates using MOCVD. The films grown with dimethylzinc to germane flow rate ratio R greater than 10 show mirror-smooth surface morphology. Films grown with R less than 10 show a high density of twinning, including both double position and growth twins. Compared to films grown on (001) GaP substrates, the layers on (111) GaP generally show a higher density of microstructural defects. TEM electron diffraction patterns show that the films grown on (111) GaP substrates are more disordered than films grown on (001) GaP under comparable conditions. The growth rate on (111) GaP substrates is about 2.5 times slower than that on (001) GaP, and films grown on Si substrates show extensive twinning formation. Both TEM and SEM examinations indicate that smooth epitaxial overgrowth may be easier on (111) Si substrates than on (001) Si.

Xing, G. C.↗

Effects of oscillatory speed and mutual overlap on the tribological behavior of PTFE and selected PTFE-based self-lubricating composites

The wear reducing actions of bronze, graphic powder and discontinuous glass fiber within a PTFE matrix have been demonstrated in oscillatory contact with stainless steel, at two different amplitudes, over a range of speeds. The secondary effects on the friction of the PTFE have also been investigated. The effects of oscillation amplitude on frictional surface morphology have been observed for these composites. The friction and wear of the unfilled PTFE matrix were both found to increase as speed increased, with wear going through a transition from a low- to high-rate regime. The speed at which this transition occurs increases with decreasing oscillatory amplitude.

Blanchet, Thierry A.↗

An overview of the LeRC CSTI thermal management program

This report presents an integrated multielement project effort, currently being carried out at NASA LeRC, for the development of space heat rejection subsystems, with special emphasis on lightweight radiators, in support of SEI power system technology, and in particular the SP-100 program. Principal project elements include both contracted and in-house efforts. Included in the first category are two contracts aimed at the development of advanced radiator concepts, and demonstration of a flexible fabric heat pipe radiator concept. In-house work is designed to guide and support the overall program by system integration studies, heat pipe testing and analytical code development, radiator surface morphology alteration for emissivity enhancement, and composite materials research focused on the development of lightweight high conductivity fins.

Juhasz, Albert J.↗

Thermal control paints on LDEF: Results of sub-experiment 802-18

Several thermal control paints were flown on the LDEF, including the white paints Chemglaze A276, S13GLo, and YB-71, and the black paint D-111. The effects of low earth orbit, which includes UV radiation and atomic oxygen, varied significantly with each paint and its location on LDEF. This paper will examine the performance of these paints as determined by changes in their optical and physical properties, including solar absorptance, surface chemical changes, and changes in surface morphology. It will also provide a correlation of these optical and physical property changes to the physical phenomena that occurred in these materials during the LDEF mission.

Jaggers, Christopher H.↗

An overview of the Lewis Research Center CSTI thermal management program

An integrated multi-element project effort, currently being carried out at NASA LeRC, for the development of space heat rejection subsystems, with special emphasis on lightweight radiators, in support of SEI power system technology, and in particular the SP-100 program, is reported. Principal project elements include both contracted and in-house efforts. Included in the first category are two contracts aimed at the development of advanced radiator concepts, and demonstration of a flexible fabric heat pipe radiator concept. In-house work is designed to guide and support the overall program by system integration studies, heat pipe testing and analytical code development, radiator surface morphology alteration for emissivity enhancement, and composite materials research focused on the development of lightweight high conductivity fins.

Juhasz, Albert J.↗

Elemental boron-doped p(+)-SiGe layers grown by molecular beam epitaxy for infrared detector applications

SiGe/Si heterojunction internal photoemission (HIP) detectors have been fabricated utilizing molecular beam epitaxy of p(+)-SiGe layers on p(-)-Si substrates. Elemental boron from a high-temperature effusion cell was used as the dopant source during MBE growth, and high doping concentrations have been achieved. Strong infrared absorption, mainly by free-carrier absorption, was observed for the degenerately doped SiGe layers. The use of elemental boron as the dopant source allows a low MBE growth temperature, resulting in improved crystalline quality and smooth surface morphology of the Si(0.7)Ge(0.3) layers. Nearly ideal thermionic emission dark current characteristics have been obtained. Photoresponse of the HIP detectors in the long-wavelength infrared regime has been demonstrated.

Lin, T. L.↗

Atomic oxygen effects on thin film space coatings studied by spectroscopic ellipsometry, atomic force microscopy, and laser light scattering

The University of Nebraska is currently evaluating Low Earth Orbit (LEO) simulation techniques as well as a variety of thin film protective coatings to withstand atomic oxygen (AO) degradation. Both oxygen plasma ashers and an electron cyclotron resonance (ECR) source are being used for LEO simulation. Thin film coatings are characterized by optical techniques including Variable Angle Spectroscopic Ellipsometry, Optical spectrophotometry, and laser light scatterometry. Atomic Force Microscopy (AFM) is also used to characterize surface morphology. Results on diamondlike carbon (DLC) films show that DLC degrades with simulated AO exposure at a rate comparable to Kapton polyimide. Since DLC is not as susceptible to environmental factors such as moisture absorption, it could potentially provide more accurate measurements of AO fluence on short space flights.

Synowicki, R. A.↗

Vapor transport and crystal growth of GeSe under normal and high acceleration

Physical vapor transport experiments on GeSe in the presence of 2 atm xenon and for a nominal temperature difference of 600-500 C were performed under 1 g, 5 g, and 10 g acceleration conditions. Under high acceleration and destabilizing conditions, the GeSe crystals are generally larger than those under 1 g, stabilizing, and up to three orders of magnitude larger in surface area than those under 1 g, destabilizing conditions. The mass transport rates of the 5 g and 10 g destabilizing experiments are considerably greater than those of the 10 g, stabilizing, and 1 g experiments. The observed increase in mass flux (under destabilizing conditions) with acceleration is significantly greater than the anticipated dependence (mass flux proportional to g exp 1/4) for laminar, boundary-layer driven free convection. In view of the considerable convection under high acceleration, destabilizing conditions, the surface morphology and bulk crystallinity of the large crystal platelets are unexpectedly good.

Wiedemeier, H.↗

Selected results for metals from LDEF experiment A0171

Metal specimens in disk type and ribbon configurations of interest to various programs at the Marshall Space Flight Center were exposed to the LEO environment for 5.8 years on Long Duration Exposure Facility (LDEF) Experiment A0171. Most of the metals flown were well heat sunk in the LDEF experiment tray which experienced benign temperatures, but a few metals were thermally isolated allowing them to experience greater thermal extremes. All metal specimens whose preflight weights were known showed a weight change as a result of exposure. Optical property and mass changes are attributed principally to atomic oxygen exposures. Silver and copper were grossly affected whereas tantalum, molybdenum, and several preoxidized alloys were the least affected. Metals contained in this experiment are shown. Results including mass, surface morphology, and optical property changes from selected evaluations of these metals are presented.

Whitaker, Ann F.↗

Polymer matrix composites on LDEF experiments M0003-9 and M0003-10

Over 250 polymer matrix composites were exposed to the natural space environment on Long Duration Exposure Facility (LDEF) experiments M0003-9 and 10. The experiments included a wide variety of epoxy, thermoplastic, polyimide, and bismalimide matrix composites reinforced with graphite, glass, or organic fibers. A review of the significant observations and test results obtained to date is presented. Estimated recession depths from atomic oxygen exposure are reported and the resulting surface morphologies are discussed. The effects of the LDEF exposure on the flexural strength and modulus, short beam shear strength, and coefficient of thermal expansion of several classes of bare and coated composites are reviewed. Lap shear data are presented for composite-to-composite and composite-to-aluminum alloy samples that were prepared using different bonding techniques and subsequently flown on LDEF.

Steckel, Gary L.↗

Constraints on the thermal evolution of Venus inferred from Magellan data

The impact craters with diameters from 1.5 to 280 km compiled from Magellan observations indicate that the crater population on Venus has a completely spatially random distribution and the size/density distribution of craters with diameters greater than or equal to 35 km is consistent with a 'production' population with an age of 500 plus or minus 250 m.y. The similarity in size distribution from area to area indicates that the crater distribution is independent of crater size. Also, the forms of the modified craters are virtually identical to those of the pristine craters. These observations imply that Venus reset its cratering record by global resurfacing 500 m.y. ago, and resurfacing declined relatively fast. The fact that less than 40 percent of all craters have been modified and that the few volcanically embayed craters are located on localized tectonic regions indicate that only minor and localized volcanism and tectonism have occurred since the latest vigorous resurfacing event approximately 500 m.y. ago and the interior of Venus has been solid and possibly colder than Earth's. This is because the high-temperature lithosphere of Venus would facilitate upward ascending of mantle plumes and result in extensive volcanism if the venusian upper mantle were as hot as or hotter than Earth's. Therefore, the present surface morphology of Venus may provide useful constraints on the pattern of that vigorous convection, and possibly on the thermal state of the venusian mantle. We examine this possibility through numerical calculations of three-dimensional thermal convection models in a spherical shell with temperature- and pressure-dependent Newtonian viscosity, temperature-dependent thermal diffusivity, pressure-dependent thermal expansion coefficient, and time-dependent internal heat production rate solar magnitude.

Arkani-Hamed, Jafar↗

Internal strain analysis of ceramics using scanning laser acoustic microscopy

Quantitative studies of material behavior characteristics are essential for predicting the functionality of a material under its operating conditions. A nonintrusive methodology for measuring the in situ strain of small dimeter (to 11 microns) ceramic fibers under uniaxial tensile loading and the local internal strains of ceramics and ceramic composites under flexural loading is introduced. The strain measurements and experimentally observed mechanical behavior are analyzed in terms of the microstructural development and fracture behavior of each test specimen evaluated. Measurement and analysis of Nicalon silicon carbide (SiC) fiber (15 microns diameter) indicate that the mean elastic modulus of the individual fiber is 185.3 GPa. Deviations observed in the experimentally determined elastic modulus values between specimens were attributed to microstructural variations which occur during processing. Corresponding variations in the fracture surface morphology were also observed. The observed local mechanical behavior of a lithium alumino-silicate (LAS) glass ceramic, a LAS/SiC monofilament composite, and a calcium alumino-silicate (CAS)/SiC fully reinforced composite exhibits nonlinearities and apparent hysteresis due to the subcritical mechanical loading. Local hysteresis in the LAS matrices coincided with the occurrence of multiple fracture initiation sites, localized microcracking, and secondary cracking. The observed microcracking phenomenon was attributed to stress relaxation of residual stresses developed during processing, and local interaction of the crack front with the microstructure. The relaxation strain and stress predicted on apparent mechanical hysteresis effects were defined and correlated with the magnitude of the measured fracture stress for each specimen studied. This quantitative correlation indicated a repeatable measure of the stress at which matrix microcracking occurred for stress relief of each material system. Stress relaxation occurred prior to the onset of steady state cracking conditions. The relaxation stress occurred at 18.5 percent of the fracture stress in LAS and 11.0 percent of the yield stress in CAS/SiC. The relaxation stress ratio was dependent upon the dominant fracture mode of the LAS/SiC specimens. Relaxation stress ratios greater than 0.30 were observed for specimens which fractured due to shear at the fiber matrix interface; specimens which fracture due to tensile cracking had relaxation stress ratios less than 0.30. The stress relaxation ratio appeared to be a specific characteristic of the glass ceramic material. The measured stress relaxation for LAS indicated a measure of the inherent residual stresses in the material due to processing and suggested localized toughening mechanisms for brittle material structures.

Kent, Renee M.↗

Radiator technology

Radiator technology is discussed in the context of the Civilian Space Technology Initiative's (CSTI's) high capacity power-thermal management project. The CSTI project is a subset of a project to develop a piloted Mars nuclear electric propulsion (NEP) vehicle. The following topics are presented in vugraph form: advanced radiator concepts; heat pipe codes and testing; composite materials; radiator design and integration; and surface morphology.

Juhasz, Albert J.↗

Thermal control paints on LDEF: Results of M0003 sub-experiment 18

Several thermal control paints were flown on the Long Duration Exposure Facility (LDEF), including the white paints Chemglaze A276, S13GLO, and YB-71, and the black paint D-111. The effects of low earth orbit, which includes those induced by UV radiation and atomic oxygen, varied significantly with each paint and its location on LDEF. For example, samples of Chemglaze A276 located on the trailing edge of LDEF darkened significantly due to UV-induced degradation of the paint's binder, while leading edge samples remained white but exhibited severe atomic oxygen erosion of the binder. Although the response of S13GLO to low earth orbit is much more complicated, it also exhibited greater darkening on trailing edge samples as compared to leading edge samples. In contrast, YB-71 and D-111 remained relatively stable and showed minimal degradation. The performance of these paints as determined by changes in their optical and physical properties, including solar absorptance as well as surface chemical changes and changes in surface morphology is examined. It will also provide a correlation of these optical and physical property changes to the physical phenomena that occurred in these materials during the LDEF mission.

Jaggers, C. H.↗

Solid propellant exhausted aluminum oxide and hydrogen chloride - Environmental considerations

Measurements of gaseous hydrogen chloride (HCl) and particulate aluminum oxide (Al2O3) were made during penetrations of five Space Shuttle exhaust clouds and one static ground test firing of a shuttle booster. Instrumented aircraft were used to penetrate exhaust clouds and to measure and/or collect samples of exhaust for subsequent analyses. The focus was on the primary solid rocket motor exhaust products, HCl and Al2O3, from the Space Shuttle's solid boosters. Time-dependent behavior of HCl was determined for the exhaust clouds. Composition, morphology, surface chemistry, and particle size distributions were determined for the exhausted Al2O3. Results determined for the exhaust cloud from the static test firing were complicated by having large amounts of entrained alkaline ground debris (soil) in the lofted cloud. The entrained debris may have contributed to neutralization of in-cloud HCl.

Cofer, W. R., III↗

Low earth simulation and materials characterization

Oxygen plasma ashers and an electron cyclotron resonance (ECR) sources are currently being used for low Earth orbit (LEO) simulation. The suitability of each of these simulation techniques is considered. Thin film coatings are characterized by optical techniques, including variable-angle spectroscopic ellipsometry, optical spectrophotometry, and laser light scatterometry. Atomic force microscopy (AFM) has been used to characterize the surface morphology of thin aluminum films as a function of substrate temperature during deposition. Results on diamondlike carbon (DLC) films show that DLC degrades with simulated atomic oxygen (AO) exposure at a rate comparable to Kapton polyimide. Since DLC is not as susceptible as Kapton to environmental factors such as moisture absorption, it could potentially provide more accurate measurements of AO fluence on short space flights.

Synowicki, R. A.↗