Development of optical coatings for cds thin film solar cells second quarterly report, 1 mar. - 1 jun. 1965
Optical coatings for cadmium sulfide thin film solar cells
CADMIUM SULFIDE↗
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Results for “solar optics”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Solar active regions associated with some individual events
Optical observations of solar active regions associated with some individual events
OPTICAL INSTRUMENT↗
Thermodynamically Stable, Plasmonic Transition Metal Oxide Nanoparticle Solar Selective Absorbers towards 95% Optical-to-Thermal Conversion Efficiency at 750 °C
Generation 3 (Gen) concentrating solar power (CSP) systems requires a high operation temperature ≥750°C to increase the power-cycle efficiency towards ≥50%. However, such a high operation temperature poses a notable challenge to high temperature materials. On the receiver side, a critical challenge is the lack of solar selective absorbers that demonstrate both high optical-to-thermal energy conversion efficiency η therm approaching 95% and long-term thermal stability at >750°C in air. Existing solar absorbers either have limited η therm ≤89% or deteriorate significantly within 500 h at 750°C; some of these also require costly vacuum deposition for stringent thickness control. Therefore, it is highly desirable to simultaneously achieve η therm ~95% AND high thermal stability at 750°C for future generations of CSP receivers. This project has investigated and developed low-cost, highly scalable spray-coated transition metal oxide nanoparticle (NP) pigmented solar selective coatings on various types of Inconel alloy tube sections that are thermodynamically stable at 750-800°C in air, maintaining η therm >94.3%(93.2%) under a solar concentration ratio of C=1000 after 60 simulated day-night cycles at 750ºC (800ºC) (1 cycle=12 h at 750 or 800°C and 12h ramping down to 25°C). We have also coated up to 48 inches long receiver tubes for preliminary solar testing under Norwich Technology’s parabolic trough systems, demonstrating notably improved performance in solar heating compared to benchmark Pyromark 2500 coatings. Two key innovations have been developed in this project: (1) We achieved an unprecedented high thermal efficiency >94% by optimizing the d-band optical absorption spectra of transition metal ions, engineering their valences and stoichiometry; (2) We were able to maintain or even slightly increase the efficiency when operating at 750°C in air by engineering the interdiffusion of transition metal ions between the coating and the Inconel substrate to our advantage. Featuring high-temperature solar spectral selectivity and thermodynamic stability in air, as well as low-cost, highly scalable solution-chemical synthesis and spray coating techniques, this innovation in solar selective absorber technology alone accounts for nearly 40% of the targeted reduction in the levelized cost of electricity (LCOE) from the receiver, thermal energy storage, and operation & maintenance combined by 2030, as proposed by the U.S. Department of Energy. For a 110 MWe CSP power plant, this LCOE reduction from the solar selective coating alone transfers to ~$\$ $1.9 M increase in annual profit based on a sales price of 10¢/kWh (or an annual sale of $50 M/year). The high solar absorptance (~98%) NP pigment materials developed in this project are equally applicable to volumetric receivers either as a coating or as bigger ceramic microspheres after sintering, potentially benefiting Gen3 falling particle CSP technologies. All these contributions facilitate the larger scale deployment of CSP systems with energy storage capability to address the intermittency issue of solar energy towards dispatchable solar electricity, bridging the temporal gap between peak solar electricity production and peak electricity consumption. The collaboration with Norwich Technologies and Brayton Energy in this project will also facilitate the future commercialization of this new solar selective coating technology developed in this SIPS project.
14 SOLAR ENERGY↗
mfrsr7nchlangley
Langley analysis of 7 narrowband channel mfrsr instrument, to derive solar constants and optical depths.
54 ENVIRONMENTAL SCIENCES↗
Active cavity radiometer
The active cavity radiometer (ACR) experiment on the Spacelab 1 mission to measure the total solar irradiance is discussed. Short and long term variations in the total solar output of optical energy are studied. Solar total irradiance observation provides information on the solar cycle and other long term trends in solar output that are of climatological significance as well as short term solar physics phenomena. The interaction of solar radiation with the Earth's atmosphere, oceans, and land masses provides the primary driving forces for the formation of weather systems and the determination of climate. Astrophysical measurements determine the total energy flux. The principal role of the ACR observations support extended solar irradiance experiments on free flying satellites. Solar irradiance measurements are important in the establishment of the radiation scale at the solar total flux level in the international system of units (SI).
Willson, R. C.↗
Luminescent solar concentrators and related methods of manufacturing
Luminescent solar concentrators in accordance with various embodiments of the invention can be designed to minimize photon thermalization losses and incomplete light trapping using various components and techniques. Cadmium selenide core, cadmium sulfide shell (CdSe/CdS) quantum dot (“QD”) technology can be implemented in such devices to allow for near-unity QDs and sufficiently large Stokes shifts. Many embodiments of the invention include a luminescent solar concentrator that incorporates CdSe/CdS quantum dot luminophores. In further embodiments, anisotropic luminophore emission can be implemented through metasurface/plasmonic antenna coupling. In several embodiments, red-shifted luminophores are implemented. Additionally, top and bottom spectrally-selective filters, such as but not limited to selectively-reflective metasurface mirrors and polymeric stack filters, can be implemented to enhance the photon collection efficiency. In some embodiments, luminescent solar concentrator component is optically connected in tandem with a planar Si subcell, forming a micro-optical tandem luminescent solar concentrator.
Needell, David R.↗
Reflected fluxes for broken clouds over a Lambertian surface
Reflected fluxes are calculated for broken cloudiness (i.e., nonplane parallel) as a function of cloud cover, cloud optical depth, solar zenith angle and surface albedo. These calculations extend previous results for broken cloud reflected fluxes over a black surface. The present study demonstrates that not only radiances but also radiative fluxes over high albedo surfaces may be decreased by the presence of broken cloudiness. Conventional wisdom states that cloud radiances (brightnesses) are always greater than the background. While most cloud retrieval schemes are built around this assumption, it is incorrect for clouds over high albedo surfaces such as found in polar regions. However, the most startling and counterintuitive conclusion of this study is that nonabsorbing finite clouds over a highly reflecting surface will decrease the system albedo. As a result, surface absorption is increased, the result of multiple scattering between surface and cloud layer, controlled by cloud morphology and cloud optical thickness. A simple parameterization of the effects of cloud contamination upon retrieved albedo is given in terms of solar zenith angle, cloud optical depth, surface albedo, cloud cover, and plane-parallel cloud albedo. In this way, the effects of broken cloudiness are modeled in terms of easily computed plane-parallel values.
Welch, Ronald M.↗
Contamination of optical surfaces
The effect of molecular contamination on Space Station optical surfaces is examined. In particular, contamination of solar voltaic power sources and optical solar reflectors for thermal control or solar dynamic power generation is addressed. The published Space Station requirements for molecular contamination accretion and for the monitoring of such accretion is discussed in the context of the historical performance of space systems. Specific reference is made to the results from the Spacecraft Charging at High Altitudes (SCATHA) ML12 experiment.
Arnold, Graham S.↗
On-Orbit Measurements of Solar Exclusion Angle for Modular Agile Scalable Optical Terminal (MAScOT) on the ILLUMA-T Mission
The Integrated LCRD Low-Earth Orbit User Modem and Amplifier Terminal (ILLUMA-T) optical communications payload operated on the International Space Station (ISS) for 8 months, concluding in June 2024. ILLUMA-T made the ISS the first space-based user to communicate with NASA’s Laser Communications Relay Demonstration (LCRD). ILLUMA-T was also the first flight demonstration of the Modular, Agile, Scalable Optical Terminal (MAScOT) which will also be used in the Orion Artemis II Optical Communications (O2O) program, where it will provide an optical communications link for the crew aboard the Artemis II mission. Often optical and radio frequency communications systems have outages when they are pointing close to the Sun, where unwanted incident and scattered solar energy significantly reduces or prohibits operations. The MAScOT was designed to reduce the impact of any solar scatter through optical design, material choices, surface treatments and high cleanliness levels. Based on optical scattering models, a solar exclusion angle of 10 degrees was established for ILLUMA-T. This paper presents optical scattering modeling predictions, pre-launch laboratory testing results, and on-orbit measurements of solar scatter at angles ranging from 3 to 25 degrees.
optical communications↗
Solar Effects on Tensile and Optical Properties of Hubble Space Telescope Silver-Teflon(Registered Trademark) Insulation
A section of the retrieved Hubble Space Telescope (HST) solar array drive arm (SADA) multilayer insulation (MLI), which experienced 8.25 years of space exposure, was analyzed for environmental durability of the top layer of silver-Teflon (DuPont) fluorinated ethylene propylene (Ag-FEP). Because the SADA MLI had solar and anti-solar facing surfaces and was exposed to the space environment for a long duration, it provided a unique opportunity to study solar effects on the environmental degradation of Ag-FEP, a commonly used spacecraft thermal control material. Data obtained included tensile properties, solar absorptance, surface morphology and chemistry. The solar facing surface was found to be extremely embrittled and contained numerous through-thickness cracks. Tensile testing indicated that the solar facing surface lost 60% of its mechanical strength and 90% of its elasticity while the anti-solar facing surface had ductility similar to pristine FEP. The solar absorptance of both the solar facing surface (0.155 plus or minus 0.032) and the anti-solar facing surface (0.208 plus or minus 0.012) were found to be greater than pristine Ag-FEP (0.074). Solar facing and anti-solar facing surfaces were microscopically textured, and locations of isolated contamination were present on the anti-solar surface resulting in increased localized texturing. Yet, the overall texture was significantly more pronounced on the solar facing surface indicating a synergistic effect of combined solar exposure and increased heating with atomic oxygen erosion. The results indicate a very strong dependence of degradation, particularly embrittlement, upon solar exposure with orbital thermal cycling having a significant effect.
deGroh, Kim, K.↗
A Solar Reflectance Method for Retrieving Cloud Optical Thickness and Droplet Size Over Snow and Ice Surfaces
Cloud optical thickness and effective radius retrievals from solar reflectance measurements are traditionally implemented using a combination of spectral channels that are absorbing and non-absorbing for water particles. Reflectances in non-absorbing channels (e.g., 0.67, 0.86, 1.2 micron spectral window bands) are largely dependent on cloud optical thickness, while longer wavelength absorbing channels (1.6, 2. 1, and 3.7 micron window bands) provide cloud particle size information. Cloud retrievals over ice and snow surfaces present serious difficulties. At the shorter wavelengths, ice is bright and highly variable, both characteristics acting to significantly increase cloud retrieval uncertainty. In contrast, reflectances at the longer wavelengths are relatively small and may be comparable to that of dark open water. A modification to the traditional cloud retrieval technique is devised. The new algorithm uses only a combination of absorbing spectral channels for which the snow/ice albedo is relatively small. Using this approach, retrievals have been made with the MODIS Airborne Simulator (MAS) imager flown aboard the NASA ER-2 from May - June 1998 during the Arctic FIRE-ACE field deployment. Data from several coordinated ER-2 and University of Washington CV-580 in situ aircraft observations of liquid water stratus clouds are examined. MAS retrievals of optical thickness, droplet effective radius, and liquid water path are shown to be in good agreement with the in situ measurements. The initial success of the technique has implications for future operational satellite cloud retrieval algorithms in polar and wintertime regions.
Platnick, S.↗
Fine Pitch Grids for an X-Ray Solar Imaging Spectrometer Fabricated by Optical Lithography and XeF2 Etching
Fine-pitch, sub-collimating X-ray grids have been developed for an instrument in the High Energy Solar Spectroscopic Imager , a proposed NASA mission. In addition to high-energy x- rays, the instrument requires collimation of photons with energies of less than 4 keV such that free-standing grids are required that have no material between the grid slats. Fabrication of these grids is described.
x-ray↗
Advances in second generation ultra-low power CMOS active pixel sensor imagers for remote sensing, star tracking, optical comm and low cost solar array/antenna boom deployment metrology
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camera-on-a-chip remote sensing star tracking opti↗
Cosine-corrected optical diffuser
In solar energy utilization studies, correct measurements of flux arriving at other angles to optical axis must be given. Developed device (Cosine diffuser) significantly reduces measurement errors. In combination of radiation transmitter and diffuser co-operating with collimated optical instrument, relative aperture of instrument is filled.
Estey, R. S.↗
End-to-End System Test and Optical Performance Evaluation for the Solar and Heliosphere Observatory (SOHO) Ultraviolet Coronagraph Spectrometer (UVCS)
The UVCS is one of the instruments carried by the Solar and Heliospheric Observatory (SOHO), a joint NASA/ESA Spacecraft launched in November 1995. It is designed to perform ultraviolet spectroscopy and visible light polarimetry of the extended solar corona. The primary scientific objectives of the UVCS investigation are to study the physical processes occurring in the extended solar corona, such as: the mechanism of acceleration of the solar wind, the mechanism of coronal plasma heating, the identification of solar wind sources, and the investigation of the plasma properties of the solar wind. The UVCS End-to-End test activities included a comprehensive set of system level functional and optical tests. Although performed under severe schedule constraints, the End-to-End System Test was very successful and served to fully validate the UVCS optical design. All test results showed that the primary scientific objectives of the UVCS Mission were achievable.
Carosso, Paolo A.↗
Polarization aberrations in the solar activity measurements experiments (SAMEX) solar vector magnetograph
An optical design and polarization analysis of the Air Force/NASA Solar Activity Measurements Experiments solar vector magnetograph optical system is performed. Polarization aberration theory demonstrates that conventional telescope coating designs introduce unacceptably high levels of polarization aberrations into the optical system. Several ultralow polarization mirror and lens coatings designs for this instrument are discussed. Balancing of polarization aberrations at different surfaces is demonstrated.
Mcguire, James P., Jr.↗
Thermal Materials and Coatings for Near Rectilinear Halo Orbit (NRHO)
Passive thermal control of a spacecraft is reliant on external surface optical properties (solar absorptivity and IR emissivity), which degrade over time depending on length of mission, material or coating, and natural and induced environments. Understanding the degradation and resulting End of Life (EOL) optical properties enables optimization of the thermal performance and reduces risk. The environmental factors that affect degradation of materials and coatings include UV, solar wind, vacuum, contamination, lunar dust, atomic oxygen, and more. Future spacecraft such as Gateway will be flying in the Near Rectilinear Halo Orbit (NRHO), an environment that has not been flown before and environmental factors are different from Low Earth Orbit. There is no on orbit data for materials in this environment, and optical property data from on-orbit and ground experiments for other environments is of limited use. This 1.5 hour short course will explore optical properties and degradation by introducing the expected environment of NRHO, types of materials and coatings that could be used, how to estimate their EOL properties, and future work. This course will focus on the NRHO environment, but it will be beneficial for anyone interested in optical property degradation in the space environment.
Optics↗
Thermodynamic limits for simultaneous energy harvesting from the hot sun and cold outer space
The sun and outer space are two of the most important fundamental thermodynamic resources for renewable energy harvesting. A significant amount of work has focused on understanding the fundamental limit of energy harvesting from the sun. More recently, there have been several theoretical analyses of the fundamental limit of energy harvesting from outer space. However, far less is understood about the fundamental limits of simultaneous energy harvesting from both the sun and outer space. Here, we consider and introduce various schemes that are capable of simultaneous energy harvesting and elucidate the fundamental thermodynamic limits of these schemes. We show that the theoretical limits can far exceed the previously established limit associated with utilizing only one thermodynamic resource. Our results highlight the significant potential of simultaneous energy harvesting and indicate new fundamental opportunities for improving the efficiency of energy harvesting systems.
14 SOLAR ENERGY↗