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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Nitrogen derived from Combined Algal Processing supports algae cultivation for biofuels

Algae biomass, a biofuel feedstock with potential to reduce global CO 2 emissions, is currently too expensive Nitrogen, a significant input and life cycle cost, requires research on recycling and additional sources to reduce costs. Integral to nitrogen recycling is the knowledge of actual nitrogen requirements in outdoor ponds, thus data from the Unified Field Studies of the Algae Testbed Public-Private Partnership was analyzed. The data showed that Nannochloropsis oceanica used 14–24 mg/L NH 4 + per harvest cycle for robust growth. Nitrogen recycled directly from the algae conversion process will likely be the primary source of nitrogen for algae cultivation. Harvested algae can be fractionated via Combined Algal Processing (CAP), where algae are pretreated, fermented, and the fuel feedstocks (e. g. ethanol, lipids) are removed leaving a nitrogen rich slurry. Chlorella vulgaris grew robustly in nitrogen-free media supplemented with CAP residues through 4 harvest cycles with no inhibition. The amount of nitrogen as free ammonium available for recycling directly without further processing was insufficient (~4% of total needed), thus the nitrogen fixing bacteria, Azotobacter vinelandii, was investigated as a means for increasing ammonium concentration in CAP residues. This organism was shown to be proficient at growth on sugars liberated from algae biomass during pretreatment and sustained algae growth using A. vinelandii supernatants was also demonstrated. Using Azotobacter to increase ammonium concentrations on-site using an inexpensive biological process to generate the necessary ammonium for outdoor algae cultivation improves sustainability of algae biofuels by avoiding the energy intensive steps of typical ammonium production and transport. Furthermore, these results show that byproducts of algae conversion begin to close nitrogen demand and, with further supplementation by diazotrophic bacteria or protein hydrolysis, may completely replace current energyintensive and costly industrial nitrogen sources offering a path to increased economic feasibility and improved life cycle analysis of algae-based biofuels.

09 BIOMASS FUELS↗

Pyomo.DOE: An open-source package for model-based design of experiments in Python

Predictive mathematical models are a cornerstone of science and engineering. Yet selecting, calibrating, and validating said science-based models often remains an art in practice. Model-based design of experiments (MBDoE) provides a systematic framework to maximize information gain from experiments while minimizing time and resource costs. But MBDoE remains limited to niche application areas, in part because practitioners must integrate expertise in statistics, computational optimization, and modeling. To help reduce this barrier, we introduce Pyomo.DOE, an open-source package for MBDoE. Pyomo.DOE uses a nonlinear sensitivity analysis code k_aug to quickly approximate the Fisher information matrix and leverages a new stochastic programming abstraction. We demonstrate Pyomo.DOE with the first application of MBDoE to fixed-bed breakthrough experiments, which highlights the power of Pyomo.DOE to quantify the value of experimental modifications a priori for large-scale partial differential-algebraic equation (PDAE) models. Here we also provide a mathematical primer on MBDoE targeted at general chemical engineers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ball Motion and Near-Field Spray Characteristics of a Gasoline Direct Injection Injector using an X-ray Phase-Contrast Imaging Technique under High-Injection Pressures

Here, the purpose of this study is to visualize the ball (needle) motion and near-field spray characteristics of a gasoline direct injection injector under different injection conditions and analyze the effect of the internal structure of the injector on the ball motion, near-field spray velocity, and post-injection process. The injection pressure is set to 10MPa, 20 MPa, and 30 MPa, and the energization duration is fixed at 1.5 ms. An advanced X-ray technique with high transmittance and low scattering, is used to visualize the internal structure and near-field spray characteristics of the injector, which is impossible with general light sources. The ball is found to tilt to the right in the Y-axial direction during stable motion because the driving force of fuel on the ball is larger on the left side owing to the larger distance of the ball from the left wall. In addition, during stable motion, the near-field velocity of a hole with a smaller inlet angle is significantly higher than that of a hole with a larger inlet angle. The hole with a smaller inlet angle display better atomization characteristics during the post-injection process under all values of injection pressure.

47 OTHER INSTRUMENTATION↗

beluga

Submission-beluga is an open-source optimal control software that uses publicly available indirect methods to model inequality constraints at boundaries. This release of beluga introduces a method known as UTM, modified handling of constraints to support the UTM method, and includes bug fixes and related requirements changes.SAND2020-12847 M Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

Sparapany, Michael↗

High-energy inelastic neutron scattering data taken at the SEQUOIA spectrometer.

INS measurements were performed using the Fine Resolution Chopper Spectrometer SEQUOIA at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory. A powder sample of SrCoGe2O6 was loaded in an aluminum can for the measurements and a CCR was used to cool the sample down to 6 K. Data were collected using fixed incident neutron energies of 100 and 30 meV.

MATERIALS SCIENCE↗

Constraints on the Cosmic Expansion History from GWTC–3

We use 47 gravitational wave sources from the Third LIGO–Virgo–Kamioka Gravitational Wave Detector Gravitational Wave Transient Catalog (GWTC–3) to estimate the Hubble parameter H(z), including its current value, the Hubble constant H0. Each gravitational wave (GW) signal provides the luminosity distance to the source, and we estimate the corresponding redshift using two methods: the redshifted masses and a galaxy catalog. Using the binary black hole (BBH) redshifted masses, we simultaneously infer the source mass distribution and H(z). The source mass distribution displays a peak around 34 M ⊙ , followed by a drop-off. Assuming this mass scale does not evolve with the redshift results in a H(z) measurement, yielding H 0 = $68$$^{+12}_{–8}$km s –1 Mpc –1 (68% credible interval) when combined with the H 0 measurement from GW170817 and its electromagnetic counterpart. This represents an improvement of 17% with respect to the H 0 estimate from GWTC–1. The second method associates each GW event with its probable host galaxy in the catalog GLADE+, statistically marginalizing over the redshifts of each event's potential hosts. Assuming a fixed BBH population, we estimate a value of H 0 = $68$$^{+8}_{–6}$km s –1 Mpc –1 with the galaxy catalog method, an improvement of 42% with respect to our GWTC–1 result and 20% with respect to recent H 0 studies using GWTC–2 events. However, we show that this result is strongly impacted by assumptions about the BBH source mass distribution; the only event which is not strongly impacted by such assumptions (and is thus informative about H 0 ) is the well-localized event GW190814.

79 ASTRONOMY AND ASTROPHYSICS↗

Key Drivers for Offshore Wind Deployment in the Western United States

The western coast of the United States has abundant natural resources, including wind, sun, and water. Despite strong ocean winds, offshore wind energy (OSW) in the Western United States is in the early stages of technology development due largely to the deep water off the coast, which requires floating platforms rather than fixed‐bottom turbines. Floating OSW increases the technical difficulty of installation and thus the cost relative to both fixed‐bottom OSW and land‐based turbines. OSW is a potential generation option to help meet increasing demand on the west coast of the United States because it likely has fewer land‐use conflicts than other technologies and complements sources in the existing electricity supply by providing energy during times of high system stress. This paper examines the possible drivers and barriers to OSW deployment on the West Coast using the National Laboratory of the Rockies' state‐of‐the‐art capacity expansion model and the Regional Energy Deployment System (ReEDS) model. We use ReEDS to explore a multitude of future scenarios looking at key drivers for OSW deployment, including variations on the cost of OSW, electricity demand growth, and the availability of competing technologies to examine the factors that may play a role in OSW growth. Assuming coastal state policies such as renewable portfolio and clean energy standards remain in place, we find that OSW can play a role in meeting electricity demand and provide energy during stressful grid conditions and find that deployment from the least‐cost investment model ranges from 7.6 to 38 GW by 2045.

17 WIND ENERGY↗

Diazotrophs Show Signs of Restoration in Amazon Rain Forest Soils with Ecosystem Rehabilitation

Biological nitrogen fixation can be an important source of nitrogen in tropical forests that serve as a major CO 2 sink. Extensive deforestation of the Amazon is known to influence microbial communities and the biogeochemical cycles they mediate. However, it is unknown how diazotrophs (nitrogen-fixing microorganisms) respond to deforestation and subsequent ecosystem conversion to agriculture, as well as whether they can recover in secondary forests that are established after agriculture is abandoned. To address these knowledge gaps, here we combined a spatially explicit sampling approach with high-throughput sequencing of nifH genes. The main objectives were to assess the functional distance decay relationship of the diazotrophic bacterial community in a tropical forest ecosystem and to quantify the roles of various factors that drive the observed changes in the diazotrophic community structure. We observed an increase in local diazotrophic diversity (α-diversity) with a decrease in community turnover (β-diversity), associated with a shift in diazotrophic community structure as a result of the forest-to-pasture conversion. Both diazotrophic community turnover and structure showed signs of recovery in secondary forests. Changes in the diazotrophic community were primarily driven by the change in land use rather than differences in geochemical characteristics or geographic distances. The diazotroph communities in secondary forests resembled those in primary forests, suggesting that at least partial recovery of diazotrophs is possible following agricultural abandonment. IMPORTANCE The Amazon region is a major tropical forest region that is being deforested at an alarming rate to create space for cattle ranching and agriculture. Diazotrophs (nitrogen-fixing microorganisms) play an important role in supplying soil N for plant growth in tropical forests. It is unknown how diazotrophs respond to deforestation and whether they can recover in secondary forests that establish after agriculture is abandoned. Using high-throughput sequencing of nifH genes, we characterized the response of diazotrophs’ β-diversity and identified major drivers of changes in diazotrophs from forest-to-pasture and pasture-to-secondary-forest conversions. Studying the impact of land use change on diazotrophs is important for a better understanding of the impact of deforestation on tropical forest ecosystem functioning, and our results on the potential recovery of diazotrophs in secondary forests imply the possible restoration of ecosystem functions in secondary forests.

59 BASIC BIOLOGICAL SCIENCES↗

Hub and Spoke Modeling to support Agile Combat Employment

Here, the 2022 National Defense Strategy (NDS) shifts focus primarily to the People’s Republic of China (PRC) as the pacing challenge, with acknowledgement of the other threats. President Joe Biden introduced the updated version by stating the U.S. is living in a decisive decade. While the country does not know when the next conflict will happen, leadership believes it will happen soon and the DoD is preparing for this eventuality in the Indo-Pacific region by rethinking operations and concepts. Traditionally, large, fixed installations have been the primary means of operating and generating airpower for the United States Air Force (USAF). Additionally, the service has the capabilities to establish contingency locations based on two primary criteria: a runway and a water source. However, policies and strategy must be updated to create a more agile and dispersed force.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Inferring UAV Position Relative to Smartphone Sensor Based on Acoustic Characteristics

As commercial and non-commercial unmanned aerial vehicles (UAVs) improve technologically and increase in accessibility, their potential for use in actions antithetical to nuclear non-proliferation efforts increases as well. The ability to identify and locate UAVs using ubiquitous, inexpensive hardware and software would be advantageous as both a deterrent and an initial warning system. Our team looks to utilize smartphones as acoustic sensors to record and characterize UAV movement based on the sound produced while in flight. Multi-rotor UAVs produce identifiable acoustic spectral characteristics with frequencies and harmonics corresponding to motor revolutions per minute and the propeller characteristics. As the source moves closer to the receiver these spectral patterns remain relatively stable (at slow speeds), while the energy observed from the waves increases. The goal of this work is to utilize a small network of smartphone sensors with known, fixed positions to infer the relative position of an in-flight UAV with respect to the position of the smartphones through the variation in acoustic energy.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Indoor Wireless Localization of Uncooperative Sources Using a Ray Tracing Model

Indoor geolocation of radio frequency (RF) trans- mitters is challenging due to site-specific multipath effects, especially when the sources are uncooperative. A source being uncooperative means that a-priori the transmit time, location, and power are unknown. It is proposed to use a site-specific ray tracing model to generate realistic indoor RF responses, perform geolocation using multiple methods, and compare their performance. This work will look at two types of geolocation algorithms: (1) time-difference of arrival (TDOA) and (2) re- ceived signal strength Indicator (RSSI) fingerprinting or pattern- matching-based methods. An indoor space will be simulated with a grid of fixed receivers and a grid of transmit locations using Remcom’s Wireless InSite. Using the output of the Wireless InSite simulation the response from any given transmit location can be generated and used to evaluate geolocation performance.

indoor source localization, Wireless InSite, re- c↗

Proposal for a proton-bunch compression experiment at IOTA in the strong space-charge regime

The longitudinal compression of intense proton bunches with strong space-charge force is an essential component of a proton-based muon source for a muon collider. This paper discusses a proton-bunch compression experiment at the Integrable Optics Test Accelerator (IOTA) storage ring at Fermilab to explore optimal radio frequency (RF) cavity and lattice configurations. IOTA is a compact fixed-energy storage ring that can circulate a 2.5-MeV proton beam with varying beam parameters and lattice configurations. The study will aim to demonstrate a bunch-compression factor of at least 2 in the IOTA ring while examining the impact of intense space-charge effects on the compression process.

43 PARTICLE ACCELERATORS↗

Proposal for a Proton-Bunch Compression Experiment at IOTA in the Strong Space-Charge Regime

The longitudinal compression of intense proton bunches with strong space-charge force is an essential component of a proton-based muon source for a muon collider. This paper discusses a proton-bunch compression experiment at the Integrable Optics Test Accelerator (IOTA) storage ring at Fermilab to explore optimal radio frequency (RF) cavity and lattice configurations. IOTA is a compact fixed-energy storage ring that can circulate a 2.5-MeV proton beam with varying beam parameters and lattice configurations. The study will aim to demonstrate a bunch-compression factor of at least 2 in the IOTA ring while examining the impact of intense space-charge effects on the compression process.

43 PARTICLE ACCELERATORS↗

Adiabatic Longitudinal Island Formation Due to Phase Modulation Using BLonD

The studies of adiabatic island generation through tracking near the quarter integer resonance and separately, through phase modulation was conducted using the accelerator code BLonD. Parameters from the Hadron Storage Ring (HSR) were used in the model. The demonstration of resonance island formation through phase modulation will help to understand this possible source of beam dilution during the store and further control of the bunch shaping. In this document, an algorithm to calculate the 5 th , 7 th , and N th order resonances is given, tracking results are presented, and the stable fixed point calculations with comparison to Poincaré contours are given.

43 PARTICLE ACCELERATORS↗

Mixed gain detector configurations for time-resolved X-ray solution scattering

X-ray detection at X-ray free-electron lasers is challenging in part due to the XFEL's extremely short and intense X-ray pulses. Experimental measurements are further complicated by the large fluctuations inherent to the self-amplified spontaneous emission process producing the X-rays. At the Linac Coherent Light Source the ePix10ka2M detector offers multiple gain modes, and auto-ranging between these, to increase the dynamic range while retaining low noise. For diffuse scattering techniques, such as time-resolved X-ray solution scattering, where the shape of the scattering pattern largely does not change between exposures, a fixed mix of different gain modes offers many of the same advantages as auto-ranging. We find that configuring individual ASICs in separate gain modes does not impact the intensity linearity of the gain response and has a limited effect on the effective dynamic range in regions with different gain mode settings while avoiding the complexities of auto-ranging. Small (<5%) non-linear gain contributions arise when pixels on the same ASIC are configured in different gain modes. We present a configuration scheme that is designed to select the optimal mixed gain configuration to minimize effects of saturation in the high-/medium-gain region, while maximizing the number of pixels with higher gain to improve the signal-to-noise ratio.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

tRNA functional signatures classify plastids as late-branching cyanobacteria

Eukaryotes acquired the trait of oxygenic photosynthesis through endosymbiosis of the cyanobacterial progenitor of plastid organelles. Despite recent advances in the phylogenomics of Cyanobacteria, the phylogenetic root of plastids remains controversial. Although a single origin of plastids by endosymbiosis is broadly supported, recent phylogenomic studies are contradictory on whether plastids branch early or late within Cyanobacteria. One underlying cause may be poor fit of evolutionary models to complex phylogenomic data. Using Posterior Predictive Analysis, we show that recently applied evolutionary models poorly fit three phylogenomic datasets curated from cyanobacteria and plastid genomes because of heterogeneities in both substitution processes across sites and of compositions across lineages. To circumvent these sources of bias, we developed CYANO-MLP, a machine learning algorithm that consistently and accurately phylogenetically classifies (“phyloclassifies”) cyanobacterial genomes to their clade of origin based on bioinformatically predicted function-informative features in tRNA gene complements. Classification of cyanobacterial genomes with CYANO-MLP is accurate and robust to deletion of clades, unbalanced sampling, and compositional heterogeneity in input tRNA data. CYANO-MLP consistently classifies plastid genomes into a late-branching cyanobacterial sub-clade containing single-cell, starch-producing, nitrogen-fixing ecotypes, consistent with metabolic and gene transfer data. Phylogenomic data of cyanobacteria and plastids exhibit both site-process heterogeneities and compositional heterogeneities across lineages. These aspects of the data require careful modeling to avoid bias in phylogenomic estimation. Furthermore, we show that amino acid recoding strategies may be insufficient to mitigate bias from compositional heterogeneities. However, the combination of our novel tRNA-specific strategy with machine learning in CYANO-MLP appears robust to these sources of bias with high accuracy in phyloclassification of cyanobacterial genomes. CYANO-MLP consistently classifies plastids as late-branching Cyanobacteria, consistent with independent evidence from signature-based approaches and some previous phylogenetic studies.

59 BASIC BIOLOGICAL SCIENCES↗