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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

A Novel Method for Remediation of PCBs in Weathered Coatings

Polychlorinated biphenyls (PCBs) are a group of synthetic aromatic compounds with the general formula C 12H1oCl that were historically used in industrial paints, caulking material and adhesives, as their properties enhanced structural integrity, reduced flammability and boosted antifungal properties. Although the United States Environmental Protection Agency (USEPA) has banned the manufacture of PCBs since 1979, they have been found in at least 500 of the 1,598 National Priorities List (Superfund) sites identified by the USEPA. Prior to the USEPA's ban on PCB production, PCBs were commonly used as additives in paints and asphalt-based adhesives that were subsequently applied to a variety of structures. Government facilities constructed as early as 1930 utilized PCB-containing binders or PCB-containing paints, which are now leaching into the environment and posing ecological and worker health concerns. To date, no definitive in situ, non-destructive method is available for the removal of PCBs found in weathered coatings or on painted structures/equipment. The research described in this paper involves the laboratory development and field-scale deployment of a new and innovative solution for the removal and destruction of PCBs found in painted structures or within the binding or caulking material on structures. The technology incorporates a Bimetallic Treatment System (BTS) that extracts and degrades only the PCBs found on the facilities, leaving the structure virtually unaltered.

Brooks, Kathleen B.↗
NASA NTRS2012

Zero-Valent Metallic Treatment System and Its Application for Removal and Remediation of Polychlorinated Biphenyls (Pcbs)

PCBs are removed from contaminated media using a treatment system including zero-valent metal particles and an organic hydrogen donating solvent. The treatment system may include a weak acid in order to eliminate the need for a coating of catalytic noble metal on the zero-valent metal particles. If catalyzed zero-valent metal particles are used, the treatment system may include an organic hydrogen donating solvent that is a non-water solvent. The treatment system may be provided as a "paste-like" system that is preferably applied to natural media and ex-situ structures to eliminate PCBs.

Quinn, Jacqueline W.↗
NASA NTRS2012

Active Debris Removal and the Challenges for Environment Remediation

Recent modeling studies on the instability of the debris population in the low Earth orbit (LEO) region and the collision between Iridium 33 and Cosmos 2251 have underlined the need for active debris removal. A 2009 analysis by the NASA Orbital Debris Program Office shows that, in order to maintain the LEO debris population at a constant level for the next 200 years, an active debris removal of about five objects per year is needed. The targets identified for removal are those with the highest mass and collision probability products in the environment. Many of these objects are spent upper stages with masses ranging from 1 to more than 8 metric tons, residing in several altitude regions and concentrated in about 7 inclination bands. To remove five of those objects on a yearly basis, in a cost-effective manner, represents many challenges in technology development, engineering, and operations. This paper outlines the fundamental rationale for considering active debris removal and addresses the two possible objectives of the operations -- removing large debris to stabilize the environment and removing small debris to reduce the threat to operational spacecraft. Technological and engineering challenges associated with the two different objectives are also discussed.

Liou, J. C.↗
NASA NTRS2012

Laser Remediation of Threats Posed by Small Orbital Debris

The continually increasing amount of orbital debris in near Earth space poses an increasing challenge to space situational awareness. Recent collisions of spacecraft caused abrupt increases in the density of both large and small debris in near Earth space. An especially challenging class of threats is that due to the increasing density of small (1 mm to 10 cm dimension) orbital debris. This small debris poses a serious threat since: (1) The high velocity enables even millimeter dimension debris to cause serious damage to vulnerable areas of space assets, e.g., detector windows; (2) The small size and large number of debris elements prevent adequate detection and cataloguing. We have identified solutions to this threat in the form of novel laser systems and novel ways of using these laser systems. While implementation of the solutions we identify is challenging we find approaches offering threat mitigation within time frames and at costs of practical interest. We base our analysis on the unique combination of coherent light specifically structured in both space and time and applied in novel ways entirely within the vacuum of space to deorbiting small debris. We compare and contrast laser based small debris removal strategies using ground based laser systems with strategies using space based laser systems. We find laser systems located and used entirely within space offer essential and decisive advantages over groundbased laser systems.

Fork, Richard L.↗
NASA NTRS2009

A New Formulation for the Removal and Remediation of Polychlorinated Biphenyls in Painted Structures

This new technology report will describe the laboratory development of a new and innovative solution for the removal and destruction of PCBs found in painted structures or within the binding or caulking material on structures. The technology incorporates a Bimetallic Treatment System (BTS) that extracts and degrades only the PCBs found on the facilities, leaving in most cases the structure virtually unaltered.

Quinn, Jacqueline↗
NASA NTRS2006

Bimetallic Treatment System (BTS) for Removal and Remediation of Polychlorinated Biphenyl from Marshall Space Flight Center's 4696 Fl Stand

This Office of Space Flight (OSF)-funded project sought to demonstrate the application of a Bi-metallic Treatment System (BTS) to remove and degrade PCBs found on NASA facilities. The project initiated with the collection of PCB-containing materials from various MSFC and KSC structures, followed by laboratory evaluation of the BTS' PCB-removal efficiency, and concluded with a field demonstration at MSFC. The project evaluated the optimum formulation required to remove PCBs from aged and weathered paint with the goal of achieving final PCB concentrations less than 50 mg/Kg or 50 percent reduction where PCB starting levels were already below the 50 mg/Kg levels. Using lessons learned from this study, it was anticipated that the research team would be better able to make further recommendation on application strategies for future use of BTS for the treatment of PCB laden coatings on structures.

Quinn, Jacqueline↗
NASA NTRS2013

Trace Contaminant Control: An In-Depth Study of a Silica-Titania Composite for Photocatalytic Remediation of Closed-Environment Habitat Air

This collection of studies focuses on a PCO system for the oxidation of a model compound, ethanol, using an adsorption-enhanced silica-TiO2 composite (STC) as the photocatalyst; studies are aimed at addressing the optimization of various parameters including light source, humidity, temperature, and possible poisoning events for use as part of a system for gaseous trace-contaminant control system in closed-environment habitats. The first goal focused on distinguishing the effect of photon flux (i.e., photons per unit time reaching a surface) from that of photon energy (i.e., wavelength) of a photon source on the PCO of ethanol. Experiments were conducted in a bench-scale annular reactor packed with STC pellets and irradiated with either a UV-A fluorescent black light blue lamp O max=365 nm) at its maximum light intensity or a UV-C germicidal lamp O. max=254 nm) at three levels of light intensity. The STC-catalyzed oxidation of ethanol was found to follow zero-order kinetics with respect to CO2 production, regardless of the photon source. Increased photon flux led to increased EtOH removal, mineralization, and oxidation rate accompanied by lower intermediate concentration in the effluent. The oxidation rate was higher in the reactor irradiated by UV-C than by UV-A (38.4 vs. 31.9 nM s-1 ) at the same photon flux, with similar trends for mineralization (53.9 vs. 43.4%) and reaction quantum efficiency (i.e., photonic efficiency, 63.3 vs. 50.1 nmol C02 ~mol photons-1 ). UV-C irradiation also led to decreased intermediate concentration in the effluent compared to UV -A irradiation. These results demonstrated that STC-catalyzed oxidation is enhanced by both increased photon flux and photon energy. The effect of temperature and relative humidity on the STC-catalyzed degradation of ethanol was also determined using the UV-A light source at its maximum intensity.

Coutts, Janelle L.↗
NASA NTRS2013

The Orbital Debris Problem and the Challenges for Environment Remediation

Orbital debris scientists from major international space agencies, including JAXA and NASA, have worked together to predict the trend of the future environment. A summary presentation was given to the United Nations in February 2013. The orbital debris population in LEO will continue to increase. Catastrophic collisions will continue to occur every 5 to 9 years center dot To limit the growth of the future debris population and to better protect future spacecraft, active debris removal, should be considered.

Liou, J.-C.↗