Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “molecular”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15

Molecular gas and star formation in HI-deficient Virgo cluster galaxies

Mapping of the CO emission line in 42 Virgo cluster galaxies reveals that the molecular gas contents and distributions are roughly normal in severaly HI-deficient Virgo spirals. The survival of the molecular component mitigates the impact of the HI-stripping on star formation and subsequent galactic evolution. For spirals which are deficient in HI by a factor of 10, far-infrared, H alpha line, and nonthermal radio continuum luminosities are lower by no more than a factor of 2. The fact that the inner galactic disks are stripped of HI, while CO is normal, suggests that the lifetime of the molecular phase is approximately one billion years in the inner regions of luminous spirals.

Kenney, Jeffrey D.↗

Structure and kinematics of the molecular spiral arms in M51

Mapping of the CO(1-0) emission from the spiral galaxy was made with the Onsala 20 m antenna. The observations show that the emission is considerably enhanced in spiral arms which appear to originate as intense ridges of emission about 1 kpc from the nucleus. One of the main objectives for the 1986 observations was to study the variations of the tangential velocity component of molecular gas across a spiral arm. The radial velocity was found to have a velocity shift similar to that predicted by the density wave theory. The present (1986) observations of the inner southern spiral arm of M51 show that the tangential velocity component also behaves in a way which conforms with the density wave model. The molecular arms were compared with the H alpha ionized gas arms of Tully (1974) and it was found that the ionized gas appears to have its maximum intensity slightly outside the molecular arm.

Rydbeck, G.↗

The effects of molecular weight on the single lap shear creep and constant strain rate behavior of thermoplastic polyimidesulfone adhesive

The bonded shear creep and constant strain rate behaviors of zero, one, and three percent endcapped thermoplastic polyimidesulfone adhesive were examined at room and elevated temperatures. Endcapping was accomplished by the addition of phthalic anhydrides. The primary objective was to determine the effects of molecular weight on the mechanical properties of the adhesive. Viscoelastic and nonlinear elastic constitutive equations were utilized to model the adhesive. Ludwik's and Crochet's relations were used to describe the experimental failure data. The effects of molecular weight changes on the above mentioned mechanical behavior were assessed. The viscoelastic Chase-Goldsmith and elastic nonlinear relations gave a good fit to the experimental stress strain behavior. Crochet's relations based on Maxwell and Chase-Goldsmith models were fit to delayed failure data. Ludwik's equations revealed negligible rate dependence. Ultimate stress levels and the safe levels for creep stresses were found to decrease as molecular weight was reduced.

Dembosky, Stanley K.↗

Observational constraints on the interaction of giant molecular clouds with the solar system

The properties of the molecular cloud distribution are summarized, with special emphasis on the solar neighborhood. It is shown that the mass density within molecular clouds is sufficiently low that passing or grazing encounters cannot be significant in the perturbation of cometary orbits at 40,000 AU. The mean time for the sun between penetrating encounters of GMCs is about 1.5 Gyr with a typical duration of 1 Myr. The long time interval between encounters rules out a link between short-term periodicities in the geologic record and molecular cloud passages.

Scoville, N. Z.↗

Bipolar flows, molecular gas disks, and the collapse and accretion of rotating interstellar clouds

Rigorous numerical models of the collapse and accretion of rotating, axisymmetric, isothermal interstellar clouds are studied. The results show that molecular gas disks and evacuated bipolar cavities both appear to be natural consequences of the collapse of rotating interstellar clouds. Dynamically significant magnetic fields may not be necessary for explaining either phenomenon. The models strongly support theoretical models of the type where an isotropic wind from a pre-main sequence star is extrinsically collimated by a rotationally derived molecular gas cloud. The models imply that collimation should be strongest on small scales where rotational effects are most important, i.e., in the dense region of the molecular gas disk.

Boss, Alan P.↗

Molecules in galaxies. IV - Molecular and atomic hydrogen in Virgo cluster galaxies

If gas and dust are well mixed in a galaxy, the dust mass should be proportional to the sum of the masses of atomic and molecular gas. This assumption has been used to estimate the mean conversion ratio between the flux in the CO J = 1-0 line and the molecular gas mass of a galaxy using a set of observations of the 100 microns continuum flux density, the H I 21 cm line flux and the CO line flux for a sample of spiral galaxies in the Virgo cluster; these galaxies have a wide variation in the ratio of CO to H I line flux. The result, N(H2) = 6.3 + or - 3.5 x 10 to the 20th mol/sq cm/(K x km/s), is in agreement with values inferred from observations of the molecular interstellar medium in the Galaxy.

Knapp, G. R.↗

Star formation in molecular clouds - Observation and theory

Star-formation (SF) processes occurring on the scale of giant molecular clouds (10 to the 6th solar masses and 10 to the 20th cm) or smaller are discussed, reviewing the results of recent theoretical and observational investigations. Topics examined include the origin of stellar masses; bimodal SF; initial mass functions; binary stars, bound clusters, and hierarchical fragmentation; and the efficiency of SF. The properties of molecular clouds and the origin of substructures in molecular clumps are explored in detail, and consideration is given to gravitational collapse and protostars, bipolar outflows from young stellar objects, visible young stellar objects, and the implications for binary-star and planetary-system formation.

Shu, Frank H.↗

I(CO)/N(H2) conversions and molecular gas abundances in spiral and irregular galaxies

Observations of emission in the J = 1-0 rotational transition of interstellar CO are used to obtain column densities and masses of hydrogen. By taking into account the effects of variations in molecular cloud parameters on conversion factors between integrated CO intensity and molecular hydrogen column density, it is shown that conversion factors are very sensitive to the kinetic temperature of the emitting gas. Results indicate that the gas temperatures in systems with high star formation rates can be quite high, and it is suggested that use of a standard conversion factor will lead to systematic overestimation of the amount of molecular gas.

Maloney, Philip↗

The large-scale distribution of molecular gas in the first Galactic quadrant

The emission parameters for the molecular component of the interstellar medium are determined throughout the first Galactic quadrant. Face-on maps of the peak midplane molecular density, scale height, and offset from b = 0 deg with roughly 300 pc resolution are presented. These maps are compared with the distribution of cataloged H II regions to test whether both species trace the same Galactic locations. The properties of the spiral (or ringlike) arms are deduced from the derived images and pitch-angle upper limits are estimated. The H II regions are strongly correlated with the dense molecular rings.

Clemens, Dan P.↗

HCO emission from H II-molecular cloud interface regions

A survey of well-known molecular clouds in the four strongest HCO N(k-,k+) = 1(01)-O(60) hyperfine transitions has been carried out to determine the prevalence of HCO and to study its chemistry. HCO emission was observed in seven molecular clouds. Three of these, NGC 2264, W49, and NGC 7538, were not previously known sources of HCO. In addition, NGC 2024 and Sgr B2 were mapped and shown to have extensive HCO emission. The survey results show the HCO abundance to be enhanced in H II-molecular cloud interface regions and support a correlation between C(+) and HCO emission. The strength of the HCO emission in NGC 2024 is interpreted in terms of this enhancement and the source structure and proximity to Earth.

Schenewerk, M. S.↗

Influence of substrate misorientation on defect and impurity incorporation in GaAs/AlGaAs heterostructures grown by molecular-beam epitaxy

GaAS/AlGaAs heterostructures have been grown by molecular-beam epitaxy on GaAs substrates intentionally oriented (tilted) a few degrees (0-6.5) off the (001) plane towards either (111)A, (111)B, or (011). It was observed that the 4-K photoluminescence and low-field electron transport properties of these structures may be functions of the substrate tilt angle and tilt direction, depending on the concentration of impurities incorporated during growth. A substrate tilt during molecular-beam epitaxy is observed to have the largest effect on these properties when the background impurity concentration in the molecular-beam epitaxial machine is high. This supports the contention that the observed changes in material characteristics are due to differences in the incorporation of defects and impurities. The incorporation of defects and impurities are reduced by using substrates tilted toward (111)A, in comparison to nominally flat (001) substrates or substrates tilted toward (111)B.

Radulescu, D. C.↗

Molecular clouds in the Carina arm - The largest objects, associated regions of star formation, and the Carina arm in the Galaxy

The Columbia CO survey of the southern Galactic plane is used to identify giant molecular clouds and cloud complexes in the Vela-Carina-Centaurus section of the Galaxy. Twenty-seven giant molecular clouds between l = 270 and 300 deg are catalogued and their heliocentric distances given. In addition, 16 clouds at l greater than 300 deg beyond the solar circle extend the catalog to include the very distant portion of the Carina arm. The most massive clouds in the catalog trace the Carina arm over 23 kpc in the plane of the Galaxy. The average mass of these objects is 1.4 x 10 to the 6th solar, and their average spacing along the arm is 700 pc. The composite distribution projected onto the Galactic plane of the largest molecular clouds in the Carina arm and of similarly massive clouds in the first and second quadrants strongly suggests that the Carina and Sagittarius arms form a single spiral arm about 40 kpc in length wrapping two-thirds of the way around the Galaxy. Descriptions of each cloud, including identification of associated star-forming regions, are presented in an appendix.

Grabelsky, D. A.↗

Measurement Of Molecular Mobilities Of Polymers

New molecular-probe technique used to measure molecular mobility of polymer. Method based on use of time-resolved electron-spin resonance (ESR) spectroscopy to monitor decay of transient nutation amplitudes from photoexcited triplet states of probe molecules with which polymer is doped. The higher molecular mobility of polymer matrix, the faster nutation amplitudes of the probe molecules decay.

Kim, Soon Sam↗

Solution of multi-center molecular integrals of Slater-type orbitals

The troublesome multi-center molecular integrals of Slater-type orbitals (STO) in molecular physics calculations can be evaluated by using the Fourier transform and proper coupling of the two center exchange integrals. A numerical integration procedure is then readily rendered to the final expression in which the integrand consists of well known special functions of arguments containing the geometrical arrangement of the nuclear centers and the exponents of the atomic orbitals. A practical procedure was devised for the calculation of a general multi-center molecular integrals coupling arbitrary Slater-type orbitals. Symmetry relations and asymptotic conditions are discussed. Explicit expressions of three-center one-electron nuclear-attraction integrals and four-center two-electron repulsion integrals for STO of principal quantum number n=2 are listed. A few numerical results are given for the purpose of comparison.

Tai, H.↗

Star formation rates and the far-infrared luminosity of Galactic molecular clouds

The CO luminosity, far-IR luminosity, and virial mass of 55 molecular clouds are determined and related to star formation rates (SFRs) in the clouds. The SFR of OB stars per unit of available molecular mass is found to be independent of cloud mass and varies widely over a range of about 100 for clouds of mass between 30,000 and five million solar masses. The far-IR luminosity is proportional to the first power of the CO luminosity for clouds undergoing high-mass star formation. There are massive clouds without any current high-mass star formation. The average gas depletion time is about 2.5 billion yr. The far-IR luminosity-to-mass ratio for isolated or weakly interacting spiral galaxies observed by IRAS is twice that for the average Galactic molecular cloud. The star formation mechanism operating in strongly interacting galaxies is five times more efficient than that of the most active Galactic cloud and 30 times that of the average Galactic cloud.

Mooney, T. J.↗

No molecular gas disk in S106

The radio and optical bipolar H II region, S106, is bisected by a dark lane. The premain-sequence object, S106 IR, which is the source of a powerful ionized stellar wind, is the exciting source of this region and is found at the center of the equatorial emission gap. The existence of a massive, extended, molecular gas disk has previously been suggested as an explanation for the peculiar morphology of this source, and S106 has widely been quoted as the best example of theoretically posited accretion disks. The new, high-resolution, CS and (C-13)O observations presented show that the molecular emission, previously attributed to a disk structure, actually originates from distinct masses of molecular gas, swept up from the ambient cloud core by the ionized lobes.

Barsony, M.↗

Correlation of molecular valence- and K-shell photoionization resonances with bond lengths

The relationship between the interatomic distance and the positions of valence-shell and K-shell sigma(asterisk) photoionization resonances is investigated theoretically for the molecules C2, F2, N2, O2, CO, NO, C2H2, C2H4, C2H6, HCN, H2CO, N20, CO2, and C2N2. The results of molecular-orbital computations are presented in three-dimensional diagrams, which are shown to be similar to the wave functions of a particle in a cylindrical well, confirming the validity of free-electron molecular-orbital (FEMO) approximations for modeling the potential along the symmetry axis. FEMO orbital energies and resonance positions are found to be in good agreement with previous theoretical and experimental results. Also included is a Feshbach-Fano analysis of the relevance of virtual-valence orbitals to the appearance of single-channel resonances in molecular photoionization cross sections.

Sheehy, J. A.↗

Nonequilibrium molecular motion in a hypersonic shock wave

Molecular velocities have been measured inside a hypersonic, normal shock wave, where the gas experiences rapid changes in its macroscopic properties. As first hypothesized by Mott-Smith, but never directly observed, the molecular velocity distribution exhibits a qualitatively bimodal character that is derived from the distribution functions on either side of the shock. Quantitatively correct forms of the molecular velocity distribution function in highly nonequilibrium flows can be calculated, by means of the Direct Simulation Monte Carlo technique.

Pham-Van-diep, G.↗