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At least 271 records · Page 15

Worldwide surface extremes

Information needed to fabricate, transport, test, and launch space vehicles requires statistical meteorological data for various geographical areas. A brief review of world surface extremes is presented that illustrates the large extremum values that occur in some global areas and compares them with those currently used in space vehicle design.

Daniels, G. E.↗

Venus Surface Composition from Radio/radar Measurements

Three different radio techniques were used to study the electrical properties of the surface of Venus. The reflectivity of the surface at near normal incidence was studied using radar from the Pioneer Venus Orbiter (PVO) spacecraft. These measurements have inferred the corresponding dielectric constants. Surface emissivities were calculated using measurements of thermal emission brightness temperature obtained both from spacecraft and from the ground. These measurements also have inferred dielectric constant. The degree of linear polarization associated with thermal energy emitted from the surface at various angles was examined. The dielectric constant was calculated. The radar data have provided the highest surface resolution of the three techniques, and were the first to show the unusually high values of Fresnel reflection coefficient (approaching 0.40 in extreme cases) that are associated with many of the elevated regions of Venus. The distribution of small scale surface roughness was estimated.

Pettengill, G. H.↗

Exobiological implications of dust aggregation in planetary atmospheres: An experiment for the gas-grain simulation facility

The Gas-Grain Simulation Facility (GGSF) will provide a microgravity environment where undesirable environmental effects are reduced, and thus, experiments involving interactions between small particles and grains can be more suitably performed. Slated for flight aboard the Shuttle in 1992, the ESA glovebox will serve as a scientific and technological testbed for GGSF exobiology experiments as well as generating some basic scientific data. Initial glovebox experiments will test a method of generating a stable, mono-dispersed cloud of fine particles using a vibrating sprinkler system. In the absence of gravity and atmospheric turbulence, it will be possible to determine the influence of interparticle forces in controlling the rate and mode of aggregation. The experimental chamber can be purged of suspended matter to enable multiple repetitions of the experiments. Of particular interest will be the number of particles per unit volume of the chamber, because it is suspected that aggregation will occur extremely rapidly if the number exceeds a critical value. All aggregation events will be recorded on high-resolution video film. Changes in the experimental procedure as a result of surprise events will be accompanied by real-time interaction with the mission specialist during the Shuttle flight.

Huntington, J. L.↗

Acetone in the atmosphere: Distribution, sources, and sinks

Acetone (CH3COCH3) was found to be the dominant nonmethane organic species present in the atmosphere sampled primarily over eastern Canada (0-6 km, 35 deg-65 deg N) during ABLE3B (July to August 1990). A concentration range of 357 to 2310 ppt (= 10(exp -12) v/v) with a mean value of 1140 +/- 413 ppt was measured. Under extremely clean conditions, generally involving Arctic flows, lowest (background) mixing ratios of 550 +/- 100 ppt were present in much of the troposphere studied. Correlations between atmospheric mixing ratios of acetone and select species such as C2H2, CO, C3H8, C2Cl4 and isoprene provided important clues to its possible sources and to the causes of its atmospheric variability. Biomass burning as a source of acetone has been identified for the first time. By using atmospheric data and three-dimensional photochemical models, a global acetone source of 40-60 Tg (= 10(exp 12) g)/yr is estimated to be present. Secondary formation from the atmospheric oxidation of precursor hydrocarbons (principally propane, isobutane, and isobutene) provides the single largest source (51%). The remainder is attributable to biomass burning (26%), direct biogenic emissions (21%), and primary anthropogenic emissions (3%). Atmospheric removal of acetone is estimated to be due to photolysis (64%), reaction with OH radicals (24%), and deposition (12%). Model calculations also suggest that acetone photolysis contributed significantly to PAN formation (100-200 ppt) in the middle and upper troposphere of the sampled region and may be important globally. While the source-sink equation appears to be roughly balanced, much more atmospheric and source data, especially from the southern hemisphere, are needed to reliably quantify the atmospheric budget of acetone.

Singh, H. B.↗

Stability of the Martian atmosphere: Is heterogeneous catalysis essential?

A comprehensive homogeneous gas phase photochemical model is developed to study the problem of stability of the Martian atmosphere. The one-dimensional model extends from the ground up to 220 km, passing through the homopause at 125 km. The model thus couples the lower (neutral) atmosphere to the ionosphere above which provides significant downward flux of carbon monoxide and oxygen atoms. It is concluded on the basic of currently accepted values for globally and seasonally averaged water vapor abundance, dust opacity and the middle atmospheric eddy mixing coefficient, as well as the relevant laboratory data (particularly the temperature dependence of CO2 absorption cross section and the rate constant for CO+OH reaction), that the rate of re-formation of carbon dioxide exceeds its photolytic destruction rate by about 40%. Furthermore, it is found that this result is virtually independent of the choice of eddy mixing coefficient, unless its value in the middle atmosphere exceeds 10(exp 8) sq cm/sec or is far smaller than 10(exp 5)sq cm/sec, or the dust opacity, unless it exceeds unity, or the water vapor mixing ratio at the surface, unless it is far smaller (less than or = 1 ppm) or far greater (greater than or = 500 ppm) than the average value (approximately 150 ppm). Since none of these extremes represent globally and seasonally averaged conditions on Mars, we propose that the present model requires existence of a mechanism to throttle down the recycling rate of carbon dioxide on Mars. Therefore, it is suggested that a heterogeneous process which provides a sink to the species that participate in the recycling of CO2, i.e., H2O, H2O2, OH, CO or O, in particular, may be necessary to bring about the balance between the CO2 recycling rate and its photolytic destruction rate. Aerosols of dust or ice (pure or doped water or carbon dioxide ice present in the atmosphere of Mars) can provide the appropriate adsorption sites for the above heterogeneous process. Despite our conclusion that some heterogeneous process may be needed, it is important to recognize that one-dimensional models can only provide first-order results which, most likely, represent globally and seasonally averaged conditions. However, it is only after actual temporal, latitudinal and longitudinal variations of relevant atmospheric parameters are included in the model that one can determine fuly whether the problem of atmospheric stabiltiy still continues to persist and whether some heterogeneous process is required to correct it.

Atreya, Sushil K.↗

Validation of a New Procedure for Impedance Eduction in Flow

A new impedance eduction procedure is validated by comparing the educed impedance spectrum to that of an older but well-tested eduction procedure. The older procedure requires the installation of a microphone array in the liner test section but the new procedure removes this requirement. A 12.7-mm stainless steel plate and a conventional liner consisting of a perforated plate bonded to a honeycomb core are tested. Test data is acquired from a grazing flow, impedance tube facility for a range of source frequencies and mean flow Mach numbers for which only plane waves are cut on. For the stainless steel plate, the educed admittance spectrum using the new procedure shows an improvement over that of the old procedure. This improvement shows up primarily in the educed conductance spectrum. Both eduction procedures show discrepancies in educed admittance in the mid-frequency range. Indications are that this discrepancy is triggered by an inconsistency between the measured eduction data (that contains boundary layer effects) and the two eduction models (for which the boundary layer is neglected). For the conventional liner, both eduction procedures are in very good agreement with each other. Small discrepancies occur for one or two frequencies in the mid-frequency range and for frequencies beyond the cut on frequency of higher-order duct modes. This discrepancy in the midfrequency range occurs because an automated optimizer is used to educe the impedance and the objective function used by the optimizer is extremely flat and therefore sensitive to initial starting values. The discrepancies at frequencies beyond the cut on frequency of higher order duct modes are due to the assumption of only plane waves in the impedance eduction model, although higher order modes are propagating in the impedance tube facility.

Watson, W. R.↗

Aerosol Meteorology of the Maritime Continent for the 2012 7SEAS Southwest Monsoon Intensive Study - Part 1: Regional-scale Phenomena

The largest 7 Southeast Asian Studies (7SEAS) operation period within the Maritime Continent (MC) occurred in the August-September 2012 biomass burning season. Included was an enhanced deployment of Aerosol Robotic Network (AERONET) sun photometers, multiple lidars, and field measurements to observe transported smoke and pollution as it left the MC and entered the southwest monsoon trough. Here we describe the nature of the overall 2012 southwest monsoon (SWM) and biomass burning season to give context to the 2012 deployment. The MC in 2012 was in a slightly warm El Nino Southern Oscillation (ENSO) phase and with spatially typical burning activity. However, overall fire counts for 2012 were 10 lower than the Reid et al. (2012) baseline, with regions of significant departures from this norm, ranging from southern Sumatra (+30) to southern Kalimantan (42). Fire activity and monsoonal flows for the dominant burning regions were modulated by a series of intraseasonal oscillation events (e.g., Madden-Julian Oscillation, or MJO, and boreal summer intraseasonal oscillation, or BSISO). As is typical, fire activity systematically progressed eastward over time, starting with central Sumatran fire activity in June related to a moderately strong MJO event which brought drier air from the Indian Ocean aloft and enhanced monsoonal flow. Further burning in Sumatra and Kalimantan Borneo occurred in a series of significant events from early August to a peak in the first week of October, ending when the monsoon started to migrate back to its wintertime northeastern flow conditions in mid-October. Significant monsoonal enhancements and flow reversals collinear with tropical cyclone (TC) activity and easterly waves were also observed. Islands of the eastern MC, including Sulawesi, Java, and Timor, showed less sensitivity to monsoonal variation, with slowly increasing fire activity that also peaked in early October but lingered into November. Interestingly, even though fire counts were middling, resultant AERONET 500nm aerosol optical thickness (AOT) from fire activity was high, with maximums of 3.6 and 5.6 in the Sumatra and Kalimantan source regions at the end of the burning season and an average of approximately 1. AOTs could also be high at receptor sites, with a mean and maximum of 0.57 and 1.24 in Singapore and 0.61 and 0.8 in Kuching Sarawak. Ultimately, outside of the extreme 2015 El Nino event, average AERONET AOT values were higher than any other time since sites were established. Thus, while satellite fire data, models, and AERONET all qualitatively agree on the nature of smoke production and transport, the MC's complex environment resulted in clear differences in quantitative interpretation of these datasets.

Reid, Jeffrey S.↗

Evaluation of Near-Surface Air Temperature from Reanalysis over the United States and Ukraine: Application to Winter Wheat Yield Forecasting

In this work we evaluate the near-surface air temperature datasets from the ERA-Interim, JRA55, MERRA2, NCEP1, and NCEP2 reanalysis projects. Reanalysis data were first compared to observations from weather stations located on wheat areas of the United States and Ukraine, and then evaluated in the context of a winter wheat yield forecast model. Results from the comparison with weather station data showed that all datasets performed well (r2>0.95) and that more modern reanalysis such as ERAI had lower errors (RMSD ~ 0.9) than the older, lower resolution datasets like NCEP1 (RMSD ~ 2.4). We also analyze the impact of using surface air temperature data from different reanalysis products on the estimations made by a winter wheat yield forecast model. The forecast model uses information of the accumulated Growing Degree Day (GDD) during the growing season to estimate the peak NDVI signal. When the temperature data from the different reanalysis projects were used in the yield model to compute the accumulated GDD and forecast the winter wheat yield, the results showed smaller variations between obtained values, with differences in yield forecast error of around 2% in the most extreme case. These results suggest that the impact of temperature discrepancies between datasets in the yield forecast model get diminished as the values are accumulated through the growing season.

GSOD↗

Non-Classical Stress Concentration Behavior in a Radically Stretched Hyperelastic Sheet Containing a Circular Hole

Non-classical stress concentration behavior in a stretched circular hyperelastic sheet (outer radius b = 10 in., thickness t = 0.0625 in.) containing a central hole (radius a = 0.5 in.) was analyzed. The hyperelastic sheet was subjected to different levels of remote radial stretchings. Nastran large-strain large-deformation analysis and the Blatz-Ko large deformation theory were used to calculate the equal-biaxial stress concentration factors K. The results show that the values of K calculated from the Blatz-Ko theory and Nastran are extremely close. Unlike the classical linear elasticity theory, which gives the constant K = 2 for the equal-biaxial stress field, the hyperelastic K values were found to increase with increased stretching and can exceed the value K = 6 at a remote radial extension ratio of 2.35. The present K-values compare fairly well with the K-values obtained by previous works. The effect of the hole-size on K-values was investigated. The values of K start to decrease from a hole radius a = 0.125 in. down to K = 1 (no stress concentration) as a shrinks to a = 0 in. (no hole). Also, the newly introduced stretch and strain magnification factors {K(sub λ),K(sub ε) } are also material- and deformation-dependent, and can increase from linear levels of {1.0, 4.0} and reaching {3.07, 4.61}, respectively at a remote radial extension ratio of 2.35.

stress concentration↗

Sources of Sulfate Found in Mounds and Lakes at the Lewis Cliffs Ice Tongue, Transantarctic

Massive but highly localized Na-sulfate mounds (mirabilite, Na2SO4.10H2O) have been found at the terminal moraine of the Lewis Cliffs Ice Tongue (LCIT), Antarctica. (Sigma)34S and (Sigma)18O values of LCIT mirabilite range from +48.8 to +49.3% (CDT), and -16.6 to -17.1% (V-SMOW), respectively, while (Delta)17O average -0.37% (V-SMOW). LCIT mirabilite mounds are isotopically different from other mirabilite mounds found in coastal regions of Antarctica, which have isotope values close to seawater compositions. (Sigma)18O and (Delta)17O values suggest the incorporation of isotopically light glacial water. Data point to initial sulfate formation in an anoxic water body, either as a stratified anoxic deep lake on the surface, a sub-glacial water reservoir, or a sub-glacial lake. Several surface lakes of varying size are also present within this region of the LCIT, and in some cases are adjacent to the mirabilite mounds. O and D isotope compositions of surface lakes confirm they are derived from a mixture of glacial ice and snow that underwent moderate evaporation. (Sigma)18O and (Sigma)D (V-SMOW) values of snow, ice, and lake water range from -64.2 to -29.7%, and -456.0 to -231.7%, respectively. However, the isotope chemistry of these surface lakes is extremely different from the mounds. Dissolved SO4-2 (Sigma)34S and (Sigma)18O values range from +12.0 to +20.0% and -12.8 to -22.2% (the most negative (Sigma)18O of terrestrial sulfate ever reported), respectively, with sulfate (Delta)17O ranging from +0.93 to 2.24%. Ion chromatography data show that lake water is fresh to brackish in origin, with TDS less than 1500 ppm, and sulfate concentration less than 431 ppm. Isotope and chemical data suggest that these lakes are unlikely the source of the mirabilite mounds. We suggest that lake water sulfate is potentially composed of a mixture of atmospheric sulfate and minor components of sulfate of weathering origin, much like the sulfate in the polar plateau soils of the McMurdo Dry Valleys. A simple model explains mirabilite mound formation at the LCIT. Sulfur redox processes could occur sub-glacially as a result of liquid-water-based glacial conditions (Alpine style glacier), most likely formed by pressure melting of overlying ice (Aharon, GCA, 52, 2321-2331). We suggest that the aqueous base of the LCIT contains dissolved SO42- and is anoxic where sulfate reduction to H2S, HS-, or native sulfur takes place. Sulfide is removed by either precipitation as sulfide minerals or by escape of H2S (neither of which have been observed). Mirabilite precipitation is likely the result of evaporation or freezing of sulfate-rich brines as they reach the surface where they manifest themselves as mounds. Pressure from the overlying ice contributing to a pressure-melting scenario that creates the sub-glacial aqueous environment also contributes to the mechanism of upward transport of the sulfate-rich fluids. Further evidence to support this upward transport model comes from the nature of ice motion at the LCIT. Cassidy et al (Meteoritics, 27, 490-525, 1992) pointed out that it is the vertical ice motion in this area that creates the meteorite-stranding surface that could also account for upward transport of sulfate-rich fluids. Alternatively, mirabilite was deposited in a similar condition as present-day coastal Antarctica when the LCIT was wetter and warmer

Socki, Richard↗

Association of Presolar Grains with Molecular Cloud Material in IDPs

Anhydrous interplanetary dust particles (IDPs) collected in the stratosphere appear chemically, mineralogically, and texturally primitive in comparison to meteorites. Particles that escape significant atmospheric entry heating have highly unequilibrated mineralogy, are volatile element rich, and, overall, appear to have escaped significant parent body hydrothermal alteration. These IDPs are comprised of the building blocks of the solar system. The strongest evidence that anhydrous IDPs are primitive is that they contain abundant stardust and molecular cloud material. In particular, presolar silicates were first identified in IDPs and are present in abundances (450-5,500 ppm) that are well above that observed in primitive meteorites (less than 170 ppm). The most fragile (cluster) IDPs also commonly exhibit large H and N isotopic anomalies that likely originated by isotopic fractionation during extremely low temperature chemical reactions in a presolar cold molecular cloud. The D/H ratios exceed that of most primitive meteorites, and in rare cases reach values directly observed from simple gas phase molecules in cold molecular clouds. The most extreme D- and N-15-enrichments are usually observed at the finest spatial scales (0.5-2 microns) that can be measured. These observations suggest that D and N-15 hotspots are in fact preserved nuggets of molecular cloud material, and that the materials within them also have presolar origins. The advanced capabilities of the NanoSIMS ion microprobe now enable us to test this hypothesis. Here, we report two recent examples of presolar silicates found to be directly associated with molecular cloud material.

Messenger, S.↗

Investigation of use of space data in watershed hydrology

The author has identified the following significant results. Ground truth data have been compiled and 256 rainfall runoff events have been used to detemine coefficients for two storm runoff equations that apply to the 20 study watersheds. Two scenes have been processed using CCT data. Data pertinent to each of the study watersheds have been excerpted from the tapes. A computer program and display technique has been developed to retrieve the data from irregular shaped areas and store it in a format that allows future display of only the area desired. Means, standard deviations, and distributions have been determined for extreme dry and extreme wet conditions in the dormant season. Mean digital values show some variation between watersheds when dry, but no significant differences when wet. Standard deviations of digital values diminish drastically under wet dormant conditions. Thus the standard deviations may be a good indicator of influence of moisture. Distributions of seven bit values show that odd numbers are prevalent and irregular distribution may influence some classification schemes now in use.

Blanchard, B.↗

Non-numeric computation for high eccentricity orbits

Geocentric orbits of large eccentricity (e = 0.9 to 0.95) are significantly perturbed in cislunar space by the sun and moon. The time-history of the height of perigee, subsequent to launch, is particularly critical. The determination of 'launch windows' is mostly concerned with preventing the height of perigee from falling below its low initial value before the mission lifetime has elapsed. Between the extremes of high accuracy digital integration of the equations of motion and of using an approximate, but very fast, stability criteria method, this paper is concerned with the developement of a method of intermediate complexity using non-numeric computation. The computer is used as the theory generator to generalize Lidov's theory using six osculating elements. Symbolic integration is completely automatized and the output is a set of condensed formulae well suited for repeated applications in launch window analysis. Examples of applications are given.

Sridharan, R.↗

DSS 43 antenna gain analysis for Voyager Uranus encounter: 8.45-GHz radio science data correction

A malfunction of the Deep Space Network (DSN) 64-meter antenna in Australia forced the antenna to operate with a mispositioned subreflector during the Voyager Uranus encounter period (January 24, 1986). Because of changing main reflector shape and quadripod position as a function of elevation angle, the antenna gain and pointing were not as expected, and the 8.45 GHz received signal level changed during the pass. The study described here used the Geometrical Theory of Diffraction (GTD) analysis to determine actual antenna gain and pointing during that period in an attempt to reconstruct the radio science data. It is found that the 1.4 dB of signal variation can be accounted for by antenna geometry changes and pointing error. Suggested modifications to the values measured during the pass are presented. Additionally, an extremely useful tool for the analysis of gravity deformed reflectors was developed for use in future antenna design and analysis projects.

Slobin, S. D.↗

A comprehensive comparison between skin and multi-channel sea surface temperatures as derived from AVHRR

Global maps of Satellite Measured Surface Skin Temperature (SMSST), MultiChannel Sea Surface Temperature (MCSST) and Cross Product Sea Surface Temperature (CPSSR) are computed from imagery of the Advanced Very High Resolution Radiometer (AVHRR) for five fortnights in 1984/85. They demonstrate systematic latitudinal variations and regional extremes of the differences with greatest root mean square values of 0.7K between MCSST and SMSST found at low latitudes. Mean differences range from 0.1K between CPSST and SMSST to 0.45K between MCSST and SMSST. A part of the differences might be attributed to the skin cooling at the sea surface. A parameterization of the bulk skin temperature difference is derived from in situ field measurements. This can be used to find a relation between satellite measured bulk and skin temperatures.

Schluessel, Peter↗

Carbon cycling in high-latitude ecosystems

The carbon-rich soils and peatlands of high-latitude ecosystems could substantially influence atmospheric concentrations of CO2 and CH4 in a changing climate. Currently, cold, often waterlogged conditions retard decomposition, and release of carbon back to the atmosphere may be further slowed by physical protection of organic matter in permafrost. As a result, many northern ecosystems accumulate carbon over time (Billings et al., 1982; Poole and Miller, 1982), and although such rates of accumulation are low, thousands of years of development have left Arctic ecosystems with an extremely high soil carbon content; Schlesinger's (1984) average value of 20.4 kg C/m(sup 2) leads to a global estimate of 163 x 10(exp 15) g C. All GCM simulations of a doubled CO2 climate predict the greatest warming to occur in the polar regions (Dickinson, 1986; Mitchell, 1989). Given the extensive northern carbon pools and the strong sensitivity of decomposition processes to temperature, even a slight warming of the soil could dramatically alter the carbon balance of Arctic ecosystems. If warming accelerates rates of decomposition more than rates of primary production, a sizeable additional accumulation of CO2 in the atmosphere could occur. Furthermore, CH4 produced in anaerobic soils and peatlands of the Arctic already composes a good percentage of the global efflux (Cicerone and Oremlund, 1988); if northern soils become warmer and wetter as a whole, CH4 emissions could dramatically rise. A robust understanding of the primary controls of carbon fluxes in Arctic ecosystems is critical. As a framework for a systematic examination of these controls, we discussed a conceptual model of regional-scale Arctic carbon turnover, including CH4 production, and based upon the Century soil organic matter model.

Townsend, Alan↗

Role of the Hudson Bay lowland as a source of atmospheric methane

Based on point measurements of methane flux from wetlands in the boreal and subarctic regions, northern wetlands are a major source of atmospheric methane. However, measurements have not been carried out in large continuous peatlands such as the Hudson Bay Lowland (HBL) (320,000 sq km) and the Western Siberian lowland (540,000 sq km), which together account for over 30% of the wetlands north of 40 deg N. To determine the role the Hudson Bay Lowland as a source of atmospheric methane, fluxes were measured by enclosures throughout the 1990 snow-free period in all the major wetland types and also by an aircraft in July. Two detailed survey areas were investigated: one (approximately 900 sq km) was in the high subarctic region of the northern lowland and the second area (approximately 4,800 sq km) straddled the Low Subarctic and High Boreal regions of the southern lowland. The fluxes were integrated over the study period to produce annual methane emissions for each wetland type. The fluxes were then weighted by the area of 16 different habitats for the southern area and 5 habitats for the northern area, as determined from Landsat thematic mapper to yield an annual habitat-weighted emission. On a per unit area basis, 1.31 +/- 0.11 and 2.79 +/- 0.39 g CH4 m(exp -2)/yr were emitted from the southern and northern survey areas, respectively. The extrapolated enclosure estimates for a 3-week period in July were compared to within 10% of the flux derived by airborne eddy correlation measurements made during the same period. The aircraft mean flux of 10 +/- 9 mg CH4 m(exp -2)/d was not statistically different from the extrapolated mean flux of 20 +/- 16 mg CH4 m(exp -2)/d. The annual habitat-weighted emission for the entire HBL using six wetland classes is estimated as 0.538 +/- 0.187 Tg CH4/yr (range of extreme cases is 0.057 to 2.112 Tg CH4/yr). This value is much lower than expected, based on previous emission estimates from northern wetlands.

Roulet, Nigel T.↗

Flow Visualization of Low Prandtl Number Fluids using Electrochemical Measurements

It is well established that residual flows exist in contained liquid metal processes. In 1-g processing, buoyancy forces often drive these flows and their magnitudes can be substantial. It is also known that residual flows can exist during microgravity processing, and although greatly reduced in magnitude, they can influence the properties of the processed materials. Unfortunately, there are very few techniques to visualize flows in opaque, high temperature liquid metals, and those available are not easily adapted to flight investigation. In this study, a novel technique is developed that uses liquid tin as the model fluid and solid-state electrochemical cells constructed from Yttria-Stabilized Zirconia (YSZ) to establish and measure dissolved oxygen boundary conditions. The melt serves as a common electrode for each of the electrochemical cells in this design, while independent reference electrodes are maintained at the outside surfaces of the electrolyte. By constructing isolated electrochemical cells at various locations along the container walls, oxygen is introduced or extracted by imposing a known electrical potential or passing a given current between the melt and the reference electrode. This programmed titration then establishes a known oxygen concentration boundary condition at the selected electrolyte-melt interface. Using the other cells, the concentration of oxygen at the electrolyte-melt interface is also monitored by measuring the open-circuit potentials developed between the melt and reference electrodes. Thus the electrochemical cells serve to both establish boundary conditions for the passive tracer and sense its path. Rayleigh-Benard convection was used to validate the electrochemical approach to flow visualization. Thus, a numerical characterization of the second critical Rayleigh numbers in liquid tin was conducted for a variety of Cartesian aspect ratios. The extremely low Prandtl number of tin represents the lowest value studied numerically. Additionally, flow field oscillations are visualized and the effect of tilt on convecting systems is quantified. Experimental studies of the effect of convection in liquid tin are presented. Three geometries are studied: (1) double electrochemical cell with vertical concentration gradients; (2) double cell with horizontal concentration gradients; and (3) multiple cells with vertical temperature gradients. The first critical Rayleigh number transition is detected with geometry (1) and it is concluded that current measurements are not as affected by convection as EMF measurements. The system is compared with numerical simulations in geometry (2), and oscillating convection is detected with geometry (3).

Crunkleton, D.↗