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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Effect of grafting density on the two-dimensional assembly of nanoparticles

Employing grazing-incidence small-angle X-ray scattering (GISAXS) and X-ray reflectivity (XRR), we demonstrate that films composed of polyethylene glycol (PEG)-grafted silver nanoparticles (AgNPs) and gold nanoparticles (AuNPs), as well as their binary mixtures, form highly stable hexagonal structures at the vapor–liquid interface. These nanoparticles exhibit remarkable stability under varying environmental conditions, including changes in pH, mixing concentration, and PEG chain length. Short-chain PEG grafting produces dense, well-ordered films, while longer chains produce more complex, less dense quasi-bilayer structures. AuNPs exhibit higher grafting densities than AgNPs, leading to more ordered in-plane arrangements. In binary mixtures, AuNPs dominate the population at the surface, while AgNPs integrate into the system, expanding the lattice without forming a distinct binary superstructure. In conclusion, these results offer valuable insights into the structural behavior of PEG-grafted nanoparticles and provide a foundation for optimizing binary nanoparticle assemblies for advanced nanotechnology applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Architecture-Dependent Thin Film Self-Assembly of Star Polystyrene-poly(2-vinylpyridine) Block Copolymers

Controlling the orientation of nanostructured block copolymer (BCP) thin films is essential for their use in templating, transport, and pattern transfer. Conventional efforts mainly focus on adjusting enthalpic interactions between the blocks and interfaces, while entropic contributions are often overlooked. Here, we show that the morphology of BCP thin films can be precisely tuned by the architectural design of star BCPs. Specifically, we synthesized multiarm star BCPs with a polystyrene (PS) core and poly(2-vinylpyridine) (P2VP) corona, which exhibits a lamellar microdomain morphology. The entropic penalty associated with a parallel orientation of the microdomains to the substrate is controlled by varying the number of arms comprising the star BCPs, from 2-arms (triblock) to 3-arms and 4-arms. We systematically investigated the thin film morphology at different depths using grazing incidence small-angle X-ray and neutron scattering (GISAXS and GISANS), atomic force microscopy (AFM), water contact angle (WCA), and interference microscopy. The results show that 2-arm star BCPs show a parallel orientation, the 3-arm star BCPs form a uniform PS film at the air surface with a vertical orientation of the microdomains underneath, and the 4-arm star BCPs exhibit a parallel microdomain orientation at the air surface with mixed parallel and perpendicular microdomain orientation in the bulk. Additionally, we found that the inclination angle of microdomains at the edges of islands and holes, resulting from the incommensurability between film thickness and the characteristic period of the microdomain morphology, increases with a higher number of arms. This suggests a greater grain boundary tilt angle in the microdomains of star-shaped block copolymers (BCPs). When silicon substrates were modified with PS homopolymer, the selective interaction between substrate and core blocks promotes a parallel orientation for the 4-arm star BCPs. In conclusion, this work shows that control of arm number in star BCPs affords diverse BCP thin film morphologies, offering insights into the star BCP conformations in thin films across different depths.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Direct Observation of Morphological and Chemical Changes during the Oxidation of Model Inorganic Ligand-Capped Particles

Functionalization and volatilization are competing reactions during the oxidation of carbonaceous materials and are important processes in many different areas of science and technology. Here, we present a combined ambient pressure X-ray photoelectron spectroscopy (APXPS) and grazing incidence X-ray scattering (GIXS) investigation of the oxidation of oleic acid ligands surrounding NaYF 4 nanoparticles (NPs) deposited onto SiO x /Si substrates. While APXPS monitors the evolution of the oxidation products, GIXS provides insight into the morphology of the ligands and particles before and after the oxidation. Our investigation shows that the oxidation of the oleic acid ligands proceeds at O 2 partial pressures of below 1 mbar in the presence of X-rays, with the oxidation eventually reaching a steady state in which mainly CH x and –COOH functional groups are observed. The scattering data reveal that the oxidation and volatilization reaction proceeds preferentially on the side of the particle facing the gas phase, leading to the formation of a chemically and morphologically asymmetric ligand layer. This comprehensive picture of the oxidation process could be obtained only by combining the X-ray scattering and APXPS data. The investigation presented here lays the foundation for further studies of the stability of NP layers in the presence of reactive trace gases and ionizing radiation and for other nanoscale systems where chemical and morphological changes happen simultaneously and cannot be understood in isolation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

A Robotic High-Throughput Grid-Search Platform for Mapping Phase Behavior in Triblock Copolymer–Homopolymer Blends

We present a high-throughput experimental investigation of the phase behavior in triblock copolymers (PS-b-PB-b-PS and PS-b-PI-b-PS) and polystyrene (PS) homopolymer blends as a function of homopolymer molecular weight (MW) and blend ratio. Using a robotic thin-film processing platform (NOVA) integrated with Grazing Incidence Small-Angle X-ray Scattering (GISAXS) and Atomic Force Microscopy (AFM), we systematically mapped the order–disorder transition (ODT) boundaries and domain spacing evolution across a broad MW range (4.0–101.3 kDa) with varying homopolymer loadings (10% to 90%). The results reveal three distinct regimes: low-MW homopolymers, corresponding to the wet-brush regime produced only gradual domain swelling before disordering at high blend ratios (weight fraction); medium-MW homopolymers, corresponding to thedry-brush regime induced significant domain spacing increase up to 80% followed by earlier disordering, while high-MW homopolymers led to macrophase separation with minimal changes in domain spacing. Additionally, coarse-grained molecular dynamics simulations confirmed our experimental finding that in the low-MW region, the PS homopolymer uniformly distributed in the PS domain. These findings demonstrate that homopolymer molecular weight critically governs both the extent of domain swelling and the onset of disorder in triblock copolymer systems. This high-throughput platform enables the rapid mapping of composition–morphology relationships and can be integrated with AI/ML tools for designing next-generation nanostructured polymers.

36 MATERIALS SCIENCE↗
NASA NTRS2007

Seeking to Improve Low Energy Neutral Atom Detection in Space

The detection of energetic neutral atoms allows for the remote examination of the interactions between plasmas and neutral populations in space. Before these neutral atoms can be measured, they must first be converted to ions. For the low energy end of this spectrum, interaction with a conversion surface is often the most efficient method to convert neutrals into ions. It is generally thought that the most efficient surfaces are low work functions materials. However, by their very nature, these surfaces are highly reactive and unstable, and therefore are not suitable for space missions where conditions cannot be controlled as they are in a laboratory. We therefore are looking to optimize a stable surface for conversion efficiency. Conversion efficiency can be increased either by changing the incident angle of the neutral particles to be grazing incidence and using stable surfaces with high conversion efficiencies. We have examined how to increase the angle of incidence from -80 degrees to -89 degrees, while maintaining or improving the total active conversion surface area without increasing the overall volume of the instrument. We are developing a method to micro-machine silicon, which will reduce the volume to surface area ratio by a factor of 60. We have also examined the material properties that affect the conversion efficiency of the surface for stable surfaces. Some of the parameters we have examined are work function, smoothness, and bond structure. We find that for stable surfaces, the most important property is the smoothness of the surface.

Shappirio, M.↗
NASA NTRS1989

Atmospheric entry heating of micrometeorites

A computer simulation of the atmospheric entry deceleration and heating of cosmic dust particles has been developed and the predicted peak temperatures are compared to the earlier closed-form mathematical solutions of Whipple (195) and Fraundorf (1980). A 20-micron diameter particle of density 1 gm/cu cm having a velocity of 10 km/s at infinity and entering the atmosphere at normal incidence reaches a peak temperature of 1159 K. The duration of the heating pulse is about 8 s but the particle remains within 100 K of the peak temperature for only 1.0 s. As the angle of incidence decreases, the peak temperature reached on entry also decreases, and the duration of the temperature pulse increases. Comparison with the Whipple amd Fraundorf models indicates that they accurately assess the entry heating for cosmic dust particles of moderate or higher densities and entry angles near normal incidence. As particle density decreases or the entry angle nears grazing incidence, they overestimate the peak temperature.

Flynn, G. J.↗
NASA NTRS2004

Validation of an Impedance Education Method in Flow

This paper reports results of a research effort to validate a method for educing the normal incidence impedance of a locally reacting liner, located in a grazing incidence, nonprogressive acoustic wave environment with flow. The results presented in this paper test the ability of the method to reproduce the measured normal incidence impedance of a solid steel plate and two soft test liners in a uniform flow. The test liners are known to be locally react- ing and exhibit no measurable amplitude-dependent impedance nonlinearities or flow effects. Baseline impedance spectra for these liners were therefore established from measurements in a conventional normal incidence impedance tube. A key feature of the method is the expansion of the unknown impedance function as a piecewise continuous polynomial with undetermined coefficients. Stewart's adaptation of the Davidon-Fletcher-Powell optimization algorithm is used to educe the normal incidence impedance at each Mach number by optimizing an objective function. The method is shown to reproduce the measured normal incidence impedance spectrum for each of the test liners, thus validating its usefulness for determining the normal incidence impedance of test liners for a broad range of source frequencies and flow Mach numbers. Nomenclature

Watson, Willie R.↗
NASA NTRS2007

Optimization of Acoustic Pressure Measurements for Impedance Eduction

As noise constraints become increasingly stringent, there is continued emphasis on the development of improved acoustic liner concepts to reduce the amount of fan noise radiated to communities surrounding airports. As a result, multiple analytical prediction tools and experimental rigs have been developed by industry and academia to support liner evaluation. NASA Langley has also placed considerable effort in this area over the last three decades. More recently, a finite element code (Q3D) based on a quasi-3D implementation of the convected Helmholtz equation has been combined with measured data acquired in the Langley Grazing Incidence Tube (GIT) to reduce liner impedance in the presence of grazing flow. A new Curved Duct Test Rig (CDTR) has also been developed to allow evaluation of liners in the presence of grazing flow and controlled, higher-order modes, with straight and curved waveguides. Upgraded versions of each of these two test rigs are expected to begin operation by early 2008. The Grazing Flow Impedance Tube (GFIT) will replace the GIT, and additional capabilities will be incorporated into the CDTR. The current investigation uses the Q3D finite element code to evaluate some of the key capabilities of these two test rigs. First, the Q3D code is used to evaluate the microphone distribution designed for the GFIT. Liners ranging in length from 51 to 610 mm are investigated to determine whether acceptable impedance eduction can be achieved with microphones placed on the wall opposite the liner. This analysis indicates the best results are achieved for liner lengths of at least 203 mm. Next, the effects of moving this GFIT microphone array to the wall adjacent to the liner are evaluated, and acceptable results are achieved if the microphones are placed off the centerline. Finally, the code is used to investigate potential microphone placements in the CDTR rigid wall adjacent to the wall containing an acoustic liner, to determine if sufficient fidelity can be achieved with 32 microphones available for this purpose. Initial results indicate 32 microphones can provide acceptable measurements to support impedance eduction with this test rig.

Jones, M. G.↗
NASA NTRS1989

Small blaze angle gratings with various surface treatments for use in the extreme ultraviolet

Three replica gratings made from a single master, including two epoxy-overcoated gratings with different thicknesses of gold and one grating replicated directly in gold, were studied by measuring and comparing the performances of the gratings in EUV light at grazing incidence angles. The results show that, in situations which require a very low grazing angle, high-quality, mechanically ruled straight groove gratings provide good efficiency and uniform blaze independent of coating thickness up to 1000 A. However, the technique of direct replication in the surface material seems to result in substantially more light scattering and does not seem to have other obvious advantages.

Miller, Anne↗
NASA NTRS2001

Preliminary Results from Coordinated UVCS-CDS-Ulysses Observations

The June 2000 quadrature between the Sun, Earth, and Ulysses took place with Ulysses at a distance of 3.35 AU from the Sun and at heliocentric latitude 58.2 deg south, in the southeast quadrant. This provided an opportunity to observe the corona close to the Sun with Coronal Diagnostic Spectrometer (CDS) and Ultraviolet Coronograph Spectrometer (UVCS) and, subsequently, to sample the same plasma when it reached Ulysses. Here we focus on simultaneous observations of UVCS and CDS made on June 12, 13, 16 and 17. The UVCS data were acquired at heliocentric altitudes ranging from 1.6 to 2.2 solar radii, using different grating positions, in order to get a wide wavelength range. CDS data consisted of Normal Incidence Spectrometer (NIS) full wavelength rasters of 120" x 150" centered at altitudes up to 1.18 solar radii, together with Grazing Incidence Spectrometer (GIS) 4" x 4" rasters within the same field of view, out to 1.2 solar radii. The radial direction to Ulysses passed through a high latitude streamer, throughout the 4 days of observations, Analysis of the spectra taken by UVCS shows a variation of the element abundances in the streamer over our observing interval: however, because the observations were in slightly different parts of the streamer on different days, the variation could be ascribed either to a temporal or spatial effect. The oxygen abundance, however, seems to increase at the edge of the streamer, as indicated by previous analyses. This suggests the variation may be a function of position within the streamer, rather than a temporal effect. Oxygen abundances measured by SWICS on Ulysses are compared with the CDS and UVCS results to see whether changes measured in situ follow the same pattern.

Parenti, S.↗
NASA NTRS1982

Imaging performance of a normal incidence soft X-ray telescope

Measurements are presented of the imaging performance of a normal incidence spherical soft X-ray mirror at BK-alpha (67.6 A). The reflector was a 124-layer coating consisting of alternating Re-W alloy and C layers with a protective C overcoat 34 A thick deposited on a Zerodur substrate. Measurements made at an angle of 1.5 deg off axis with the prototype of the Einstein Observatory high resolution imager reveal the resolution of the mirror to be about 1 arcsec FWHM, with 50% of the reflected power within the detector field of 512 arcsec contained within a diameter of 5 arcsec. The data demonstrate the practicality and potential good performance of normal-incidence soft X-ray optics, and show that the scattering performances of such devices may be as good or better than the best grazing incidence devices.

Henry, J. P.↗
DOE OSTI2020

Performance simulation of the soft gamma-ray concentrator

The soft gamma-ray concentrator is a telescope mission concept utilizing a suitable arrangement of bent multilayer structures of alternating low- and high-density materials. This lens is able to channel gamma-ray photons via total external reflection and concentrate the incident radiation to a point. The channeling technique offers the potential for concentrating gamma rays with focal lengths <10 m and energies >100 keV, beyond the reach of current grazing-incidence hard x-ray mirrors. For the performance estimation of such an instrument, we have developed a flexible set of computer modeling tools to compute the optical properties of multilayer structures, predict the channeling efficiency for a given multilayer configuration, and aid in the optimization of potential gamma-ray concentrator-based telescope designs. This modeling includes the multilayer optical properties calculated by the IMD software, the ray tracing using an IDL code, and the focal plane detector simulation by MEGAlib. We illustrate the potential of this approach by presenting simulated astronomical observations from a balloon-borne platform. The final result, including simulated effective area, instrument sensitivity, and polarization performance, shows that the gamma-ray concentrator will provide greatly increased sensitivity for next-generation soft gamma-ray missions with modest cost and complexity.

47 OTHER INSTRUMENTATION↗
NASA NTRS1991

On the vectorial photoelectric effect at 2.69 keV

Recent experiments conducted to study the vectorial photoelectric effect with CsI, Al2O3 and Si photocathodes at 2.69 keV indicate null results. Detailed analysis shows that previously measured modulation can be well explained by geometrical misalignment and a combination of the asymmetric shape of the incident X-ray beam and a small detection area of the photoelectron detector. After the elimination of the sources of spurious modulation, we observed a modulation factor of less than 3 percent for a grazing incidence angle as small as 5 deg. There is no observable difference in the pulse height distribution between s and p states.

Shaw, P. S.↗
NASA NTRS2001

Instrument Development for X-Ray Astronomy

Current x-ray observatories such as Chandra and XMM-Newton have delivered spectacular results at soft-x-ray energies thanks to their grazing incidence mirrors. To continue these advances necessitates the development of mirrors with even larger collecting areas, yet within manageable weights and budgets, and focal detectors with improved energy resolution. At higher energies where x-ray critical-grazing angles become very small, x-ray optics have typically not been employed and thus this region remains relatively unexplored at high sensitivity levels and fine angular resolutions. This situation is changing with the development of hard-x-ray optics carried aloft by high-altitude balloons, which promise to bring about dramatic advances. This presentation will review developments in all these areas.

Ramsey, Brian↗
NASA NTRS1984

Normal incidence multilayer mirrors for extreme ultraviolet astronomy

Sputtered multilayer coatings allow the use of normal incidence optics in the extreme ultraviolet (EUV) region below 500 A. Multilayer mirrors can be tailored to provide images at strong EUV lines in the sun and stars, in many cases making more efficient use of the telescope aperture than grazing incidence optics. Alternatively, the bandpass can be broadened at the expense of peak effective area, by varying the multilayer structure over the mirror surface. Such mirrors can also serve as optical elements in spectrographs for investigation of specific emission and absorption line complexes, and are self-filtering in that they reject nearby geocoronal and cosmic resonance line backgrounds. Current efforts at the Lockheed Palo Alto Research Laboratory in the design, fabrication, and testing of EUV multilayer mirrors are discussed. This program includes the design and fabrication of normal incidence EUV multilayer mirrors, and the deposition of multilayers on lacquer-coated substrates.

Stern, R. A.↗
NASA NTRS1988

Soft X-ray/extreme ultraviolet images of the solar atmosphere with normal incidence multilayer optics

High-resolution images of the sun in the soft-X-ray/XUV range have been obtained with normal-incidence multilayer coated optics (MCOs) during a sounding-rocket flight on October 23, 1987 from White Sands. MCOs were used in two Cassegrain telescopes, as off-axis primary mirrors, and as tertiary mirrors operating with a Wolter-Schwarzschild (WS) grazing-incidence mirror. The inherent energy-selective property of MCOs allowed distinct groups of emission lines to be isolated in the solar corona and the transition region. Images were recorded at 173 and 256 A with the Cassegrain telescopes, at 256 A with a Herschelian telescope, and at 44, 173, and 256 A with the WS hybrid telescope. In addition, soft-X-ray images in the 8-18-A bandpass were obtained at the prime focus of the WS optics. The images show many features of the solar corona and transition region, including magnetically confined loops of hot solar plasma, coronal plumes, polar coronal holes, supergranulation, and features associated with overlying cool prominences.

Lindblom, Joakim F.↗
NASA NTRS1996

Sub-arcsec X-Ray Telescope for Imaging The Solar Corona In the 0.25 - 1.2 keV Band

We have developed an X-ray telescope that uses a new technique for focusing X-rays with grazing incidence optics. The telescope was built with spherical optics for all of its components, utilizing the high quality surfaces obtainable when polishing spherical (as opposed to aspherical) optics. We tested the prototype X-ray telescope in the 300 meter vacuum pipe at White Sands Missile Range, NM. The telescope features 2 degee graze angles with tungsten coatings, yielding a bandpass of 0.25-1.5 keV with a peak effective area of 0.8 sq cm at 0.83 keV. Results from X-ray testing at energies of 0.25 keV and 0.93 keV (C-K and Cu-L) verify 0.5 arcsecond performance at 0.93 keV. Results from modeling the X-ray telescope's response to the Sun show that the current design would be capable of recording 10 half arcsecond images of a solar active region during a 300 second NASA sounding rocket flight.

Gallagher, Dennis↗