SEARCH · Engineering Papers

Results for “spectral expansion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15

All sources NASA NTRS DOE OSTI

NASA NTRS1994

Coccolithophorid blooms in the global ocean

The global distribution pattern of coccolithophrid blooms was mapped in order to ascertain the prevalence of these blooms in the world's oceans and to estimate their worldwide production of CaCO3 and dimethyl sulfide (DMS). Mapping was accomplished by classifying pixels of 5-day global composites of coastal zone color scanner imagery into bloom and nonbloom classes using a supervised, multispectral classification scheme. Surface waters with the spectral signature of coccolithophorid blooms annually covered an average of 1.4 x 10(exp 6) sq km in the world oceans from 1979 to 1985, with the subpolar latitudes accounting for 71% of this surface area. Classified blooms were most extensive in the Subartic North Atlantic. Large expanses of the bloom signal were also detected in the North Pacific, on the Argentine shelf and slope, and in numerous lower latitude marginal seas and shelf regions. The greatest spatial extent of classified blooms in subpolar oceanic regions occurred in the months from summer to early autumn, while those in lower latitude marginal seas occurred in midwinter to early spring. Though the classification scheme was effcient in separating bloom and nonbloom classes during test simulations, and biogeographical literature generally confirms the resulting distribution pattern of blooms in the subpolar regions, the cause of the bloom signal is equivocal in some geographic areas, particularly on shelf regions at lower latitudes. Standing stock estimates suggest that the presumed Emiliania huxleyi blooms act as a significant source of calcite carbon and DMS sulfur on a regional scale. On a global scale, however, the satellite-detected coccolithophorid blooms are estimated to play only a minor role in the annual production of these two compounds and their flux from the surface mixed layer.

Brown, Christopher W.↗

NASA NTRS1997

On the Asymptotic Regimes and the Strongly Stratified Limit of Rotating Boussinesq Equations

Asymptotic regimes of geophysical dynamics are described for different Burger number limits. Rotating Boussinesq equations are analyzed in the asymptotic limit, of strong stratification in the Burger number of order one situation as well as in the asymptotic regime of strong stratification and weak rotation. It is shown that in both regimes horizontally averaged buoyancy variable is an adiabatic invariant for the full Boussinesq system. Spectral phase shift corrections to the buoyancy time scale associated with vertical shearing of this invariant are deduced. Statistical dephasing effects induced by turbulent processes on inertial-gravity waves are evidenced. The 'split' of the energy transfer of the vortical and the wave components is established in the Craya-Herring cyclic basis. As the Burger number increases from zero to infinity, we demonstrate gradual unfreezing of energy cascades for ageostrophic dynamics. The energy spectrum and the anisotropic spectral eddy viscosity are deduced with an explicit dependence on the anisotropic rotation/stratification time scale which depends on the vertical aspect ratio parameter. Intermediate asymptotic regime corresponding to strong stratification and weak rotation is analyzed where the effects of weak rotation are accounted for by an asymptotic expansion with full control (saturation) of vertical shearing. The regularizing effect of weak rotation differs from regularizations based on vertical viscosity. Two scalar prognostic equations for ageostrophic components (divergent velocity potential and geostrophic departure ) are obtained.

Babin, A.↗

DOE OSTI2025

Raman Fingerprints of Phase Transitions and Ferroic Couplings in van der Waals Multiferroic CuCrP 2 S 6

CuCrP 2 S 6 (CCPS), a type-II multiferroic material, exhibits unique phase transitions involving ferroelectric, antiferroelectric, and antiferromagnetic ordering. Here, in this study, we conduct a comprehensive investigation on the intricate phase transitions and their multiferroic couplings in CCPS across a wide temperature range from 4 to 345 K through Raman spectroscopic measurements down to 5 cm –1 . We first assign the observed Raman modes with the support of theoretical calculations and angle-resolved polarized Raman measurements. We further present clear signatures of phase transitions from the analyses of temperature-dependent Raman spectral parameters. Particularly, two low-frequency soft modes are observed at 36.1 cm –1 and 70.5 cm –1 below 145 K, indicating the antiferroelectric to quasi-antiferroelectric transition. Moreover, phonon mode hardening is observed when the temperature increases from 4 to 65 K, suggesting negative thermal expansion (NTE) and strong magnetoelastic coupling below 65 K. These findings advance the understanding of vdW multiferroic CCPS, paving the way for future design and engineering of multiferroicity in cutting-edge technologies, such as spintronics and quantum devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

The influence of laser energy on deuterium emission characteristics from a Zircaloy-4 plasma

Laser-produced plasma coupled with optical emission spectroscopy (OES) is a promising technique for detecting certain isotopes, with unique capabilities such as standoff and rapid detection and minimal to no sample preparation requirements. The key figure-of-merit for isotopic analysis using optical spectroscopy tools is the linewidth relative to the isotope shift. Although the isotopes of hydrogen (1H, 2H, and 3H) possess large isotopic shifts (1H–2H ≈ 180 pm, 1H–3H ≈ 240 pm), being a light element, the H transitions are susceptible to various broadening mechanisms in the plasma environment. One of the critical parameters that influence the linewidth of a transition in an LPP is the incident laser energy. In the present study, we evaluated the role of laser energy on plume expansion dynamics, deuterium emission intensity, and linewidth in a nanosecond laser-produced Zircaloy-4 plasma. The changes in 2Hα emission intensity and linewidth were investigated for varying laser fluence and time after plasma onset. Spatially resolved and spatially integrated OES were performed and compared to investigate the emission spectral features and linewidth of 2Hα. Monochromatic two-dimensional time-resolved imaging was also performed to understand the morphology of the deuterium and protium emission relative to all species in the plume. Our results showed that 1Hα and 2Hα emissions predominantly occur closer to the target. Measurements of 2Hα linewidth approached similar values at later times of plasma evolution regardless of the laser energy. The linewidths of the 2Hα transition showed insignificant differences between spatially resolved and spatially integrated measurements.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1974

Viscous, radiating hypersonic flow about a blunt body

The viscous, radiating hypersonic flow past an axisymmetric blunt body is analyzed based on the Navier-Stokes equations, plus a radiative equation of transfer derived from the Milne-Eddington differential approximation. The fluid is assumed to be a perfect gas with constant specific heats, a constant Prandtl number of order unity, a viscosity coefficient varying as a power of the temperature, and an absorption coefficient varying as the first power of the density and as a power of the temperature. The gray gas assumption is invoked, thereby making the absorption coefficient independent of the spectral frequency. Limiting forms of the solutions are studied as the freestream Mach number freestream Reynolds number and the temperature ratio across the shock wave, go to infinity, and as the Bouguer number and the density ratio across the shock wave go to zero. The method of matched asymptotic expansions is used in the analysis, and it is shown that there is a far-field precursor, composed of two regions, in which the fluid mechanics can be neglected for all practical purposes but included for completeness.

Passamaneck, R. S.↗

NASA NTRS2001

Effects of Eddy Viscosity on Time Correlations in Large Eddy Simulation

Subgrid-scale (SGS) models for large. eddy simulation (LES) have generally been evaluated by their ability to predict single-time statistics of turbulent flows such as kinetic energy and Reynolds stresses. Recent application- of large eddy simulation to the evaluation of sound sources in turbulent flows, a problem in which time, correlations determine the frequency distribution of acoustic radiation, suggest that subgrid models should also be evaluated by their ability to predict time correlations in turbulent flows. This paper compares the two-point, two-time Eulerian velocity correlation evaluated from direct numerical simulation (DNS) with that evaluated from LES, using a spectral eddy viscosity, for isotropic homogeneous turbulence. It is found that the LES fields are too coherent, in the sense that their time correlations decay more slowly than the corresponding time. correlations in the DNS fields. This observation is confirmed by theoretical estimates of time correlations using the Taylor expansion technique. Tile reason for the slower decay is that the eddy viscosity does not include the random backscatter, which decorrelates fluid motion at large scales. An effective eddy viscosity associated with time correlations is formulated, to which the eddy viscosity associated with energy transfer is a leading order approximation.

He, Guowei↗

NASA NTRS2000

A close-up look at Io from Galileo's near-infrared mapping spectrometer

Infrared spectral images of Jupiter's volcanic moon Io, acquired during the October and November 1999 and February 2000 flybys of the Galileo spacecraft, were used to study the thermal structure and sulfur dioxide distribution of active volcanoes. Loki Patera, the solar system's most powerful known volcano, exhibits large expanses of dark, cooling lava on its caldera floor. Prometheus, the site of long-lived plume activity, has two major areas of thermal emission, which support ideas of plume migration. Sulfur dioxide deposits were mapped at local scales and show a more complex relationship to surface colors than previously thought, indicating the presence of other sulfur compounds.

long duration↗

DOE OSTI2023

The Spectroscopic Data Processing Pipeline for the Dark Energy Spectroscopic Instrument

Abstract We describe the spectroscopic data processing pipeline of the Dark Energy Spectroscopic Instrument (DESI), which is conducting a redshift survey of about 40 million galaxies and quasars using a purpose-built instrument on the 4 m Mayall Telescope at Kitt Peak National Observatory. The main goal of DESI is to measure with unprecedented precision the expansion history of the universe with the baryon acoustic oscillation technique and the growth rate of structure with redshift space distortions. Ten spectrographs with three cameras each disperse the light from 5000 fibers onto 30 CCDs, covering the near-UV to near-infrared (3600–9800 Å) with a spectral resolution ranging from 2000 to 5000. The DESI data pipeline generates wavelength- and flux-calibrated spectra of all the targets, along with spectroscopic classifications and redshift measurements. Fully processed data from each night are typically available to the DESI collaboration the following morning. We give details about the pipeline’s algorithms, and provide performance results on the stability of the optics, the quality of the sky background subtraction, and the precision and accuracy of the instrumental calibration. This pipeline has been used to process the DESI Survey Validation data set, and has exceeded the project’s requirements for redshift performance, with high efficiency and a purity greater than 99% for all target classes.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1988

Theoretical studies of mass loss and shock phenomena in cool star envelopes

To show the difficulty of producing the blue-shifted emission of (O I) and (S II) from T Tauri stars directly in the stellar wind, an element of gas in a radially expanding stellar wind was followed as it cooled and recombined. Results indicate that T Tauri winds must be heated at large distances from the star to produce the (S II) emission. A shock between the wind and the disk is an attractive mechanism to produce this heating. When the theory is applied to a simple disk model, a number of predictions and implications are evident, for example, that some T Tauri stars eject mass near the equatorial plane. In a second study, spectral energy distributions of T Tauri stars were analyzed to place limits on the amount of accretion which might occur during the early phase of stellar evolution. The best match to H-alpha line profiles is for models in which the turbulent velocity dominates close to the star, while expansion dominates farther out. Such a model predicts, for instance, that a mass loss rate of 1/10,000,000 solar masses per year is required to account for the blue-shifted Na I absorption of some objects.

Hartmann, Lee↗

NASA NTRS1993

High-resolution X-ray spectroscopy of the supernova remnant N132D

A joint nonequilibrium ionization analysis of spectral data from the Einstein Observatory of the SNR N132D in the LMC is presented on the basis of data from the Focal Plane Crystal Spectrometer (FPCS) and the Solid State Spectrometer (SSS), and lower spectral resolution data from the IPC and the Monitor Proportional Counter (MPC). The FPCS detected individual emission lines of O VII, O VIII, Ne IX, Ne X, Fe XVII, and possibly Fe XX. Measured line widths for the oxygen lines suggest Doppler broadening that is roughly consistent with optically measured expansion velocities of 2250 km/s. At the SSS/IPC temperature, FPCS flux ratios constrain the O/Fe abundance to be at least 1.9 times its solar value and the O/Ne abundance to be 0.2-1.0 times its solar value. Models for remnants with progenitor masses of 20 and 25 solar masses are completely consistent with the data, while remnants with progenitor masses of 13 and 15 solar masses can be made consistent if the progenitors are required to eject a large fraction of their iron cores.

Hwang, Una↗

NASA NTRS1985

Adiabatic deceleration of secondary antiprotons in the envelopes of supernova exploding in dense clouds

On the basis of well established cosmic ray propagation models, the expected flux of antiprotons in cosmic rays within the few-hundred MeV region is small by comparison with the observed flux. Observational data are presently approached through the examination of the possibility of antiproton production by supernova (SN) envelopes during the expansion phase and while undergoing the consequent adiabatic deceleration. In the case of the SN explosions in dense clouds treated, the SN remnant is decelerated within a few thousand years, generating may antiprotons whose spectrum can be calculated by taking all energy loss processes into account and examining the remnant's spectral evolution. Attention is also given to the possibility of obtaining the antiproton spectrum with enhanced flux at low energies.

Stephens, S. A.↗

NASA NTRS1985

Dispersion characteristics for wide slotlines on low-permittivity substrates

A spectral-domain Galerkin method is used to calculate the dispersion characteristics of wide slotlines on low-permittivity substrates that are electrically thin. The range of parameters covered are d/lambda sub 0 = 0.006-0.06, W/lambda sub 0 = 0.005-2.0, and epsilon sub r = 2.22, 3.0, 3.8, and 9.8. The choice of expansion and testing functions makes possible the extraction of the asymptotic form of the infinite integrals, resulting in a computationally efficient solution. The agreement between calculated and measured slot wavelengths on narrow and wide slots is generally within 2.0 percent over 2-6 GHz.

Janaswamy, R.↗

NASA NTRS1989

Fourier transform methods in local gravity modeling

New algorithms were derived for computing terrain corrections, all components of the attraction of the topography at the topographic surface and the gradients of these attractions. These algoriithms utilize fast Fourier transforms, but, in contrast to methods currently in use, all divergences of the integrals are removed during the analysis. Sequential methods employing a smooth intermediate reference surface were developed to avoid the very large transforms necessary when making computations at high resolution over a wide area. A new method for the numerical solution of Molodensky's problem was developed to mitigate the convergence difficulties that occur at short wavelengths with methods based on a Taylor series expansion. A trial field on a level surface is continued analytically to the topographic surface, and compared with that predicted from gravity observations. The difference is used to compute a correction to the trial field and the process iterated. Special techniques are employed to speed convergence and prevent oscillations. Three different spectral methods for fitting a point-mass set to a gravity field given on a regular grid at constant elevation are described. Two of the methods differ in the way that the spectrum of the point-mass set, which extends to infinite wave number, is matched to that of the gravity field which is band-limited. The third method is essentially a space-domain technique in which Fourier methods are used to solve a set of simultaneous equations.

Harrison, J. C.↗

NASA NTRS2006

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions. A New Generation of Laboratory & Space Studies

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. A long-standing and major challenge for laboratory astrophysics has been to measure the spectra of large carbon molecules in laboratory environments that mimic (in a realistic way) the physical conditions that are associated with the interstellar emission and absorption regions [1]. This objective has been identified as one of the critical Laboratory Astrophysics objectives to optimize the data return from space missions [2]. An extensive laboratory program has been developed to assess the properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space. We present and discuss the gas-phase electronic absorption spectra of neutral and ionized PAHs measured in the UV-Visible-NIR range in astrophysically relevant environments and discuss the implications for astrophysics [1]. The harsh physical conditions of the interstellar medium characterized by a low temperature, an absence of collisions and strong VUV radiation fields - have been simulated in the laboratory by associating a pulsed cavity ringdown spectrometer (CRDS) with a supersonic slit jet seeded with PAHs and an ionizing, penning-type, electronic discharge. We have measured for the {\it first time} the spectra of a series of neutral [3,4] and ionized [5,6] interstellar PAHs analogs in the laboratory. An effort has also been attempted to quantify the mechanisms of ion and carbon nanoparticles production in the free jet expansion and to model our simulation of the diffuse interstellar medium in the laboratory [7]. These experiments provide {\it unique} information on the spectra of free, large carbon-containing molecules and ions in the gas phase. We are now, for the first time, in the position to directly compare laboratory spectral data on free, cold, PAH ions and carbon nano-sized carbon particles with astronomical observations in the UV-NIR range (interstellar UV extinction, DIBs in the NUV-NIR range). This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems Le., the "new frontier space missions" (Spitzer, HST, COS, JWST, SOFIA,...).

Salama, Farid↗

DOE OSTI2025

Ab-initio simulation of spin-vibronic spectra of methoxy radical

Despite the fact that experimental and theoretical work on the spectrum of methoxy has stretched from the microwave to the ultraviolet and proceeded for nearly 50 years, parts of the spectrum have remained a challenge to simulate theoretically and make reliable line-by-line assignments. The spectral complexity arises because the radical has a non-zero electron spin and significant vibronic coupling between the two elec- tronic components of the ground state due to the presence of a conical intersection. This work describes a completely ab initio effort to understand and assign the spin- vibronic levels of the X 2E state from 0 to above 3000 cm−1, a region that includes the fundamental transitions of the C-H symmetric and asymmetric stretches that have not previously been identified uniquely. A potential energy surface for methoxy was calculated at the EOM-CCSDT/ANO1 level of theory. Subsequently this potential energy surface was fit to a quartic power series expansion of all nine vibrational nor- mal coordinates (as determined at the minimum of the conical intersection) by the use of a machine-learning-based algorithm. After the addition of spin-orbit coupling, the spin-vibronic problem was solved using both the Krylov-Schur and Lanczos algorithms with the SOCJT3 software to converge eigenvalues up to 3500 cm−1 and their eigen- vectors. The latter were used, in conjunction with the calculated dipole moment and its derivatives (calculated using finite differences at EOM-CCSDT/ANO1 level), to determine spectral intensities for the spin-vibronic spectra. The calculated transition frequencies and intensities were used to simulate and assign the observed transitions of the spin-vibronic spectra of the radical. The credibility of the assignments and their significance is discussed in detail.

Sharma, Ketan [University of Florida, Gainesville,↗

NASA NTRS1990

The millimeter- and submillimeter-wave spectrum of (C-13)H3OH revisited

A total of 245 previously unobserved millimeter- and submillimeter-wave transitions of (C-13)H3OH for J not above 10 were assigned on the basis of measurements with a spectrometer which uses 40-60 GHz klystrons as fundamental radiation sources. These transitions were combined with the previously assigned 596 transitions and were analyzed using a modified internal-axis-method model which treats the symmetric (A) and degenerate (E) substates separately. As a result of the expansion of the (C-13)H3OH data set to cover the same range as the data set of a previous (C-12)H3OH analysis by Anderson et al. (1990), rigid criteria of self-consistency could be applied for the selection and the value of the constants between the isotopic species. The spectral constants obtained were used to make accurate predictions of 562 additional transitions of (C-13)H3OH for v(t) = 0, 1, 2 and rotational quantum number J equal to or less than 12.

Anderson, Todd↗

NASA NTRS1991

A nonthermal radio halo surrounding M82

Radio maps at several frequencies are presented which reveal an extended halo of nonthermal emission surrounding the starburst galaxy M82. The origin of this halo is probably synchrotron radiation from relativistic electrons originally produced in SNR, swept out of the disk by the extensive wind associated with the galaxy. The halo appears to be asymmetrical, with an enhancement occurring about 1 arcmin to the south, and on a larger scale there is excess emission to the north. Possible causes of this effect are addressed. The spectral index measured using data at 6, 20, 49, and 90 cm is about -0.4 + or - 0.1 in the nucleus, steepening to about -1.0 in the halo. A simple model is invoked which involves outward convection of relativistic particles with electron energy losses by inverse Compton scattering against IR photons and adiabatic expansion.

Seaquist, E. R.↗

DOE OSTI2021

Radiation Belt Response to Fast Reverse Shock at Geosynchronous Orbit

Fast reverse shocks (FRSs) cause the magnetosphere to expand, by contrast to the well-known compressions caused by the impact of fast forward shocks (FFS). Usually, FFSs are more geoeffective than FRSs, and consequently the inner magnetosphere dynamic responses to both shock types can be quite different. In this study, we investigate for the first time the radiation belt response to an FRS impact using multi-satellite observations and numerical simulations. Spacecraft on the dayside observed decreases in magnetic field strength and energetic (~40–475 keV) particle fluxes. Timing analysis shows that the magnetic field signature propagated from the dayside to the nightside magnetosphere. Particles with different energies vary simultaneously at each spacecraft, implying a non-dispersive particle response to the shock. Spacecraft located at lower L-shells did not record any significant signatures. The observations indicate a local time dependence of the response associated with the shock inclination, with the clearest signatures being observed in the dusk–midnight sector. Simulations underestimate the amplitude of the magnetic field variations observed on the nightside. The observed decreases in the electron intensities result from a combination of radial gradient and adiabatic effects. The radial gradients in the spectral index appear to be the dominant contributor to the observed variations of electrons seen on the dayside (near noon and dusk) and on the nightside (near midnight). This work shows that even an FRS can affect the radiation belts significantly and provides an opportunity to understand their dynamic response to a sudden expansion of the magnetosphere.

79 ASTRONOMY AND ASTROPHYSICS↗