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At least 271 records · Page 15

Statistical modelling and Bayesian inversion for a Compton imaging system: application to radioactive source localization

Abstract This paper presents a statistical forward model for a Compton imaging system, called Compton imager. This system, under development at the University of Illinois Urbana Champaign, is a variant of Compton cameras with a single type of sensors which can simultaneously act as scatterers and absorbers. This imager is convenient for imaging situations requiring a wide field of view. The proposed statistical forward model is then used to solve the inverse problem of estimating the location and energy of point-like sources from observed data. This inverse problem is formulated and solved in a Bayesian framework by using a Metropolis within Gibbs algorithm for the estimation of the location, and an expectation-maximization algorithm for the estimation of the energy. This approach leads to more accurate estimation when compared with the deterministic standard back-projection approach, with the additional benefit of uncertainty quantification in the low photon imaging setting.

Tarpau, Cécilia (ORCID:0000000286539490)↗

Projection of distributed-collector solar-thermal electric power plant economics to years 1990-2000

A preliminary comparative evaluation of distributed-collector solar thermal power plants was undertaken by projecting power plant economics of selected systems to the 1990 to 2000 time frame. The selected systems include: (1) fixed orientation collectors with concentrating reflectors and vacuum tube absorbers, (2) one axis tracking linear concentrator including parabolic trough and variable slat designs, and (3) two axis tracking parabolic dish systems including concepts with small heat engine-electric generator assemblies at each focal point as well as approaches having steam generators at the focal point with pipeline collection to a central power conversion unit. Comparisons are presented primarily in terms of energy cost and capital cost over a wide range of operating load factors. Sensitvity of energy costs for a range of efficiency and cost of major subsystems/components is presented to delineate critical technological development needs.

Fujita, T.↗

Characterizing Cold Giant Planets in Reflected Light: Lessons from 50 Years of Outer Solar System Exploration and Observation

A space based coronagraph, whether as part of the WFIRST/AFTA mission or on a dedicated space telescope such as Exo-C or -S, will be able to obtain photometry and spectra of multiple gas giant planets around nearby stars, including many known from radial velocity detections. Such observations will constrain the masses, atmospheric compositions, clouds, and photochemistry of these worlds. Giant planet albedo models, such as those of Cahoy et al. (2010) and Lewis et al. (this meeting), will be crucial for mission planning and interpreting the data. However it is equally important that insights gleaned from decades of solar system imaging and spectroscopy of giant planets be leveraged to optimize both instrument design and data interpretation. To illustrate these points we will draw on examples from solar system observations, by both HST and ground based telescopes, as well as by Voyager, Galileo, and Cassini, to demonstrate the importance clouds, photochemical hazes, and various molecular absorbers play in sculpting the light scattered by solar system giant planets. We will demonstrate how measurements of the relative depths of multiple methane absorption bands of varying strengths have been key to disentangling the competing effects of gas column abundances, variations in cloud height and opacity, and scattering by high altitude photochemical hazes. We will highlight both the successes, such as the accurate remote determination of the atmospheric methane abundance of Jupiter, and a few failures from these types of observations. These lessons provide insights into technical issues facing spacecraft designers, from the selection of the most valuable camera filters to carry to the required capabilities of the flight spectrometer, as well as mission design questions such as choosing the most favorable phase angles for atmospheric characterization.

atmospheric methane abundance↗

Selenium Migration and Local Structures in Cu‐Doped CdSeTe Solar Cells after Aging

Selenium grading plays a critical role in state-of-the-art Cadmium Telluride photovoltaic cells by enhancing long-wavelength absorption and extending minority carrier lifetimes —key to enabling the current performance record of 23.08%. However, very little is understood about selenium motion. In this study, a comprehensive, multimodal, and multiscale approach is employed to investigate Se migration and local structural changes in copper (Cu)-doped CdSeTe solar cells subjected to accelerated stress. X-ray fluorescence (XRF) microscopy shows unexpected levels of Se diffusion after 500 h under heat (75°C) and light (0.8 suns, 80 mW/cm 2 ), suggesting the coexistence of fast and slow diffusion channels even at low temperatures, with unexpectedly low activation energies (<0.85 eV). X-ray Absorption Near Edge Structure (XANES) analysis indicates a preferential migration of Se atoms to anionic lattice sites and a reduction in Se-Cl co-passivation at Te-terminated dislocation cores. Furthermore, these findings point to a reconfiguration of Se local environments and highlight the potential role of extended structural defects in enabling Se transport at low temperatures. Additionally, XANES results suggest that the presence of metallic Cu across the absorber layer may contribute to back-contact degradation and reduced hole density in both fresh and aged devices.

14 SOLAR ENERGY↗

Effect of downstream massive blowing on Jovian entry heating.

An analysis for viscous radiating shock layer flow over a blunt body with massive blowing is presented. Detailed equilibrium computations for the thermodynamics and transport properties are included in the solution. Molecular band and atomic line, as well as continuum radiation are included. For a typical Jovian entry problem, a 40% reduction in total radiative flux at stagnation point, due to the injection of carbon gas, was found. The reduction increases to about 70% at about four body nose radii downstream. The increase of flux reduction indicates that most of the radiative energy is absorbed by the injected carbon gas and dumped into the wake. An examination of the spectral distribution of the surface radiative flux reveals that most of the flux reduction occurs in molecular bands of C2.

Chou, Y. S.↗

The discovery of 50 minute periodic absorption events from 4U 1915-05

An analysis of X-ray observations shows that the steady flux from 4U 1915-05 undergoes periodic absorption dips with a period of 50 minutes. This period most probably represents the underlying orbital period of the system, and variations in the depth and duration of these events suggest that they are caused by a bulge on the edge of the accretion disk at the point where the gas stream impacts the disk. The mass-losing star in this system is probably a low-mass white dwarf, and the spectrum of the dips indicates that the metallicity of the absorbing material is at least a factor of 17 below solar values. The discovery of the 50-minute binary period supports earlier suggestions that X-ray burst sources are in binary systems.

White, N. E.↗

Fractography of composite delamination

Studies were made of the fractography of mode 2 delamination and the impact damage of carbon fiber reinforced polymer composites. Laminates fractured under mode 2 loading were potted in a clear epoxy polymer, sectioned and polished and examined using transmission and reflection light microscopy. There were only occasional fibers bridging the mode 2 cracks. These cracks were not always visible probably because the crack opening displacement was too small as to be resolved using light microscopy. A study was made of the effect of repetitive impacts on laminates of AS4/3501-6 and IM6/3501-6. Plots of cumulative impact energy vs cumulative absorbed energy exhibited a sharp change in slope which corresponded to the damage area reaching the edges of the specimen. The initial slope was highly reproducible for both composite materials. On the other hand, the intersection point between the two slopes, where the damage area reaches the specimen edges, was highly variable between specimens. This variability is tentatively ascribed to differences in laminate quality.

Source record↗

CO2 greenhouse in the early martian atmosphere: SO2 inhibits condensation

Many investigators of the early martian climate have suggested that a dense carbon dioxide atmosphere was present and warmed the surface above the melting point of water (J.B. Pollack, J.F. Kasting, S.M. Richardson, and K. Poliakoff 1987. Icarus 71, 203-224). However, J.F. Kasting (1991. Icarus 94, 1-13) pointed out that previous thermal models of the primitive martian atmosphere had not considered the condensation of CO2. When this effect was incorporated, Kasting found that CO2 by itself is inadequate to warm the surface. SO2 absorbs strongly in the near UV region of the solar spectrum. While a small amount of SO2 may have a negligible effect by itself on the surface temperature, it may have significantly warmed the middle atmosphere of early Mars, much as ozone warms the terrestrial stratosphere today. If this region is kept warm enough to inhibit the condensation of CO2, then CO2 remains a viable greenhouse gas. Our preliminary radiative modeling shows that the addition of 0.1 ppmv of SO2 in a 2 bar CO2 atmosphere raises the temperature of the middle atmosphere by approximately 10 degrees, so that the upper atmosphere in a 1 D model remains above the condensation temperature of CO2. In addition, this amount of SO2 in the atmosphere provides an effective UV shield for a hypothetical biosphere on the martian surface.

NASA Discipline Exobiology↗

Design and Performance of Micro-Spec, an Ultra Compact High-Sensitivity Far-Infrared Spectrometer for SPICA

Micro-Spec (u-Spec) is a high-performance spectrometer working in the 250-700-micrometer wavelength range, whose modules use low-loss superconducting microstrip transmission lines on a single 4-inch-diameter silicon wafer. Creating the required phase delays in transmission lines rather than free space allows such an instrument to have, in principle, the performance of a meter-scale grating spectrometer. Such a dramatic size reduction enables classes of instruments for space that would be impossible with conventional technologies. This technology can dramatically enhance the long-wavelength capability of the space infrared telescope for cosmology and astrophysics SPICA. u-Spec is analogous to a grating spectrometer. The phase retardation generated by the reflection from the grating grooves is instead produced by propagation through a transmission line. The power received by a broadband antenna is progressively divided by binary microstrip power dividers, and the required phase delays are generated by different lengths of microstrip transmission lines. by arranging these outputs along a circular focal surface, the analog of a Rowland spectrometer can he created. The procedure to optimize the Micro-Spec design is based on the stigmatization and minimization of the light path function in a two-dimensional hounded region, which results in an optimized geometry arrangement with three stigmatic points. In addition, in order to optimize the overall efficiency of the instrument, the emitters are directed to the center of the focal surface. The electric field amplitude and phase as well as the power transmitted and absorbed throughout the region are analyzed. Measurements are planned in late summer to validate the designs.

Cataldo, Giuseppe↗

Why are Lead Iodide‐Based Perovskite Precursor Inks Yellow?

A challenge faced by metal halide perovskite (MHP) photovoltaics is scaling up solution deposition processes to realize rapid and inexpensive manufacturing. The challenge lies in completely understanding and controlling solution speciation, nucleation, and self-assembly of iodoplumbate complexes during solvent evaporation as the liquid transforms into gels and solids. An accurate description of solution species, at all points in the transformation, is a prerequisite to design robust and reliable processes. Here, in this study, the common assumption that initial monoplumbate solution species typically invoked (e.g., [PbI 6 ] 4− ) are certainly not the origin of optical absorbance at >400 nm wavelengths is disproved, as are many large particles of common “intermediate” iodoplumbate phases with face- or edge-sharing connectivity. Instead, a new perspective is offered, involving (partially) corner-sharing iodo(poly)plumbates (>1 Pb 2+ per complex) that experience highly dynamic chemical environments. It is outlined how the MHP field would benefit by elucidating these phenomena. Future work is required to determine the size and kinetic behavior of polyplumbate species, and contextualize these findings in relation to broader trends in materials chemistry beyond MHPs. Ultimately, a complete explanation for the solution speciation, optical absorbance signatures, and the color of MHP precursor inks remains an open challenge to the community.

14 SOLAR ENERGY↗

X-Ray Absorption Toward the Einstein Ring Source PKS 1830-211

PKS 1830-211 is an unusually radio-loud gravitationally lensed quasar. In the radio spectrum, the system appears as two compact, dominant features surrounded by relatively extended radio emission that forms an Einstein ring. As the line of sight to it passes close to our Galactic center, PKS 1830-211 has not been detected in wave bands other than the radio and X-ray so far. Here we present X-ray data of PKS 1830-211 observed with ROSAT Position Sensitive Proportional Counter. The X-ray spectrum shows that absorption in excess of the Galactic contribution is highly likely, which at the redshift of the lensing galaxy (z(sub t)=0.886) corresponds to N(sub H)=3.5((sup 0.6)(sub -0.5))x10(exp 22) atoms sq cm. The effective optical extinction is large, A(sub V)(observed) is greater than or approximately 5.8. When corrected for this additional extinction, the two-point optical to X-ray slope alpha(sub ox) of PKS 1830-211 lies just within the observed range of quasars. It is argued here that both compact images must be covered by the X-ray absorber(s) that we infer to be the lensing galaxy (galaxies). The dust-to-gas ratio along the line of sight within the lensing galaxy is likely to be somewhat larger than for our Galaxy.

Mathur, Smita↗

Additive manufacturing of cobalt-based alloy on tool steel by directed energy deposition

Cladding hard-surfacing alloys on tool steel is an effective approach to enhance the surface properties of tool steel. In this study, a Co-based alloy was deposited on tool steel by Directed Energy Deposition (DED) following a three-factor three-level design of experiment matrix with varied laser power, scan speed, and powder flow rate. The microstructure of the deposits was characterized using scanning electron microscopy (SEM). The residual stress on the surface of the samples was measured by the X-ray diffraction (XRD) sin2? technique. The parameters that produced promising deposits were used to fabricate samples for tensile test, four-point bending test, Charpy impact test, and hardness measurement. Our result reveals that the processing parameters have a significant role in the residual stress of the coatings. Residual stress reduces with the increase of laser energy density. Cracks were found at samples with energy density below a threshold. Tensile testing of the coating/substrate combined structure reveals fracture at the coatings with an ultimate tensile strength of 633.9 ± 54.7 MPa. The bi-material interface survived the tensile test, indicating a strong interfacial bond. The four-point bending test of coating/substrate laminates shows an ultimate flexure strength of 860.6 ± 36.9 MPa. Cracks initiated from the coatings ignored the interface and penetrated the substrate, suggesting a solid bi-material bond. Charpy impact test shows the absorbed energy of coating/substrate laminates is more than doubled that of the substrate.

36 MATERIALS SCIENCE↗

Containerless study of metal evaporation by laser induced fluorescence

Laser induced fluorescence (LIF) detection of atomic vapors was used to study evaporation from electromagnetically levitated and CW CO2 laser-heated molybdenum spheres and resistively-heated tungsten filaments. Electromagnetic (EM) levitation in combination with laser heating of tungsten, zirconium, and aluminum specimens was also investigated. LIF intensity vs temperature data were obtained for molybdenum atoms and six electronic states of atomic tungsten, at temperatures up to the melting point of each metal. The detected fraction of the emitted radiation was reduced by self-absorption effects at the higher experimental temperatures. Vaporization enthalpies derived from data for which less than half the LIF intensity was self-absorbed were -636 + or - 24 kJ/g-mol for Mo and 831 + or - 32 kJ/g-mol for W. Space-based applications of EM levitation in combination with radiative heating are discussed.

Schiffman, Robert A.↗

HST Spatially Resolved Spectra of the Accretion Disc and Gas Stream of the Nova-Like Variable UX Ursae Majoris

Time-resolved eclipse spectroscopy of the nova-like variable UX UMa obtained with the Hubble Space Telescope/Faint Object Spectrograph (HST/FOS) on 1994 August and November is analysed with eclipse mapping techniques to produce spatially resolved spectra of its accretion disk and gas stream as a function of distance from the disk centre. The inner accretion disk is characterized by a blue continuum filled with absorption bands and lines, which cross over to emission with increasing disk radius, similar to that reported at optical wavelengths. The comparison of spatially resolved spectra at different azimuths reveals a significant asymmetry in the disk emission at ultraviolet (UV) wavelengths, with the disk side closest to the secondary star showing pronounced absorption by an 'iron curtain' and a Balmer jump in absorption. These results suggest the existence of an absorbing ring of cold gas whose density and/or vertical scale increase with disk radius. The spectrum of the infalling gas stream is noticeably different from the disc spectrum at the same radius suggesting that gas overflows through the impact point at the disk rim and continues along the stream trajectory, producing distinct emission down to 0.1 R(sub LI). The spectrum of the uneclipsed light shows prominent emission lines of Lyalpha, N v lambda1241, SiIV Lambda 1400, C IV Lambda 1550, HeII Lambda 1640, and MgII Lambda 2800, and a UV continuum rising towards longer wavelengths. The Balmer jump appears clearly in emission indicating that the uneclipsed light has an important contribution from optically thin gas. The lines and optically thin continuum emission are most probably emitted in a vertically extended disk chromosphere + wind. The radial temperature profiles of the continuum maps are well described by a steady-state disc model in the inner and intermediate disk regions (R greater than or equal to 0.3R(sub LI) ). There is evidence of an increase in the mass accretion rate from August to November (from V = 10 (exp -8.3 +/-0.1) to 10(exp -8.1 +/- 0.1 solar mass yr(exp -1)), in accordance with the observed increase in brightness. Since the UX UMA disc seems to be in a high mass accretion, high-viscosity regime in both epochs, this result suggests that the mass transfer rate of UX UMA varies substantially (approximately equal to 50 per cent) on time-scales of a few months. It is suggested that the reason for the discrepancies between the prediction of the standard disk model and observations is not an inadequate treatment of radiative transfer in the disc atmosphere, but rather the presence of addition important sources of light in the system besides the accretion disk (e.g., optically thin contiuum emission from the disk wind and possible absorption by circumstellar cool gas).

Baptista, Raymundo↗

The Present and Future of Secondary Organic Aerosol Direct Forcing on Climate

Secondary organic aerosols (SOA), a subset of organic aerosols that are chemically produced in the atmosphere, are included in climate modeling calculations using very simple parameterizations. Estimates on their shortwave forcing on climate span almost two orders of magnitude, being potentially comparable to sulfate direct forcing. In the longwave, a neglected part of the spectrum when it comes to SOA, the direct SOA forcing could exceed that of sulfate and black carbon, although in absolute values it is much weaker than the shortwave forcing. Critical for these estimates is the vertical distribution of the climate active agents, pointing to SOA temperature-dependent volatility. Over the last few years, research also revealed the highly oxidized character of organic aerosol and its chemical aging in the atmosphere that partially leads to the formation of brown carbon, an absorbing form of organic aerosol. This review summarizes critical advances in the understanding of SOA behavior and properties relevant to direct climate forcing and puts them in perspective with regard to primary organic aerosol and brown carbon. These findings also demonstrate an emerging dynamic picture of organic aerosol that has not yet been integrated in climate modeling. The challenges for the coming years in order to reduce uncertainties in the direct organic aerosol climate impact are discussed. High priority for future model development should be given to the dynamic link between “white” and “brown” organic aerosol and between primary and secondary organic aerosol. The SOA temperature-dependent volatility parameterizations and wavelength-dependent refractive index should be also included.

Kostas Tsigaridis↗

A Process with Decoupled Absorber Kinetics and Solvent Regeneration through Membrane Dewatering and In-Column Heat Transfer (Final Report)

This report summarizes the work conducted on project DE-FE0031604 where University of Kentucky Center for Applied Energy (UK CAER) has validated its intensified CO 2 capture process through substantial enhancements to the kinetics of the absorption process and energy reductions by absorber temperature profile modification, dewatering and heat integration technologies for achieving significant capital and operating cost reductions. To address DOE’s objective of improving post-combustion CO 2 capture technology and reducing associated cost, UK CAER employed an intensified process which combined three key aspects targeted at overcoming inherent limitations or barriers in the conventional CO 2 capture and desorption process. The process designed to be independent of the type of solvent used, included (1) the use of 3-D printed two-channel structured packing material to control the temperature profile and increase the CO 2 absorption rate in the absorber, (2) a zeolite membrane dewatering unit for dewatering of the carbon-rich solvent to decouple solvent concentration needs for CO 2 absorption and desorption, and (3) a rich-split feed with two-phase flow heat transfer prior to the stripper that provided a secondary point of vapor generation to provide energy savings in steam extraction and solvent regeneration. The project was executed over two budget periods. This involved testing of individual process components which included the advanced heat transfer packing and the dewatering membrane on UK CAER’s 30 liter per minute (L/min) CO 2 (3” Column) capture bench unit with simulated flue gas in the first budget period. Subsequent scaled-up testing of these components together with the split-feed configuration were also tested in UK CAER’s 0.1 MWth CO 2 capture unit with coal-derived flue gas in the second-budget period. Long term studies were done during this period to assess process and solvent performance over extended duration. Project partners Lawrence Livermore National Laboratory (LLNL) and Media & Process Technology (MPT) led the development efforts for the advanced packing material and dewatering membrane respectively. Data from the long term testing was used as input for an environmental, health and safety (EH&S) assessment for the process and scaled technology performed by ALL4 LLC. Trimeric Corporation also completed a techno-economic analysis (TEA) for the UK CAER technology which was compared to the DOE reference Case B12B. Tests on the 3” column capture unit showed that the advanced heat transfer packing could be used to lower the bulge temperature in the absorber, and this was also proven in the scaled testing in the 0.1 MWth CO 2 capture unit. The bulge temperature could be lowered by >10 °C, changing the temperature profile in the absorber, and showed potential to enhance absorption with the ability to tailor the profile to provide conditions suitable for a solvent’s properties and kinetics. Conditions for short term evaluation of a 19” zeolite dewatering membrane on the 3” column capture unit yielded desirable fluxes and sustained rejection rates of >80%. However, for the scaled testing of six membrane modules consisting of 21 parts of 31-inch-long membrane tubes in each bundle (surface area 0.3 m 2 ), over a more extended duration, similar rejection rates could not be achieved. With the split-feed of the rich stream to the stripper, improved heat recovery minimized waste heat exiting the top of the stripper. The stripper exhaust temperatures could be reduced by >10 °C; reducing the amount of water vaporization contributed to lowering the regeneration energy by ~ 15%. The energy benefit could be sustained from the long term monitoring of the solvent performance. The solvent properties were not significantly impacted over the long-term operations. The benefits of the UK CAER process demonstrated experimentally were mostly validated from the TEA comparing a commercial scale application of the technology to DOE reference Case B12B. The cost of CO 2 capture for the UK CAER technology was estimated to be ~$34.97/tonne of CO 2 captured; a reduction of 23% compared to Case B12B. The increase in cost of electricity was also shown to be 16% lower than that of Case B12B. The total parasitic demand was also shown to be 11% lower. The key drivers for the benefits are a result of the process intensification approaches employed in the UK CAER technology for enhanced solvent performance, effective heat recovery and improved energy performance. The EH&S assessment did not find any major environmental concerns or barriers to the full scale implementation of the technology.

20 FOSSIL-FUELED POWER PLANTS↗

Surface Water Disinfection Byproducts and Organic Matter Characterization Data Associated with: “Disinfection byproducts formed during drinking water treatment reveal an export control point for dissolved organic matter in a subalpine headwater stream”

This dataset is associated with the publication “Disinfection byproducts formed during drinking water treatment reveal an export control point for dissolved organic matter in a subalpine headwater stream” published in Water Research X (Leonard et al. 2022; https://doi.org/10.1016/j.wroa.2022.100144). The associated study analyzed temporal trends from the Town of Crested Butte water treatment facility and synoptic sampling at Coal Creek in Crested Butte, Colorado, US. This work demonstrates how drinking water quality archives combined with synoptic sampling and targeted analyses can be used to identify and understand export control points for dissolved organic matter. This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) metadata and international geo-sample number (IGSN) mapping file; (4) dissolved organic carbon (DOC), ultraviolet absorbance at 254 nanometers (UV254), total nitrogen (TN), and specific ultraviolet absorbance (SUVA) data; (5) disinfection bioproduct formation potential (DBP-FP) data; (6) readme; (7) methods codes; (8) water collection protocol; (9) folder of high resolution characterization of organic matter via 12 Tesla Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory); and (10) folder of excitation emissions matrix (EEM) spectra. The FTICR folder contains a file of DOC (measured as non-purgeable organic carbon; NPOC) used for FTICR sample preparation. The FTICR folder also contains three subfolders: one subfolder containing the raw .xml data files, one containing the processed data, and the other containing instructions for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. All files are .csv, .pdf, .dat, .R, .ref, or .xml

54 ENVIRONMENTAL SCIENCES↗

Optical communication with semiconductor laser diodes

A 25 megabit/sec direct detection optical communication system that used Q=4 PPM signalling was constructed and its performance measured under laboratory conditions. The system used a single-mode AlGaAs laser diode transmitter and low noise silicon avalanche photodiode (APD) photodetector. Comparison of measured performance with the theoretical revealed that modeling the APD output as a Gaussian process under conditions of negligible background radiation and low (less than 10 to the -12 power A) APD bulk leakage currents leads to substantial underestimates of optimal APD gain to use and overestimates of system bit error probability. A procedure is given to numerically compute system performance which uses the more accurate Webb's Approximation of the exact Conradi distribution for the APD ouput signal that does not require excessive amounts of computer time (a few minutes of VAX 8600 CPU time per system operating point). Examples are given which illustrate the breakdown of the Gaussian approximation in assessing system performance. This system achieved a bit error probability of 10 to the -6 power at a received signal energy corresponding to an average of 60 absorbed photons/bit and optimal APD gain of 700.

Davidson, F.↗