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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Effects of AP size distribution on the pressure-coupled response function

Progress in theoretical and experimental research to determine effects of AP size distribution on the pressure-coupled response function is presented. The theoretical model was based upon a preferred frequency mechanism in which ordered fluctuations in the propellant formulation, dependent upon the heterogeneity, contributed to the response. Experiments to charaterize and relate the heterogeneity to response function behavior consisted of scanning electron microscope studies and measurements of dynamic burning at constant pressure. The concept, differences between ideal models and real propellants, and results thus far obtained are discussed.

Cohen, N. S.↗
DOE OSTI2022

Carbon emission responsive building control: A case study with an all-electric residential community in a cold climate

In the United States, buildings account for 35% of total energy-related carbon dioxide emissions, making them important contributors to decarbonization. Carbon intensities in the power grid are time-varying and can fluctuate significantly within hours, so shifting building loads in response to the carbon intensities can reduce a building’s operational carbon emissions. This paper presents a rule-based carbon responsive control framework that controls the setpoints of thermostatically controlled loads responding to the grid’s carbon emission signals in real time. Based on this framework, four controllers are proposed with different combinations of carbon accounting methods and control rules. To evaluate their performance, we performed simulation studies using models of a 27-home, all-electric, net zero energy residential community located in Basalt, Colorado, United States. The carbon intensity data of four future years from the Cambium data set are adopted to account for the evolving resource mix in the power grid. Various performance metrics, including energy consumption, carbon emission, energy cost, and thermal discomfort, were used to evaluate the performance of the controllers. Sensitivity analysis was also conducted to determine how the control thresholds and intervals affect the controllers’ performance. Simulation results indicate that the carbon responsive controllers can reduce the homes’ annual carbon emissions by 6.0% to 20.5%. However, the energy consumption increased by 0.9% to 6.7%, except in one scenario where it decreased by 2.2%. Compared to the baseline, the change in energy cost was between –2.9% and 3.4%, and thermal discomfort was also maintained within an acceptable range. The little impact on energy cost and thermal discomfort indicates there are no potential roadblocks for customer acceptance when rolling out the controllers in utility programs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

The Sensitivity of Chemical Kinetic Models on Flame Transfer Functions in Acoustic Fluctuation Environments with Varying Equivalence Ratios

Various factors affect the heat release response of flames – thermodynamics, hydrodynamics, acoustics, etc. The coupling of heat release rate and acoustics, in particular, is essential to the design of combustion devices so as to avoid adverse effects during their operation. Modeling flames in acoustic environments requires an accurate understanding of the fundamental physics that occurs when flames interact with a fluctuating pressure field. Over the past couple of decades, researchers have been quantifying the impact of this fluctuating pressure field on the unsteady heat release rate. The flame transfer functions computed have also been shown to depend on the level of detail in the chemical kinetic model. This paper attempts to bridge the gap between these studies to understand how sensitive the flame transfer function is to various kinetic models. The problem is studied by performing multiple one-dimensional simulations using the low-Mach solver NGA. The detailed GRI-Mech 3.0 will be used for comparison. Also, the pressure amplitude and reactant equivalence ratio are varied to understand how the environment affects this sensitivity.

Girdhar, Anant↗
NASA NTRS1989

Late Pleistocene and Holocene Glacial Evolution and Isotasy in the Antarctic Peninsula

Employing a numerical model of Payne et al. that simulates the late-Pleistocene evolution of the former Antarctic Peninsula Ice Sheet (APIS) as a basis, we compute the present-day postglacial vertical isostasy of this region. The region may also experience significant mid-to late-Holocene glacial mass changes. Climate and oceanographic studies indicate that the ice mass imbalance of this region may be of larger magnitude that elsewhere in Antarctica. We compute the crustal response to these more recent ice mass changes and Holocene fluctuations with a simple gravitating Earth model consisting of an elastic lithosphere and a viscoelastic mantle (half-space). The calculations demonstrate that the present-day response could be significant, possibly at the level of about 4 - 11 mm/yr. Such significant crustal motion could be driven by glacial mass changes integrated over the last 1000 years if the regional mantle viscosity is below about 2 x 10(exp 20) Pa sec. In this lower viscosity range, present-day crustal motion has a significant phase-lagged character and the composite lithosphere/mantle viscoelastic response to late-Holocene events dominates over purely elastic (instantaneous) responses to present-day ice mass changes. For a higher mantle viscosity, greater than about 5 x 10(exp 20) Pa sec, the predicted present-day vertical isostasy is dominated by gravitational response to glacial unloading during the 18 - 6 kyr BP collapse of the APIS, and is analogous to that known to be occurring in the Gulf of Bothnia and Hudson Bay.

Ivins, E. R.↗
DOE OSTI2020

Raman Response in the Nematic Phase of FeSe

Raman experiments on bulk FeSe revealed that the low-frequency part of the B 1g Raman response R B1 g (Ω), which probes nematic fluctuations, rapidly decreases below the nematic transition at T n ~ 85 K. Such behavior is expected when a gap opens up and at a first glance is inconsistent with the fact that FeSe remains a metal below Tn. We argue that the drop of R B1 g (Ω) can be ascribed to the fact that the nematic order drastically changes the orbital content of low-energy excitations near hole and electron pockets, making them nearly mono-orbital. In this situation, the B 1g Raman response gets reduced by the same vertex corrections that enforce charge conservation in the symmetric Raman channel. The reduction holds at low frequencies and gives rise to gaplike behavior of R B1 g (Ω). Here, we also show that the enhancement of the B 1g Raman response near T n is consistent with the sign change of the nematic order parameter between hole and electron pockets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2000

Influence of the Polysilicon Gate on the Random Dopant Induced Threshold Voltage Fluctuations in Sub 100 nm MOSFETS with Thin Gate Oxides

In this paper for the first time we study the influence of the polysilicon gate on the random dopant induced threshold voltage fluctuations in sub 100 nm MOSFETs with tunnelling gate oxides. This is done by using an efficient 3D 'atomistic' simulation technique described elsewhere. Devices with uniform channel doping and with low doped epitaxial channels have been investigated. The simulations reveale that the polysilicon gate is responsible for a substantial fraction of the threshold voltage fluctuations in both devices when the gate oxide is scaled to tunnelling thickness in the range of 1 - 2 nm.

Asenov, Asen↗
NASA NTRS2002

3D Finite Element Analysis of Particle-Reinforced Aluminum

Deformation in particle-reinforced aluminum has been simulated using three distinct types of finite element model: a three-dimensional repeating unit cell, a three-dimensional multi-particle model, and two-dimensional multi-particle models. The repeating unit cell model represents a fictitious periodic cubic array of particles. The 3D multi-particle (3D-MP) model represents randomly placed and oriented particles. The 2D generalized plane strain multi-particle models were obtained from planar sections through the 3D-MP model. These models were used to study the tensile macroscopic stress-strain response and the associated stress and strain distributions in an elastoplastic matrix. The results indicate that the 2D model having a particle area fraction equal to the particle representative volume fraction of the 3D models predicted the same macroscopic stress-strain response as the 3D models. However, there are fluctuations in the particle area fraction in a representative volume element. As expected, predictions from 2D models having different particle area fractions do not agree with predictions from 3D models. More importantly, it was found that the microscopic stress and strain distributions from the 2D models do not agree with those from the 3D-MP model. Specifically, the plastic strain distribution predicted by the 2D model is banded along lines inclined at 45 deg from the loading axis while the 3D model prediction is not. Additionally, the triaxial stress and maximum principal stress distributions predicted by 2D and 3D models do not agree. Thus, it appears necessary to use a multi-particle 3D model to accurately predict material responses that depend on local effects, such as strain-to-failure, fracture toughness, and fatigue life.

Shen, H.↗
NASA NTRS1977

Characterization of nonGaussian atmospheric turbulence for prediction of aircraft response statistics

Mathematical expressions were derived for the exceedance rates and probability density functions of aircraft response variables using a turbulence model that consists of a low frequency component plus a variance modulated Gaussian turbulence component. The functional form of experimentally observed concave exceedance curves was predicted theoretically, the strength of the concave contribution being governed by the coefficient of variation of the time fluctuating variance of the turbulence. Differences in the functional forms of response exceedance curves and probability densities also were shown to depend primarily on this same coefficient of variation. Criteria were established for the validity of the local stationary assumption that is required in the derivations of the exceedance curves and probability density functions. These criteria are shown to depend on the relative time scale of the fluctuations in the variance, the fluctuations in the turbulence itself, and on the nominal duration of the relevant aircraft impulse response function. Metrics that can be generated from turbulence recordings for testing the validity of the local stationary assumption were developed.

Mark, W. D.↗
NASA NTRS1987

Transfer function analysis of the autonomic response to respiratory activity during random interval breathing

We report a new method for the noninvasive characterization of the frequency response of the autonomic nervous system (ANS) in mediating fluctuations in heart rate (HR). The approach entails computation of the transfer function magnitude and phase between instantaneous lung volume and HR. Broad band fluctuations in lung volume were initiated when subjects breathed on cue to a sequence of beeps spaced randomly in time. We studied 10 subjects in both supine and standing positions. The transfer function, averaged among all the subjects, showed systematic differences between the two postures, reflecting the differing frequency responses of the sympathetic and parasympathetic divisions of the ANS.

Non-NASA Center↗
NASA NTRS2017

Wavenumber-frequency Spectra of Pressure Fluctuations on a Generic Space Vehicle Measured via Unsteady Pressure-Sensitive Paint

Time histories of pressure fluctuations on a generic, hammerhead space vehicle model were measured using unsteady Pressure-Sensitive Paint (uPSP). The test was conducted in the 11-foot transonic wind tunnel of NASA Ames Research Center over a Mach number range of 0.6 M 1.2, and angles of attack of -4 4. The model was coated with a porous binder and PtTFPP-based porous polymer paint. An elaborate system of four high-speed cameras, and forty LED lamps was used for image acquisition. Various steps for image registration, reduction of shot noise, photogrammetry procedure to map images from the four cameras on a grid for the model, and finally a calibration procedure to convert the measured fluctuations in light intensity to fluctuating pressure, are discussed in the paper. The calibration process using a set of unsteady pressure sensors mounted on the model, was found to overcome some of the inherent problems of the fast response paint, such as rapid photo-degradation, non-linearity in pressure response, and significant temperature sensitivity. Comparison of spectra of pressure fluctuations between UPSP and pressure sensors demonstrated the ability of the paint to faithfully follow fluctuations up to 10 kHz, the maximum attempted. It was also found that the camera bit-depth and the illumination level limited the lowest measurable levels of pressure fluctuations to around 140dB. The large data set exposed various critical transonic flow physics not seen before, such as a coupling of the shock motion on the Payload Fairing (PF) with the separated flow region on the upper stage of the launch vehicle, and upstream convection of pressure fluctuation on PF at certain Mach numbers. The data also confirmed the expectation of a general lowering of the coefficient of pressure fluctuation with Mach number. The availability of the data set on a dense, regularly-spaced, surface grid allowed for the calculation of wavenumber-frequency (k-) spectra via straightforward applications of Fourier transform. The k- spectra were compared for the separated flow regions on the Second Stage, and the shock-boundary layer interactions on PF. The former showed self-similarity with Mach number while the latter was distinctly different, and confirmed the upstream propagation of pressure fluctuations. The k- spectra were dominated by the convected fluctuations; the acoustic domain was not discernable. These data, valuable for the vibro-acoustics analysis of aerospace vehicles, are believed to be the first obtained for the transonic flight regime, and pave the path for application on production models of aerospace vehicles.

buffet↗
DOE OSTI2021

Toward nonthermal control of excited quantum materials: framework and investigations by ultrafast electron scattering and imaging

Quantum material systems upon applying ultrashort laser pulses provide a rich platform to access excited material phases and their transformations that are not entirely like their equilibrium counterparts. The addressability and potential controls of metastable or long-trapped out-of-equilibrium phases have motivated interests both for the purposes of understanding the nonequilibrium physics and advancing the quantum technologies. Thus far, the dynamical spectroscopic probes eminently focus on microscopic electronic and phonon responses. For characterizing the long-range dynamics, such as order parameter fields and fluctuation effects, the ultrafast scattering probes offer direct sensitivity. Bridging the connections between the microscopic dynamics and macroscopic responses is central toward establishing the nonequilibrium physics behind the light-induced phases. Here, we present a path toward such understanding by cross-examining the structure factors associated with different dynamical states obtained from ultrafast electron scattering, imaging, and modeling. We give the basic theoretical framework on describing the non-equilibrium scattering problems and briefly describe how such framework relates to the out-of-equilibrium phenomena. We give effective models outlining the emergences of nonthermal critical points, hidden phases, and non-equilibrium relaxational responses from vacuum-suspended rare-earth tritellurides, tantalum disulfides thin films, and vanadium dioxide nanocrystalline materials upon light excitations.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1995

Triggering of longitudinal combustion instabilities in solid rocket motors: Nonlinear combustion response

Pulsed oscillations in solid rocket motors are investigated with emphasis on nonlinear combustion response. The study employs a wave equation governing the unsteady motions in a two-phase flow, and a solution technique based on spatial- and time-averaging. A wide class of combustion response functions is studied to second-order in fluctuation amplitude to determine if, when, and how triggered instabilities arise. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Based on the behavior of model dynamical systems, introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be the manner in which the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse.

Wicker, J. M.↗
DOE OSTI2024

Principles of two-dimensional terahertz spectroscopy of collective excitations: The case of Josephson plasmons in layered superconductors

Two-dimensional terahertz spectroscopy (2DTS), a terahertz analog of nuclear magnetic resonance, is a new technique poised to address many open questions in complex condensed matter systems. The conventional theoretical framework used ubiquitously for interpreting multidimensional spectra of discrete quantum level systems is, however, insufficient for the continua of collective excitations in strongly correlated materials. Here, in this work, we develop a theory for 2DTS of a model collective excitation, the Josephson plasma resonance in layered superconductors. Starting from a mean-field approach at temperatures well below the superconducting phase transition, we obtain expressions for the multidimensional nonlinear responses that are amenable to intuition derived from the conventional single-mode scenario. We then consider temperatures near the superconducting critical temperature T c , where dynamics beyond mean-field become important and conventional intuition fails. As fluctuations proliferate near T c , the dominant contribution to nonlinear response comes from an optical parametric drive of counterpropagating Josephson plasmons, which gives rise to 2D spectra that are qualitatively different from the mean-field predictions. As such, and in contrast to one-dimensional spectroscopy techniques, such as third harmonic generation, 2DTS can be used to directly probe thermally excited finite-momentum plasmons and their interactions. Our theory can readily be tested in cuprates, and we discuss implications beyond the present context of Josephson plasmons.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2000

Polysilicon Gate Enhancement of the Random Dopant Induced Threshold Voltage Fluctuations in Sub-100 nm MOSFET's with Ultrathin Gate Oxide

In this paper, we investigate various aspects of the polysilicon gate influence on the random dopant induced threshold voltage fluctuations in sub-100 nm MOSFET's with ultrathin gate oxides. The study is done by using an efficient statistical three-dimensional (3-D) "atomistic" simulation technique described else-where. MOSFET's with uniform channel doping and with low doped epitaxial channels have been investigated. The simulations reveal that even in devices with a single crystal gate the gate depletion and the random dopants in it are responsible for a substantial fraction of the threshold voltage fluctuations when the gate oxide is scaled-in the range of 1-2 nm. Simulation experiments have been used in order to separate the enhancement in the threshold voltage fluctuations due to an effective increase in the oxide thickness associated with the gate depletion from the direct influence of the random dopants in the gate depletion layer. The results of the experiments show that the both factors contribute to the enhancement of the threshold voltage fluctuations, but the effective increase in the oxide-thickness has a dominant effect in the investigated range of devices. Simulations illustrating the effect or the polysilicon grain boundaries on the threshold voltage variation are also presented.

Asenov, Asen↗
DOE OSTI2022

Computing Thermodynamic Properties of Fluids Augmented by Nanoconfinement: Application to Pressurized Methane

Nanoconfined fluids exhibit remarkably different thermodynamic behavior compared to the bulk phase. These confinement effects render predictions of thermodynamic quantities of nanoconfined fluids challenging. In particular, confinement creates a spatially varying density profile near the wall that is primarily responsible for adsorption and capillary condensation behavior. Significant fluctuations in thermodynamic quantities, inherent in such nanoscale systems, coupled to strong fluid–wall interactions give rise to this near-wall density profile. Empirical models have been proposed to explain and model these effects, yet no first-principles based formulation has been developed. We present a statistical mechanics framework that embeds such a coupling to describe the effect of the fluid–wall interaction in amplifying the near-wall density behavior for compressible gases at elevated pressures such as pressurized methane in confinement. We show that the proposed theory predicts accurately the adsorbed layer thickness as obtained with small-angle neutron scattering measurements. Furthermore, the predictions of density under confinement from the proposed theory are shown to be in excellent agreement with available experimental and atomistic simulations data for a range of temperatures for nanoconfined methane. While the framework is presented for evaluating the near-wall density, owing to its rigorous foundation in statistical mechanics, the proposed theory can also be generalized for predicting phase-transition and nonequilibrium transport of nanoconfined fluids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

High frequency beam oscillation keyhole dynamics in laser melting revealed by in-situ x-ray imaging

The metal additive manufacturing industry is actively developing instruments and strategies to enable higher productivity, optimal build quality, and controllable as-built microstructure. A beam controlling technique, laser oscillation has shown potential in all these aspects in laser welding; however, few attempts have been made to understand the underlying physics of the oscillating keyholes/melt pools which are the prerequisites for these strategies to become a useful tool for laser-based additive manufacturing processes. Here, to address this gap, we utilized a synchrotron-based X-ray operando technique to image the dynamic keyhole oscillation in Ti-6Al-4V using a miniature powder bed fusion setup. We found good agreement between the experimental observations and simulations performed with a validated Lattice Boltzmann multiphysics model. The study revealed the continuous and periodic fluctuations in the characteristic keyhole parameters that are unique to the oscillating laser beam processing and responsible for the chevron pattern formation at solidification. In particular, despite the intrinsic longer-range fluctuation, the oscillating technique displayed potential for reducing keyhole instability, mitigating porosity formation, and altering surface topology. These insights on the oscillating keyhole dynamics can be useful for the future development and application of this technique.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Analytic and numerical vibronic spectra from quasi-classical trajectory ensembles

The truncated Wigner approximation to quantum dynamics in phase space is explored in the context of computing vibronic line shapes for monomer linear optical spectra. We consider multiple model potential forms including a shifted harmonic oscillator with both equal and unequal frequencies on the ground and excited state potentials as well as a shifted Morse potential model. For the equal-frequency shifted harmonic oscillator model, we derive an analytic expression for the exact vibronic line shape that emphasizes the importance of using a quantum mechanical distribution of phase space initial conditions. For the unequal-frequency shifted harmonic oscillator model, we are no longer able to obtain an exact expression for the vibronic line shape in terms of independent deterministic classical trajectories. We show how one can rigorously account for corrections to the truncated Wigner approximation through nonlinear responses of the line shape function to momentum fluctuations along a classical trajectory and demonstrate the qualitative improvement in the resulting spectrum when the leading-order quantum correction is included. Finally, we numerically simulate absorption spectra of a highly anharmonic shifted Morse potential model. We find that, while finite quantization and the dissociation limit are captured with reasonable accuracy, there is a qualitative breakdown of the quasi-classical trajectory ensemble’s ability to describe the vibronic line shape when the relative shift in Morse potentials becomes large. The work presented here provides clarity on the origin of unphysical negative features known to contaminate absorption spectra computed with quasi-classical trajectory ensembles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1976

A study of a plume induced separation shock wave, including effects of periodic plume unsteadiness

A wind tunnel investigation was conducted to study the flow field in which separation is caused by an expanding plume, with emphasis on effects associated with periodic unsteadiness in the plume. The separation shock was photographed with high speed motion pictures, from which mean shock position and excursion data were reported. Pressure fluctuations were measured beneath the separation shock. A response of the separation shock to plume periodic unsteadiness was identified, and the magnitude of a corresponding transfer function was defined. Small harmonic effects in plume response to periodic unsteadiness were noted. The stabilizing effect of a lateral surface protuberance near the separation shock wave was investigated. The protuberance configuration was a lateral circular cylinder, and various diameters, all less than the boundary layer thickness, were employed.

Doughty, J. O.↗