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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Effect of velocity ratio on plane mixing layer development

An experimental study has been conducted to investigate the effect of velocity ratio on the development of a plane mixing layer to self-similarity. Plane mixing layers with five different velocity ratios (0.5, 0.6, 0.7, 0.8 and 0.9) were generated in a newly designed mixing layer wind tunnel with both initial boundary layers tripped. For each velocity ratio, mean flow and turbulence measurements were obtained at eight streamwise locations with a single cross-wire probe. The results indicate that the splittter plate wake plays a very dominant and, in some cases, a lasting role in the development of the mixing layer. For velocity ratios between 0.5 and 0.7, self-similarity of the mixing layer was observed with the asymptotic states comparable. Mixing layers with the higher velocity ratios failed to achieve a self-similar state within the measurement domain. The development distance decreased with increasing velocity ratio up to 0.7, after which it appeared to increase. Almost all of the observed effects may be attributed to the presence and subsequent behavior of the splitter plate wake.

Mehta, R. D.↗
NASA NTRS1992

Slush hydrogen pressurized expulsion studies at the NASA K-Site Facility

An experiment test series of the slush hydrogen (SLH2) project at the NASA LeRC Plum Brook K-Site Facility was completed. This testing was done as part of the characterization and technology database development on slush hydrogen required for the National Aero-Space Plane (NASP) Program. The primary objective of these experiments was to investigate tank thermodynamic parameters during the pressurized expulsion of slush hydrogen. To accomplish this, maintenance of tank pressure control was investigated during pressurized expulsion of slush hydrogen using gaseous hydrogen and gaseous helium pressurant. In addition, expulsion tests were performed using gaseous helium for initial pressurization, then gaseous hydrogen during expulsion. These tests were conducted with and without mixing of the slush hydrogen. Results from the testing included an evaluation of tank pressure control, pressurant requirements, SLH2 density change, and system mass and energy balances.

Whalen, Margaret V.↗
NASA NTRS1992

Slush hydrogen pressurized expulsion studies at the NASA K-Site Facility

An experiment test series of the slush hydrogen (SLH2) project at the NASA LeRC Plum Brook K-Site Facility was completed. This testing was done as part of the characterization and technology database development on slush hydrogen required for the National Aero-Space Plane (NASP) Program. The primary objective of these experiments was to investigate tank thermodynamic parameters during the pressurized expulsion of slush hydrogen. To accomplish this, maintenance of tank pressure control was investigated during pressurized expulsion of slush hydrogen using gaseous hydrogen and gaseous helium pressurant. In addition, expulsion tests were performed using gaseous helium for initial pressurization, then gaseous hydrogen during expulsion. These tests were conducted with and without mixing of the slush hydrogen. Results from the testing included an evaluation of tank pressure control, pressurant requirements, SLH2 density change, and system mass and energy balances.

Whalen, Margaret V.↗
NASA NTRS1993

Local isotropy in distorted turbulent boundary layers at high Reynolds number

This is a report on the continuation of our experimental investigations of the hypothesis of local isotropy in shear flows. This hypothesis, which states that at sufficiently high Reynolds numbers the small-scale structures of turbulent motions are independent of large-scale structures and mean deformations, has been used in theoretical studies of turbulence and computational methods such as large-eddy simulation. Since Kolmogorov proposed his theory, there have been many experiments, conducted in wakes, jets, mixing layers, a tidal channel, and atmospheric and laboratory boundary layers, in which attempts have been made to verify - or refute - the local-isotropy hypothesis. However, a review of the literature over the last five decades indicated that, despite all these experiments in shear flows, there was no consensus in the scientific community regarding this hypothesis, and, therefore, it seemed worthwhile to undertake a fresh experimental investigation into this question.

Saddoughi, Seyed G.↗
NASA NTRS1995

Effects of Initial Conditions on a Single Jet in Crossflow

An experimental investigation of the effects of jet inlet flow conditions has been conducted for the isothermal mixing of a single jet injected into a crossflow. Jet penetration and mixing was studied using planar Mie scattering to measure time-averaged jet mixture fraction distributions. The effects of 'passive' control methods such as jet 'tabs' and jet swirl are reported. Mixing effectiveness, determined using a spatial unmixedness parameter based on the variance of the mean jet concentration distributions, was compared to a baseline case of a round jet injected into a uniform crossflow. All results are compared at a jet-to-mainstream momentum-flux ratio of 8.5. In the near-field, the mixing rates are similar to, or less than, the baseline configuration using this measure of mixedness. None of the tested configurations appear to significantly augment mixing within a downstream distance of 3 diameters of an equivalent-area round orifice.

Liscinsky, D. S.↗
NASA NTRS1996

Functional and Multifunctional Polymers: Materials for Smart Structures

The ultimate goal of the research in smart structures and smart materials is the development of a new generation of products/devices which will perform better than products/devices built from passive materials. There are a few examples of multilayer polymer systems which function as smart structures, e.g. a synthetic muscle which is a multilayer assembly of a poly(ethylene) layer, a gold layer, and a poly(pyrrole) layer immersed in a liquid electrolyte. Oxidation and reductions of the active pyrrole layer causes the assembly to reversibly deflect and mimic biological muscles. The drawback of such a setup is slow response times and the use of a liquid electrolyte. We have developed multifunctional polymers which will eliminate the use of a liquid electrolyte, and also because the functionalities of the polymers are within a few hundred angstroms, an improved response time to changes in the external field should be possible. Such multifunctional polymers may be classified as the futuristic 'smart materials.' These materials are composed of a number of different functionalities which work in a synergistic fashion to function as a device. The device performs on the application of an external field and such multifunctional polymers may be scientifically labeled as 'field responsive polymers.' Our group has undertaken a systematic approach to develop functional and multifunctional polymers capable of functioning as field responsive polymers. Our approach utilizes multicomponent polymer systems (block copolymers and graft copolymers), the strategy involves the preparation of block or graft copolymers where the functionalities are limited to different phases in a microphase separated system. Depending on the weight (or volume) fractions of each of the components, different microstructures are possible. And, because of the intimate contact between the functional components, an increase in the synergism between the functionalities may be observed. In this presentation, three examples of multifunctional polymers developed in our labs will be reported. The first class of multifunctional polymers are the microphase separated mixed (ionic and electronic) conducting or MIEC block copolymers. The second class being developed in our labs are the biocompatible conductive materials and the conductive fluids. The final class may be considered microwave active smart polymers.

Arnold, S.↗
NASA NTRS2016

Evaluating A Priori Ozone Profile Information Used in TEMPO Tropospheric Ozone Retrievals

Ozone (O3) is a greenhouse gas and toxic pollutant which plays a major role in air quality. Typically, monitoring of surface air quality and O3 mixing ratios is primarily conducted using in situ measurement networks. This is partially due to high-quality information related to air quality being limited from space-borne platforms due to coarse spatial resolution, limited temporal frequency, and minimal sensitivity to lower tropospheric and surface-level O3. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite is designed to address these limitations of current space-based platforms and to improve our ability to monitor North American air quality. TEMPO will provide hourly data of total column and vertical profiles of O3 with high spatial resolution to be used as a near-real-time air quality product. TEMPO O3 retrievals will apply the Smithsonian Astrophysical Observatory profile algorithm developed based on work from GOME, GOME-2, and OMI. This algorithm uses a priori O3 profile information from a climatological data-base developed from long-term ozone-sonde measurements (tropopause-based (TB) O3 climatology). It has been shown that satellite O3 retrievals are sensitive to a priori O3 profiles and covariance matrices. During this work we investigate the climatological data to be used in TEMPO algorithms (TB O3) and simulated data from the NASA GMAO Goddard Earth Observing System (GEOS-5) Forward Processing (FP) near-real-time (NRT) model products. These two data products will be evaluated with ground-based lidar data from the Tropospheric Ozone Lidar Network (TOLNet) at various locations of the US. This study evaluates the TB climatology, GEOS-5 climatology, and 3-hourly GEOS-5 data compared to lower tropospheric observations to demonstrate the accuracy of a priori information to potentially be used in TEMPO O3 algorithms. Here we present our initial analysis and the theoretical impact on TEMPO retrievals in the lower troposphere.

ozone↗
NASA NTRS2016

Evaluating a Priori Ozone Profile Information Used in TEMPO Tropospheric Ozone Retrievals

Ozone (O3) is a greenhouse gas and toxic pollutant which plays a major role in air quality. Typically, monitoring of surface air quality and O3 mixing ratios is primarily conducted using in situ measurement networks. This is partially due to high-quality information related to air quality being limited from space-borne platforms due to coarse spatial resolution, limited temporal frequency, and minimal sensitivity to lower tropospheric and surface-level O3. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite is designed to address these limitations of current space-based platforms and to improve our ability to monitor North American air quality. TEMPO will provide hourly data of total column and vertical profiles of O3 with high spatial resolution to be used as a near-real-time air quality product.TEMPO O3 retrievals will apply the Smithsonian Astrophysical Observatory profile algorithm developed based on work from GOME, GOME-2, and OMI. This algorithm uses a priori O3 profile information from a climatological data-base developed from long-term ozone-sonde measurements (tropopause-based (TB) O3 climatology). It has been shown that satellite O3 retrievals are sensitive to a priori O3 profiles and covariance matrices. During this work we investigate the climatological data to be used in TEMPO algorithms (TB O3) and simulated data from the NASA GMAO Goddard Earth Observing System (GEOS-5) Forward Processing (FP) near-real-time (NRT) model products. These two data products will be evaluated with ground-based lidar data from the Tropospheric Ozone Lidar Network (TOLNet) at various locations of the US. This study evaluates the TB climatology, GEOS-5 climatology, and 3-hourly GEOS-5 data compared to lower tropospheric observations to demonstrate the accuracy of a priori information to potentially be used in TEMPO O3 algorithms. Here we present our initial analysis and the theoretical impact on TEMPO retrievals in the lower troposphere.

TEMPO↗
NASA NTRS2020

Structural evolution, electrochemical kinetic properties, and stability of A-site doped perovskite Sr(1-x)Yb(x)CoO(3-δ)

Mixed ionic and electronic conducting (MIEC) perovskite SrCoO(3-δ) is a widely studied (electro)catalyst for the oxygen reduction reaction (ORR) and possesses different crystal structures at different temperatures. These temperature dependent phase transitions significantly impact the ordering of oxygen vacancies and electrochemical kinetic properties as well as the reliability of the related devices. Some of the crystal structures formed, e.g. hexagonal phases, turn out to be almost impermeable to oxygen gas. Therefore, it is important to stabilize the crystal structure of SrCoO(3-δ) that favors the ORR over a wide temperature range. Herein, the partial substitution of the A-site Sr with Yb is systematically studied, including synthesis, characterization and analysis of structural evolution, electrochemical kinetic properties, thermal stability, and stability in a CO2-containing atmosphere. The results indicate that Sr(0.90)Yb(0.10)CoO(3-δ) is able to stabilize the tetragonal crystal structure with less ordered oxygen vacancies, leading to polarization resistances of 0.051, 0.115 and 0.272 U sq.cm at 750, 700 and 650 °C, respectively, on symmetrical cells. Sr(0.90)Yb(0.10)CoO(3-δ) demonstrates a very stable surface oxygen vacancy distribution and electronic structure near oxygen vacancies but dissociation of adsorbed oxygen molecules into atomic oxygen is affected by surface Sr segregation, and polarization resistance degradation is mainly induced by surface Sr segregation. Furthermore, Sr(0.90)Yb(0.10)CoO(3-δ) exhibits excellent thermal stability as well as excellent recovery stability and improved polarization performance after a few pure air/CO2-containing air treatment cycles at 700 °C. However, a hysteresis behavior of polarization performance is observed at 650 °C during gas cycling treatment, which may cause long-term degradation of the Sr(0.90)Yb(0.10)CoO(3-δ) electrode. The different polarization behaviors during gas cycling treatment are induced by different sensitivities of the formed surface strontium carbonate and chemisorbed surface oxo-carbonaceous species to different operating temperatures.

electrochemical kinetic↗
NASA NTRSDate not supplied

USM3D Simulations for Third Sonic Boom Workshop

The NASA USM3D flow solver was used to compute test cases for the Third AIAA Sonic Boom Prediction Workshop (SBPW3). The test cases include a nearfield biconvex shock-plume interaction wind tunnel model, and the C608 Low Boom Flight Demonstrator. Numerical simulations were conducted on the mixed-element and tetrahedral grids provided by the workshop committee, as well as a family of grids generated by an in-house approach for sonic boom analyses known as BoomGrid. The near-field pressure signatures were extracted, propagated to the ground and the perceived loudness levels on the ground were computed. The USM3D near-field pressure signatures, corresponding ground signatures, and loudness levels on the ground are compared with that of mean values from other workshop participants. The effect of three flux-limiters on the accuracy of near-field pressure signatures prediction was investigated and results are compared with that of mean values from other workshop participants. The effect of using wall function grids in accurately predicting near-field pressure signatures was also evaluated.

Supersonics↗
NASA NTRSDate not supplied

USM3D Simulations for the Third Sonic Boom Prediction Workshop (SBPW-3)

The NASA USM3D flow solver was used to compute test cases for the Third AIAA Sonic Boom Prediction Workshop (SBPW3). The test cases include a nearfield biconvex shock-plume interaction wind tunnel model, and the C608 Low Boom Flight Demonstrator. Numerical simulations were conducted on the mixed-element and tetrahedral grids provided by the workshop committee, as well as a family of grids generated by an in-house approach for sonic boom analyses known as BoomGrid. The near-field pressure signatures were extracted, propagated to the ground and the perceived loudness levels on the ground were computed. The USM3D near-field pressure signatures, corresponding ground signatures, and loudness levels on the ground are compared with that of mean values from other workshop participants. The effect of three flux-limiters on the accuracy of near-field pressure signatures prediction was investigated and results are compared with that of mean values from other workshop participants. The effect of using wall function grids in accurately predicting near-field pressure signatures was also evaluated.

Supersonics↗
NASA NTRS2022

USM3D Simulations for the Third AIAA Sonic Boom Prediction Workshop

The NASA USM3D flow solver was used to compute test cases for the Third AIAA Sonic Boom Prediction Workshop (SBPW3). The test cases included a nearfield biconvex shock-plume interaction wind tunnel model and the C608 Low Boom Flight Demonstrator. Numerical simulations were conducted on the mixed-element and tetrahedral grids provided by the workshop committee, as well as a family of grids generated by an in-house approach known as BoomGrid. The nearfield pressure signatures were extracted and propagated to the ground, and the perceived loudness levels on the ground were computed. The USM3D nearfield pressure signatures, corresponding ground signatures, and loudness levels on the ground were compared with that of mean values from other workshop participants. The effect of three flux-limiters on the accuracy of nearfield pressure signature prediction was investigated and results were compared with that of mean values from other workshop participants. The effect of using wall-function models for predicting nearfield pressure signatures was also evaluated. Results showed that the overpressure signatures extracted from the wall-modeled simulations and the wall-resolved simulations are in good agreement. The use of wall functions (wall-modeled simulations) allowed for approximately 23% savings in the time to solution and yielded comparable perceived loudness levels on the ground to the wall-resolved Reynolds-averaged Navier Stokes simulations.

Supersonics↗
NASA NTRSDate not supplied

The Impact of Controlled Rest on Neurobehavioral Outcomes at Top-of-Descent

INTRODUCTION: Long and irregular working hours can lead to fatigue in aviation operations. In some regions, a short nap taken on the flight deck (known as controlled rest) can be used as a countermeasure to unexpected in-flight sleepiness. We aimed to investigate the impact of taking controlled rest on neurobehavioral measures at top-of-descent. METHODS: Data from 120 long-haul (> 6 h flight duration), unaugmented flights were analyzed (n = 31 pilots). Pilots wore actigraphs and completed sleep logs before and during trips. At pre-flight and top-of-descent, pilots completed a 5-minute psychomotor vigilance task (PVT) and Karolinska Sleepiness Scale (KSS). A series of mixed-effects models were conducted to assess the impact of controlled rest on outcome measures at top-of-descent. Sleep duration in the prior 48 hours, timing of the flight, and pre-flight scores for each measure were included as covariates. RESULTS: Due to missing data, complete data from 76 flights (n = 28 participants) were available in the models examining the PVT metrics, and data from 83 flights (n = 29 participants) were available in the analyses of the KSS. Pilots who took controlled rest had faster response speeds at top-of-descent (p = .03, η2p = 0.07; estimated marginal mean [EMM] = 4.19, standard error [SE] = 0.07, 95% CI [4.08, 4.29]) than those who did not take controlled rest (EMM = 4.00, SE = 0.05, 95% CI [3.86, 4.14]). There were no differences by controlled rest status for KSS scores and PVT lapses (p values > .05, η2p values ≤ 0.01). DISCUSSION: Our results suggest that taking controlled rest may improve vigilant attention at critical phases of flight and, thus, may be a useful fatigue management tool during unaugmented flights. Further research is necessary to determine the impact of factors on the decision to take controlled rest (e.g., airline culture, personal preference) and how the controlled rest policy is applied in practice.

aviation↗
DOE OSTI2020

Manufacturing of thick composite electrode using solvent mixtures

A method of making an electrode includes the step of dispersing an active electrode material and a conductive additive in a solvent to create a mixed dispersion. The solvent has a surface tension less than 40 mN/m and an ozone forming potential of no more than 1.5 lbs. ozone/lb. solvent. A surface of a current collector is treated to raise the surface energy of the surface to at least the surface tension of the solvent or the mixed dispersion. The dispersed active electrode material and conductive additive are deposited on the current collector. The coated surface is heated to remove solvent from the coating.

25 ENERGY STORAGE↗
DOE OSTI2020

DOE-BU-26096-4

The infiltration of nanoparticle electrocatalysts into solid oxide fuel cell (SOFC) electrodes has been proven to produce a high density of electrochemically active sites, and reduce charge transfer polarization losses in SOFC electrodes. This is crucial for intermediate temperature operation, as these losses increase greatly at lower temperatures. Nickel-yttria stabilized zirconia (Ni-YSZ) cermets are low-cost, and exhibit excellent stability, but their main disadvantage stems from nickel coarsening and performance loss over their operational lifetimes. Infiltration of electrocatalyst nanoparticles has been shown to mitigate nickel coarsening and the consequent anode degradation. In this work, the effects of these infiltrants have been observed in a standard Ni-YSZ electrode. In addition to nickel, mixed ionic and electronic conducting (MIEC) phases have been infiltrated into Ni-YSZ scaffolds and their performance characterized using electrochemical impedance spectroscopy (EIS). Cross-sectional microscopy of fractured cells has been used to compare electrode microstructure and particle statistics. A model has been proposed to explain the origin of anode performance enhancement from nanoscale electrocatalysts.

Mo, Boshan↗
NASA NTRS1976

Analysis of distortion data from TF30-P-3 mixed compression inlet test

A program was conducted to reduce and analyze inlet and engine data obtained during testing of a TF30-P-3 engine operating behind a mixed compression inlet. Previously developed distortion analysis techniques were applied to the data to assist in the development of a new distortion methodology. Instantaneous distortion techniques were refined as part of the distortion methodology development. A technique for estimating maximum levels of instantaneous distortion from steady state and average turbulence data was also developed as part of the program.

King, R. W.↗
DOE OSTI2022

Numerical study of multi-component flow and mixing in a scaled fission product venting system

Numerical simulation of isothermal multi-component gas flow was conducted to study fluid flow and mixing in a scaled low-pressure, low-temperature test facility for the fission product venting system (FPVS) of a gas cooled fast reactor (GFR). The geometry of FPVS test facility was an open loop including gradual expansion coupling and two 90°pipe elbows. First, the validation of large eddy simulation (LES) wall-adapting local eddy-viscosity (WALE) turbulent model was performed for transitional flow in a circular pipe with gradual expansion. The reactingFOAM solver in OpenFOAM v8 was employed. By introducing appropriate turbulence disturbance at the flow inlet, such as turbulence intensity, the numerical results showed good agreement in (1) the velocity profile downstream of the pipe expansion measured by particle image velocimetry (PIV) in this study, and (2) the reattachment length reported in the literature. Using this validated model, the numerical simulation of flow and component mixing was performed for the FPVS with an inlet flowrate corresponding to a Reynolds number of 2,400 to investigate the flow behavior and component mixing. Standard deviation of the mass fraction of component, referred to as absolute mixing index (AMI), was calculated to quantify the mixing of components, showing that the component mixing length determined by AMI is related to the reattachment length downstream of the expansion. Additionally, this study was able to identify the best location in the FPVS test facility to measure the velocity and concentration profies where multicomponent flow is well mixed.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Structural mapping and tuning of mixed halide ions in amorphous sulfides for fast Li-ion conduction and high deformability

Amorphous sulfides are among the most promising candidates for solid electrolytes (SEs) owing to their excellent deformability and acceptable Li-ion conductivity (σion) at room temperature. However, the complex atomic structure of these amorphous materials without long-range ordering results in a lack of structural understanding and difficulties in tuning material properties. Here, in this study, we performed structural mapping of glassy sulfide SEs composed of various anion clusters using a combinatorial atomic level analysis of synchrotron X-ray-based pair distribution function (PDF) and reverse Monte-Carlo (RMC) methods, demonstrating the potential to tune σ ion in glass SEs. First, we prepared a new glassy sulfide with a mixed anion framework of two halogens (Br and I) as atomic anions, with PS 4 3- molecular anions in a Li 2 S–P 2 S 5 -based glass SE. At a specific Br content, [(Li 2 S) 0.658 (LiI 0.9 LiBr 0.1 ) 0.342 ] 0.825 [P 2 S 5 ] 0.175 recorded a σ ion of 2.27 mS cm -1 , the highest value for any glass sulfides reported to date; however, its elastic modulus was still suppressed to 14.48 GPa. PDF and RMC calculations successfully provided structural mapping of anion clusters, including two halogens. Molecular dynamics simulations of each composition confirmed that flexible coordination caused by the rattling of small polarizable Br ions in the mixed halogens of glassy SEs contributed to the superior σ ion . Our results may provide new insights into the design of superior glassy SEs that play key roles in all-solid-state batteries requiring fast Li-ion conduction and high deformability.

36 MATERIALS SCIENCE↗