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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Global Electrification of Vehicles and Intertwined Material Supply Chains of Cobalt, Copper and Nickel

Electric vehicles (EVs) will be an important part of a low-carbon economy. Future EV adoption depends on overcoming multiple barriers, including charging infrastructure, sufficient electricity generation, and the availability of battery raw materials at acceptable costs, including cobalt, copper and nickel – which typically are co-produced. Various EV projections have been made, along with associated requirements for battery raw materials (demand). There have been separate assessments of the availability of raw materials (supply). However, integrated assessments of supply and demand and their interaction over time are lacking to support decision-making. Using a dynamic market model that reflects the co-produced nature of cobalt, copper and nickel production as well as recycling, we estimate global output of these three metals under different EV growth scenarios from 2020 to 2040. In this work, results suggest that starting in 2025, replacement demand for battery raw materials becomes important. Thus, estimates for future material demand that consider only demands from new EVs are incomplete and misleading. EV deployment and associated increased demand for raw materials will have a greater impact on prices for cobalt than nickel and, in turn, for nickel than copper. High EV deployment scenarios will be difficult to achieve without larger supplies of copper, nickel and cobalt than forthcoming under the conditions modeled here, which anticipates a six-year time lag between a demand increase and the expansion of metal-production capacity. Shortening battery lifetimes and improving collection and recycling rates increase secondary supply, but the extent to which these factors support additional EV deployment is mixed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Fortalecimiento de la Electrificación Rural en Honduras: Una Evaluación Integrada de PV+BESS y Usos Productivos de la Electricidad en Gracias a Dios, Honduras [Empowering Rural Electrification in Honduras: An Integrated Assessment of PV/BESS and Productive Uses of Electricity in Gracias a Dios] (Spanish Translation)

Honduras faces significant challenges in its energy sector, particularly in rural areas where access to reliable and affordable electricity remains limited. The flagship rural electrification initiative for Honduras Secretary of Energy (SEN) is the Politica de Acceso Universal a la Electricidad (PAUEH - Universal Electricity Access Policy), a key solution for addressing this energy poverty is the deployment of more than 1700 distributed solar and hybrid mini-grid solutions. In late 2023 as a first step towards supporting SEN's electrification efforts, the National Renewable Energy Laboratory (NREL) developed a literature review of SEN electrification policy documents and conducted a series of technical capacity-building workshops with SEN and other energy sector stakeholders in Honduras focused on using NREL's open-source REopt tool to conduct techno-economic assessments and develop least-cost optimizations for potential solar + storage mini-grid systems. Building on some initial capacity building on mini-grid modeling, the National Renewable Energy Laboratory (NREL) worked with SEN to develop a detailed techno-economic assessment for electrifying two schools, a healthcare clinic, and a hospital in a hypothetical community within the department of Gracias a Dios. The analysis also evaluates the business case for cold storage productive use of energy (PUE) applications for the fisheries value chain and how the incorporation of these PUE loads potentially impacts both the viability of the PV+BESS solutions as well as local economic development. By assessing the potential for deployment of integrated PV/BESS systems to both support critical community services like education and healthcare, as well as potential for downstream enterprise and economic development, this analysis represents a first step that can help to inform specific strategies for development of pilot PV+BESS projects aligned with national priorities and sector level planning under PAUEH. This is the Spanish translation of NREL/TP-7A40-90865.

14 SOLAR ENERGY↗
DOE OSTI2023

EVI-Pro for Bogota Columbia [Slides]

The transportation sector is one of the largest producers of greenhouse gas emissions globally, with 37% of global CO 2 emissions in 2021 according to the International Energy Agency. Transitioning from internal combustion engine vehicles powered by fossil fuels to electrified transportation is a critical component in reducing those emissions significantly over the coming decades and avoiding the worst consequences of climate change. With governments and automakers increasingly announcing electrification targets and a progression away from the production and sale of internal combustion engine vehicles, a robust network of charging infrastructure must be built to enable the widespread use of electric vehicles (EVs). Some of the greatest hurdles to EV deployment are linked to the buildout of the required charging infrastructure including where it should be built, what types and how much charging would be optimal given high costs of installation, and the impact on the electrical grid. To this end, the National Renewable Energy Laboratory (NREL) conducts extensive research on EV deployment, including the development of the EVI-Pro model used to plan the future buildout of charging infrastructure given the travel patterns in a region. This document summarizes work done by NREL in the Bogotá, Colombia region to help Colombia plan for its EV deployment goals.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Mixing-Controlled Compression Ignition Combustion with Low-Lifecycle-CO 2 Fuels

Reducing lifecycle carbon-dioxide (CO 2 ) and toxic emissions via electrification or switching to carbon-free fuels is not currently feasible for many off-road, rail, and marine applications. This is due to factors including excessive cost, weight, or size of a battery of sufficient capacity to meet the application requirements, lack of infrastructure, insufficient time for recharging, demanding duty cycles, and severe ambient conditions. The guiding vision for the activities described herein is to enable rapid, cost-effective reductions of the environmental impacts of such applications by using improved, high efficiency engine combustion strategies with currently available and emerging low lifecycle-CO 2 fuels (LLCFs). This report summarizes progress toward achieving this vision in two project areas. The first is a Technology Commercialization Fund (TCF) project focused on facilitating the commercialization of ducted fuel injection (DFI) with LLCFs. The second is a more fundamental, Advanced Combustion Engines (ACE) research project focused on elucidating a new strategy called lean mixing-controlled combustion (LMCC) for use with emerging LLCFs.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2025

Modeling the Air Quality Impacts of Future Energy Scenarios

Many greenhouse gas (GHG) emission reduction measures achieve simultaneous reductions in air pollutants. Human-Earth system models can estimate such emission changes in the energy system but using them in chemistry-transport models (CTMs) to study their air quality impacts involves resource-intensive emissions processing. This is greatly simplified by an emissions scaling approach linking state-level emissions estimated by a human-Earth system model to a CTM. A scenario continuing pre-2022 energy policy in the U.S. to 2050 shows widespread air quality improvements over the 2015 baseline from SO 2 and NO x emission reductions of 50–80% from electricity generation and light-duty vehicles. Scenarios of GHG mitigation and vehicle electrification at the state and national level add further benefits. However, PM 2.5 increases from increased use of wood heating and bioenergy suggest that additional PM 2.5 management may be needed when using biofuels. In conclusion, this approach helps assess multiple future energy scenarios efficiently without sacrificing chemical detail in the air quality simulations.

air quality↗
DOE OSTI2022

Development of a water source heat pump hardware-in-the-loop (HIL) testing facility for smart building applications

Over the last decade, the global fight against climate change through electrification has led to an increase in research on building heating, ventilation, and air conditioning (HVAC) systems that utilize intelligent control algorithms to provide demand-side grid service while maintaining the thermal comfort of building occupants. As the pivotalpoint between building electricity consumption and indoor thermal comfort, high-efficiency electrical heatpumps are at the center of these emerging studies, and various grid-interactive and occupant-comfort control algorithms have been developed for them. The impact of these algorithms on the heatpump operation andperformance under different weather, building load, and grid requests calls for investigation and verification via experimental tests with actual heat pumps integrated with real-time building and grid responses. This study presents a Water-Source Heat Pump Hardware-in-The-Loop (HIL) Test Facility developed with the capability to perform such tests. The hardware configuration for this testfacility introduces a hydronic system that emulates the conditions for the heat pump water-side, and a duct system that emulates conditions for the heat pump airside. Both data acquisition and emulator control are implemented through the National Instruments (NI) LabVIEW software running on an NI PXIplatform. The HIL mechanism based on the hardware-software integration that allows the testbed to communicate with a generic simulation environment is also discussed. Currently, the test facility setup includes a single heatpump and virtual building model in EnergyPlus coupled with an occupant behavioral model in MATLAB. Preliminary test results of the current setup demonstrate the building load emulator's ability to track the simulated gone temperature with a Root Mean Square Deviation (RSME) below 0.12°C (0.216°F). An uncertainty analysis based on sensor accuracies shows that the heat pump coefficient of performance (COP) can be measured with a relative uncertainty of 10.4% in cooling and 3.7% in heating. Apartfrom the current testing on a single heat pump, the test facility also provides the flexibility to include additional heat pumps to form a heat pump cluster, as well as coupling the heat pump with active thermal storage to provide enhanced demandflexibility.

Calfa, Caleb↗
DOE OSTI2021

10 New Insights in Climate Science 2020 - a Horizon Scan

We summarize some of the past year’s most important findings within climate change-related research. New research has improved our understanding of Earth’s sensitivity to carbon dioxide, finds that permafrost thaw could release more carbon emissions than expected and that the uptake of carbon in tropical ecosystems is weakening. Adverse impacts on human society include increasing water shortages and impacts on mental health. Options for solutions emerge from rethinking economic models, rights-based litigation, strengthened governance systems and a new social contract. The disruption caused by COVID-19 could be seized as an opportunity for positive change, directing economic stimulus towards sustainable investments.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Performance assessment of a real water source heat pump within a hardware-in-the-loop (HIL) testing environment

Over the last decade, the global fight against climate change through electrification has led to an increase in research on building heating, ventilation, and air conditioning (HVAC) systems that utilize intelligent control algorithms to provide demand-side grid service while also maintaining the thermal comfort of building occupants. As the pivotal point between building electricity consumption and indoor thermal comfort, high-efficiency electrical vapor-compression heat pumps are at the center of these emerging studies, and various grid-interactive and occupant-comfort control algorithms have been developed for them. The impact of these algorithms on heat pump operation and performance when subjected to different weather conditions, building loads, and grid requests calls for investigation and verification via experimental testing with actual heat pumps integrated with real-time building and grid responses. This study introduces a Water-Source Heat Pump (WSHP) Hardware-in-The-Loop (HIL) Test Facility that is the first of its kind. This testbed utilizes a 2-ton variable speed water-to-air heat pump that is capable of interacting with a virtual environment currently comprised of an EnergyPlus (E+) building simulation, an agent-based occupant behavioral model, and a single U-tube ground-loop heat exchanger (GLHE) model. Detailed descriptions of the testbed’s physical design and operation, virtual environment, as well as their mutual communication is provided. An uncertainty analysis is also performed under manufacturer specified heating and cooling design conditions. This analysis shows that the total load across the WSHP’s demand side heat exchanger, i.e., the sum of its latent and sensible components, can be measured with a relative uncertainty of ± 10.4% and ± 3.6% in cooling and heating mode respectively. The WSHP’s coefficient of performance (COP) can be measured with relative uncertainties of ± 10.4% in cooling mode, and ± 3.7% in heating mode. A preliminary 24-h experimental demonstration is then performed utilizing the DOE prototype small commercial office building model in E+. The simulation takes place in Atlanta, GA on the date of 08/26/15 from 12:00 AM to 11:59 PM using TMY3 weather data. Here, the results from this demonstration show that over the course of this experiment the simulated outputs of zone dry-bulb temperature, zone humidity ratio, and WSHP inlet water temperature can be tracked by testbed emulators up to a root mean squared error (RMSE) of ± 0.27 °C, ± 0.376 g/kg, and ± 0.85 °C respectively. The WSHP’s dynamic behavioral characteristics and performance are also captured, and correspond well with the authors’ previous understanding of heat pump efficiency as a function of evaporator and condenser fluid inlet conditions respectively.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Precise Motion Control of Hybrid Hydraulic Electric Architecture (HHEA)

Off-highway heavy-duty vehicles have been long-standing users of hydraulic systems for power transmission and control. However, traditional hydraulic systems suffer from significant energy losses which lead to increased operating costs and a larger carbon footprint due to higher CO2 emissions. Improving the efficiency of these mobile machines is crucial not only for reducing their environmental impact but also for saving billions of dollars in operating costs. Currently, the state-of-the-art Load Sensing Architecture uses throttling valves for control, which significantly reduces its efficiency and does not recuperate energy from over-running loads. Researchers have developed several architectures such as Common Pressure Rail systems, Displacement Control, STEAM, and Electrohydraulic Architecture to improve the efficiency of off-road mobile machines. However, each of these architectures has its drawbacks. To increase system efficiency and take advantage of electrification benefits, our research group has developed a novel Hybrid Hydraulic-Electric Architecture (HHEA). The HHEA can significantly improve efficiency, decrease the size of electrical components, and maintain control performance. This new architecture has the potential to revolutionize the off-highway mobile machine industry and lead to a more sustainable future. The HHEA uses a set of common pressure rails to provide the majority of power to the actuators via power-dense hydraulics and uses electric motors for precise control and power modulation. In the context of off-road mobile machines, energy savings are undoubtedly important but it is equally important to consider the machines’ ability to perform tasks with precision and accuracy according to given commands. Therefore, precise motion control is of utmost importance to maintain the utility of Hybrid Hydraulic-Electric Architecture (HHEA). The HHEA presents a unique challenge to motion control due to the discrete pressure changes that occur when the system switches between selected pressure rails. These changes are made to minimize system inefficiencies or to keep the system within the torque capability of the electric motor. Hence, it is important to solve the motion control challenges for HHEA. This thesis aims at developing an effective motion control strategy for HHEA. The dissertation presents a two-tiered control strategy for HHEA, comprising a high-level and a low-level controller. The primary responsibility of the high- level controller is to optimize energy efficiency by making informed pressure rail selections. On the other hand, the low-level controller is focused on achieving precise motion control of the HHEA, which is crucial for realizing the desired reference trajectories. To achieve this, the low-level controller utilizes a passivity-based backstepping integral controller as the nominal control, which handles the motion control between two pressure rail switches. Additionally, a separate least norm controller is utilized as a transition controller to manage motion control during pressure rail transitions. The effectiveness of the combined control strategy is demonstrated through experiments conducted on two hardware-in-the-loop testbeds. Furthermore, the HHEA is installed on the boom and stick actuators of a backhoe arm to build a Human-in-the-Loop system that a human operator can control. A real-time rail switching algorithm is developed to determine pressure rail switching based on present duty cycle information from the operator. Modifications have been made to the human-machine interface to achieve more intuitive control. Modifications include performing control in the task-oriented coordinates, incorporating pressure feedback to enhance control with physical interaction, and using velocity field control to simplify multi-degree-of-freedom tasks and to enable novice operators to perform them with reduced risk, improved efficiency, and productivity. The research in this dissertation makes significant contributions to the field of off-road mobile machine control, providing a novel and effective control strategy for the HHEA, and demonstrating the potential for simplified machine operation.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2025

Policy implications of net-zero emissions: A multi-model analysis of United States emissions and energy system impacts

Many countries, subnational jurisdictions, and companies are setting net-zero emissions goals; however, questions remain about strategies to reach these targets, policy measures, technology gaps, and economic impacts. Here, we investigate the potential policy implications of reaching economy-wide net-zero CO 2 emissions across the United States by 2050 using results from a multi-model comparison with 14 energy-economic models. Model results suggest that achieving net-zero CO 2 targets depends on policies that accelerate deployment of zero- and low-emitting technologies that have seen rapid cost reductions in recent years (including wind, solar, battery storage, and electric vehicles) as well as relatively nascent options (including carbon capture and storage, advanced biofuels, low-carbon hydrogen, advanced nuclear, and long-duration energy storage). While net-zero policies are likely to lower fossil fuel consumption, including considerable coal and petroleum reductions, achieving net-zero emissions does not necessarily mean phasing out all fossil fuels. Model results indicate that the Inflation Reduction Act’s energy and climate provisions amplify near-term decarbonization but that net-zero policies have larger impacts on long-run outcomes. Stringent climate policy can have large fiscal impacts on tax revenue and government spending—revenues from carbon pricing and subsidies for carbon removal range from 0.1 % to 3.7 % of GDP in 2050 across models. Each dollar per metric ton carbon price leads to a 0.06 % to 0.31 % reduction in economy-wide CO 2 emissions relative to a reference scenario with current policies. Spending on energy across the economy decreases relative to today for many models under reference and net-zero policies, especially as a share of GDP, due primarily to end-use electrification and energy efficiency.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

A Methodology for Defining Affordability in Commercial Buildings and its Impact on Underserved Communities

Commercial buildings are at the heart of any community. Investments towards the health and performance of community buildings can support a wide range of critical community and individual benefits; however, many buildings have been left behind in these investments due to a spectrum of barriers, especially those located in underserved communities. This portfolio of work stands with the intent that if we can create solutions to support the hardest-to-reach commercial buildings in gaining equitable access to energy efficiency, zero energy, and zero carbon solutions, we can support all commercial buildings with these goals. To understand success and barriers, and identify new, innovative, and impactful solutions, NREL is taking a four-part approach to: 1. Develop a methodology for defining affordability in commercial buildings and understand its impact on underserved communities, 2. Work with trusted, local organizations to address barriers that impede access to cost-effective, holistic, building performance improvements, 3. Support minority-focused developer incubator programs for, and within, underserved communities, and 4. Identify overlapping value streams that support underserved community and utility needs.

building electrification↗
DOE OSTI2022

Eaton High Impact Project (Cooperative Research and Development Final Report)

The NREL team will partner with Eaton to evaluate control strategies for managing Electric bus (E-bus) fleets for grid services. NREL will develop a replicable platform for evaluating EV fleet management and quantifying benefits from grid services. The proposal will cover the technology areas of solar, energy storage, mobility, and buildings.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2021

Integrated U.S. nationwide corridor charging infrastructure planning for mass electrification of inter-city trips

This study introduces an integrated modeling framework to evaluate long-term national corridor charging infrastructure requirements in the United States to support the growing inter-city charging demand with the rapid growth in the battery electric vehicle (BEV) market. The core model is an optimization model that considers spatial and temporal dimensions and models heterogeneous behaviors between travelers. The model also introduces the travelers’ inconvenience cost function by linking travelers’ acceptance of the charging infrastructure with exogenous technology and social factors. The inconvenience cost function simulates mode choice between BEVs and alternative modes by heterogenous travelers. We applied the framework to assess the inter-regional charging infrastructure requirements for the entire U.S. mainland interstate highway network. We evaluated impacts on the infrastructure design and its public acceptance with changes in policy, technology, and demographic characteristics, and we also quantified the importance of modeling full-scale inter-regional charging infrastructure requirements compared to the conventional regional level analyses.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Identifying Regions Favorable for Geothermal Heating and Cooling Storage

Space heating and cooling represents the single largest category of in building energy use for U.S. residential and commercial buildings, with heating representing 61% of residential and 46% commercial energy consumption. Building heating technologies are dominated by natural gas technologies, and are an important opportunity for building electrification to enable a transition to a low CO 2 energy system. FLXenabler study is a joint analysis effort among multiple analysis teams at NREL and focused on examining the role of geothermal heating and cooling (GHC) system with thermal energy storage (TES) providing flexibility. Utilizing information from ResStock the amount of energy consumption associated with heating and cooling by state was calculated. We applied adjusted load shapes to estimate the a maximum grid savings potential of using TES to address building space conditioning. Normalizing grid, fuel, and emissions impacts locations with higher favorability for further study in FLXenabler were identified.

15 GEOTHERMAL ENERGY↗
DOE OSTI2026

California Price Response Potential Study

California's energy landscape is undergoing a significant transformation, driven by the increasing integration of renewable energy sources, the increased adoption of distributed energy resources, the electrification of end-use loads, and the growing need for grid efficiency. To address these challenges, recent revisions to the State’s Load Management Standards (LMS) require all of California’s large utilities and community choice aggregators (CCAs) to offer dynamic electricity pricing options to customers by 2027. Dynamic pricing, which involves varying electricity rates based on real-time supply and demand conditions, offers a promising solution for optimizing grid operations, reducing costs, and incentivizing efficient use of grid capacity. Effective implementation of dynamic pricing requires understanding the potential impacts on customer bills, system load, and the cost-effectiveness of automation technologies. This study aims to evaluate the load response of various end-use devices to hourly dynamic prices. The end-uses studied here are space cooling, space heating, water heating, crop irrigation, pool and spa pumps, and electric vehicle (EV) charging, all for both residential and commercial applications, except for crop irrigation. In 2030, these end uses are forecasted to account for 18% of annual electricity demand in the state, but 40% of demand in the peak net load hour. By modeling possible price-responsive load dispatch algorithms and assessing the resulting impacts on both individual bills and the overall grid, we seek to inform policymakers and utilities about the potential benefits and challenges associated with dynamic pricing, and considerations for the design of dynamic pricing tariffs. Additionally, we will explore the cost effectiveness of adopting automation technologies to enable devices to respond more effectively to real-time price signals. This study considers a range of price profiles, accounting for differences across utilities and customer classes, and presents scenarios for dynamic price design via variation in the percentage of total customer electric costs that are allocated dynamically (versus constituting a fixed portion of the hourly volumetric price). We present results focused primarily on 2030, forecasting electricity prices under both low and high-cost scenarios, to inform longer-term tariff design considerations. We design tariffs by starting with 2019 prices that were calculated according to CalFUSE guidance (CPUC, 2022) and that have been used in recent studies; these prices are all-in volumetric rates that vary by utility and are revenue-neutral to each customer class. They are developed by considering six electricity cost components that are allocated hourly based on system load indicators (gross and net load, and wholesale prices). These prices are forecasted to 2030 for low and high cost scenarios, considering recent trends in total electricity costs with and without years of substantial wildfire mitigation investments. These tariffs, which allocate all costs on an hourly basis, are considered our “Full” dynamic tariff design scenario, while two additional scenarios explore allocating a portion of costs as a flat volumetric charge: the “Medium” scenario allocates 50% of revenue dynamically (and keeps 50% flat), while the “Mild” scenario allocates 20% of revenue dynamically. The 20% dynamic allocation on the Mild scenario aims to represent a case where only the marginal operating costs of the grid are included in the dynamic price.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

A Review on Simulation Platforms for Agent-Based Modeling in Electrified Transportation

As the use of combustion engine vehicles plays a deciding role in global warming, we can observe a trend to replace them with electric vehicles (EV) driven by new environmentally conscious policies and increasing technological capabilities. With improvements in driving range and reduction in prices come new challenges that may hamper the progress towards complete battery driven transportation. A major challenge for the increasing EV adoption is the planning of extensions to existing infrastructure or the inclusion of new infrastructure components in the planning process. This demands increasingly complex planning tools that can simulate the interplay between different stakeholders in modern transportation scenarios such as EVs, charging stations, energy providers, and general transportation participants. Simulation platforms for agent-based modeling in transportation have been developed as effective interactive tools that allow planners to explore different trade-offs across different scenarios with the ability to simulate the impact of policy or infrastructure decisions on the different stakeholders in the simulation. This article surveys several of the major simulation platforms that include modern EV-based forms of transportation and allow the simulation of relevant infrastructure components alongside the well established transportation simulations. These tools allow researchers to analyze expected traffic flow, identify possible charging station locations based on area demand, predict electrical grid demand, and more. Here this survey intends to make it easier for researchers to identify and apply a simulation platform in the context of supporting the increasing electrification of the transportation sector, enabling more efficient simulation and planning capabilities in this domain.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Understanding of Low‐Porosity Sulfur Electrode for High‐Energy Lithium–Sulfur Batteries

Abstract The lithium–sulfur (Li–S) battery is a promising technology for large‐scale energy storage and vehicle electrification due to its high theoretical energy density and low cost. Reducing the sulfur cathode porosity has been identified recently as a viable strategy for improving the cell practical energy density and minimizing pore‐filling electrolytes to extend cell life at lean electrolyte conditions. Direct use of a low‐porosity cathode for Li–S battery results in poor electrode wetting, nonuniform electrode reactions, and thus early cell failure. To understand and mitigate the barriers associated with the use of low‐porosity electrodes, multiscale modeling is performed to predict electrode wetting, electrolyte diffusion, and their impacts on sulfur reactions in Li–S cells by explicitly considering the electrode wettability impacts and electrode morphologies. The study elucidates the critical impact of low tortuosity and large channel pore design for promoting electrode wetting and species diffusion. It is suggested that the secondary particle size should be comparable with the electrode thickness to effectively promote electrolyte wettability and sulfur reactivity. This study provides new insights into the low‐porosity electrode material and designs and is expected to accelerate the development of practical high‐energy Li–S batteries.

25 ENERGY STORAGE↗
DOE OSTI2023

Gas-Phase Composition as a Predictive Metric for Calendar Life Behavior of Next-Generation Silicon Anodes

The expansion of renewable technologies and electrification of the transportation sector is driving increased demand for next-generation battery materials that provide higher power and energy density with superior cycling and calendar life stability. Silicon (Si) has a theoretical capacity nearly 10x that of graphite, and is therefore a promising anode material candidate to meet these rigorous performance demands. While leading Si anode battery demonstrations are approaching target metrics for cycle life, a series of complex and interrelated modes of reactivity lead to reduced calendar life and therefore challenge practical adoption of these materials. Deconvoluting the degradation processes that impact Si calendar life is critical to informing the rational and accelerated design of improved Si materials. In the present work, we employ novel sampling techniques and GC-MS-FID characterization to measure gas-phase composition during initial Si cycling, which we tie to selective mechanisms of Si passivation. We utilize a tiered analysis approach to identify and quantify the gas-phase reaction products associated with three advanced Si material candidates under practical operating conditions. Ex situ analysis of Si powders (pure chemical reactivity) is coupled with nondestructive in situ sampling of Si electrodes in a practical pouch-cell format (coupled chemical and electrochemical reactivity). We link the observed gas-phase species evolution to electrochemical behavior and measured calendar life of the three Si materials. Further, we evaluate the voltage-resolved evolution of gas-phase species for one such Si nanomaterial, where nonmonotonic gas generation implies competition between passivating reaction pathways. The measured gas-phase compositional data serves as a critical input for our advanced electrochemical SEI models to identify favorable vs unfavorable reaction pathways to stabilize Si. In addition to bolstering a fundamental understanding of Si reactivity, the present approach informs specific and quantifiable gas-phase metrics tied to calendar life improvements in Si, which can streamline and accelerate the process of next-generation material development.

DIRECT ENERGY CONVERSION,ENERGY STORAGE↗