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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

High-Temperature Modal Survey of a Hot-Structure Control Surface

Ground vibration tests are routinely conducted for supporting flutter analysis for subsonic and supersonic vehicles; however, for hypersonic vehicles, thermoelastic vibration testing techniques are neither well established nor routinely performed. New high-temperature material systems, fabrication technologies and high-temperature sensors expand the opportunities to develop advanced techniques for performing ground vibration tests at elevated temperatures. When high-temperature materials, which increase in stiffness when heated, are incorporated into a hot-structure that contains metallic components that decrease in stiffness when heated, the interaction between those materials can affect the hypersonic flutter analysis. A high-temperature modal survey will expand the research database for hypersonics and improve the understanding of this dual-material interaction. This report discusses the vibration testing of the carbon-silicon carbide Ruddervator Subcomponent Test Article, which is a truncated version of a full-scale hot-structure control surface. Two series of room-temperature modal test configurations were performed in order to define the modal characteristics of the test article during the elevated-temperature modal survey: one with the test article suspended from a bungee cord (free-free) and the second with it mounted on the strongback (fixed boundary). Testing was performed in the NASA Dryden Flight Research Center Flight Loads Laboratory Large Nitrogen Test Chamber.

Spivey, Natalie D.↗

Lower-Conductivity Thermal-Barrier Coatings

Thermal-barrier coatings (TBCs) that have both initial and post-exposure thermal conductivities lower than those of yttria-stabilized zirconia TBCs have been developed. TBCs are thin ceramic layers, generally applied by plasma spraying or physical vapor deposition, that are used to insulate air-cooled metallic components from hot gases in gas turbine and other heat engines. Heretofore, yttria-stabilized zirconia (nominally comprising 95.4 atomic percent ZrO2 + 4.6 atomic percent Y2O3) has been the TBC material of choice. The lower-thermal-conductivity TBCs are modified versions of yttria-stabilized zirconia, the modifications consisting primarily in the addition of other oxides that impart microstructural and defect properties that favor lower thermal conductivity.

Miller, Robert A.↗

Cases for Additive Manufacturing on the International Space Station

There are thousands of plastic or non-structural metal components on the International Space Station (ISS), any of which could require replacing sometime between resupply missions. While these may not be life critical, it can cause significant delays to flight projects that have to wait several weeks to months to receive a key part one that could have been designed and built on-board the ISS within a few hours. A plastic deposition additive manufacturing process is a low-energy, low-mass solution to many common needs on board the ISS.

Cooper, Kenneth G.↗

Spark-integrated propellant injector head with flashback barrier

High performance propellants flow through specialized mechanical hardware that allows for effective and safe thermal decomposition and/or combustion of the propellants. By integrating a sintered metal component between a propellant feed source and the combustion chamber, an effective and reliable fuel injector head may be implemented. Additionally the fuel injector head design integrates a spark ignition mechanism that withstands extremely hot running conditions without noticeable spark mechanism degradation.

Mungas, Gregory Stuart↗

Dynamically variable spot size laser system

A Dynamically Variable Spot Size (DVSS) laser system for bonding metal components includes an elongated housing containing a light entry aperture coupled to a laser beam transmission cable and a light exit aperture. A plurality of lenses contained within the housing focus a laser beam from the light entry aperture through the light exit aperture. The lenses may be dynamically adjusted to vary the spot size of the laser. A plurality of interoperable safety devices, including a manually depressible interlock switch, an internal proximity sensor, a remotely operated potentiometer, a remotely activated toggle and a power supply interlock, prevent activation of the laser and DVSS laser system if each safety device does not provide a closed circuit. The remotely operated potentiometer also provides continuous variability in laser energy output.

Gradl, Paul R.↗

A Multifunctional Smart Coating for Autonomous Corrosion Control

Corrosion is a destructive process that often causes failure in metallic components and structures. Protective coatings are the most commonly used method of corrosion control. However, progressively stricter environmental regulations have resulted in the ban of many commercially available corrosion protective coatings due to the harmful effects of their solvents or corrosion inhibitors. This work concerns the development of a multifunctional, smart coating for the autonomous control of corrosion. This coating is being developed to have the inherent ability to detect the chemical changes associated with the onset of corrosion and respond autonomously to control it. The multi-functionality of the coating is based on micro-encapsulation technology specifically designed for corrosion control applications. This design has, in addition to all the advantages of other existing microcapsules designs, the corrosion controlled release function that allows the delivery of corrosion indicators and inhibitors on demand only when and where needed. Corrosion indicators as well as corrosion inhibitors have been incorporated into microcapsules, blended into several paint systems, and tested for corrosion detection and protection efficacy. This

Calle, Luz Marina↗

Luminescence-Based Diagnostics of Thermal Barrier Coating Health and Performance

Thermal barrier coatings (TBCs) are typically composed of translucent ceramic oxides that provide thermal protection for metallic components exposed to high-temperature environments in both air- and land-based turbine engines. For advanced turbine engines designed for higher temperature operation, a diagnostic capability for the health and performance of TBCs will be essential to indicate when a mitigating action needs to be taken before premature TBC failure threatens engine performance or safety. In particular, it is shown that rare-earth-doped luminescent sublayers can be integrated into the TBC structure to produce luminescence emission that can be monitored to assess TBC erosion and delamination progression, and to map surface and subsurface temperatures as a measure of TBC performance. The design and implementation of these TBCs with integrated luminescent sublayers are presented.

Eldridge, Jeffrey I.↗

Optical Diagnostics for High-Temperature Thermal Barrier Coatings

Thermal barrier coatings (TBCs) are typically composed of translucent ceramic oxides that provide thermal protection for metallic components exposed to high-temperature environments, such as in jet turbine engines. Taking advantage of the translucent nature of TBCs, optical diagnostics have been developed that can provide an informed assessment of TBC health that will allow mitigating action to be taken before TBC degradation threatens performance or safety. In particular, rare-earth-doped luminescent sublayers have been integrated into the TBC structure to produce luminescence that monitors TBC erosion, delamination, and temperature gradients. Erosion monitoring of TBC-coated specimens is demonstrated by utilizing visible luminescence that is excited from a sublayer that is exposed by erosion. TBC delamination monitoring is achieved in TBCs with a base rare-earth-doped luminescent sublayer by the reflectance-enhanced increase in luminescence produced in regions containing buried delamination cracks. TBC temperature monitoring is demonstrated using the temperature-dependent decay time for luminescence originating from the specific coating depth associated with a rare-earth-doped luminescent sublayer. The design and implementation of these TBCs with integrated luminescent sublayers is discussed, including co-doping strategies to produce more penetrating near-infrared luminescence. It is demonstrated that integration of the rare-earth-doped sublayers is achieved with no reduction in TBC life. In addition, results for multilayer TBCs designed to also perform as radiation barriers are also presented.

Eldridge, Jeffrey I.↗

Multilayer Thermal Barrier Coating (TBC) Architectures Utilizing Rare Earth Doped YSZ and Rare Earth Pyrochlores

To allow for increased gas turbine efficiencies, new insulating thermal barrier coatings (TBCs) must be developed to protect the underlying metallic components from higher operating temperatures. This work focused on using rare earth doped (Yb and Gd) yttria stabilized zirconia (t' Low-k) and Gd2Zr2O7 pyrochlores (GZO) combined with novel nanolayered and thick layered microstructures to enable operation beyond the 1200 C stability limit of current 7 wt% yttria stabilized zirconia (7YSZ) coatings. It was observed that the layered system can reduce the thermal conductivity by approximately 45 percent with respect to YSZ after 20 hr of testing at 1316 C. The erosion rate of GZO is shown to be an order to magnitude higher than YSZ and t' Low-k, but this can be reduced by almost 57 percent when utilizing a nanolayered structure. Lastly, the thermal instability of the layered system is investigated and thought is given to optimization of layer thickness.

Thermal Barrier Coating↗

Additive Manufacturing of Liquid Rocket Engine Combustion Devices: A Summary of Process Developments and Hot-Fire Testing Results

Additive Manufacturing (AM) is an emerging technology with a focus on complex metallic component fabrication: Enables complex shapes and internal features that were not possibly with traditional manufacturing techniques, and significant schedule and overall lifecycle cost reductions. To date at the NASA Marshall Space Flight Center (MSFC), combustion devices component hardware ranging in size from 100 - 35,000 lbf has been designed and manufactured using AM and many of these pieces have been hot-fire tested.

Gradl, Paul↗

Stress Corrosion Evaluation of Elgiloy Alloy for the ISS ECLSS — Universal Waste Management System

Elgiloy® alloy (UNS R30003)—a spring material per AMS 5876D (reference 1)—is one among several alloys recently evaluated for stress corrosion cracking resistance in support of the International Space Station (ISS) Environmental Control and Life Support System (ECLSS). Elgiloy was evaluated particularly for its expected use in the Universal Waste Management System (described in references 2 and 3). Data for other alloys previously evaluated were reported in references 4 and 5. Materials included in reference 4 are Inconel 625, Hastelloy® C276, commercially pure titanium, titanium with 6% aluminum and 4% vanadium (Ti6Al4V), extra-low interstitial Ti6Al4V, and Cronidur 30. The results for Nitinol 60 are in reference 5. During the water recovery process, the metallic components fabricated from these materials are exposed to acidic solutions used for waste treatment. The purpose of the current and previous stress corrosion evaluations is to determine if these materials have adequate stress corrosion resistance.

Torres, Pablo D.↗

IIAB IRON METEORITES: FORMATION AND RELATION TO OTHER METEORITE GROUPS.

The IIAB iron meteorites are one of the largest iron meteorite groups that formed by fractional crystallization [1]. Iron meteorites formed over a range of oxygen fugacities (fO2)[2], most formed relatively reduced at~ IW–4to –2.5 (IABs), where IW= iron-wüstite buffer, to relatively oxidized at IW–1(IVBs) [2,3]. While the IIABs contain reduced mineral phases (daubré elite [1]),the fO2for IIABs is poorly constrained. The fO2of iron meteorites may have become more reducing during cooling, with oxidized phases (i.e., chromite) forming at higher temperatures and daubré elite forming at lower temperatures [4]. The O-and Cr-isotope compositions of silicates and chromite in meteorites, including iron meteorites, can determine potential genetic links to other meteorite sand con-strain if a meteorite is from the non-carbonaceous (NC) or carbonaceous (CC) group [e.g., 5–8]. Iron meteorite groups have been identified as being in the NCor CC group using Mo[9]and Ni [10] isotope compositions of their metallic component. Numerous iron meteorites contain minor amounts of silicates and oxides [e.g., 11], but most have not been analyzed for their Cr or Ti isotope compositions, with some exceptions (e.g., IIIABs [6,7],a IIG, and a IIAB[7]). We analyzed the compositions of silicates and chromite in six IIAB iron meteorites to investigate the relationship between IIABs and known meteorite groups, the fO2of IIABs, and the origin of chromite in the IIABs. *full abstract in document

Meteorite↗

NASA NDE Fracture Critical Detectable Flaw Sizes History and Methodology

NASA requires that NDE methods and inspectors demonstrate 90% Probability of Detection (POD) with 95% confidence for critical flaw sizes when inspecting fracture critical metallic components. NASA addresses the known variability of NDE inspector capability in two ways. The first, Special NDE, requires that every inspector demonstrate the required 90/95 POD, which is resource intensive. The second approach is Standard NDE for which conservative flaw sizes for different NDE methods are provided such that it is expected that most properly trained inspectors will exceed the 90/95 POD requirement. As such, individual POD demonstration testing is not required. The origin of NASA Standard NDE dates to the start of the Space Shuttle Program in the early 1970’s. In the first study to quantitatively assess NDE methods and inspectors, the performance of multiple inspectors was evaluated for different NDE methods using a large set of fatigue cracked specimens. A rudimentary POD analysis was performed to estimate the 90/95 POD flaw size for each inspector for each method. Additionally, the average and standard deviation of the 90/95 POD flaw size across the multiple inspectors was calculated to estimate the flaw size for which 95 percent of inspectors would provide the 90/95 POD capability. These estimated 90/95/95 POD flaw sizes evolved into the NASA Standard NDE flaw sizes still in use for structural analysis five decades later. The methodology for performing Standard NDE POD studies was never documented in NASA requirements. Furthermore, POD analysis methods have significantly evolved since this seminal study. Likewise, NDE methods have improved and there has been a push to reassess Standard NDE flaw sizes for existing methods, and to develop Standard NDE flaw sizes for new methods such as digital radiography. In this study, a Standard NDE POD methodology was developed and baselined using the historical data. This reanalysis of the historical data identified several deficiencies in the original test plan as well as an overall lack of conservatism in the estimated 90/95/95 POD flaw sizes. The results of this historical review and the new methodology are being incorporated into an update of NASA NDE POD requirements.

Nondestructive Evaluation↗

The Repair Maintenance and Fabrication Facility in the Common Habitat Architecture

The Common Habitat Architecture seeks to increase the habitability of long-duration human spaceflight systems. A key aspect of this is vehicle survivability. Missions beyond low Earth orbit need onboard capabilities for Repair, Maintenance, And Fabrication (RMAF) to overcome potential contingency scenarios. Strategies employed in historic human spaceflight such as redundancy management, reliability, sparing, orbital replacement units, and aborts may be insufficient by themselves. Based on subject matter input, a list of 53 critical failures defining a set of incidents that can render a key spacecraft subsystem inoperable were generated. A subsequent analysis found that a robust in-space RMAF system capable of performing 14 key functions can potentially repair a subsystem plagued by any of these failures. An ancillary benefit is this capability may provide psychological benefits to the crew, by enabling greater self-sufficiency in earth-independent problem solving. A basic RMAF facility has been defined for the Common Habitat, consisting of five workstations. A work bench and computer workstation provide a multipurpose horizontal work surface, computing interface, and tools storage. A CNC machining center provides a subtractive manufacturing capability for metals and plastics. A multi-material 3D printing facility provides additive manufacturing capabilities for plastic, metals, and printed electronics. A welding facility is used for joining metal components where a higher strength is needed than can be achieved with fasteners or adhesives. A glovebox facility is used to perform work that is too hazardous for any of the other workstations. This may include hardware brought in from outside the spacecraft that could potentially contaminate the cabin environment. Forward work includes considering the accommodation of additional manufacturing processes not modeled in the current system, assessing the ability of systems to operate in partial gravity and microgravity environments, incorporation of the system into the Common Habitat Computer Aided Design (CAD) model, bottoms-up mass estimating, and a crew time analysis.

Habitat↗

Thermal Analysis of the SIRIUS3 Nuclear Propulsion Fuel Calibration Experiment

NASA is considering Nuclear Thermal Propulsion (NTP) for long range extraterrestrial missions; these engines eject hot hydrogen gas heated by a nuclear reactor for rocket thrust. To economize the use of hydrogen to the greatest extent possible, the NTP engines will be expected to, in a very short time (i.e., on the order of a minute or less), go from warm$(\sim 300 K)$ zero power conditions to full operational power, with a coolant outlet temperature on the order of 2700–3000 K \cite{en15176181}. These conditions will introduce significant thermomechanical stresses on the NTP fuel. The objective of the SIRIUS series of experiments is to examine the performance of candidate NTP fuel materials when subjected to temperature ramp rates that are prototypical of NTP system startup and operation. The SIRIUS experiments are a series of experiments that will be irradiated in the TREAT reactor and are subjected to power ramps and cycles that are prototypical for NTP operation. The experiments will be accomplished by executing a series of shaped transients on the SIRIUS specimens while collecting in situ specimen temperature data. These tests will determine whether operational startup ramps and peak temperatures will result in detrimental fuel performance phenomena (i.e. fuel deformation, fragmentation and cracking) To this end, INL has been evaluating a number of SIRIUS experiments, and these evaluations include thermal analysis of the SIRIUS experiments. Thermal analysis were performed for the calibration irradiation of the SIRIUS-3 experiment, and the focus of this memo is to document the results from the calibration irradiation thermal analysis. The thermal analysis reveals that radiation heat emission of the outer fuel elements and conduction to different metal components such as the molybdenum element tubes remove significant quantities of heat from the fuel element specimen, and future experiment designs need to consider these heat transfer mechanics. This paper begins with a brief experiment overview with a discussion of the fuel sample and experiment configuration. The experiment and model description section is followed by a set of results with a brief discussion, and finally the memo concludes with suggestion for future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

ASME, Section III, Division 5, Metallic

Presentation on American Society of Mechanical Engineers (ASME) Section III, Division 5 design rules for metallic components at the ASME Boiler and Pressure Vessel (BPV) III International Meeting, September 25 to 28, 2023

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

On the Corrosion Response of Novel Heat Exchangers Manufactured by Casting of Al-Ce-Mg Alloy

Developing low-cost and durable heat exchangers is critical for next-generation heating, ventilation, air conditioning, and refrigeration systems. The emerging requirement to minimize the total refrigerant charge inventory while ensuring a uniform distribution of refrigerant has led to the deployment of advanced manufacturing strategies. At the same time, corrosion is a longstanding issue for metal components, especially those used in heat exchanger (HX) applications. In this study, Al-Ce-Mg alloy-based HXs have been investigated. The corrosion resistance of HXs prototype manufactured by the casting process has been examined and the potential of a new manufacturing approach has been explored to meet the requirements of emerging needs.

Brechtl, Jamieson↗

Characterization of Rare-earth Doped Thermal Barrier Coatings for Phosphor Thermometry

Thermal Barrier Coatings have been extensively used to protect and insulate the metallic components in turbine engines from extreme environments to achieve higher turbine inlet temperatures, resulting in an increase in combined engine cycle efficiency, lowering NOx emissions and fuel consumption. Additionally, as the major failure mechanisms determining lifetime are thermally activated during engine operation, uncertainty in temperature measurements affects lifetime prediction. Early detection of Thermal Barrier Coatings spallation symptoms, associated with local delamination induced temperature changes, can reduce forced engine outages. Further improvements are envisioned with the development of more reliable measurement techniques. For this purpose, Phosphor Thermometry has been considered a promising method for precision monitoring of turbine blade coatings that contain embedded phosphor dopants. In this work, a modified four-flux Kubelka-Munk model for luminescent rare-earth doped Thermal Barrier Coating configurations supported the design and the fabrication of viable sensing coatings for potential industrial implementation. Phosphor Thermometry instrumentation was developed with the objective of expanding capabilities of the technique, using a synchronized acquisition method on sensing coatings. Experiments on an innovative Erbium-Europium co-doped Yttria-Stabilized Zirconia coating have demonstrated the effectiveness of this advanced Phosphor Thermometry instrument with enhanced sensitivity and extended temperature range. Delamination progression monitoring was achieved for the first time using a Thermal Barrier Coating configuration subjected to indentation that includes a thin luminescent layer deposited on the surface and associating the multi-layer configuration with a predictive model that evaluates the advancement of the degradation of the coatings. To further ensure the integrity of the phosphor doped coatings, synchrotron X-ray diffraction was performed to characterize the specific residual strains and thermal expansion of the materials, determining mechanical robustness and compatibility with state-of-the-art Thermal Barrier Coatings. The outcomes of this work pave the way for in-situ temperature measurements on phosphor-doped turbine blade coatings with increased performance and accuracy.

Fouliard, Quentin↗