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At least 271 records · Page 15

A comparison of wrought and powder metallurgical FeCrAl claddings under simulated LWR accident transients

Iron-chromium-aluminum (FeCrAl) alloys are potential accident tolerant fuel (ATF) cladding candidates for light-water reactors but are difficult to fabricate as thin-walled tubes via conventional cast-and-wrought routes. Powder metallurgy (PM) offers a manufacturing alternative with improved compositional control, but its transient accident performance has not been directly benchmarked against wrought variants. This study evaluates the burst behavior of commercially developed PM-processed FeCrAl alloys, PM-C26M (Fe-12Cr-6Al-2Mo) and the high precipitate density FA-SMT (Fe-22Cr-5Al-3Mo), under simulated light-water reactor accident transient conditions. Burst testing was conducted using the Severe Accident Test Station with heating rates of 5 °C/s and 50 °C/s and internal pressures ranging from 25 MPa to 100 MPa. PM-C26M reproduced wrought C26M burst behavior within 7–37 °C across the stress range, indicating that PM processing does not compromise transient strength. FA-SMT exhibited markedly higher burst temperatures and reduced heating-rate sensitivity, consistent with its engineered precipitate strengthening. FA-SMT rupture exhibited axial "unzipping" rather than the lateral tearing characteristic of PM- and wrought C26M. Post-test EBSD and fractography indicate that this behavior is strongly correlated with strain-gated intergranular void nucleation associated with the dense precipitate architecture of FA-SMT, a response absent in the comparatively clean PM-C26M matrix and consistent with rupture morphologies reported for oxide-dispersion strengthened (ODS) FeCrAl of similar base-matrix chemistry to PM-C26M. These findings highlight the potential of powder metallurgy as a viable fabrication route for ATF claddings from an accident performance standpoint.

Bell, Sam [ORNL] (ORCID:0000000251905657)↗

Ultra-Fast Vertical Ordering of Lamellar Block Copolymer Films on Unmodified Substrates

To utilize the full potential of block copolymer (BCP) thin films for use in technological devices ranging from ion conduction membranes, transistors to nanowire array antennas, rapid self- assembly of lamellar block copolymers (l-BCPs) with vertically oriented lamellar domains on a variety of unmodified substrates is needed. l-BCPs have an inherently larger interfacial area for transport compared to their cylindrical counterpart. Our observations demonstrate that the as-cast weakly ordered vertically oriented state of l-BCP films of polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) from directional evaporation of select solvents, act as “seed templates” for their ultra-fast evolution (~30 s) into well-ordered vertically oriented nanostructures, using a thermal gradient-based Cold Zone Annealing (CZA) technique. Furthermore, vertical lamellae are obtained on unmodified substrates, Quartz and Kapton, and the kinetics of l-BCP ordering is much faster by CZA as compared to the isotropic oven annealing. The rapid ordering kinetics of vertical l-BCPs is tested and found applicable to different molecular weights and film thicknesses ranging from 20 nm to 480 nm, which ultimately flip over to their equilibrium parallel morphology at upper limits of annealing times. This rapid ordering strategy for vertical orientation of l-BCPs using roll-to-roll compatible CZA would be highly relevant for fundamental studies of interfacial transport as well as for industrial applications from membranes to nanowires.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Deep Reinforcement Learning Based Volt-VAR Optimization in Smart Distribution Systems

This paper develops a model-free volt-VAR optimization (VVO) algorithm via multi-agent deep reinforcement learning (DRL) in unbalanced distribution systems. This method is novel since we cast the VVO problem in distribution networks to an intelligent deep Q-network (DQN) framework, which avoids solving a specific optimization model directly when facing time-varying operating conditions in the systems. We consider statuses/ratios of switchable capacitors, voltage regulators, and smart inverters installed at distributed generators as the action variables of the agents. A delicately designed reward function guides these agents to interact with the distribution system, in the direction of reinforcing voltage regulation and power loss reduction simultaneously. The forward-backward sweep method for radial three-phase distribution systems provides accurate power flow results within a few iterations to the DRL environment. The proposed method realizes the dual goals for VVO. We test this algorithm on the unbalanced IEEE 13-bus and 123-bus systems. Numerical simulations validate the excellent performance of this method in voltage regulation and power loss reduction.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Epoxy resins produce improved plastic scintillators

Plastic scintillator produced by the substitution of epoxy resins for the commonly used polystyrene is easy to cast, stable at room temperature, and has the desirable properties of a thermoset or cross-linked system. Such scintillators can be immersed directly in strong solvents, an advantage in many chemical and biological experiments.

Markley, F. W.↗

Comparative thermal fatigue resistance

Nineteen cast nickel-base alloys, five cast cobalt-base alloys, and two wrought nickel-base alloys are included in study. Five nickel-base alloys have directionally-solidified polycrystalline grain structure. Three diffusion coatings and vapor-deposited overlay coating are also included in investigation.

Bizon, P. T.↗

Nickel-hydrogen battery integration study for the Multimission Modular Spacecraft

A study has been performed to determine the feasibility of using nickel-hydrogen batteries as replacements for the nickel-cadmium batteries currently used for energy storage in the Multimission Modular Spacecraft under a contract with NASA Goddard Space Flight Center. The battery configuration was selected such that it meets volumetric and mounting constraints of the existing battery location, interfaces electrically with existing power conditioning and distribution equipment, and maintains acceptable cell operating temperatures. The battery contains 21, 50 ampere-hour cells in a cast aluminum structural frame. Cells used in the battery design are those developed under the Air Force's Aero Propulsion Laboratory funding and direction. Modifications of the thermal control system were necessary to increase the average output power capability of the Modular Power Subsystem.

Mueller, V. C.↗

An application of compound scaling to wind tunnel model design

An approach was developed for the stiffness design of aeroelastically scaled wind tunnel models. The object of designing such models is to make a structure whose stiffness matches a desired stiffness distribution. This design problem is cast as a formal constrained optimization problem and worked with two different optimization methods. A previous effort used the modified method of feasible directions (MFD) as implemented in a general purpose finite element based optimization code. In this effort, a special purpose finite element based optimization program was written and run using both MFD and compound scaling optimization methods. Results are presented comparing the final designs obtained using MFD and compound scaling.

French, Mark↗

A Wind Tunnel Study of Icing Effects on a Business Jet Airfoil

Aerodynamic wind tunnel tests were conducted to study the effects of various ice accretions on the aerodynamic performance of a 36-inch chord, two-dimensional business jet airfoil. Eight different ice shape configurations were tested. Four were castings made from molds of ice shapes accreted in an icing wind tunnel. Two were made using computationally smoothed tracings of two of the ice shapes accreted in the icing tunnel. These smoothed profiles were then extended in the spanwise direction to form a two-dimensional ice shape. The final two configurations were formed by applying grit to the smoothed ice shapes. The ice shapes resulted in as much as 48% reduction in maximum lift coefficient from that of the clean airfoil. Large increases in drag and changes in pitching moment were also observed. The castings and their corresponding smoothed counterparts yielded similar results. Little change in performance was observed with the addition of grit to the smoothed ice shapes. Changes in the Reynolds number (from 3 x 10(exp 6) to 10.5 x 10(exp 6) and Mach number (from 0.12 to 0.28) did not significantly affect the iced-airfoil performance coefficients.

Addy, Harold E., Jr.↗

Impact of droplet oxidation on mechanical properties of an Al-7Si-0.4Mg alloy fabricated with liquid metal jetting

Droplet-on-demand liquid metal jetting (DOD-LMJ) is a new method for additive manufacturing of bulk structural alloys. Here, we report on the microstructure, tensile, and fatigue properties of an Al-7Si-0.4Mg (A356) alloy fabricated with LMJ. Liquid metal droplets were shielded by high-purity Ar gas shroud during deposition. Atom probe tomography revealed that a few nanometers thick (Al-Mg-Si)-O oxide film formed on the droplets despite Ar gas shielding. Tensile tests on peak-aged LMJ A356 alloy showed that yield strength was isotropic (250 MPa), but ductility was lower in the build direction (6.1 ± 1.4 %) compared to the transverse direction (9.4 ± 1.0 %). Lower ductility in the build direction was attributed to delamination of metal-oxide interfaces at layer boundaries. The ductility and yield strength of LMJ A356 were similar to cast A356 and laser powder bed fused (LPBF) A357 alloys, indicating the limited impact of oxide film on tensile properties. The oxide film severely impacted the fatigue properties. Fatigue resistance of LMJ A356 was limited by fatigue crack initiation at lack-of-fusion defects and fatigue crack propagation along layer boundaries by delamination of the metal-oxide interface. The fatigue strength of LMJ A356 at 60 MPa was lower than cast A356 and LPBF A357 alloys in the peak-aged condition. This research underscores the need for managing droplet oxidation during LMJ additive manufacturing of structural alloys.

42 ENGINEERING↗

CAST-10-2/DOA 2 Airfoil Studies Workshop Results

During the period of September 23 through 27, 1988, the Transonic Aerodynamics Division at the Langely Research Center hosted an International Workshop on CAST-10-2/DOA 2 Airfoil Studies. The CAST-10 studies were the outgrowth of several cooperative study agreements among the NASA, the NAE of Canada, the DLR of West Germany, and the ONERA of France. Both theoretical and experimental CAST-10 airfoil results that were obtained form an extensive series of tests and studies, were reviewed. These results provided an opportunity to make direct comparisons of adaptive wall test section (AWTS) results from the NASA 0.3-meter Transonic Cryogenic Tunnel and ONERA T-2 AWTS facilities with conventional ventilated wall wind tunnel results from the Canadian high Reynolds number two-dimensional test facility. Individual papers presented during the workshop are included.

Ray, Edward J.↗

A natural conservative flux difference splitting for the hyperbolic systems of gasdynamics

Gasdynamic hyperbolic systems are treated by a novel conservative flux difference splitting upwind method which is applicable to explicit or implicit and iterative or direct schemes, for marching in time or space with the Euler or compressible Navier-Stokes equations. The method is able to capture sharp shocks correctly by maintaining global conservation. The embedded characteristics formulation is cast in the volumetric internal energy primitive variable, which is effective for real as well as perfect gases. Higher order upwind formulae are constructed from the distribution of pieces of the simple internal flux difference splitting, and the method reverts to first order at the appropriate points in order not to violate the domain of dependence by differencing across discontinuities. At insignificant computational overhead, switching is done by simple algebraic extensions of the truth functions that determine upwind direction for the first order scheme.

Lombard, C. K.↗

Hexagonal uniformly redundant arrays for coded-aperture imaging

Uniformly redundant arrays are used in coded-aperture imaging, a technique for forming images without mirrors or lenses. This technique is especially important for the high energy X-ray and gamma-ray region above 20 kev. In this technique, a mask consisting of opaque (closed) and trasparent (open) areas is placed between the photon sources to be imaged and a position sensitive detector or a detector array. Each source casts a shadow pattern of the mask or aperture onto the detector. This shadow pattern may be viewed as an encoded signal for that source direction. If each possible source code is unique, the detected composite of overlapping shadow patterns may be decoded to produce an image of the source distribution.

Finger, M. H.↗

Solar radiation on a catenary collector

A tent-shaped structure with a flexible photovoltaic blanket acting as a catenary collector is presented. The shadow cast by one side of the collector produces a shadow on the other side of the collector. This self-shading effect is analyzed. The direct beam, the diffuse, and the albedo radiation on the collector are determined. An example is given for the insolation on the collector operating on Viking Lander 1 (VL1).

Crutchik, M.↗

The hidden geometry of particle collisions

We establish that many fundamental concepts and techniques in quantum field theory and collider physics can be naturally understood and unified through a simple new geometric language. The idea is to equip the space of collider events with a metric, from which other geometric objects can be rigorously defined. Our analysis is based on the energy mover’s distance, which quantifies the “work” required to rearrange one event into another. This metric, which operates purely at the level of observable energy flow information, allows for a clarified definition of infrared and collinear safety and related concepts. A number of well-known collider observables can be exactly cast as the minimum distance between an event and various manifolds in this space. Jet definitions, such as exclusive cone and sequential recombination algorithms, can be directly derived by finding the closest few-particle approximation to the event. Several area- and constituent-based pileup mitigation strategies are naturally expressed in this formalism as well. Finally, we lift our reasoning to develop a precise distance between theories, which are treated as collections of events weighted by cross sections. In all of these various cases, a better understanding of existing methods in our geometric language suggests interesting new ideas and generalizations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Report on use of Inoculants in Missile Application Alloys

This report documents the status of current inoculant research relevant to missile application alloys and MTCR control language. The information is intended to provide data on current inoculants for us determining the current state of development and identifying potential research directions. Although there has been significant scientific research into the development and synthesis of inoculants, their current availability is limited is traditional powder inoculants employed during casting processes. However, research continues the development of complex oxides, ribbon materials, high entropy alloys, and other inoculant product forms, including the use of inoculants in the melt pools produced during additive manufacturing. Research to date has focused primarily on aluminum and steel alloys with emphasis on refining grain structures and evolving equiaxed morphologies while increasing strength and castability. The primary inoculants in steel and cast irons include TiN, SiC, FeSi75, and Ce which have increased strength properties. Chief inoculants for Al alloys often include TiC, SiC, Al3Sc(x) and TiB2 to aid in precipitation and refinement. Ti and Ni alloys have fewer research activities involving inoculants, although TiN, TiB, ZrN and LaB6 (for Ti alloys) and WC, Co3FeNb2, and CrFeNb (for Ni alloys) have been used. Sic, Al2O3, Mg and Ti are key inoculants for Mg alloys. Multiple cast alloys from each of the material classes demonstrated increased strength and performance properties using inoculants, with several approaching requirements applicable to missile service environments. The continued evolution of advanced manufacturing capabilities is making it easier to produce high temperature near net shape structural materials using inoculant powders. These shapes may include the geometric shapes addressed within the MTCR (tubes and limited wall thicknesses). The use of inoculants may enable further development of high temperature alloys into near net shapes traditionally produced via casting processes due to limited ductility. This may decrease material and manufacturing costs. In addition, inoculation provides controlled kinetics and achievable chemical segregation that enables potential for far-from equilibrium thermodynamic microstructures and chemistries that could provide new metastable alloy states and subsequent properties to address co-design engineering constraints, including needs for increased strength and ductility. It is recommended that specific material combinations within these alloy classes be carefully watched as the materials evolve, with controls aimed at those having material properties above current MTCR levels. This specifically includes the use of refractory inoculants in alloys, and the application of inoculants in high strength and high temperature alloys via additive manufacturing processes, with care to link capabilities to product forms similar to the current requirements on tube geometries and material feed stocks. The continued development of nanoparticle inoculants will increase strength and ductility of high strength castings and additive manufactured metallic components. For example, adding inoculants into the casting of maraging steels and other precipitation strengthened alloys may drastically elevate mechanical properties above the control limit of current regulations.

36 MATERIALS SCIENCE↗

Supersonic Flow of Chemically Reacting Gas-Particle Mixtures. Volume 2: RAMP - A Computer Code for Analysis of Chemically Reacting Gas-Particle Flows

A computer program written in conjunction with the numerical solution of the flow of chemically reacting gas-particle mixtures was documented. The solution to the set of governing equations was obtained by utilizing the method of characteristics. The equations cast in characteristic form were shown to be formally the same for ideal, frozen, chemical equilibrium and chemical non-equilibrium reacting gas mixtures. The characteristic directions for the gas-particle system are found to be the conventional gas Mach lines, the gas streamlines and the particle streamlines. The basic mesh construction for the flow solution is along streamlines and normals to the streamlines for axisymmetric or two-dimensional flow. The analysis gives detailed information of the supersonic flow and provides for a continuous solution of the nozzle and exhaust plume flow fields. Boundary conditions for the flow solution are either the nozzle wall or the exhaust plume boundary.

Penny, M. M.↗

Ultrasonic measurement of porosity in casts and welds

The development of a quantitative nondestructive method which involves ultrasonic attenuation measurements in frequency domain to determine volume fraction of porosity in aluminum cast is discussed. The aluminum alloy A357 casting samples were produced at the Ohio State University Foundry with controlled porosity contents ranging from 0% to 6%. A computer controlled system was used to direct ultrasonic beam to a test sample to different places to conduct ultrasonic attenuation measurements. The plot of attenuation coefficients as a function of frequency was then evaluated based on existing theories to determine volume fraction of porosity and pore size.

Adler, L.↗

Planetary Regolith Microstructure: An Unexpected Opposition Effect Result

The Opposition Effect (OE) is the non-linear increase in the intensity of light scattered from a surface as phase angle approaches 0 deg. It is seen in laboratory experiments and in remote sensing observations of planetary surfaces. Understanding the OE is a requirement to fitting photometric models which will produce meaningful results about regolith texture. Our previous laboratory studies are consistent with the hypothesis that the OE in particulate materials is due to two processes, Shadow Hiding (SHOE) and Coherent Backscattering (CBOE). SHOE arises because, as phase angle approaches zero, shadows cast by regolith grains on other grains become invisible to the observer. CBOE results from constructive interference between rays traveling the same path but in opposite directions. In this study we measured the angular scattering properties of 9 mixtures of Aluminum Oxide and Boron Carbide powders of the same particle diameter (25 microns). The reflectance of the materials ranged from 7% (pure B4C) to 91% (pure Al2O3). Along with the reflectance phase curve we measured the circular polarization ratio (CPR) - the ratio of the intensity of the light returned with the same helicity as the incident light to that with the opposite helicity. An increase in CPR with decreasing phase angle indicates increased multiple scattering and is consistent with CBOE (Hapke, 1993). Popular conceptions of CBOE (Belskaya et al, 2003) hold that materials of higher albedo would exhibit increased multiple scattering and that the contribution of CBOE to the OE would increase as albedo increases. Remarkably, we find the highest albedo samples did not have the strongest CBOE opposition peaks. Instead, the maximum CBOE contribution is observed in samples with reflectance between 15 and 40%.

Nelson, R. M.↗