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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Hybrid Organic Inorganic Perovskites: Physical Properties and Applications (in 4 Volumes)

This four-volume handbook gives a state-of-the-art overview of hybrid organic inorganic perovskites, both two dimensional (2D) and three dimensional (3D), from synthesis and characterization and simulation to optoelectronic devices (such as solar cells and light emitting diodes), spintronics devices and catalysis application. The editors, coming from academia and national laboratory, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 30 expert authors in 21 chapters, they construct the story of hybrid perovskite structural and optical properties, electronic and spintronic response, laser action, and catalysis from varied viewpoints: materials science, chemical engineering, and energy engineering. The four volumes are arranged according to the focus material properties. Volume 1 is focused on the material physical properties including structure, deposition characteristic and the structure of the electronic bands and excitons of these compounds. Volume 2 covers the hybrid perovskite optical properties including the ultrafast optical response, photoluminescence and laser action. Volume 3 contains the spin response of these compounds including application such as spin valves, photogalvanic effect, and magnetic response of light emitting diodes and solar cell devices. Finally, and highly relevant to tomorrow's energy challenges, volume 4 is focused on the physics and device properties of the most relevant applications of the hybrid perovskites, namely photovoltaic solar cells. The text contains many high-quality colorful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with the hybrid organic inorganic perovskites.

applications↗
DOE OSTI2020

Opportunities for Research and Development of Hybrid Power Plants

Hybrid power plants show promise to provide significant value to the electric grid system especially as shares of renewable energy in systems increase from 10% to 20% or more. Many manufacturers and developers are proactively developing hybrid power plant strategies to ensure plant profitability in markets where it’s important to provide energy that is more predictable and controllable, with higher capacity values, as well as various ancillary services to the grid system. However, there still are many questions around if and when hybrid power plants make sense versus leaving it to the larger grid system to ensure low cost and reliable supply by engaging directly with all individual assets. This report summarizes literature on the state-of-the-art in research concerning hybrid power plants from multiple perspectives including: 1) resource and market opportunities, 2) technology selection and sizing, 3) physical design, and 4) operation and control. The emphasis was placed on wind and solar hybrid power plants (with or without storage) but additional technologies were briefly considered and merit further investigation.

17 WIND ENERGY↗
DOE OSTI2020

Hybrid Electric Drivetrain Testing and Design (CRADA CRD-17-00699 Final Report)

Hybrid electric drivetrains have recently become of a great interest in the medium and heavy-duty vehicle market as it enables substantial reduction of petroleum use, vehicle level fuel use and criteria pollutant emissions. These vehicle performance improvements are not only economically beneficial for business operations relying on large fleets of vehicles, they are also paramount for curbing energy use and the negative effects of vehicle operations on the environment. Efficient Drivetrains, Inc. (EDI), acquired in July 2018 by Cummins, Inc., is a small company focused on development of medium and heavy-duty hybrid electric drivetrains. EDI has already developed the general hardware architecture of their drivetrain system, but there is still a significant effort to be done on optimizing the system in terms of control strategies and component sizing in order to maximize the benefits of the hybrid drivetrain. Historically, hybrid electric systems have proven to deliver better fuel economy in certain applications than their conventional counterparts. Particular areas of advantageous applications are vocations with kinetically intensive transient duty cycles and operations requiring some sort of power take off whose power demand is not well matched to the size of the vehicle’s main engine, thus forcing it to operate in extremely inefficient operating modes. Hybrid drivetrains can be at a disadvantage when pressed into duty cycle operation consisting of extensive steady state highway cruise due to various design compromises optimized for more transient operation. This can also lead to increase in vehicle emissions if the system is not optimized properly. Ample opportunity for extensive optimization is needed to overcome these obstacles.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

Hybrid Electric Drivetrain Testing and Design (CRADA CRD-17-00699 Final Report)

Hybrid electric drivetrains have recently become of a great interest in the medium and heavy-duty vehicle market as it enables substantial reduction of petroleum use, vehicle level fuel use and criteria pollutant emissions. These vehicle performance improvements are not only economically beneficial for business operations relying on large fleets of vehicles, they are also paramount for curbing energy use and the negative effects of vehicle operations on the environment. Efficient Drivetrains, Inc. (EDI), acquired in July 2018 by Cummins, Inc., is a small company focused on development of medium and heavy-duty hybrid electric drivetrains. EDI has already developed the general hardware architecture of their drivetrain system, but there is still a significant effort to be done on optimizing the system in terms of control strategies and component sizing in order to maximize the benefits of the hybrid drivetrain. Historically, hybrid electric systems have proven to deliver better fuel economy in certain applications than their conventional counterparts. Particular areas of advantageous applications are vocations with kinetically intensive transient duty cycles and operations requiring some sort of power take off whose power demand is not well matched to the size of the vehicle’s main engine, thus forcing it to operate in extremely inefficient operating modes. Hybrid drivetrains can be at a disadvantage when pressed into duty cycle operation consisting of extensive steady state highway cruise due to various design compromises optimized for more transient operation. This can also lead to increase in vehicle emissions if the system is not optimized properly. Ample opportunity for extensive optimization is needed to overcome these obstacles.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Hybrid Heavy Duty Diesel Powertrain for Off-Road Applications (Final Technical/Scientific Report)

In this program, a heavy-duty hybrid powersystem, consisting of a 30% downsized diesel engine and a front-end accessory drive (FEAD) incorporating a high-speed flywheel (HSFW) energy storage system, a mechanical-drive turbocharger (SuperTurbo), and motor-generator units (MGU) was developed and demonstrated. The high efficiency core 13L engine coupled with the hybrid elements was physically validated across various off-road machine and transient work cycles with the ultimate goal of demonstrating 17% efficiency improvement with equivalent transient response as the 18L diesel engine this concept powersystem would replace. The project culminated in a physical demonstration of the high-efficiency powersystem in a high-capability test cell with the engine, all the hybrid devices, controls, and required performance and emissions measurements. Based on the combination of physical validation and rigorous system simulation, the following program conclusions may be drawn: (1) The developed hybrid H2D2 powersystem demonstrated a range of efficiency improvement of 10.5 - 25.6%, with a midpoint of 17.9%; (2) Transient load response on; (3) The HSFW system was validated to achieve peak assisting of 110kW at 12,000 Nm/sec ramp rates; (4) The powersystem was validated to be capable of meeting U.S. EPA Tier 4 Final off-road emissions through transient NRTC testing; (5) A Total Cost of Ownership (TCO) analysis and found that the core 13L engine would pay back immediately (adoption of start/stop would pay back in less than one year, and the full hybrid system payback was three years.)

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2020

An Applied Strategy for Using Empirical and Hybrid Models in Online Monitoring

The monitoring of plant equipment for failure prediction is one of the key contributors to operation and maintenance (O&M) costs for a nuclear power plant (NPP) because O&M monitoring depends on labor-intensive activities that are required to meet high equipment reliability standards. These activities rely primarily on humans for information gathering, condition diagnosis, and predictive analysis. Online monitoring aims to automate these activities by relying on sensors to replace human information gathering and machine learning to replace human analysis and decision making. To facilitate automated monitoring, a systematic strategy for anomaly detection is needed to optimally use the available sensor data, empirical models, and physics-supported models. This strategy is essential to provide credible reasoning on why and when an empirical (i.e., purely data-driven) versus hybrid (i.e., physics-supported) approach should be used and to determine the ideal mix of these two approaches for a defined anomaly detection scope. The extant methods usually adopt an ad hoc trial-and-error approach that, in addition to being time-consuming and costly, is also highly subjective; it is impacted by the background and the skill set of the personnel making the decisions. Thus, such an approach cannot guarantee an optimum outcome. This represents the motivation of the current research effort, which is focused on devising a scientifically supported strategy for the optimum selection of anomaly detection methods. This report presents a detailed assessment of the main anomaly detection techniques within the empirical or hybrid method streams. Empirical methods include pattern, statistical, and causal inference. Hybrid methods include the use of physics models to train and test data methods, reduce data dimensionality, reduce data-model complexity, augment data, and reduce empirical uncertainty; hybrid methods also include the use of data to tune physics models. The listed techniques within these two streams represent the vast majority of techniques performed for anomaly detection. Using the techniques as outcomes, a strategy was developed to enable a systematic decision-making process to lead to one of these techniques. The strategy is driven by key decision points related to data relevance, simple modeling feasibility, data inference, physics-modeling value, data dimensionality, physics knowledge, method of validation, performance, data availability and suitability for training and testing, cause-effect, entropy inference, and model fitting. Each of these decision points in the strategy is explained in detail in this report with examples, along with the scientific basis behind the decisions and outcomes in common and simplified terminology. The strategy is developed for use by any NPP staff with basic engineering or science knowledge. A user-friendly graphical state flow diagram was also developed as a visual presentation of the strategy. The strategy was tested and demonstrated through two pilot projects for the application of anomaly detection at an NPP. Each pilot had two use cases: an initial case in which certain decisions were made that resulted in one or more empirical techniques and a revised use case where one or more key decisions were modified resulting in using a set of hybrid methods.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

Characterization of Gramicidin A in Triblock and Diblock Polymersomes and Hybrid Vesicles via Continuous Wave Electron Paramagnetic Resonance Spectroscopy

Studying membrane proteins in a native environment is crucial to understanding their structural and/or functional studies. Often, widely accepted mimetic systems have limitations that prevent the study of some membrane proteins. Micelles, bicelles, and liposomes are common biomimetic systems but have problems with membrane compatibility, limited lipid composition, and heterogeneity. To overcome these limitations, polymersomes and hybrid vesicles have become popular alternatives. Polymersomes form from amphiphilic triblock or diblock copolymers and are considered more robust than liposomes. Hybrid vesicles are a combination of lipids and block copolymers that form vesicles composed of a mixture of the two. These hybrid vesicles are appealing because they have the native lipid environment of bilayers but also the stability and customizability of polymersomes. Gramicidin A was incorporated into these polymersomes and characterized using continuous wave electron paramagnetic resonance (CW-EPR) and transmission electron microscopy (TEM). EPR spectroscopy is a powerful biophysical technique used to study the structure and dynamic properties of membrane proteins in their native environment. Spectroscopic studies of gramicidin A have been limited to liposomes; in this study, the membrane peptide is studied in both polymersomes and hybrid vesicles using CW-EPR spectroscopy. Lineshape analysis of spin-labeled gramicidin A revealed linewidth broadening, suggesting that the thicker polymersome membranes restrict the motion of the spin label more when compared to liposome membranes. Statement of Significance: Understanding membrane proteins’ structures and functions is critical in the study of many diseases. In order to study them in a native environment, membrane mimetics must be developed that can be suitable for obtaining superior biophysical data quality to characterize structural dynamics while maintaining their native functions and structures. Many currently widely accepted methods have limitations, such as a loss of native structure and function, heterogeneous vesicle formation, restricted lipid types for the vesicle formation for many proteins, and experimental artifacts, which leaves rooms for the development of new biomembrane mimetics. The triblock and diblock polymersomes and hybrid versicles utilized in this study may overcome these limitations and provide the stability and customizability of polymersomes, keeping the biocompatibility and functionality of liposomes for EPR studies of membrane proteins.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Hybrid Solid Oxide Fuel Cell/Gas Turbine Model Development for Electric Aviation

A thermodynamic model was developed and validated to analyze a high-performance solid oxide fuel cell and gas turbine (SOFC-GT) hybrid power system for electric aviation. This study used a process simulation software package (ProMax) to study the role of SOFC design and operation on the feasibility and performance of the hybrid system. Standard modules, including compressor, turbine, heat exchanger, reforming reactor, and combustor were used from the ProMax tool suite while a custom module was created to simulate the SOFC stack. The model used an SOFC test data set as an input. Additional SOFC stack performance effects, such as pressure, temperature, and utilization of air and fuel, were added from open source data. System performance predictors were SOFC specific power, fuel-to-electricity conversion efficiency, and hybrid system efficiency. Using these input data and predictors, a static thermodynamic performance model was created that can be modified for different system configurations and operating conditions. Prior to creating the final aircraft performance model, initial demonstration models were developed to validate output results. We used the NASA SOFC model as a benchmark, which was created with their Numerical Propulsion System Simulator (NPSS) software framework. Our output results matched within 1% of both the NASA model and open source SOFC performance data. With confidence gained in the accuracy of this model, a 1-MW SOFC-GT hybrid power system was constructed for an aircraft propulsion concept. Overall hybrid system efficiencies of > 75% FTE were observed during standard 36,000 feet cruise flight conditions.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS2016

Energy Conversion and Storage Requirements for Hybrid Electric Aircraft

Among various options for reducing greenhouse gases in future large commercial aircraft, hybrid electric option holds significant promise. In the hybrid electric aircraft concept, gas turbine engine is used in combination with an energy storage system to drive the fan that propels the aircraft, with gas turbine engine being used for certain segments of the flight cycle and energy storage system being used for other segments. The paper will provide an overview of various energy conversion and storage options for hybrid electric aircraft. Such options may include fuel cells, batteries, super capacitors, multifunctional structures with energy storage capability, thermoelectric, thermionic or a combination of any of these options. The energy conversion and storage requirements for hybrid electric aircraft will be presented. The role of materials in energy conversion and storage systems for hybrid electric aircraft will be discussed.

Energy Conversion↗
NASA NTRS2017

Spacecraft/Rover Hybrids for the Exploration of Small Solar System Bodies: Final Report: NASA NIAC - Phase II Study

This study investigated a mission architecture that allows the systematic and affordable in-situ exploration of small solar system bodies, such as asteroids, comets, and Martian moons (Figure 1). The architecture relies on the novel concept of spacecraft/rover hybrids,which are surface mobility platforms capable of achieving large surface coverage (by attitude controlled hops, akin to spacecraft flight), fine mobility (by tumbling), and coarse instrument pointing (by changing orientation relative to the ground) in the low-gravity environments(micro-g to milli-g) of small bodies. The actuation of the hybrids relies on spinning three internal flywheels. Using a combination of torques, the three flywheel motors can produce a reaction torque in any orientation without additional moving parts. This mobility concept allows all subsystems to be packaged in one sealed enclosure and enables the platforms to be minimalistic. The hybrids would be deployed from a mother spacecraft, which would act as a communication relay to Earth and would aid the in-situ assets with tasks such as localization and navigation (Figure 1). The hybrids are expected to be more capable and affordable than wheeled or legged rovers, due to their multiple modes of mobility (both hopping and tumbling), and have simpler environmental sealing and thermal management (since all components are sealed in one enclosure, assuming non-deployable science instruments). In summary, this NIAC Phase II study has significantly increased the TRL (Technology Readiness Level) of the mobility and autonomy subsystems of spacecraft/rover hybrids, and characterized system engineering aspects in the context of a reference mission to Phobos. Future studies should focus on improving the robustness of the autonomy module and further refine system engineering aspects, in view of opportunities for technology infusion.

mobility platforms↗
NASA NTRS2020

Ignition and Burn in a Hybrid Nuclear Fuel for a Pulsed Rocket Engine

This work explores the parameter space of a cylindrical hybrid nuclear fuel in support of a z-pinch driven pulsed fission-fusion (PuFF) engine. 0D power balance and 1D burn wave calculations have been performed to explore the parameter space of hybrid cylindrical nuclear fuels. The boundary of minimal initial conditions needed to reach breakeven are found within the context of the model. The effects of initial conditions upon the yield at the end of burn wave expansion are also determined. The model is used to examine the minimum initial energies predicted to result in yields of a few MJ. The goal of this work is to guide fuel design, inform future models and experiments as well as look for the most efficient parameter space for ignition in a z-pinch driven hybrid nuclear reaction. The impact of initial parameters upon ignition, burn, and gain are discussed. It is found that a hybrid cylindrical target may breakeven with initial energy near the axis of approximately 4 to 6 MJ in lithium deuteride/uranium 235 fuel. It is also found that magnetic field can lower the threshold further of which the magnitude changes across the parameter space. The dual fusion/fission reactions are found to boost each other leading to lower initial driving energies needed to reach breakeven in the hybrid cylindrical nuclear fuel.

fission↗
NASA NTRSDate not supplied

An Active Model Split for Hybrid RANS/LES of Compressible Flows

Hybrid RANS/LES models have consistently shown superior accuracy over RANS in predictions of massively separated flows. However, these models have experienced difficulties with modeled stress depletion, smooth-wall separated flow, and shock-separated flows. The Active Model Split (AMS) hybridization was created to address some of the fundamental shortcomings of traditional hybrid RANS/LES models. While previous work considered incompressible flows, this paper demonstrates how the AMS framework can be extended to address compressible flows. AMS-based hybrid models for the turbulent heat flux and turbulent transport terms in the total energy equation are presented. This compressible hybrid RANS/LES framework is demonstrated on a subsonic channel, a supersonic channel, and a transonic shock-boundary layer interaction. Record includes video of presentation, to view download the mp4 video attached run time of 10 mins 18 secs.

hybrid RANS/LES↗
NASA NTRSDate not supplied

Electrical Energy Storage Design Space Exploration for a Hybrid-Electric Six Passenger Quadrotor

Hybrid-electric architectures are a promising means to achieve clean and efficient aircraft propulsion needed for small, short-range electric vertical takeoff and landing (eVTOL) class vehicles. This paper explores the design space for a six-passenger quadrotor hybrid-electric propulsion system and shows that hybrid architectures that are more efficient than engine-only architectures can be built with near-term battery technology (~150 Wh/kg at the pack level). Data obtained shows that hybrid-electric propulsion systems can achieve 28 percent block fuel reduction and 27 percent total energy cost savings over a 120 nautical mile (nmi) mission compared to conventional turboshaft architectures. This work suggests that hybrids are likely the most efficient architectures that can be produced in the near term for this class of vehicle and motivates further development in this area.

Hybrid-electric↗
NASA NTRSDate not supplied

Electrical Energy Storage Design Space Exploration for a Hybrid-Electric Six-Passenger Quadrotor

Hybrid-electric architectures are a promising means to achieve clean and efficient aircraft propulsion needed for small, short-range electric vertical takeoff and landing class vehicles. This paper explores the design space for a six-passenger quadrotor hybrid-electric propulsion system and shows that hybrid architectures that are more efficient than engine-only architectures can be built with near-term battery technology (approximately 150 Wh/kg at the pack level). Data obtained shows that hybrid-electric propulsion systems can achieve 37 percent block fuel reduction and 35 percent total energy cost savings over a 120 nautical mile mission compared to conventional turboshaft architectures. This work suggests that hybrids are likely the most efficient architectures that can be produced in the near term for this class of vehicle and motivates further development in this area.

parallel hybrid electric aircraft↗
DOE OSTI2022

Renewable-Storage Hybrids in a Decarbonized Electricity Supply

We explore the potential impacts of growing industry interest in hybrid systems comprising PV and battery technologies on the results and findings of the Solar Futures Study (2021). Through comparison of Solar Futures Study scenarios with and without PV-battery hybrid configurations enabled (in the same grid planning model), we find that the highest net-value hybrid configuration depends strongly on power sector carbon policy, which increases the value of more forward-looking designs. While the availability of PV-battery hybrid configurations primarily displaces standalone PV and battery capacity, we find that it (a) increases solar's share of total capacity and generation and (b) reduces required transmission expansion and associated costs under scenarios that combine aggressive cost reductions and power sector decarbonization policy. Results will also be presented for the complementarity and economic value of wind-PV hybrids with varying amounts of energy storage.

complementarity↗
DOE OSTI2025

Hybrid Doping Strategy with High‐Entropy Cu/Fe Surface Modification and Zr Bulk Incorporation for Ni‐Rich Cathodes

A hybrid doping strategy combining Zr 4+ bulk doping with high-entropy Cu 2+ /Fe 3+ surface doping is developed to enhance the structural and interfacial stability of Ni-rich layered oxide cathodes. Cu and Fe are selectively introduced at the particle surface via a surface-selective ion-exchange process, forming a ≈15 nm Fe-rich layer while preserving the layered framework. Compared to the pristine cathode, the hybrid sample exhibits significantly improved electrochemical performance in both half-cell and full-cell configurations. In half-cells, the hybrid retains 88.5% and 90.2% after 100 cycles at 1C under 4.6 and 4.5 V, respectively. During high-voltage full-cell cycling, the hybrid cathode maintains over 80% capacity retention, whereas the pristine counterpart retains less than 10% under identical conditions over the same cycling period. XPS, EELS, and DEMS analyses confirm improved oxygen retention, suppressed gas evolution, and stable surface chemistry, while DFT calculations indicate enhanced Me–O bonding in the selected Fe 0.75 Cu 0.25 (Mn 1/16 Co 2/16 Ni 13/16 )O 2 surface composition, which is identified through DFT-calculated mixing energy reaching a minimum at this ratio, indicating the most thermodynamically favorable configuration. In conclusion, these results demonstrate the effectiveness of this hybrid doping strategy in mitigating coupled degradation pathways in Ni-rich cathodes.

15 GEOTHERMAL ENERGY↗
DOE OSTI2020

A hybrid cyt c maturation system enhances the bioelectrical performance of engineered Escherichia coli by improving the rate-limiting step

Bioelectronic devices can use electron flux to enable communication between biotic components and abiotic electrodes. We have modified Escherichia coli to electrically interact with electrodes by expressing the cytochrome c from Shewanella oneidensis MR-1. However, we observe inefficient electrical performance, which we hypothesize is due to the limited compatibility of the E. coli cytochrome c maturation (Ccm) systems with MR-1 cytochrome c. Here we test whether the bioelectronic performance of E. coli can be improved by constructing hybrid Ccm systems containing protein domains from both E. coli and S. oneidensis MR-1. The hybrid CcmH increased cytochrome c expression by increasing the abundance of CymA 60%, while only slightly changing the abundance of the other cytochromes c. Electrochemical measurements showed that the overall current from the hybrid ccm strain increased 121% relative to the wildtype ccm strain, with an electron flux per cell of 12.3 ± 0.3 fA·cell -1 . Additionally, the hybrid ccm strain doubled its electrical response with the addition of exogenous flavin, and quantitative analysis of this demonstrates CymA is the rate-limiting step in this electron conduit. These results demonstrate that this hybrid Ccm system can enhance the bioelectrical performance of the cyt c expressing E. coli, allowing the construction of more efficient bioelectronic devices.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2026

Process-level cost analysis of hybrid manufacturing pathways for aerospace structural components

Hybrid manufacturing is a promising route for producing complex aerospace components, yet systematic cost benchmarking across multiple additive-subtractive pathways remains limited. This study presents a comprehensive process-based cost analysis of seven hybrid manufacturing routes, including laser powder bed fusion (L-PBF), powder- and wire-directed energy deposition (DED), wire arc additive manufacturing (WAAM), additive friction stir deposition (AFSD), metal binder jetting (MBJ), and agility forging, followed by scanning and finish machining. Parametric cost models incorporating direct material, labor, and energy costs were developed. L-PBF results are discussed in detail for a pickle fork component and directly compared with commercial pricing. Across all hybrid routes, labor emerged as the dominant cost driver, contributing more than 70% of total manufacturing cost in some cases. AFSD exhibited the lowest cost for aluminum components, with MBJ being its 316 L stainless steel counterpart, after accounting for geometric scaling. Benchmarking against industrial quotes suggests that hybrid manufacturing can achieve cost levels comparable to those of commercial services, although labor-intensive processes exhibit greater deviation. The analysis highlights automation of material handling, setup, and supervision as key opportunities for improving economic competitiveness. Overall, the proposed framework provides a quantitative basis for evaluating and optimizing hybrid manufacturing pathways for aerospace applications.

Baruah, Sweta [ORNL] (ORCID:0009000174256207)↗