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At least 271 records · Page 15

Electrolytes for Low-Temperature Operation of Li-CFx Cells

A report describes a study of electrolyte compositions selected as candidates for improving the low-temperature performances of primary electrochemical cells that contain lithium anodes and fluorinated carbonaceous (CFx) cathodes. This study complements the developments reported in Additive for Low-Temperature Operation of Li-(CF)n Cells (NPO- 43579) and Li/CFx Cells Optimized for Low-Temperature Operation (NPO- 43585), which appear elsewhere in this issue of NASA Tech Briefs. Similar to lithium-based electrolytes described in several previous NASA Tech Briefs articles, each of these electrolytes consisted of a lithium salt dissolved in a nonaqueous solvent mixture. Each such mixture consisted of two or more of the following ingredients: propylene carbonate (PC); 1,2-dimethoxyethane (DME); trifluoropropylene carbonate; bis(2,2,2-trifluoroethyl) ether; diethyl carbonate; dimethyl carbonate; and ethyl methyl carbonate. The report describes the physical and chemical principles underlying the selection of the compositions (which were not optimized) and presents results of preliminary tests made to determine effects of the compositions upon the low-temperature capabilities of Li-CFx cells, relative to a baseline composition of LiBF4 at a concentration of 1.0 M in a solvent comprising equal volume parts of PC and DME.

Smart, Marshall C.↗

Li/CFx Cells Optimized for Low-Temperature Operation

Some developments reported in prior NASA Tech Briefs articles on primary electrochemical power cells containing lithium anodes and fluorinated carbonaceous (CFx) cathodes have been combined to yield a product line of cells optimized for relatively-high-current operation at low temperatures at which commercial lithium-based cells become useless. These developments have involved modifications of the chemistry of commercial Li/CFx cells and batteries, which are not suitable for high-current and low-temperature applications because they are current-limited and their maximum discharge rates decrease with decreasing temperature. One of two developments that constitute the present combination is, itself, a combination of developments: (1) the use of sub-fluorinated carbonaceous (CFx wherein x<1) cathode material, (2) making the cathodes thinner than in most commercial units, and (3) using non-aqueous electrolytes formulated especially to enhance low-temperature performance. This combination of developments was described in more detail in High-Energy-Density, Low- Temperature Li/CFx Primary Cells (NPO-43219), NASA Tech Briefs, Vol. 31, No. 7 (July 2007), page 43. The other development included in the present combination is the use of an anion receptor as an electrolyte additive, as described in the immediately preceding article, "Additive for Low-Temperature Operation of Li-(CF)n Cells" (NPO- 43579). A typical cell according to the present combination of developments contains an anion-receptor additive solvated in an electrolyte that comprises LiBF4 dissolved at a concentration of 0.5 M in a mixture of four volume parts of 1,2 dimethoxyethane with one volume part of propylene carbonate. The proportion, x, of fluorine in the cathode in such a cell lies between 0.5 and 0.9. The best of such cells fabricated to date have exhibited discharge capacities as large as 0.6 A h per gram at a temperature of 50 C when discharged at a rate of C/5 (where C is the magnitude of the current, integrated for one hour, that would amount to the nominal charge capacity of a cell).

Smart, Marshall C.↗

Pre-Flight Characterization of Samples for the MISSE-7 Spacesuit Fabric Exposure Experiment

A series of six sample spacesuit pressure garment assembly (PGA) fabric samples were prepared for the Materials International Space Station Experiment 7 (MISSE-7) flight experiment to test the effects of damage by lunar dust on the susceptibility of the fabrics to radiation damage. These included pristine Apollo-era fluorinated ethylene-propylene (FEP) fabric, Apollo-era FEP fabric that had been abraded with JSC-1A lunar simulant, and a piece of Alan Bean s Apollo 12 PGA sectioned from near the left knee. Also included was a sample of pristine orthofabric, and orthofabric that had been abraded to two different levels with JSC-1A. The samples were characterized using optical microscopy, field emission scanning electron microscopy, and atomic force microscopy. Two sets of six samples were then loaded in space environment exposure hardware, one of which was stored as control samples. The other set was affixed to the MISSE-7 experiment package, and will be mounted on the International Space Station, and exposed to the wake-side low Earth orbit environment. It will be retrieved after an exposure of approximately 12 months, and returned for post flight analysis.

Gaier, James R.↗

Plumbing Fixture for a Microfluidic Cartridge

A fixture has been devised for making the plumbing connections between a microfluidic device in a replaceable cartridge and an external fluidic system. The fixture includes a 0.25-in. (6.35-mm) thick steel plate, to which the cartridge is fastened by two 10-32 thumb screws. The plate holds one plumbing fitting for the inlet and one for the outlet of the microfluidic device. Each fitting includes a fused-silica tube of 0.006-in. (approx.0.15-mm) inside diameter within a fluorinated ethylene-propylene (FEP) tube of 0.0155-in. (approx.0.39-mm) inside diameter and 0.062- in. (approx.1.57-mm) outside diameter. The FEP tube is press-fit through the steel plate so that its exposed end is flush with the surface of the plate, and the silica tube protrudes 0.03 in. (approx.0.76 mm) from the plate/FEP-tube-end surface. The cartridge includes a glass cover plate that contains 0.06-mm-wide access ports. When the cartridge is fastened to the steel plate, the silica tubes become inserted through the access ports and into the body of the cartridge, while the ends of the FEP tubes become butted against the glass cover plate. An extremely tight seal is thereby made.

Francis, Kevin↗

Nitric Oxide and Oxygen Air-Contamination Effects on Extinction Limits of Non-Premixed Hydrocarbon-Air Flames for a HIFiRE Scramjet

Unique nitric oxide (NO) and oxygen air-contamination effects on the extinction Flame Strength (FS) of non-premixed hydrocarbon (HC) vs. air flames are characterized for 7 gaseous HCs, using a new idealized 9.3 mm straight-tube Opposed Jet Burner (OJB) at 1 atm. FS represents a laminar strain-induced extinction limit based on cross-section-average air jet velocity, Uair, that sustains combustion of a counter jet of gaseous fuel just before extinction. Besides ethane, propane, butane, and propylene, the HCs include ethylene, methane, and a 64 mole-% ethylene / 36 % methane mixture, the writer s previously recommended gaseous surrogate fuel for HIFiRE scramjet tests. The HC vs. clean air part of the work is an extension of a May 2008 JANNAF paper that characterized surrogates for the HIFiRE project that should mimic the flameholding of reformed (thermally- or catalytically-cracked) endothermic JP-like fuels. The new FS data for 7 HCs vs. clean air are thus consolidated with the previously validated data, normalized to absolute (local) axial-input strain rates, and co-plotted on a dual kinetically dominated reactivity scale. Excellent agreement with the prior data is obtained for all 7 fuels. Detailed comparisons are also made with recently published (Univ. Va) numerical results for ethylene extinction. A 2009-revised ethylene kinetic model (Univ. Southern Cal) led to predicted limits within approx. 5 % (compared to 45 %, earlier) of this writer s 2008 (and present) ethylene FSs, and also with recent independent data (Univ. Va) obtained on a new OJB system. These +/- 5 % agreements, and a hoped-for "near-identically-performing" reduced kinetics model, would greatly enhance the capability for accurate numerical simulations of surrogate HC flameholding in scramjets. The measured air-contamination effects on normalized FS extinction limits are projected to assess ongoing Arc-Heater-induced "facility test effects" of NO production (e.g., 3 mole-%) and resultant oxygen depletion (from 21 to 19.5 %), for testing the "64/36" surrogate fuel in Langley s Arc-Heated Scramjet Test Facility for HIFiRE engine designs. The FS results show a generally small (< 4 %) "nitric oxide enhancement" effect, relative to clean air, for up to 3 % NO (freestream Mach number up to 7 in Arc Jet testing). However, a progressively large "oxygendeficiency weakening" effect develops. For 3 % NO, a net weakening of 26 % in FS is derived for the "64/36" fuel vs. air. The corresponding net weakening for pure ethylene is 20 %. A number of practical recommendations regarding facility test effects are offered.

Pellett, Gerald L.↗

Two-Phase Thermal Switching System for a Small, Extended Duration Lunar Surface Science Platform

This paper describes a novel thermal control system for the Warm Electronics Box (WEB) on board a small lunar surface lander intended to support science activities anywhere on the lunar surface for an extended duration of up to 6 years. Virtually all lander electronics, which collectively dissipate about 60 W in the reference mission, are contained within the WEB. These devices must be maintained below 323 K (with a goal of 303 K) during the nearly 15-earth-day lunar day, when surface temperatures can reach 390K, and above 263 K during the nearly 15-earth-day lunar night, when surface temperatures can reach 100K. Because of the large temperature swing from lunar day-to-night, a novel thermal switching system was required that would be able to provide high conductance from WEB to radiator(s) during the hot lunar day and low (or negligible) conductance during the cold lunar night. The concept that was developed consists of ammonia variable conductance heat pipes (VCHPs) to collect heat from WEB components and a polymer wick propylene loop heat pipe (LHP) to transport the collected heat to the radiator(s). The VCHPs autonomously maximize transport when the WEB is warm and autonomously shut down when the WEB gets cold. The LHP autonomously shuts down when the VCHPs shut down. When the environment transitions from lunar night to day, the VCHPs and LHP autonomously turn back on. Out of 26 analyzed systems, this novel arrangement was able to best achieve the combined goals of zero control power, autonomous operation, long life, low complexity, low T, and landed tilt tolerance.

Bugby, David C.↗

Two-Band, Low-Loss Microwave Window

A window for a high-sensitivity microwave receiving system allows microwave radiation to pass through to a cryogenically cooled microwave feed system in a vacuum chamber, while keeping ambient air out of the chamber and helping to keep the interior of the chamber cold. The microwave feed system comprises a feed horn and a low-noise amplifier, both of which are required to be cooled to a temperature of 15 K during operation. The window is designed to exhibit very little microwave attenuation in two frequency bands: 8 to 9 GHz and 30 to 40 GHz. The window is 15 cm in diameter. It includes three layers (see figure): 1) The outer layer is made of a poly(tetrafluoroethylene) film 0.025 mm thick. This layer serves primarily to reflect and absorb solar ultraviolet radiation to prolong the life of the underlying main window layer, which is made of a polyimide that becomes weakened when exposed to ultraviolet. The poly(tetrafluoroethylene) layer also protects the main window layer against abrasion. Moreover, the inherent hydrophobicity of poly(tetrafluoroethylene) helps to prevent the highly undesirable accumulation of water on the outer surface. 2) The polyimide main window layer is 0.08 mm thick. This layer provides the vacuum seal for the window. 3) A 20-mm-thick layer of ethylene/ propylene copolymer foam underlies the main polyimide window layer. This foam layer acts partly as a thermal insulator: it limits radiational heating of the microwave feed horn and, concomitantly, limits radiational cooling of the window. This layer has high compressive strength and provides some mechanical support for the main window layer, reducing the strength required of the main window layer. The ethylene/propylene copolymer foam layer is attached to an aluminum window ring by means of epoxy. The outer poly(tetrafluoroethylene) film and the main polyimide window layer are sandwiched together and pressed against the window ring by use of a bolted clamp ring. The window has been found to introduce a microwave loss of only about 0.4 percent. The contribution of the window to the noise temperature of the microwave feed system has been found to be less than 1 K at 32 GHz and 0.2 K at 8.4 GHz.

Britcliffe, Michael↗

Mission Performance of the GLAS Thermal Control System - 7 Years In Orbit

ICESat (Ice, Cloud and land Elevation Satellite) was launched in 2003 carrying a single science instrument - the Geoscience Laser Altimeter System (GLAS). Its primary mission was to measure polar ice thickness. The GLAS thermal control architecture utilized propylene Loop Heat Pipe (LHP) technology to provide selectable and stable temperature control for the lasers and other electronics over a widely varying mission thermal environment. To minimize expected degradation of the radiators, Optical Solar Reflectors (OSRs) were used for both LHP radiators to minimize degradation caused by UV exposure in the various spacecraft attitudes necessary throughout the mission. Developed as a Class C mission, with selective redundancy, the thermal architecture was single st ring, except for temperature sensors used for heater control during normal operations. Although originally planned for continuous laser operations over the nominal three year science mission, laser anomalies limited operations to discrete measurement campaigns repeated throughout the year. For trending of the science data, these periods were selected to occur at approximately the same time each year, which resulted in operations during similar attitudes and beta angles. Despite the laser life issues, the LHPs have operated nearly continuously over this time, being non-operational for only brief periods. Using mission telemetry, this paper looks at the performance of the thermal subsystem during these periods and provides an assessment of radiator degradation over the mission lifetime.

Grob, Eric W.↗

GOES Type III Loop Heat Pipe Life Test Results

The GOES Type III Loop Heat Pipe (LHP) was built as a life test unit for the loop heat pipes on the GOES N-Q series satellites. This propylene LHP was built by Dynatherm Corporation in 2000 and tested continuously for approximately 14 months. It was then put into storage for 3 years. Following the storage period, the LHP was tested at Swales Aerospace to verify that the loop performance hadn t changed. Most test results were consistent with earlier results. At the conclusion of testing at Swales, the LHP was transferred to NASA/GSFC for continued periodic testing. The LHP has been set up for testing in the Thermal Lab at GSFC since 2006. A group of tests consisting of start-ups, power cycles, and a heat transport limit test have been performed every six to nine months since March 2006. Tests results have shown no change in the loop performance over the five years of testing. This presentation will discuss the test hardware, test set-up, and tests performed. Test results to be presented include sample plots from individual tests, along with conductance measurements for all tests performed.

Ottenstein, Laura↗

Anion-Intercalating Cathodes for High-Energy-Density Cells

A report discusses physicochemical issues affecting a fluoride-intercalating cathode that operates in conjunction with a lithium ion-intercalating anode in a rechargeable electrochemical cell described in a cited prior report. The instant report also discusses corresponding innovations made in solvent and electrolyte compositions since the prior report. The advantages of this cell, relative to other lithium-ion-based cells, are said to be greater potential (5 V vs. 4 V), and greater theoretical cathode specific capacity (0.9 to 2.2 A-h/g vs. about 0.18 A-h/g). The discussion addresses a need for the solvent to be unreactive toward the lithium anode and to resist anodic oxidation at potentials greater than about 4.5 V vs. lithium; the pertinent innovation is the selection of propylene carbonate (PC) as a solvent having significantly more stability, relative to other solvents that have been tried. The discussion also addresses the need for an electrolyte additive, denoted an anion receptor, to complex the fluoride ion; the pertinent innovation is the selection of tris(hexafluoroisopropyl) borate as a superior alternative to the prior anion receptor, which was tris(pentafluorophenyl) borate.

West, William↗

Degradation of Multi-Layer Insulation (MLI) Retrieved from the Hubble Space Telescope

Multi-Layer Insulation (MLI) returned during Servicing Mission 4 are still being analyzed. Analysis has revealed degradation of optical, thermal, and mechanical properties, increased crystallinity, and reduction in fluorine/carbon ratio of aluminized-Teflon fluorinated ethylene propylene (Al-FEP) FEP. These material properties can be affected by high temperatures on orbit, increased radiation exposure, and in some cases contamination from materials in close proximity to the insulation on orbit. Preliminary results support conclusions of previous studies: areas of Al-FEP that received higher levels of solar exposure show more degradation (high temperatures and radiation combined).

Mohammed, Jelila S.↗

Laser Ablation of Materials for Propulsion of Spacecraft

A report describes experiments performed as part of a continuing investigation of the feasibility of laser ablation of materials as a means of propulsion for small spacecraft. In each experiment, a specimen of ablative material was mounted on a torsion pendulum and irradiated with a laser pulse having an energy of 5 J. The amplitude of the resulting rotation of the torsion pendulum was taken to be an indication of the momentum transferred from the laser beam. Of the ablative materials tested, aluminum foils yielded the smallest rotation amplitudes of the order of 10 degrees. Black coating materials yielded rotation amplitudes of the order of 90 degrees. Samples of silver coated with a fluorinated ethylene propylene (FEP) copolymer yielded the largest rotation amplitudes 6 to 8 full revolutions. The report presents a theory involving heating of a confined plasma followed by escape of the plasma to explain the superior momentum transfer performance of the FEP specimens. It briefly discusses some concepts for optimizing designs of spacecraft engines to maximize the thrust obtainable by exploiting the physical mechanisms of the theory. Also discussed is the use of laser-ablation engines with other types of spacecraft engines.

Edwards, David L.↗

Geoscience Laser Altimetry System (GLAS) Loop Heat Pipe Anomaly and On Orbit Testing

The Geoscience Laser Altimetry System (GLAS) is the sole instrument on the ICESat Satellite. On day 230 of 2003, the GLAS Component Loop Heat Pipe (CLHP) entered a slow circulation mode that resulted in the main electronics box reaching its hot safing temperature, after which the entire instrument was turned off. The CLHP had a propylene working fluid and was actively temperature controlled via a heater on the compensation chamber. The slow circulation mode happened right after a planned propulsive yaw maneuver with the spacecraft. It took several days to recover the CLHP and ensure that it was still operational. The recovery occurred after the entire instrument was cooled to survival temperatures and the CLHP compensation chamber cycled on a survival heater. There are several theories as to why this slow circulation mode exhibited itself, including: accumulation of Non-Condensible Gas (NCG), the secondary wick being under designed or improperly implemented, or an expanded (post-launch) leak across the primary wick. Each of these is discussed in turn, and the secondary wick performance is identified as the most likely source of the anomalous behavior. After the anomaly, the CLHP was controlled to colder temperatures to improve its performance (as the surface tension increases with lower temperature, as does the volume of liquid in the compensation chamber) and only precursor pulses occurred later in the mission. After GLAS s last laser failed, in late 2009, a decision was made to conduct engineering tests of both LHPs to try and duplicate this flight anomaly. The engineering tests consisted of control setpoint changes, sink changes, and one similar propulsive Yaw maneuver. The only test that showed any similar anomaly precursors on the CLHP was the propulsive maneuver followed by a setpoint increase. The ICESat Satellite was placed in a decaying orbit and ended its mission on August 30, 2010 in Barents Sea.

Baker, Charles↗

Detection of Carbon Monoxide Using Polymer-Carbon Composite Films

A carbon monoxide (CO) sensor was developed that can be incorporated into an existing sensing array architecture. The CO sensor is a low-power chemiresistor that operates at room temperature, and the sensor fabrication techniques are compatible with ceramic substrates. Sensors made from four different polymers were tested: poly (4-vinylpryridine), ethylene-propylene-diene-terpolymer, polyepichlorohydrin, and polyethylene oxide (PEO). The carbon black used for the composite films was Black Pearls 2000, a furnace black made by the Cabot Corporation. Polymers and carbon black were used as received. In fact, only two of these sensors showed a good response to CO. The poly (4-vinylpryridine) sensor is noisy, but it does respond to the CO above 200 ppm. The polyepichlorohydrin sensor is less noisy and shows good response down to 100 ppm.

Homer, Margie L.↗

Bright is the New Black - Multi-Year Performance of Generic High-Albedo Roofs in an Urban Climate

High-albedo white and cool roofing membranes are recognized as a fundamental strategy that dense urban areas can deploy on a large scale, at low cost, to mitigate the urban heat island effect. We are monitoring three generic white membranes within New York City that represent a cross-section of the dominant white membrane options for U.S. flat roofs: (1) an ethylene propylene diene monomer (EPDM) rubber membrane; (2) a thermoplastic polyolefin (TPO) membrane and; (3) an asphaltic multi-ply built-up membrane coated with white elastomeric acrylic paint. The paint product is being used by New York City s government for the first major urban albedo enhancement program in its history. We report on the temperature and related albedo performance of these three membranes at three different sites over a multi-year period. The results indicate that the professionally installed white membranes are maintaining their temperature control effectively and are meeting the Energy Star Cool Roofing performance standards requiring a three-year aged albedo above 0.50. The EPDM membrane however shows evidence of low emissivity. The painted asphaltic surface shows high emissivity but lost about half of its initial albedo within two years after installation. Given that the acrylic approach is an important "do-it-yourself," low-cost, retrofit technique, and, as such, offers the most rapid technique for increasing urban albedo, further product performance research is recommended to identify conditions that optimize its long-term albedo control. Even so, its current multi-year performance still represents a significant albedo enhancement for urban heat island mitigation.

Gaffin, S. R.↗

Effect of Solar Exposure on the Atomic Oxygen Erosion of Hubble Space Telescope Aluminized-Teflon Thermal Shields

When exposed to low Earth orbital (LEO) environment, external spacecraft materials degrade due to radiation, thermal cycling, micrometeoroid and debris impacts, and atomic oxygen (AO) interaction. Collisions between AO and spacecraft can result in oxidation of external spacecraft surface materials, which can lead to erosion and severe structural and/or optical property deterioration. It is therefore essential to understand the AO erosion yield (Ey), the volume loss per incident oxygen atom (cu cm/atom), of polymers to assure durability of spacecraft materials. The objective of this study was to determine whether solar radiation exposure can increase the rate of AO erosion of polymers in LEO. The material studied was a section of aluminized-Teflon (DuPont) fluorinated ethylene propylene (Al-FEP) thermal shield exposed to space on the Hubble Space Telescope (HST) for 8.25 years. Retrieved samples were sectioned from the circular thermal shield and exposed to ground laboratory thermal energy AO. The results indicate that the average Ey of the solar facing HST Al-FEP was 1.9 10(exp -24)cu cm/atom, while the average Ey of the anti-solar HST Al-FEP was 1.5 10(exp -24)cu cm/atom. The Ey of the pristine samples was 1.6- 1.7 10(exp -24)cu cm/atom. These results indicate that solar exposure affects the post-flight erosion rate of FEP in a plasma asher. Therefore, it likely affects the erosion rate while in LEO.

Guo, Aobo↗

Analyses of Hubble Space Telescope Aluminized-Teflon Insulation Retrieved After 19 Years of Space Exposure

Since its launch in April 1990, the Hubble Space Telescope (HST) has made many important observations from its vantage point in low Earth orbit (LEO). However, as seen during five servicing missions, the outer layer of multilayer insulation (MLI) has become successively more embrittled and has cracked in many areas. In May 2009, during the 5th servicing mission (called SM4), two MLI blankets were replaced with new insulation pieces and the space-exposed MLI blankets were retrieved for degradation analyses by teams at NASA Glenn Research Center (GRC) and NASA Goddard Space Flight Center (GSFC). The MLI blankets were from Equipment Bay 8, which received direct sunlight, and Equipment Bay 5, which received grazing sunlight. Each blanket contained a range of unique regions based on environmental exposure and/or physical appearance. The retrieved MLI blanket s aluminized-Teflon (DuPont) fluorinated ethylene propylene (Al-FEP) outer layers have been analyzed for changes in optical, physical, and mechanical properties, along with space induced chemical and morphological changes. When compared to pristine material, the analyses have shown how the Al-FEP was severely affected by the space environment. This paper reviews tensile properties, solar absorptance, thermal emittance, x-ray photoelectron spectroscopy (XPS) data and atomic oxygen erosion values of the retrieved HST blankets after 19 years of space exposure.

deGroh, Kim K.↗

In-Flight Performance of the TES Loop Heat Pipe Rejection System: Seven Years in Space

The Tropospheric Emission Spectrometer (TES) instrument heat rejection system has been operating in space for nearly 8 years since launched on NASA's EOS Aura Spacecraft. The instrument is an infrared imaging fourier transform spectrometer with spectral coverage of 3.2 to 15.4 microns. The loop heat pipe (LHP) based heat rejection system manages all of the instrument components waste heat including the two mechanical cryocoolers and their drive electronics. Five propylene LHPs collect and transport the instrument waste heat to the near room temperature nadir viewing radiators. During the early months of the mission, ice contamination of the cryogenic surfaces including the focal planes led to increased cryocooler loads and the need for periodic decontamination cycles. Focal plane decontamination cycles require power cycling both cryocoolers which also requires the two cryocooler LHPs to turn off and on during each cycle. To date, the cryocooler LHPs have undergone 24 start-ups in orbit successfully. This paper reports on the TES cryocooler loop heat pipe based heat rejection system performance. After a brief overview of the instrument thermal design, the paper presents detailed data on the highly successful space operation of the loop heat pipes since instrument turn-on in 2004. The data shows that the steady-state and transient operation of the LHPs has not changed since 2004 and shows consistent and predictable performance. The LHP based heat rejection system has provided a nearly constant heat rejection heat sink for all of its equipment which has led to exceptional overall instrument performance with world class science.

allowable flight temperature↗