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NASA NTRS1974

Infrared maser emission from interstellar hydroxyl molecules

The energy structure and transition rates of the OH radical were studied in rotational and vibrational energies to provide the basis for studies of the population distributions under various exciting mechanisms. The absorption of ultra-violet or near infrared radiation which might explain the microwave emission was examined, as well as the absorption of low temperature blackbody radiation and collisions with molecular hydrogen. The results of the population studies were applied to the transfer equation, and a model of a uniform spherical cloud of OH was used with the pumping process which occurs uniformly throughout the region. The emission is unsaturated and the intensity is an exponential function of the size of the cloud for high pumping rates, and the region of unsaturated emission shrinks for lower pumping rates until the entire region is saturated, the intensity then becoming a linear function of the size of the emitting cloud.

Pelzmann, R. F., Jr.↗

NASA NTRS1998

Thermal Water Vapor Emission from Shocked Regions in Orion

Using the Long Wavelength Spectrometer on board the Infrared Space Observatory, we have observed thermal water vapor emission from a roughly circular field of view approximately 75" in diameter centered on the Orion BN-KL region. The Fabry-Perot line strengths, line widths, and spectral line shifts observed in eight transitions between 71 and 125 micron show good agreement with models of thermal emission arising from a molecular cloud subjected to a magnetohydrodynamic C-type shock. Both the breadth and the relative strengths of the observed lines argue for emission from a shock rather than from warm quiescent gas in the Orion core. Although one of the eight transitions appears anomalously strong and may be subject to the effects of radiative pumping, the other seven indicate an H2O/H2 abundance ratio on the order of 5 x 10(exp -4) and a corresponding gas-phase oxygen-to-hydrogen abundance ratio on the order of 4 x 10(exp -4). Given current estimates of the interstellar, gas-phase, oxygen and carbon abundances in the solar vicinity, this value is consistent with theoretical shock models that predict the conversion into water of all the gas-phase oxygen that is not bound as CO. The overall cooling provided by rotational transitions of H2O in this region appears to be comparable to the cooling through rotational lines of CO but is an order of magnitude lower than cooling through H2 emission. However, the model that best fits our observations shows cooling by H2O and CO dominant in that portion of the postshock region where temperatures are below approximately 800 K and neither vibrational nor rotational radiative cooling by H2 is appreciable.

Harwitt, Martin↗

NASA NTRS2002

Peptides at Membrane Surfaces and their Role in Prebiotic Evolution

Protocells had to transport ions and organic matter across membranes separating the interior of the cell from the environment, capture and utilize energy and transduce environmental signals. In a series of detailed, molecular-level computer simulations we show how these peptides in contact with membranes can acquire ordered structures and functions. We have investigated the stability of a simple alpha-helical peptide containing Leucine (L) and Serine (S) of the form (LSLLLSL)3 in a model membrane system. The parallel in-plane state is the most stable configuration. The transmembrane state is metastable, and about 15 kcal/mol is required to insert the peptide into the membrane. We investigated dimes of both (LSLLLSL)3 and glycophorin A, and show how the free energy of helix association can, at least partially, offset the free energy of insertion. We have also investigated the transmembrane pore of the influenza M2 protein. This aggregate of four identical alpha-helices, each built of 25 amino acids, forms an efficient and selective voltage-gated proton channel. Our simulations explain the gating mechanism, which can involve strands of hydrogen-bonded water through the pore or proton transfer through tautomerization of protein residues. The channel can be re-engineered to act as a simple proton pump.

Pohorille, Andrew↗

NASA NTRS2008

Calibrating the Helium Pressurization System for the Space Shuttle Liquid-Hydrogen Tank

Analysis of the results from the STS-114 tanking tests and subsequent launch called into question existing thermal and mass models of helium pressurization of the liquid hydrogen tank. This hydrogen tank, which makes up the bottom two-thirds of the External Tank, is pressurized prior to launch to avoid cavitation in the Shuttle Main Engine pumps. At about 2 minutes prior to launch, the main vent valve is closed, and pressurized helium flows into the tank ullage space to achieve set point pressure. As the helium gas cools, its pressure drops, calling for additional helium. Subsequent helium flows are provided in short, timed pulses. The number of pulses is taken as a rough leak indicator. An analysis of thermal models by Marshall Space Flight Center showed considerable uncertainty in the pressure-versus-time behavior of the helium ullage space and the ability to predict the number of pulses normally expected. Kennedy Space Center proposed to calibrate the dime-sized orifice, which together with valves, controls the helium flow quantity (Figure 1). Pressure and temperature sensors were installed to provide upstream and downstream measurements necessary to compute flow rate based on the orifice discharge coefficient. An assessment of flow testing with helium indicated an extremely costly use of this critical resource. In order to reduce costs, we proposed removing the orifices from each Mobile Launcher Platform (MLP) and asking Colorado Engineering Experiment Station Inc. (CEESI) to calibrate the flow. CEESI has a high-pressure air flow system with traceable flow meters capable of handling the large flow rates. However, literature research indicated that square-edged orifices of small diameters often exhibit significant hysteresis and nonrepeatability in the vicinity of choked or sonic flow. Fortunately, the MLP orifices behaved relatively well in testing (Figure 2). Using curve fitting of the air-flow data, in conjunction with ASME orifice modeling equations, a method of relating the helium mass flow to measured air flow data was obtained. This analysis showed that the highest uncertainty in flow occurred in the vicinity of the choking pressure ratio, as would be expected. In addition, analysis of typical flow pulses showed that most of the helium flow occurred either well below or well above this uncertain area. The final result is the ability to provide postlaunch estimates of helium mass flows that are within 1.5 percent of the actual value.

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NASA NTRS2019

Versatile Nuclear Thermal Propulsion (NTP)

A study was initiated to investigate propulsion stage and mission architecture options potentially enabled by fission energy. One initial concept is a versatile Nuclear Thermal Propulsion (NTP) system with a maximum specific impulse of 900 s and a maximum thrust (per engine) of 15 klbf. The system assumes a monopropellant stage (hydrogen), and is designed to also provide 300 lbf of thrust (potentially split between multiple thrusters) at an Isp > 500 s for orbital maneuvering and station keeping. Boost pumps are used to assist with engine decay heat removal and low thrust engine burns, and to compensate for partial tank depressurization during full thrust engine burns. Potential stage assembly orbits that take full advantage of launch vehicle payload mass and volume capabilities are being assessed. The potential for using NTP engines to also generate a small to moderate amount of electrical power is also being evaluated. A first generation versatile NTP stage could enable 8 of 9 upcoming opportunities for short (less than 24 month) round trip human missions to Mars. A second generation versatile NTP is under consideration that could potentially provide a maximum specific impulse of 1800 s at 15 klbf, and enable ambitious missions throughout the solar system. The second generation NTP system under consideration would also allow a choice of volatiles to be used as propellant. This would potentially allow in-situ resources such as water, ammonia, methane, or other compounds to be used directly as propellant by the second generation engine.

Houts, Michael G.↗

NASA NTRS2019

Versatile Nuclear Thermal Propulsion (NTP)

Houts, Mike↗

NASA NTRS2001

Lubrication of Space Shuttle Main Engine Turbopump Bearings

The Space Shuttle has three main engines that are used for propulsion into orbit. These engines are fed propellants by four turbopumps on each engine. A main element in the turbopump is the bearings supporting the rotor that spins the turbine blades and the pump impeller. These bearings are required to spin at very high speeds, support radial and thrust loads, and have high wear resistance without the benefit of lubrication. The liquid hydrogen and oxygen propellants flow through the bearings to cool the surfaces. The volatile nature of the propellants excludes any conventional means of lubrication. Lubrication for these bearings is provided by the ball separator inside the bearing. The separator is a composite material that supplies a transfer film of lubrication to the rings and balls. New separator materials and lubrication schemes have been investigated at Marshall Space Flight Center in a bearing test rig with promising results. Hybrid bearings with silicon nitride balls have also been evaluated. The use of hybrid, silicon nitride ball bearings in conjunction -with better separator materials has shown excellent results. The work that Marshall has done is being utilized in turbopumps flying on the space shuttle fleet and will be utilized in future space travel. This result of this work is valuable for all aerospace and commercial applications where high-speed bearings are used.

Gibson, Howard↗

NASA NTRS1979

Symposium /International/ on Combustion, 17th, Leeds University, Leeds, England, August 20-25, 1978, Proceedings

The Symposium focused on deflagration to detonation transition, coal combustion, turbulent-combustion interactions, kinetics, furnace combustion, inhibition and ignition, flame structure and chemistry, combustion studies, measurement techniques, fire and explosion, engine combustion, soot, and propellants and explosives. Papers were presented on numerical modeling of the deflagration-to-detonation transition, the interaction between turbulence and combustion, turbulent flame propagation in premixed gases, spray evaporation in recirculating flow, dissociation of nitric oxide in shock waves, pollutant emissions from partially mixed turbulent flames, energy transfer and quenching rates of laser-pumped electronically excited alkalis in flames, a study of flammability limits using counterflow flames, the unified theory of explosions with fuel consumption, and the dynamics and radiant intensity of large hydrogen flames.

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NASA NTRS2010

Labyrinth Seal Flutter Analysis and Test Validation in Support of Robust Rocket Engine Design

High energy-density turbomachines, like the SSME turbopumps, utilize labyrinth seals, also referred to as knife-edge seals, to control leakage flow. The pressure drop for such seals is order of magnitude higher than comparable jet engine seals. This is aggravated by the requirement of tight clearances resulting in possible unfavorable fluid-structure interaction of the seal system (seal flutter). To demonstrate these characteristics, a benchmark case of a High Pressure Oxygen Turbopump (HPOTP) outlet Labyrinth seal was studied in detail. First, an analytical assessment of the seal stability was conducted using a Pratt & Whitney legacy seal flutter code. Sensitivity parameters including pressure drop, rotor-to-stator running clearances and cavity volumes were examined and modeling strategies established. Second, a concurrent experimental investigation was undertaken to validate the stability of the seal at the equivalent operating conditions of the pump. Actual pump hardware was used to construct the test rig, also referred to as the (Flutter Rig). The flutter rig did not include rotational effects or temperature. However, the use of Hydrogen gas at high inlet pressure provided good representation of the critical parameters affecting flutter especially the speed of sound. The flutter code predictions showed consistent trends in good agreement with the experimental data. The rig test program produced a stability threshold empirical parameter that separated operation with and without flutter. This empirical parameter was used to establish the seal build clearances to avoid flutter while providing the required cooling flow metering. The calibrated flutter code along with the empirical flutter parameter was used to redesign the baseline seal resulting in a flutter-free robust configuration. Provisions for incorporation of mechanical damping devices were introduced in the redesigned seal to ensure added robustness

El-Aini, Yehia↗

NASA NTRS2010

A History of Welding on the Space Shuttle Main Engine (1975 to 2010)

The Space Shuttle Main Engine (SSME) is a high performance, throttleable, liquid hydrogen fueled rocket engine. High thrust and specific impulse (Isp) are achieved through a staged combustion engine cycle, combined with high combustion pressure (approx.3000psi) generated by the two-stage pump and combustion process. The SSME is continuously throttleable from 67% to 109% of design thrust level. The design criteria for this engine maximize performance and weight, resulting in a 7,800 pound rocket engine that produces over a half million pounds of thrust in vacuum with a specific impulse of 452/sec. It is the most reliable rocket engine in the world, accumulating over one million seconds of hot-fire time and achieving 100% flight success in the Space Shuttle program. A rocket engine with the unique combination of high reliability, performance, and reusability comes at the expense of manufacturing simplicity. Several innovative design features and fabrication techniques are unique to this engine. This is as true for welding as any other manufacturing process. For many of the weld joints it seemed mean cheating physics and metallurgy to meet the requirements. This paper will present a history of the welding used to produce the world s highest performance throttleable rocket engine.

Zimmerman, Frank R.↗

NASA NTRS2003

NASA Tech Briefs, February 2003

opics covered include: Integrated Electrode Arrays for Neuro-Prosthetic Implants; Eroding Potentiometers; Common/Dependent-Pressure-Vessel Nickel-Hydrogen Batteries; 120-GHz HEMT Oscillator With Surface-Wave-Assisted Antenna; 80-GHz MMIC HEMT Voltage-Controlled Oscillator; High-Energy-Density Capacitors; Microscale Thermal-Transpiration Gas Pump; Instrument for Measuring Temperature of Water; Improved Measurement of Coherence in Presence of Instrument Noise; Compact Instruments Measure Helium-Leak Rates; Irreversible Entropy Production in Two-Phase Mixing Layers; Subsonic and Supersonic Effects in Bose-Einstein Condensate; Nanolaminate Mirrors With "Piston" Figure-Control Actuators; Mixed Conducting Electrodes for Better AMTEC Cells; Process for Encapsulating Protein Crystals; Lightweight, Self-Deployable Wheels; Grease-Resistant O Rings for Joints in Solid Rocket Motors; LabVIEW Serial Driver Software for an Electronic Load; Software Computes Tape-Casting Parameters; Software for Tracking Costs of Mars Projects; Software for Replicating Data Between X.500 and LDAP Directories; The Technical Work Plan Tracking Tool; Improved Multiple-DOF SAW Piezoelectric Motors; Propulsion Flight-Test Fixture; Mechanical Amplifier for a Piezoelectric Transducer; Swell Sleeves for Testing Explosive Devices; Linear Back-Drive Differentials; Miniature Inchworm Actuators Fabricated by Use of LIGA; Using ERF Devices to Control Deployments of Space Structures; High-Temperature Switched-Reluctance Electric Motor; System for Centering a Turbofan in a Nacelle During Tests; Fabricating Composite-Material Structures Containing SMA Ribbons; Optimal Feedback Control of Thermal Networks; Artifacts for Calibration of Submicron Width Measurements; Navigating a Mobile Robot Across Terrain Using Fuzzy Logic; Designing Facilities for Collaborative Operations; and Quantitating Iron in Serum Ferritin by Use of ICP-MS.

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NASA NTRS1978

Study of fuel systems for LH2-fueled subsonic transport aircraft, volume 1

Several engine concepts examined to determine a preferred design which most effectively exploits the characteristics of hydrogen fuel in aircraft tanks received major emphasis. Many candidate designs of tank structure and cryogenic insulation systems were evaluated. Designs of all major elements of the aircraft fuel system including pumps, lines, valves, regulators, and heat exchangers received attention. Selected designs of boost pumps to be mounted in the LH2 tanks, and of a high pressure pump to be mounted on the engine were defined. A final design of LH2-fueled transport aircraft was established which incorporates a preferred design of fuel system. That aircraft was then compared with a conventionally fueled counterpart designed to equivalent technology standards.

Brewer, G. D.↗

NASA NTRS1987

Straight cylindrical seal for high-performance turbomachines

A straight cylindrical seal configuration representing the seal for a high-performance turbopump (e.g., the space shuttle main engine fuel pump) was tested under static (nonrotating) conditions. The test data included critical mass flux and pressure profiles over a wide range of inlet temperatures and pressures for fluid nitrogen and fluid hydrogen with the seal in concentric and fully eccentric positions. The critical mass fluxes (or leakage rates) for the concentric and fully eccentric configurations were nearly the same when based on stagnation conditions upstream of the seal. The fully eccentric configuration pressure profiles of the gas and liquid were different. Further, the pressure differences between the maximum and the minimum clearance positions were highly dependent on the geometric conditions, the temperature, and the absolute pressure at both the inlet and the exit. The pressure differences were greatest in the inlet region. The results, although complex, tend to follow the corresponding-states principles for critical flows. Gaseous injection near the seal exit plane significantly altered the pressure profiles and could be used to control turbomachine instabilities.

Hendricks, Robert C.↗

NASA NTRS1987

Three-step cylindrical seal for high-performance turbomachines

A three-step cylindrical seal configuration representing the seal for a high performance turbopump (e.g., the space shuttle main engine fuel pump) was tested under static (nonrotating) conditions. The test data included critical mass flux and pressure profiles over a wide range of inlet temperatures and pressures for fluid nitrogen and fluid hydrogen with the seal in concentric and fully eccentric positions. The critical mass flux (leakage rate) was 70% that of an equivalent straight cylindrical seal with a correspondingly higher pressure drop based on the same flow areas of 0.3569 sq cm but 85% that of the straight seal based on the third-step flow area of 0.3044 sq cm. The mass flow rates for the three step cylindrical seal in the fully eccentric and concentric positions were essentially the same, and the trends in flow coefficient followed those of a simple axisymmetric inlet configuration. However, for inlet stagnation temperatures less than the thermodynamic critical temperature the pressure profiles exhibited a flat region throughout the third step of the seal, with the pressure magnitude dependent on the inlet stagnation temperature. Such profiles represent an extreme positive direct stiffness. These conditions engendered a crossover in the pressure profile upstream of the postulated choke that resulted in a local negative stiffness. Flat and crossover profiles resulting from choking within the seal are practically unknown to the seal designer. However, they are of critical importance to turbomachine stability and must be integrated into any dynamic analysis of a seal of this configuration. In addition, choking is highly dependent on geometry, inlet-to-backpressure ratio, and inlet temperature and can occur within the seal even though the backpressure is above the critical pressure.

Hendricks, Robert C.↗

NASA NTRS1977

Vibrationally excited molecular hydrogen in Orion

Physical mechanisms for producing vibrationally excited molecular hydrogen, such as has recently been detected toward the Orion Nebula, are discussed. The most likely mechanisms are collisional excitation behind a shock moving into a molecular cloud and near-ultraviolet pumping in the H2 Lyman and Werner bands and subsequent cascade. The absolute intensities of the Orion lines require either a 10-km/s shock moving into a cloud with a density of 300,000 per cu cm or an incident near-UV flux 1 million times the mean interstellar value. The shock model is favored because it matches the observed relative line intensities and because the near-UV source, Theta-1 Ori C, may be too weak to provide the required flux. Intensities of other H2 lines in the shock model are predicted as a further observational discriminant.

Hollenbach, D. J.↗

NASA NTRS2002

Pulse Detonation Engine Test Bed Developed

A detonation is a supersonic combustion wave. A Pulse Detonation Engine (PDE) repetitively creates a series of detonation waves to take advantage of rapid burning and high peak pressures to efficiently produce thrust. NASA Glenn Research Center's Combustion Branch has developed a PDE test bed that can reproduce the operating conditions that might be encountered in an actual engine. It allows the rapid and cost-efficient evaluation of the technical issues and technologies associated with these engines. The test bed is modular in design. It consists of various length sections of both 2- and 2.6- in. internal-diameter combustor tubes. These tubes can be bolted together to create a variety of combustor configurations. A series of bosses allow instrumentation to be inserted on the tubes. Dynamic pressure sensors and heat flux gauges have been used to characterize the performance of the test bed. The PDE test bed is designed to utilize an existing calorimeter (for heat load measurement) and windowed (for optical access) combustor sections. It uses hydrogen as the fuel, and oxygen and nitrogen are mixed to simulate air. An electronic controller is used to open the hydrogen and air valves (or a continuous flow of air is used) and to fire the spark at the appropriate times. Scheduled tests on the test bed include an evaluation of the pumping ability of the train of detonation waves for use in an ejector and an evaluation of the pollutants formed in a PDE combustor. Glenn's Combustion Branch uses the National Combustor Code (NCC) to perform numerical analyses of PDE's as well as to evaluate alternative detonative combustion devices. Pulse Detonation Engine testbed.

Breisacher, Kevin J.↗

NASA NTRS2004

New Gas Polarographic Hydrogen Sensor

Polarography is the measurement of the current that flows in solution as a function of an applied voltage. The actual form of the observed polarographic current depends upon the manner in which the voltage is applied and on the characteristics of the working electrode. The new gas polarographic H2 sensor shows a current level increment with concentration of the gaseous H2 similar to those relating to metal ions in liquid electrolytes in well-known polarography. This phenomenon is caused by the fact that the diffusion of the gaseous H2 through a gas diffusion hole built in the sensor is a rate-determining step in the gaseous-hydrogen sensing mechanism. The diffusion hole artificially limits the diffusion of the gaseous H2 toward the electrode located at the sensor cavity. This gas polarographic H2 sensor. is actually an electrochemical-pumping cell since the gaseous H2 is in fact pumped via the electrochemical driving force generated between the electrodes. Gaseous H2 enters the diffusion hole and reaches the first electrode (anode) located in the sensor cavity to be transformed into an H+ ions or protons; H+ ions pass through the electrolyte and reach the second electrode (cathode) to be reformed to gaseous H2. Gas polarographic 02 sensors are commercially available; a gas polarographic 02 sensor was used to prove the feasibility of building a new gas polarographic H2 sensor.

Dominguez, Jesus A.↗

NASA NTRS2006

H2 Detection via Polarography

Polarography is the measurement of the current that flows in solution as a function of an applied voltage. The actual form of the observed polarographic current depends upon the manner in which the voltage is applied and on the characteristics of the working electrode. The new gas polarographic H2 sensor shows a current level increment with concentration of the gaseous H2 similar to those relating to metal ions in liquid electrolytes in well-known polarography. This phenomenon is caused by the fact that the diffusion of the gaseous H2 through a gas diffusion hole built in the sensor is a rate-determining step in the gaseous-hydrogen sensing mechanism. The diffusion hole artificially limits the diffusion of the gaseous H2 toward the electrode located at the sensor cavity. This gas polarographic H2 sensor is actually an electrochemical-pumping cell since the gaseous H2 is in fact pumped via the electrochemical driving force generated between the electrodes. Gaseous H2 enters the diffusion hole and reaches the first electrode (anode) located in the sensor cavity to be transformed into an H ions or protons; H ions pass through the electrolyte and reach the second electrode (cathode) to be reformed to gaseous H2. Gas polarographic O2 sensors are commercially available; a gas polarographic O2 sensor was used to prove the feasibility of building a new gas polarographic H2 sensor.

Dominquez, Jesus↗