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At least 271 records · Page 15

The Influence of the Cobalt Content on the Strength Properties of Tungsten Carbide Ceramics under Dynamic Loads

Based on the registration and analysis of the full wave profiles, the Hugoniot elastic limit and spall strength of ceramics based on tungsten carbide with different cobalt content are measured. We also study the influence of the cobalt content on the mechanical characteristics of tungsten carbide such as hardness, fracture strength, Young’s modulus, shear modulus, and sound velocity. It is shown that in the process of spalling, the failure stresses grow and the dynamic elastic limit decreases almost linearly within the scatter of their values with growing cobalt content; moreover, the value of the Hugoniot elastic limit is abruptly practically halved as the cobalt content grows from 0 to 2 wt %.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Decadal Prediction Case Study: Late Twentieth-Century North Atlantic Ocean Heat Content

Here, an ensemble of initialized decadal prediction (DP) experiments using the Community Climate System Model, version 4 (CCSM4) shows considerable skill at forecasting changes in North Atlantic upper-ocean heat content and surface temperature up to a decade in advance. Coupled model ensembles were integrated forward from each of 10 different start dates spanning from 1961 to 2006 with ocean and sea ice initial conditions obtained from a forced historical experiment, a Coordinated Ocean-Ice Reference Experiment with Interannual forcing (CORE-IA), which exhibits good correspondence with late twentieth-century ocean observations from the North Atlantic subpolar gyre (SPG) region. North Atlantic heat content anomalies from the DP ensemble correlate highly with those from the CORE-IA simulation after correcting for a drift bias. In particular, the observed large, rapid rise in SPG heat content in the mid-1990s is successfully predicted in the ensemble initialized in January of 1991. A budget of SPG heat content from the CORE-IA experiment sheds light on the origins of the 1990s regime shift, and it demonstrates the extent to which low-frequency changes in ocean heat advection related to the Atlantic meridional overturning circulation dominate temperature tendencies in this region. Similar budgets from the DP ensembles reveal varying degrees of predictive skill in the individual heat budget terms, with large advective heat flux anomalies from the south exhibiting the highest correlation with CORE-IA. The skill of the DP in this region is thus tied to correct initialization of ocean circulation anomalies, while external forcing is found to contribute negligibly (and for incorrect reasons) to predictive skill in this region over this time period.

54 ENVIRONMENTAL SCIENCES↗

Contributions of Interdecadal Pacific Oscillation and Atlantic Multidecadal Oscillation to Global Ocean Heat Content Distribution

Regional sea surface temperature (SST) mode variabilities, especially the La Niña–like Pacific Ocean temperature pattern known as the negative phase of the interdecadal Pacific oscillation (IPO) and the associated heat redistribution within the ocean, are the leading mechanisms explaining the recent global warming hiatus. Here version 1 of the Community Earth System Model (CESM) is used to examine how different phases of two leading decadal time scale SST modes, namely the IPO and the Atlantic multidecadal oscillation (AMO), contribute to heat redistribution in the global ocean in the absence of time-evolving external forcings. The results show that both the IPO and AMO contribute a similar magnitude to global mean surface temperature and ocean heat redistribution. Both modes contribute warmer surface temperature and higher upper ocean heat content in their positive phase, and the reverse in their negative phase. Regionally, patterns of ocean heat distribution in the upper few hundred meters of the tropical and subtropical Pacific Ocean depend highly on the IPO phase via the IPO-associated changes in the subtropical cell. In the Atlantic, ocean heat content is primarily associated with the state of the AMO. The interconnections between the IPO, AMO, and global ocean heat distribution are established through the atmospheric bridge and the Atlantic meridional overturning circulation. An in-phase variant of the IPO and AMO can lead to much higher surface temperatures and heat content changes than an out-of-phase variation. This result suggests that changes in the IPO and AMO are potentially capable of modulating externally forced SST and heat content trends.

54 ENVIRONMENTAL SCIENCES↗

Body Potassium Content and Radiation Dose from 40 K for the Urals Population (Russia)

Long-term whole-body monitoring of radionuclides in residents of the Urals Region has been performed at the Urals Research Center for Radiation Medicine (URCRM, Chelyabinsk). Quantification of 40 K was achieved by measuring the 40 K photopeak with four phoswich detectors in whole body counter SICH-9.1M. The current study presents the results of 40 K measurements in 3,651 women and 1,961 t -test; U -test men aged 11–90; measurements were performed in 2006–2014. The residents belonged to two ethnic groups, Turkic (Tatar, Bashkir) and Slavs (mainly Russian). The levels of 40 K-body contents depend upon gender, age, and body mass. Significant ethnic-differences were not found in 40 K-body contents and 40 K concentrations in terms of Bq per kg of body weight (in groups homogenous by age and gender). Both 40 K-body contents and concentrations were significantly higher in men than in women in all age-groups; the difference was about 25%. The measured 40 K-body content in men of 20–50 years was about 4200 Bq (134 g of K) and about 3000 Bq (95 g of K) in women. By the age of 80 these values decreased to 3200 Bq (102 g of K) in men and 2500 Bq (80 g of K) in women. Annual dose rates were maximal in the age group of 20–30 years– 0.16 mGy/y for men and 0.13 mGy/y for women. Further, the dose-rates decreased with age and in the groups of 60–80 years were 0.13 mGy/y for men and 0.10 mGy/y for women. Within groups homogeneous by age and gender, individual dose rates are described by a normal statistical distribution. The coefficient of variation ranges from 9 to 14%, and on the average is 12.5%. Doses from naturally occurring 40 K accumulated over 70 years were found to be 9.9 mGy for men and 8.3 mGy for women; over 90 years - 12.5 and 10.4 mGy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

RH-TRU Waste Content Codes (RH-TRUCON) (Rev. 21)

This document, DOE/WIPP 90-045, RH-TRU Waste Content Codes (RH-TRUCON), is a catalog of RH-TRU 72-B authorized contents and a description of methods used to demonstrate compliance with the RH-TRU Waste Authorized Methods for Payload Control (RH-TRAMPAC). All containers must have a content code approved by the Waste Isolation Pilot Plant RH-TRU Payload Engineer to be eligible for shipment. The content codes contained herein are developed under the requirements outlined in the RH-TRAMPAC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Higher Energy-Content Jet Blending Components Derived from Ethanol (CRADA 467)

This project aims to develop a new sustainable aviation fuel (SAF) that comprises favorable properties, such as high energy density, excellent thermal stability, and favorable cold fold properties. Through catalyst development, this work will provide a route to control the cycloalkane/n-alkane/iso alkane content of a next-generation fuel with minimal or no aromatic content. Combining n-alkane and iso-alkane streams (high specific energy, MJ/kg) with cycloalkanes (higher energy density, MJ/L), is expected to enable at least a 4% net increase in combined (specific (MJ/kg) and volumetric (MJ/L)) energy content without impacting ‘drop-in’ fuel requirements, such as seal swelling. PNNL and LanzaTech have already demonstrated a sustainable, non-petroleum, route to isoalkanes. However, economically attractive cycloalkane production from waste and biomass is challenged by large hydrogen requirements, preferential selectivity to aromatic compounds and low yields to jet fuel range components. Many gaps in understanding cycloalkane properties and performance in complex jet fuel mixtures remain. The close tie and integration of Purdue’s fuel property analysis, with PNNL’s process development, can lead to an economically attractive process. The fuel analysis and testing by Purdue will enable a robust understanding of the properties and behavior of the cycloalkanes produced to inform process development. Additionally, seal-swelling analysis will quantify the ability of fuel blends with zero or minimal aromatics content to satisfy the seal swell requirement of O rings. Lastly, Purdue’s system-level analysis will lead to the development of a roadmap for deployment in key regions that considers system pressures such as hydrogen, water, energy efficiency, and ease of infrastructure access.

10 SYNTHETIC FUELS↗

Inferring Water Content from Neutron Die-away Curves for Planetary Science Applications

Signatures of liquid water on planetary bodies may provide evidence for past, present, or future life elsewhere in the solar system. Multiple current and upcoming planetary science missions are prioritizing the search for water, using innovative technologies and creative algorithms. For this project, we explore the capabilities of an instrument similar to the Dragonfly spacecraft to map water content on the surface of Titan, the largest moon of Saturn. We simulate Dragonfly’s neutron observations for a variety of soil compositions and develop multiple techniques to extract water content from the resultant neutron data. Additionally, we supplement neutron observations with gamma spectroscopy in an attempt to further refine water content estimates. This work is part of a larger study to employ Gaussian process regression to estimate a map of water content along the surface of Titan. Using the estimated map, an algorithm based on prediction difference mapping is employed to optimally move multiple Dragonfly detectors around the surface of Titan, fully autonomously.

79 ASTRONOMY AND ASTROPHYSICS↗

Report on Hydrogen Content Measurements of Yttrium Hydrides

This report describes the hydrogen content measurements of yttrium samples as irradiated at Advanced Test Reactor as part of the Microreactor Program. Irradiated samples were prepared at the facilities of Analytical Research Laboratory (ARL) of Materials and Fuels Complex (MFC). Hydrogen content measurements were performed on reduced size specimens using an inert gas fusion analyzer. For a single sample, replicate samples were prepared and tested to improve statistics of results. Uncertainty analyses were conducted using two approaches to determine the hydrogen content variations in the samples. Hydrogen content of irradiated specimens were both lower and higher than the expected values, indicating stoichiometry variations. Hydrogen was detected in all samples, even for the cracked capsule’s specimens. Results also suggested a potential hydrogen redistribution is present between samples inside the capsules.

08 HYDROGEN↗

Effect of Feed Solids Content on LAW Melt Processing

The primary objective of this work was to collect data to support processing of Hanford LAW over a range of feed solids contents, extending both higher and lower than the present WTP baseline. Processing LAW at higher solids content has the potential to increase throughput and reduce the time required to process the inventory of LAW waste. Processing some LAW streams at lower than the WTP baseline solids contents may be a required condition for the direct feed approach due to the more limited pretreatment functionality and evaporation capability. A high waste loading glass formulation developed in earlier work for an LAW composition specified by ORP was used for this work. The glass composition selected for testing is ORPLA20, which is based on LAW tank AN-105; the glass has a waste loading of 31.4 wt% and an Na2O content of 24.0 wt%.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Elucidating Sorghum Biomass, Nitrogen and Chlorophyll Contents With Spectral and Morphological Traits Derived From Unmanned Aircraft System

Unmanned aircraft systems (UAS) provide an efficient way to phenotype crop morphology with spectral traits such as plant height, canopy cover and various vegetation indices (VIs) providing information to elucidate genotypic responses to the environment. In this study, we investigated the potential use of UAS-derived traits to elucidate biomass, nitrogen and chlorophyll content in sorghum under nitrogen stress treatments. A nitrogen stress trial located in Nebraska, USA, contained 24 different sorghum lines, 2 nitrogen treatments and 8 replications, for a total of 384 plots. Morphological and spectral traits including plant height, canopy cover and various VIs were derived from UAS flights with a true-color RGB camera and a 5-band multispectral camera at early, mid and late growth stages across the sorghum growing season in 2017. Simple and multiple regression models were investigated for sorghum biomass, nitrogen and chlorophyll content estimations using the derived morphological and spectral traits along with manual ground truthed measurements. Results showed that, the UAS-derived plant height was strongly correlated with manually measured plant height (r = 0.85); and the UAS-derived biomass using plant height, canopy cover and VIs had strong exponential correlations with the sampled biomass of fresh stalks and leaves (maximum r = 0.85) and the biomass of dry stalks and leaves (maximum r = 0.88). The UAS-derived VIs were moderately correlated with the laboratory measured leaf nitrogen content (r = 0.52) and the measured leaf chlorophyll content (r = 0.69) in each plot. The methods developed in this study will facilitate genetic improvement and agronomic studies that require assessment of stress responses in large-scale field trials.

59 BASIC BIOLOGICAL SCIENCES↗

Effects of Silicon Content on the Microstructures and Mechanical Properties of (AlCrTiZrV)-Si x -N High-Entropy Alloy Films

A series of (AlCrTiZrV)-Si x -N films with different silicon contents were deposited on monocrystalline silicon substrates by direct-current (DC) magnetron sputtering. The films were characterized by the X-ray diffractometry (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and nano-indentation techniques. The effects of the silicon content on the microstructures and mechanical properties of the films were investigated. The experimental results show that the (AlCrTiZrV)N films grow in columnar grains and present a (200) preferential growth orientation. The addition of the silicon element leads to the disappearance of the (200) peak, and the grain refinement of the (AlCrTiZrV)-Si x -N films. Meanwhile, the reticular amorphous phase is formed, thus developing the nanocomposite structure with the nanocrystalline structures encapsulated by the amorphous phase. With the increase of the silicon content, the mechanical properties first increase and then decrease. The maximal hardness and modulus of the film reach 34.3 GPa and 301.5 GPa, respectively, with the silicon content (x) of 8% (volume percent). The strengthening effect of the (AlCrTiZrV)-S ix -N film can be mainly attributed to the formation of the nanocomposite structure.

(AlCrTiZrV)-Six-N films↗

Role of Cr Content in Microstructure, Creep, and Oxidation Resistance of Alumina-Forming Austenitic Alloys at 850–900 °C

Creep-rupture properties and oxidation behavior of a series of alumina-forming austenitic (AFA) alloys with variations of Cr contents, based on Fe-(13.5-18)Cr-25Ni-4Al-1.5Nb-0.1C in weight percent, have been evaluated at 850–900 °C. The study investigates material responses in the properties and microstructure through compositional modifications in AFA alloys, targeting performance optimization of alloys under high-temperature, corrosive industrial environments. The creep-rupture life of the alloys at 850 °C and 30MPa monotonically decreased with increasing Cr content, which was correlated with changes in secondary phase volume fractions, such as the reduction in B2-NiAl + Laves-Fe2Nb and increase in Sigma-FeCr with Cr content. The oxidation test at 900 °C in a water-vapor containing environment revealed a range of Cr content from 13.9 to 15.7 wt.%, enabling the formation of stable, protective external alumina scale as well as preventing internal oxidation/nitridation for up to total 7000 h exposure. On the other hand, the alloys with >16.7 wt.% Cr formed Sigma precipitates, which caused a reduction in not only Cr but also Al in the austenite matrix, resulting in less oxidation resistance than other alloys. The findings will guide the further optimization of material performance in the AFA alloy series.

36 MATERIALS SCIENCE↗

Effect of Carbon on the Volume of Solid Iron at High Pressure: Implications for Carbon Substitution in Iron Structures and Carbon Content in the Earth’s Inner Core

Understanding the effect of carbon on the density of hcp (hexagonal-close-packed) Fe-C alloys is essential for modeling the carbon content in the Earth’s inner core. Previous studies have focused on the equations of state of iron carbides that may not be applicable to the solid inner core that may incorporate carbon as dissolved carbon in metallic iron. Carbon substitution in hcp-Fe and its effect on the density have never been experimentally studied. We investigated the compression behavior of Fe-C alloys with 0.31 and 1.37 wt % carbon, along with pure iron as a reference, by in-situ X-ray diffraction measurements up to 135 GPa for pure Fe, and 87 GPa for Fe-0.31C and 109 GPa for Fe-1.37C. The results show that the incorporation of carbon in hcp-Fe leads to the expansion of the lattice, contrary to the known effect in body-centered cubic (bcc)-Fe, suggesting a change in the substitution mechanism or local environment. The data on axial compressibility suggest that increasing carbon content could enhance seismic anisotropy in the Earth’s inner core. The new thermoelastic parameters allow us to develop a thermoelastic model to estimate the carbon content in the inner core when carbon is incorporated as dissolved carbon hcp-Fe. The required carbon contents to explain the density deficit of Earth’s inner core are 1.30 and 0.43 wt % at inner core boundary temperatures of 5000 K and 7000 K, respectively.

58 GEOSCIENCES↗

The Stellar Content of H72.97-69.39, a Potential Super Star Cluster in the Making

Young massive clusters and super star clusters (SSCs) represent an extreme mode of star formation. Far-infrared imaging of the Magellanic Clouds has identified one potential embedded SSC, HSO BMHERICC J72.971176-69.391112 (H72.97-69.39 in short), in the southwest outskirts of the Large Magellanic Cloud. We present Gemini Flamingos 2 and GSAOI near-infrared imaging of a 3′ × 3′ region around H72.97-69.39 in order to characterize the stellar content of the cluster. The stellar content is probed down to 1.5 M {sub ⊙}. We find substantial dust extinction across the cluster region, extending up to A {sub K} of 3. Deeply embedded stars are associated with ALMA-detected molecular gas suggesting that star formation is ongoing. The high spatial resolution of the GSAOI data allows identification of the central massive object associated with the {sup 13}CO ALMA observations and detection of fainter low-mass stars around the H30α ALMA source. The morphology of the molecular gas and the nebulosity from adjacent star formation suggest they have interacted covering a region of several parsecs. The total stellar content in the cluster is estimated from the intermediate- and high-mass stellar content to be at least 10,000 M {sub ⊙}, less than R136 with up to 100,000 M {sub ⊙} within 4.7 pc radius, but places it in the regime of an SSC. Based on the extinction determination of individual stars we estimate a molecular gas mass in the vicinity of H72.97-69.39 of 6600 M {sub ⊙}, suggesting more star formation can be expected.

74 ATOMIC AND MOLECULAR PHYSICS↗

Measurement of total electron content with a geostationary satellite during the solar eclipse of March 7, 1970.

This note deals with the measurement of the total electron content of the ionosphere at the Goddard Space Flight Center, looking towards the geostationary satellite ATS 3 during the solar eclipse of Mar. 7, 1970. Obscuration at this site was nearly total. Faraday rotation was measured with a stationary circularly polarized antenna and a dual-channel phase-lock receiver tuned to 137.350 MHz. By comparing the electrical phase of the two opposite circularly polarized components, a continuous chart recording was made of Faraday rotation vs local time. A depletion of about 25% in electron content was observed from first contact to the time of minimum electron content. The time variations of the electron content during the eclipse are briefly examined in the light of current theories of ionospheric processes.

Rangaswamy, S.↗

Ash content of bones in the pigtail monkey, Macaca nemestrina.

Ash analyses of skeletons of four adult primates, Macaca nemestrina, revealed some similarities and some marked contrasts when compared with published data on human skeletal ash. The skull in both Macaca nemestrina and man has the highest ash content of all bones in the skeleton. While the bones of the arms of humans have an ash content nearly identical to that of the legs (0.3% difference), in Macaca nemestrina the humeri and radii contain 5.4% more ash than the femora and tibiae. Similarly in Macaca nemestrina the bones of the hands contain 3.5% more ash than the bones of the feet, while in humans the same bones agree within 0.3% implying that adaptive use function is a factor in bone ash concentration. The ribs of Macaca nemestrina showed an unexpectedly high ash content in comparison with those of humans. In contrast with the relatively constant ash content throughout the vertebrae in humans, a conspicuous decrease axially was noted in Macaca nemestrina.

Vose, G. P.↗

Changes in total plasma content of electrolytes and proteins with maximal exercise.

To determine to what extent the increases in concentration of plasma proteins and electrolytes with short maximal work were a result of hemoconcentration, the changes in plasma volume and total content of the plasma constituents were simultaneously evaluated. The results obtained from six human subjects indicated that in comparison to preexercise values there was a net decrease in total content of plasma protein, sodium, and chloride in the first 2 min of the postexercise period, due primarily to a significant loss (13-15%) of plasma fluid. The total plasma potassium content was increased immediately after exercise but was significantly below the preexercise plasma content after 2 min of recovery.

Van Beaumont, W.↗

Permafrost - Relation between ice content and dielectric losses at 100 K

The dielectric response of permafrost at 100 K and vacuums of around 10 ntorr is analyzed, varying its percent ice content from 1 to 18.6. The distributions obtained correspond to dielectric relaxations of the Cole-Cole type, with maximum losses occurring in the 30- to 600-Hz frequency range. The logarithms of such maxima depend linearly on the permafrost ice content, two regions of linear variation being defined above and below 3.6% ice content. Such relations point out the feasibility of determining ice content in permafrost by electromagnetic means.

Alvarez, R.↗