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At least 271 records · Page 15

On the power spectral density of quadrature modulated signals

The conventional (no-offset) quadriphase modulation technique suffers from the fact that hardlimiting will restore the frequency sidelobes removed by proper filtering. Thus, offset keyed quadriphase modulation techniques are often proposed for satellite communication with bandpass hardlimiting. A unified theory is developed which is capable of describing the power spectral density before and after the hardlimiting process. Using the in-phase and the quadrature phase channel with arbitrary pulse shaping, analytical results are established for generalized quadriphase modulation. In particular MSK, OPSK or the recently introduced overlapped raised cosine keying all fall into this general category. It is shown that for a linear communication channel, the power spectral density of the modulated signal remains unchanged regardless of the offset delay. Furthermore, if the in phase and the quadrature phase channel have identical pulse shapes without offset, the spectrum after bandpass hardlimiting will be identical to that of the conventional QPSK modulation. Numerical examples are given for various modulation techniques. A case of different pulse shapes in the in phase and the quadrature phase channel is also considered.

Yan, T. Y.↗

Determination of Thermal Damage Threshold in THz Photomixers Using Raman Spectroscopy

The increase of device lifetime and reliability of THz photomixers will play an essential role in their possible future application. Therefore, their optimal work conditions/operation range, i.e., the maximal incident optical power should be experimentally estimated. We fabricated and tested THz photomixer devices based on nitrogen-implanted GaAs integrated with a Bragg reflector. Raman spectroscopy was applied to investigate the material properties and to disclose any reversible or irreversible material changes. The results indicate that degradation effects in the photomixer structures/material could be avoided if the total optical power density does not exceed levels of about 0.7 mW/µm 2 for 100 min of operation. Furthermore, the investigations performed during 1000 min of optical exposure on the photomixer devices’ central region comprising interdigitated metal-semiconductor-metal (MSM) structures suggest a reversible “curing” mechanism if the power density level of ~0.58 mW/µm 2 is not exceeded. Long-term operation (up to 1000 h) reveals that the photomixer structures can withstand an average optical power density of up to ~0.4 mW/µm 2 without degradation when biased at 10 V. Besides the decrease of the position of the A1g (LO) Raman mode from ~291 cm -1 down to ~288 cm -1 with increasing optical power density and operation time, broad Raman modes evolve at about 210 cm -1 , which can be attributed to degradation effects in the active photomixer/MSM area. In addition, the performed carrier lifetime and photomixer experiments demonstrated that these structures generated continuous wave sub-THz radiation efficiently as long as their optimal work conditions/operation range were within the limits established by our Raman studies.

36 MATERIALS SCIENCE↗

Recent advances in solid polymer electrolyte fuel cell technology with low platinum loading electrodes

Of all the fuel cell systems only alkaline and solid polymer electrolyte fuel cells are capable of achieving high power densities (greater than 1 W/sq cm) required for terrestrial and extraterrestrial applications. Electrode kinetic criteria for attaining such high power densities are discussed. Attainment of high power densities in solid polymer electrolyte fuel cells has been demonstrated earlier by different groups using high platinum loading electrodes (4 mg/sq cm). Recent works at Los Alamos National Laboratory and at Texas A and M University (TAMU) demonstrated similar performance for solid polymer electrolyte fuel cells with ten times lower platinum loading (0.45 mg/sq cm) in the electrodes. Some of the results obtained are discussed in terms of the effects of type and thickness of membrane and of the methods platinum localization in the electrodes on the performance of a single cell.

Srinivasan, Supramaniam↗

Joint Modeling of GD-1 and C-19 as Old Streams

DESI observational data for the GD-1 and C-19 streams are compared to stream simulations in a common evolving multi-halo potential of a Milky Way-like galaxy based on a cosmological simulation. The goal is to find the best match of the stream velocity spread and the density power spectrum stream density to simulations having either CDM or WDM subhalos. The cocoon velocity width integrated over the length of the stream is independent of orbital blurring along the stream and the power spectrum integrates over the width of the stream, sidestepping the geometric details of the streams. Streams develop from star clusters inserted at $\simeq$1 Gyr after the Big Bang and evolved for 13 Gyr to their current orbital positions. Streams in a CDM subhalo population provide the best match to the velocity width, with streams younger than 10 Gyr ruled out as insufficiently hot. The progenitor star cluster masses, which determine the fraction of stars released at late times which comprise the stream core, are found to be $\simeq 8\times 10^4 M_\odot$ for GD-1 and $\simeq 4\times 10^4 M_\odot$ for C-19, although the mass depends on the star cluster half mass radius. Stream heating leads to stream lumpiness which is measurable for the relatively large and clean GD-1 dataset. The stream density power spectrum measured along the length of the DESI GD-1 sample is in good agreement with CDM simulations, with 1.7 to 1.9 times more power than WDM 7 keV and 5.5 keV simulations.

Carlberg, Raymond G. [Toronto U.] (ORCID:000000027↗

Spatially varying seasonal modulation to tidal stream energy potential due to mixed tidal regimes in the Aleutian Islands, AK

We provide an assessment of the tidal stream energy resource of the Aleutian Islands, Alaska via a validated barotropic tidal numerical model of the region. Eight island passes are identified as energy “hotspots”. The annual mean kinetic energy fluxes, KEF , calculated at each pass vary from 1000 to 11,000 MW, while the annual available energy, AAE , varies from 5 to 42 MWh m −2 . Notable seasonal modulation to monthly power density averages and ranges are noted at some passes and not others. Seasonal adjustment is linked to the semi-annual solar declination cycle which enhances (dampens) diurnal (D 1 ) tidal amplitudes in summer/winter (spring/fall) as well as the time-varying phase lag between D 1 and semidiurnal (D 2 ) fortnightly tidal cycles. Annual variability in monthly mean power density scales with the tidal current form factor, F u , with the largest seasonal change occurring for F u > 1 (D 1 dominated tide). The spread in power density over a month is on average smaller for passes with mixed tides (F u = 1 ) than those with D 1 or D 2 dominance, as changes to fortnightly phase lag become influential to net power density ranges when tides are mixed. This study outlines overlooked, but relevant, long-term modulation to tidal streams in regions with mixed tides.

16 TIDAL AND WAVE POWER↗

Hydrocarbon-based membranes cost-effectively manage species transport and increase performance in thermally regenerative batteries

Low-temperature heat (T<130°C) can be utilized by thermally regenerative batteries (TRBs) for power production, allowing the thermal energy to be converted to storable chemical potential energy. However, TRBs suffer from high ohmic losses and ammonia crossover, which has slowed their development. In this study, we examined how the use of six different membranes influenced TRB performance, determined the most influential membrane parameters, and identified promising membrane candidates that cost-effectively increase TRB performance. Of the six membranes examined, an inexpensive, hydrocarbon CEM (Selemion CMVN) had low ammonia crossover without compromising resistance, resulting in good performance across all metrics studied. A thin anion exchange membrane (Sustainion, 50 microns) showed a high peak power density of 82 mW cm –2 due to low resistance, but the average power density and energy density were low due to high ammonia flux. Full discharge curves using Selemion CMVN provided an average power density of 26 ± 7 mW cm –2 with an energy density of 2.9 Wh L –1 , which were large improvements on previous TRBs. A techno-economic analysis showed that Selemion CMVN had the lowest levelized cost of storage ($410 per MWh) at an applied current density of 50 mA cm –2 .

25 ENERGY STORAGE↗

Fuel Cell Membrane Electrode Assemblies with Ultra-Low Pt Nanofiber Electrodes (Final Report)

H 2 /air fuel cell membrane-electrode-assemblies (MEAs) were fabricated with electrospun particle/polymer nanofiber mat cathodes (0.1 mg Pt /cm 2 or 0.2 mg Pt /cm 2 Pt/C, PtCo/C or PtNi/C) and anodes (0.1 mg/cm 2 Pt/C), where the binder was a mixture of acid-form perfluorosulfonic acid ionomer (e.g., Nafion™) and poly(acrylic acid) (PAA) carrier polymer or sodium-form PFSA with a carrier polymer of either PAA or polyethylene oxide (PEO). For the latter two cases, the water-soluble carrier was removed from the fibers after electrospinning. MEAs with Pt/C anode/cathode catalyst loadings of 0.1 mg Pt /cm2 each, an 1100 EW PFSA binder (Nafion™ dispersion), and a Nafion 211 membrane produced high power at both high and low relative humidity (RH) conditions, e.g., a maximum power density of 919 mW/cm 2 at 100% RH and 832 mW/cm 2 at 40% RH for a test at 80 °C and 200 kPa abs . The high power at low RH was attributed to nm-size pores within the fibers that trap water via capillary condensation thus maintaining a high proton conductivity of the PFSA binder in the cathode and especially the anode while minimizing/eliminating ionic isolation of catalyst particles in low water content, poorly conductive binder. At the same time, micro-porosity between fibers in the cathode allows for fast removal of electrogenerated water, thus minimizing cathode flooding. Nanofiber MEAs with Pt alloy catalyst cathodes also performed well, where a fibrous PtCo/C catalyst cathode at a loading of 0.1 mg/cm 2 produced 20% more power than a conventional powder cathode MEA, e.g., a maximum power density of 1,045 mW/cm 2 vs. 869 mW/cm 2 at 80 °C, 100% RH, and 200 kPa abs , and a PtNi/C fiber cathode MEAs prepared with Na+-form Nafion + PEO generated a maximum power of 820 mW/cm 2 at 40% RH. Fiber electrode MEAs with a neat Nafion binder (prepared from Na+-form Nafion + PEO or PAA) where the cathode Pt loading was ~0.1 mg/cm 2 exhibited a 25% loss in maximum power at 30,000 metal dissolution cycles, as compared to a 12% loss when the cathode binder was H+-form Nafion + PAA. The performance of a fiber mat electrode MEA with Pt/C catalyst (0.2 mg/cm 2 cathode loading and 0.1 mg/cm 2 anode loading) was excellent. At 80 oC and 200 kPa abs , the maximum power density was 1104 mW/cm 2 . The maximum power was independent of feed gas humidity for 40 < RH < 100%. The power loss after a metal dissolution AST (30,000 voltage cycles) was only 13%.

08 HYDROGEN↗

Multifunctional Utilization of Pitch-Coated Carbon Fibers in Lithium-Based Rechargeable Batteries

This work reports carbon fibers as an electrode material and current collector for dual-carbon and lithium-ion batteries. Here, fully graphitic and semigraphitic carbon fibers undergo anion intercalation beyond 4.5 V versus Li/Li + . Symmetric dual-carbon full cells using a pitch-coated fully graphitic carbon fiber mat as both cathode and anode delivers an energy-density of 276 and 322 Wh kg -1 at 342 W kg -1 power density in the voltage range of 3.0–5.0 and 3.0–5.2 V, respectively. On the other hand, nongraphitic carbon fibers do not exhibit anion intercalation up to 5.2 V and can be used as a current collector. They also possess a larger number of Li + storage sites in their randomly oriented microstructure when used as an anode. A lithium-ion full cell with double carbon-coated C-LiFePO 4 loaded on nongraphitic carbon fiber as a cathode and pitch-coated nongraphitic carbon fiber as an anode exhibits 202.6 and 75.2 Wh kg -1 energy density at power densities of 46.75 W kg -1 and 11.7 kW kg -1 , respectively in 2.0–3.5 V range. This pitch-coated carbon fiber-based battery configuration eliminates the need for metal foils and costly fluorinated binders, lowers overall weight of the cell, and is capable of sustaining mechanical stress and thermal shock.

PF6− intercalation↗

X-Ray Fluctuation Power Spectral Densities of Seyfert 1 Galaxies

By combining complementary monitoring observations spanning long, medium and short time scales, we have constructed power spectral densities (PSDs) of six Seyfert 1 galaxies. These PSDs span approx. greater than 4 orders of magnitude in temporal frequency, sampling variations on time scales ranging from tens of minutes to over a year. In at least four cases, the PSD shows a "break," a significant departure from a power law, typically on time scales of order a few days. This is similar to the behavior of Galactic X-ray binaries (XRBs), lower mass compact systems with breaks on time scales of seconds. NGC 3783 shows tentative evidence for a doubly-broken power law, a feature that until now has only been seen in the (much better-defined) PSDs of low-state XRBs. It is also interesting that (when one previously-observed object is added to make a small sample of seven), an apparently significant correlation is seen between the break time scale T and the putative black hole mass M(sub BH), while none is seen between break time scale and luminosity. The data are consistent with the linear relation T = M(sub BH) /10(exp 6.5) solar mass; extrapolation over 6-7 orders of magnitude is in reasonable agreement with XRBs. All of this strengthens the case for a physical similarity between Seyfert 1s and XRBs.

Markowitz, A.↗

Noise power spectral density of the Sundstrand QA-2000 accelerometer

There are no good data on low frequency (less than 0.1 Hz) power spectral density (PSD) for the Q-Flex accelerometer. However, some preliminary stability measurements were made over periods of 12 to 24 hours and demonstrated stability less than 0.5 micro-g over greater than 12 hours. The test data appear to contain significant contributions from temperature variations at that level, so the true sensor contribution may be less than that. If what was seen could be construed as a true random process, it would correspond to about 0.1 micro-g rms over a bandwidth from 10(exp -5) Hz to about 1 Hz. Other studies of low frequency PSD in flexure accelerometers have indicated that material aging effects tend to approximate a first order Markhov process. If we combine such a model with the spectrum obtained at higher frequencies, it suggests the spectrum shown here as a conservative estimate of Q-Flex noise performance.

Peters, Rex↗

Validation and Parametric Investigations of an Internal Permanent Magnet Motor Using a Lumped Parameter Thermal Model

One of the key challenges for the electric vehicle industry is to develop high-power-density electric motors. Achieving higher power density requires efficient heat removal from inside the motor. In order to improve thermal management, a multiphysics modeling framework that is able to accurately predict the behavior of the motor, while being computationally efficient, is essential. This paper first presents a detailed validation of a lumped parameter thermal network (LPTN) model of an Internal Permanent Magnet synchronous motor within the commercially available MOTOR-CAD modeling environment. The validation is based on temperature comparison with experimental data and with more detailed finite element analysis (FEA). All critical input parameters of the LPTN are considered in detail for each layer of the stator, especially the contact resistances between the impregnation, liner, laminations, and housing. Finally, a sensitivity analysis for each of the critical input parameters is provided. A maximum difference of 4% - for the highest temperature in the slot-winding and the end-winding - was found between the LPTN and the experimental data. Comparing the results from the LPTN and the FEA model, the maximum difference was 2% for the highest temperature in the slot-winding and end-winding. As for the LPTN sensitivity analysis, the thermal parameter with the highest sensitivity was found to be the liner-to-lamination contact resistance.

42 ENGINEERING↗

Validation and Parametric Investigations Using a Lumped Thermal Parameter Model of an Internal Permanent Magnet Motor

One of the key challenges for the electric vehicle industry is to develop high-power-density electric motors. Achieving higher power density requires efficient heat removal from inside the motor. In order to improve thermal management, a multi-physics modeling framework that is able to accurately predict the behavior of the motor, while being computationally efficient, is essential. This paper first presents a detailed validation of a Lumped Parameter Thermal Network (LPTN) model of an Internal Permanent Magnet (IPM) synchronous motor within the commercially available Motor-CAD® modeling environment. The IPM motor’s stator is studied at steady state, and winding losses are generated by a constant DC current. The validation is based on temperature comparison with experimental data and with more detailed Finite Element Analysis (FEA). All critical input parameters of the LPTN are considered in detail for each layer of the stator, especially the contact resistances between the impregnation, liner, laminations and housing. Finally, a sensitivity analysis for each of the critical input parameters is provided. A maximum difference of 4% — for the highest temperature in the slot windings and the end windings — was found between the LPTN and the experimental data. Comparing the results from the LPTN and the FEA model, the maximum difference was 2% for the highest temperature in the slot windings and end windings. As for the LTPN sensitivity analysis, the thermal parameter with the highest sensitivity was found to be the liner-to-lamination contact resistance. The latter is often ignored in the literature, whereas its impact on temperature rise was found to be more significant than any other contact resistance within the stator.

47 OTHER INSTRUMENTATION↗

Statistics of the radiated field of a space-to-earth microwave power transfer system

Statistics such as average power density pattern, variance of the power density pattern and variance of the beam pointing error are related to hardware parameters such as transmitter rms phase error and rms amplitude error. Also a limitation on spectral width of the phase reference for phase control was established. A 1 km diameter transmitter appears feasible provided the total rms insertion phase errors of the phase control modules does not exceed 10 deg, amplitude errors do not exceed 10% rms, and the phase reference spectral width does not exceed approximately 3 kHz. With these conditions the expected radiation pattern is virtually the same as the error free pattern, and the rms beam pointing error would be insignificant (approximately 10 meters).

Stevens, G. H.↗

Validation and Parametric Investigations Using a Lumped Thermal Parameter Model of an Internal Permanent Magnet Motor: Preprint

One of the key challenges for the electric vehicle industry is to develop high-power-density electric motors. Achieving higher power density requires efficient heat removal from inside the motor. In order to improve thermal management, a multi-physics modeling framework that is able to accurately predict the behavior of the motor, while being computationally efficient, is essential. This paper first presents a detailed validation of a Lumped Parameter Thermal Network (LPTN) model of an Internal Permanent Magnet (IPM) synchronous motor within the commercially available Motor-CAD® modeling environment. The IPM motor’s stator is studied at steady state, and winding losses are generated by a constant DC current. The validation is based on temperature comparison with experimental data and with more detailed Finite Element Analysis (FEA). All critical input parameters of the LPTN are considered in detail for each layer of the stator, especially the contact resistances between the impregnation, liner, laminations and housing. Finally, a sensitivity analysis for each of the critical input parameters is provided. A maximum difference of 4% - for the highest temperature in the slot windings and the end windings - was found between the LPTN and the experimental data. Comparing the results from the LPTN and the FEA model, the maximum difference was 2% for the highest temperature in the slot windings and end windings. As for the LTPN sensitivity analysis, the thermal parameter with the highest sensitivity was found to be the liner-to-lamination contact resistance. The latter is often ignored in the literature, whereas its impact on temperature rise was found to be more significant than any other contact resistance within the stator.

ADVANCED PROPULSION SYSTEMS↗

A conformal heat-drying direct ink writing 3D printing for high-performance lithium-ion batteries

High areal capacity electrodes hold great potential for high-energy density lithium-ion batteries (LIBs), but their poor electrochemical kinetics limit their power density. Here, in this study, high areal capacity 3D-structured LiNi 0.8 Mn 0.1 Co 0.1 O 2 cathodes (4.3 mAh cm -2 ) are prepared via 3D printing with a manner of direct ink writing. The electrodes had an enlarged electrode–electrolyte contact area, shortened diffusion pathway, and reduced intercalation-induced stress, thereby delivering enhanced rate capability and cyclability in LIBs, which is 143.6 mAh g -1 at 3C and a 60.2 % capacity retention over 800 cycles at 1C. Moreover, at electrode level, the 3D-NMC exhibits an energy and power densities of 313.1 Wh kg -1 and 657.9 W kg -1 , respectively. Furthermore, the theoretical calculation suggests that reducing the gap width will be highly beneficial to the energy and power densities. This work establishes a milestone in understanding the cycling effect on the electrode local structure, including the void area and the LiNi 0.8 Mn 0.1 Co 0.1 O 2 region, which confirms the effectiveness of 3D printing for electrode preparation.

25 ENERGY STORAGE↗

Fabrication and Characterization of Single-Particle Compacts

The programmatic objective of the advanced low enriched uranium (aLEU) fuel Project within the Office of Nonproliferation Research and Development (NA-22) is to advance the development of nuclear reactor designs, fuel materials, and fabrication technologies capable of meeting a number of challenging customer requirements, including reactor stability, extended lifetime, and power density without refueling, while using only low-enriched uranium (i.e., less than 20% enrichment of 235 U). The tandem requirements of delivering sufficient power density and maintaining fuel performance over the course of a multidecade fuel lifetime tightly constrain the field of potential fuel options. Monolithic fuel forms (e.g., fuel pellets) provide maximized density of fissile material, but they may face challenges in maintaining their structure and performance over the long reactor lifetimes envisioned in this program. Dispersion fuel forms with an inert matrix provide enhanced long-term stability but sacrifice fissile material density, and they may not provide sufficient power density over the reactor lifetime with the limit of low enrichment.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗