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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Machinable, high‐conductivity NaSICON through mitigation of humidity effects during solid‐state synthesis

The Na + super ion conductor (NaSICON, Na 1+x Zr 2 Si x P 3-x O 12 ) is a solid electrolyte well-known for fast, selective Na + transport at low temperatures, uniquely enabling sodium-based batteries. Producing high-quality NaSICON from solid-state methods, especially when cost-effective, potentially hygroscopic precursors are used, is not trivial. To understand and eliminate the influence of humidity during processing, a scheme was developed to reproducibly yield a high Na + conductivity (3.75 mS/cm at 25°C, 81.7 mS/cm at 150°C), high density (97%), and machinable NaSICON without the use of binders, sintering aids, or dopants. Controlled humidity studies over 20%–50% RH coupled with thermal, structural, and electrical analysis reveal that calcination temperatures < 1000°C leave NaSICON processing susceptible to water absorption at > 20% RH due to the presence of hygroscopic Na 3 PO 4 and Na 2 CO 3 during shaping, pressing, and sintering. Water absorption results in NaSICON with lower densities, machinability, and Na+ conductivity, due to impaired intergranular Na+ transport. At the other extreme, fully converting precursor to the NaSICON phase at 1230°C before pressing and sintering leads to poor conductivity and density. By calcining at 1000°C, excellent quality NaSICON may be produced under a range of laboratory environments, enabling low-cost production of high-conductivity, machinable NaSICON necessary the ever-growing energy storage market.

NaSICON↗
DOE OSTI2016

Comfort in High-Performance Homes in a Hot-Humid Climate

"9IBACOS monitored 37 homes during the late summer and early fall of 2014 in a hot and humid climate to better understand indoor comfort conditions. These homes were constructed in the last several years by four home builders that offered a comfort and performance guarantee for the homes. The homes were located in one of four cities: Tampa, Florida; Orlando, Florida; Houston, Texas; and San Antonio, Texas. Temperature and humidity data were collected from the thermostat and each room of the house using small, battery-powered data loggers. To understand system runtime and its impact on comfort, supply air temperature also was measured on a 1-minute interval. Overall, the group of homes only exceeded a room-to-room temperature difference of 6 degrees F for 5% of the time. For 80% of the time, the rooms in each house were within 4 degrees F of each other. Additionally, the impact of system runtime on comfort is discussed. Finally, measurements made at the thermostat were used to better understand the occupant operation of each cooling system's thermostat setpoint. Builders were questioned on their perceived impact of offering a comfort and performance guarantee. Their feedback, which generally indicates a positive perception, has been summarized in the report.

"9residential↗
DOE OSTI2016

Comfort in High-Performance Homes in a Hot-Humid Climate

IBACOS monitored 37 homes during the late summer and early fall of 2014 in a hot and humid climate to better understand indoor comfort conditions. These homes were constructed in the last several years by four home builders that offered a comfort and performance guarantee for the homes. The homes were located in one of four cities: Tampa, Florida; Orlando, Florida; Houston, Texas; and San Antonio, Texas. Temperature and humidity data were collected from the thermostat and each room of the house using small, battery-powered data loggers. To understand system runtime and its impact on comfort, supply air temperature also was measured on a 1-minute interval. Overall, the group of homes only exceeded a room-to-room temperature difference of 6 degrees Fahrenheit for 5% of the time.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Phosphoric Acid-Doped Ion-Pair Coordinated PEMs with Broad Relative Humidity Tolerance

Proton exchange membrane (PEM) capable of working over a broad operating condition window is critical for successful adoption of PEM-based electrochemical devices. In this work, phosphoric acid (PA)-doped biphenyl-backbone ion-pair coordinated PEMs were prepared by quaternization of BPBr-100, a precursor polymer, with three different tertiary amines including trimethylamine, 1-methylpiperidine, and 1,2-dimethylimidazole followed by membrane casting, ion exchange reaction to hydroxide ion, and doping with PA. The resulting PA-doped ion-pair PEMs were characterized in terms of PA doping level, proton conductivity, relative humidity (RH) tolerance, thermal stability, and mechanical properties. PA doping levels were between six and eight according to acid-base titration. The size and structure of the cation group of ion-pair polymers were found to affect the PA doping level and water uptake. Proton conductivity was studied as a function of RH over a wide range of 5% to 95% RH. Stable conductivity at 80 °C was observed up to 70% RH for 10 h. Mechanical property characterization indicates that the PA doping process resulted in more ductile membranes with significantly increased elongation at break due to the plasticization effect of PA. A combination of high proton conductivity at low RH conditions, and good humidity tolerance makes this new class of PEMs great potential candidates for use in electrochemical devices such as proton exchange membrane fuel cells and electrochemical hydrogen compressors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2000

Remote query measurement of pressure, fluid-flow velocity, and humidity using magnetoelastic thick-film sensors

Free-standing magnetoelastic thick-film sensors have a characteristic resonant frequency that can be determined by monitoring the magnetic flux emitted from the sensor in response to a time varying magnetic field. This property allows the sensors to be monitored remotely without the use of direct physical connections, such as wires, enabling measurement of environmental parameters from within sealed, opaque containers. In this work, we report on application of magnetoelastic sensors to measurement of atmospheric pressure, fluid-flow velocity, temperature, and mass load. Mass loading effects are demonstrated by fabrication of a remote query humidity sensor, made by coating the magnetoelastic thick film with a thin layer of solgel deposited Al2O3 that reversibly changes mass in response to humidity. c2000 Elsevier Science S.A. All rights reserved.

NASA Discipline Life Sciences Technologies↗
NASA NTRS2000

Magnetoelastic sensors in combination with nanometer-scale honeycombed thin film ceramic TiO2 for remote query measurement of humidity

Ribbonlike magnetoelastic sensors can be considered the magnetic analog of an acoustic bell; in response to an externally applied magnetic field impulse the sensors emit magnetic flux with a characteristic resonant frequency. The magnetic flux can be detected external to the test area using a pick-up coil, enabling query remote monitoring of the sensor. The characteristic resonant frequency of a magnetoelastic sensor changes in response to mass loads. [L.D. Landau and E. M. Lifshitz, Theory of Elasticity, 3rd ed. (Pergamon, New York, 1986). p. 100].Therefore, remote query chemical sensors can be fabricated by combining the magnetoelastic sensors with a mass changing, chemically responsive layer. In this work magnetoelastic sensors are coated with humidity-sensitive thin films of ceramic, nanodimensionally porous TiO2 to make remote query humidity sensors. c2000 American Institute of Physics.

NASA Discipline Life Sciences Technologies↗
NASA NTRS1997

Temperature and Humidity Dependence of a Polymer-Based Gas Sensor

This paper quantifies the temperature and humidity dependence of a polymer-based gas sensor. The measurement and analysis of three polymers indicates that resistance changes in the polymer films, due to temperature and humidity, can be positive or negative. The temperature sensitivity ranged from +1600 to -320 ppm/nd the relative sensitivity ranged from +1100 to -260 ppm/%.

temperature humidity gas sensor polymers↗
NASA NTRS2014

VAB Temperature and Humidity Study

In 2012, 17 data loggers were placed in the VAB to measure temperature and humidity at 10-minute intervals over a one-year period. In 2013, the data loggers were replaced with an upgraded model and slight adjustments to their locations were made to reduce direct solar heating effects. The data acquired by the data loggers was compared to temperature data provided by three wind towers located around the building. It was found that the VAB acts as a large thermal filter, delaying and reducing the thermal oscillations occurring outside of the building. This filtering is typically more pronounced at higher locations in the building, probably because these locations have less thermal connection with the outside. We surmise that the lower elevations respond more to outside temperature variations because of air flow through the doors. Temperatures inside the VAB rarely exceed outdoor temperatures, only doing so when measurements are made directly on a surface with connection to the outside (such as a door or wall) or when solar radiation falls directly on the sensor. A thermal model is presented to yield approximate filter response times for various locations in the building. Appendix A contains historical thermal and humidity data from 1994 to 2009.

Temperature↗
NASA NTRS2018

Convective Influence on the Humidity and Clouds in the Tropical Tropopause Layer During Boreal Summer

The impact of convection on the humidity and clouds in the tropical tropopause layer (TTL) during boreal summer 2007 is investigated in simulations of detailed cloud microphysical processes and their effects on the water vapor (H2O) profile along backward trajectories from the 379 K potential temperature (100‐hPa pressure) surface. Convective influence is determined by tracing the trajectories through time‐dependent fields of satellite‐based convective cloud top height. The simulated H2O mixing ratios at the 100‐hPa level and cloud occurrence fractions in the middle to upper (16–18 km) TTL exhibit a pronounced maximum over the Asian monsoon region as in observations; these local enhancements are virtually absent in the simulation without convection, indicating that convection is the dominant driver of the localized H2O and cloud maxima in the Asian summer monsoon region. Convection moistens the 100‐hPa level by 0.6 ppmv (~15%) averaged over the 10°S–50°N domain and increases tropical (10°S–30°N) mean cloud occurrence in the middle to upper TTL by ~170%. Nearly all of the convective enhancements in H2O and clouds are due to the effect of convective saturation; convectively detrained ice crystals have negligible impact. Parcels are most frequently hydrated by deep convection in the southern sector of the Asian monsoon anticyclone and subsequently dehydrated downstream of convection to the west, shifting the locations of final dehydration northwest of the cold temperature region in the northern Tropics. Infrequent, extreme deep convective systems (cloud tops exceeding 380 K) have a disproportionately large effect on TTL humidity and clouds.

Humidity↗
DOE OSTI2018

Extended Pulse-Powered Humidity-Freeze Cycling for Testing Module-Level Power Electronics

An EMI suppression capacitor (polypropylene film type) failed by 'popcorning' due to vapor outgassing in the pulse powered humidity-freeze cycles. No shorts or shunts could be detected despite mildly corroded metallization visible in the failed capacitor. Humidity-freeze cycling is optimized to break into moisture barriers. However, further studies will done on additional MLPE devices to optimize the stress testing for condensation to precipitate any weakness to short circuiting and other humidity/bias failure modes.

14 SOLAR ENERGY↗
DOE OSTI2025

AI‐Driven Robot Enables Synthesis‐Property Relation Prediction for Metal Halide Perovskites in Humid Atmosphere

Materials Acceleration Platforms (MAPs) – also known as self-driving laboratories– present a new paradigm for materials science and promise an order of magnitude accelerated materials discovery compared to the traditional trial-and-error approach. Metal halide perovskites (MHPs) are an emerging class of materials for optoelectronic applications but are plagued by irreproducible optoelectronic quality, particularly for films fabricated in a humid atmosphere. Here, in this work, a machine learning (ML)-guided closed-loop platform is developed with a multimodal data fusion approach to predict synthesis–property relations for the optical quality of MHP thin films in relative humidities (RHs) ranging from 5–55%. The efficiency of this approach is confirmed by the fast-dropping learning rate to 2% after experimentally sampling less than 1% of the possible 5,000+ combinations. The prediction of synthesis–property relations is done by optical and imaging characterizations. In situ photoluminescence characterization revealed the origin of thin film quality variation at different RH. These insights provide an avenue for controlling the MHP crystallization by fine-tuning the synthesis parameters and RH for a given chemistry, thus lifting the need for stringent atmosphere control. The MAP enables an accelerated screening and understanding of the synthesis design space, facilitating rational synthesis recipe choice for a wide range of materials.

AI-driven robot↗
DOE OSTI2022

CO 2 Capture by Hybrid Ultramicroporous TIFSIX‐3‐Ni under Humid Conditions Using Non‐Equilibrium Cycling

Abstract Although pyrazine‐linked hybrid ultramicroporous materials (HUMs, pore size <7 Å) are benchmark physisorbents for trace carbon dioxide (CO 2 ) capture under dry conditions, their affinity for water (H 2 O) mitigates their carbon capture performance in humid conditions. Herein, we report on the co‐adsorption of H 2 O and CO 2 by TIFSIX‐3‐Ni—a high CO 2 affinity HUM—and find that slow H 2 O sorption kinetics can enable CO 2 uptake and release using shortened adsorption cycles with retention of ca. 90 % of dry CO 2 uptake. Insight into co‐adsorption is provided by in situ infrared spectroscopy and ab initio calculations. The binding sites and sorption mechanisms reveal that both CO 2 and H 2 O molecules occupy the same ultramicropore through favorable interactions between CO 2 and H 2 O at low water loading. An energetically favored water network displaces CO 2 molecules at higher loading. Our results offer bottom‐up design principles and insight into co‐adsorption of CO 2 and H 2 O that is likely to be relevant across the full spectrum of carbon capture sorbents to better understand and address the challenge posed by humidity to gas capture.

Ullah, Saif↗
DOE OSTI2022

CO 2 Capture by Hybrid Ultramicroporous TIFSIX‐3‐Ni under Humid Conditions Using Non‐Equilibrium Cycling

Abstract Although pyrazine‐linked hybrid ultramicroporous materials (HUMs, pore size <7 Å) are benchmark physisorbents for trace carbon dioxide (CO 2 ) capture under dry conditions, their affinity for water (H 2 O) mitigates their carbon capture performance in humid conditions. Herein, we report on the co‐adsorption of H 2 O and CO 2 by TIFSIX‐3‐Ni—a high CO 2 affinity HUM—and find that slow H 2 O sorption kinetics can enable CO 2 uptake and release using shortened adsorption cycles with retention of ca. 90 % of dry CO 2 uptake. Insight into co‐adsorption is provided by in situ infrared spectroscopy and ab initio calculations. The binding sites and sorption mechanisms reveal that both CO 2 and H 2 O molecules occupy the same ultramicropore through favorable interactions between CO 2 and H 2 O at low water loading. An energetically favored water network displaces CO 2 molecules at higher loading. Our results offer bottom‐up design principles and insight into co‐adsorption of CO 2 and H 2 O that is likely to be relevant across the full spectrum of carbon capture sorbents to better understand and address the challenge posed by humidity to gas capture.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Evapotranspiration is resilient in the face of land cover and climate change in a humid temperate catchment

In temperate humid catchments, evapotranspiration returns more than half of the annual precipitation to the atmosphere, thereby determining the balance available to recharge groundwaters and support stream flow and lake levels. Changes in evapotranspiration rates and, therefore, catchment hydrology could be driven by changes in land use or climate. Here, we examine the catchment water balance over the past 50 years for a catchment in southwest Michigan covered by cropland, grassland, forest, and wetlands. Over the study period, about 27% of the catchment has been abandoned from row-crop agriculture to perennial vegetation and about 20% of the catchment has reverted to deciduous forest, and the climate has warmed by 1.14 °C. Despite these changes in land use, the precipitation and stream discharge, and by inference catchment-scale evapotranspiration, have been stable over the study period. The remarkably stable rates of evapotranspirative water loss from the catchment across a period of significant land cover change suggest that rainfed annual crops and perennial vegetation do not differ greatly in evapotranspiration rates, and this is supported by measurements of evapotranspiration from various vegetation types based on soil water monitoring in the same catchment. Compensating changes in the other meteorological drivers of evaporative water demand besides air temperature—wind speed, atmospheric humidity, and net radiation—are also possible but cannot be evaluated due to insufficient local data across the 50-year period. In conclusion, regardless of the explanation, this study shows that the water balance of this landscape has been resilient in the face of both land cover and climate change over the past 50 years.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Towards retrieving critical relative humidity from ground-based remote sensing observations

Nearly all parameterisations of large-scale cloud require the specification of the critical relative humidity (RHcrit). This is the gridbox-mean relative humidity at which the subgrid fluctuations in temperature and water vapour become so large that part of a subsaturated gridbox becomes saturated and cloud starts to form. Until recently, the lack of high-resolution observations of temperature and moisture variability has hindered a reasonable estimate of the RHcrit from observations. However, with the advent of ground-based measurements from Raman lidar, it becomes possible to obtain long records of temperature and moisture (co-)variances with sub-minute sample rates. Lidar observations are inherently noisy and any analysis of higher-order moments will be very dependent on the ability to quantify and remove this noise. We present an exporatory study aimed at understanding whether current noise levels of lidar-retrieved temperature and water vapour are sufficient to obtain a reasonable estimate of the RHcrit. We show that vertical profiles of RHcrit can be derived for a gridbox length of up to about 30 km (120) with an uncertainty of about 4 % (2 %). RHcrit tends to be smallest near the scale height and seems to be fairly insensitive to the horizontal grid spacing at the scales investigated here (30 - 120 km). However, larger sensitivity was found to the vertical grid spacing. As the grid spacing decreases from 400 to 100 m, RHcrit is observed to increase by about 6 %, which is more than the uncertainty in the RHcrit retrievals.

Van Weverberg, Kwinten↗
DOE OSTI2016

Morphology of U 3 O 8 materials following storage under controlled conditions of temperature and relative humidity

Changes in the visual characteristics of uranium oxide surfaces and morphology following storage under different conditions of temperature and relative humidity may provide insight into the history of an unknown sample. Sub-samples of three α-U 3 O 8 materials—one that was phase-pure and two that were phase-impure—were stored under controlled conditions for two years. We used scanning electron microscopy to image the oxides before and after storage, and a morphology lexicon was used to characterize the images. Finally, temporal changes in morphology were observed in some sub-samples, and changes were greatest following exposure to high relative humidity.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Dual-module humidity pump for efficient air dehumidification: Demonstration and performance limitations

Condensation dehumidification in conventional air conditioning technologies is energy-intensive, accounting for up to 50% of building cooling energy used in some climates. Selective vacuum membrane dehumidification (VMD) is one of the leading alternative dehumidification technologies due to its potential for significant energy savings, and the “dual-module humidity pump” is one of the most promising VMD concepts. Here, this work is the first to provide experimental proof-of-concept for the dual-module humidity pump system and provides the first thermodynamic modeling framework that accounts for realistic steady-state operating limitations, both of which are lacking in the current literature. Additionally, this work is the first to provide a system design solution that overcomes practical challenges associated with air accumulation in the vacuum channels. The experimental results in this work show that the current prototype can remove up to 45% of the water vapor in the air stream, and the vapor pressure difference in the vapor rejection module needs to be approximately 2–4 times greater than that of the dehumidification module in order to maintain balanced mass transfer. The thermodynamic model applied to typical air conditioning conditions shows that the ideal dehumidification (latent) COPs can reach up to 40, but practical COPs are limited to approximately 10. Furthermore, the model shows that the overall energy efficiency increases as the membrane air selectivity increases, though this improvement gradually starts to diminish when the membrane selectivity is increased above 10,000.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗