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The heats of solution of silver and gold in dilute Ag-Au-Sn alloys have been determined as a function of alloy composition using liquid metal solution calorimetry. From the values obtained, the various enthalpy interaction parameters in the liquid solutions have been calculated. The results are interpreted in terms of the probably bonding changes taking place between silver, gold and tin atoms.
Time constant loci and theoretical luminosity functions for various compositions and ages of metal poor globular clusters
Using experimental data obtained from applying spectroscopy to a 39-wt-% aqueous ammonium sulfate solution, it is shown that, even though specific aerosol optical constants appear quite accurate, spectral variations may exist as functions of material composition or concentration or both. Prudent users of optical constant data must then include liberal data error estimates when performing calculations or in interpreting spectroscopic surveys of collected aerosol material.
Data for the system n-pentane/n-heptane on porous Chromosorb-102 adsorbent were obtained at 150, 175, and 200 C for mixtures containing zero to 100% n-pentane by weight. Prior results showing limitations on superposition of pure component data to predict multicomponent chromatograms were verified. The thermodynamic parameter MR0 was found to be a linear function of sample composition. A nonporous adsorbent failed to separate the system because of large input sample dispersions. A proposed automated data processing scheme involving magnetic tape recording of the detector signals and processing by a minicomputer was rejected because of resolution limitations of the available a/d converters. Preliminary data on porosity and pore size distributions of the adsorbents were obtained.
The fabrication of thermistors was investigated for use as atmospheric temperature sensors in meteorological rocket soundings. The final configuration of the thin film thermistor is shown. The composition and primary functions of the six layers of the sensor are described. A digital controller for thin film deposition control is described which is capable of better than .1 A/sec rate control. The computer program modules for digital control of thin film deposition processing are included.
Experiments were conducted to study body composition as a function of acceleration (1-4.7 G) in mice and rats. It is shown that fat-free body mass is a predictable function of acceleration, and that of nine components of the fat-free body mass only skeletal muscle, liver and heart contributed to observed changes induced by delta G. Fat-free body mass was found to pass through a maximum at 1 G when it was plotted vs G for mice, rats and monkeys (1-4.7 G) and men (0-1 G).
The results of a program designed to optimize the fabrication procedures for graphite thermoplastic composites are described. The properties of the composites as a function of temperature were measured and graphite thermoplastic fan exit guide vanes were fabricated and tested. Three thermoplastics were included in the investigation: polysulfone, polyethersulfone, and polyarylsulfone. Type HMS graphite was used as the reinforcement. Bending fatigue tests of HMS graphite/polyethersulfone demonstrated a gradual shear failure mode which resulted in a loss of stiffness in the specimens. Preliminary curves were generated to show the loss in stiffness as a function of stress and number of cycles. Fan exit guide vanes of HMS graphite polyethersulfone were satisfactorily fabricated in the final phase of the program. These were found to have stiffness and better fatigue behavior than graphite epoxy vanes which were formerly bill of material.
The plugging of airfoil cooling holes by typical coal-derived fuel impurities was evaluated using doped combustion gases in an atmospheric pressure burner rig. Very high specific cooling air mass flow rates reduced or eliminated plugging. The amount of flow needed was a function of the composition of the deposit. It appears that plugging of film-cooled holes may be a problem for gas turbines burning coal-derived fuels.
The spectral reflectances of seventeen group H chondrites have been measured in the vacuum ultraviolet region, from 5 to 14 eV photon energy (250 to 90 nm, wavelength), as part of a survey of all meteorite types. Olivines, ortho-, and clino- pyroxenes are the three most important silicate minerals in these meteorites, and the spectrum of each mineral contains a distinct peak caused by a transition believed to be excitonic in nature and involving the valence-conduction bandgap. The energy at which this peak occurs varies as a function of mineral composition, and this variation has been determined from the spectra of a number of mineral standards. The observed positions of the olivine and pyroxene peaks in the meteorite spectra are compared to predicted positions based on the standard minerals.
The dependence of the composite strength on the volume proportion of fiber and the transfer factor is analyzed. Four types of diagrams are constructed for the strength of composites as a function of the volume proportion of fibers and the transfer factor.
Metabolic rate and body composition as a function of sex and age were defined in 5 species of common laboratory mammals, the mouse, hamster, rat, guinea pig and rabbit. Oxygen consumption and carbon dioxide production rates were measured individually in 6 male and 6 female animals for each of 8 age cohorts ranging from 1 month to 2 years, and for each of the species. From the results it is evident that among these small mammals there is no indication of scaling of muscularity to body size, despite the 100-fold difference in body mass represented by the skeletal musculature seems to reach a pronounced peak value at age 2 to 3 months and then declines, the fraction of the fat-free body represented by other body components in older animals must increase complementarily. Under normal gravity conditions muscularity in small laboratory mammals displays large, systematic variation as a function both of species and age. This variation must be considered when such animals are subjects of experiments to study the effects of altered gravitational loading on the skeletal musculature of the mammal.
The surface roughness height z sub 0 is a parameter which measures the effect of surface irregularities on the mean profiles which occur in the atmospheric surface layer. Over land surfaces, z sub 0 is a function of soil composition, plant canopy type and distribution and other factors such as buildings and structures. Over open water, z sub 0 depends only on the distribution of waves, wavelets and other surface irregularities. These, in turn, are thought to be determined by the mean wind within the surface layer. Large and Pond have derived an empirical relationship between the mean wind speed U sub 10 at the ten meter level over open water and the neutral drag coefficient C sub DN. Their relationship covers the range U sub 10 or = M/S. Earlier, Kondo had computed a relationship between U sub 10 and C sub DN on the basis of laboratory observations which extended down to the range of infinitely small wind speeds. An interpretation between the relationships of Large and Pond for large wind speed and of Kondo for small wind speed is presented.
Chondrules are ubiquitous constituents of primitive solar system matter, indicating that chondrule formation was an important and widespread process in the early history of the solar system. If chondrules formed from fine grained CI like precursors, some volatile fractionation must have accompanied chondrule formation. This is not likely related to a separation of chondrules from gas (and dust, fine enough to be coupled to gas) shortly after formation, a process required by most models of chondrule formation. If chondrules are continuously formed in and removed from a region of the solar nebula, the chemical environment in this region will change. Vaporization of solid increases both oxygen and sulfur in the gas relative to H. Depending on the oxygen/sulfur ratio, which may vary widely as a function of precursor composition and temperature, two cases can be distinguished: (1) sulfur requires reaction with solid to condense, and thus may become much more enriched than 0; (2) if a significant amount of silicate is vaporized together with sulfides and does not recondense, changes in H/O outweigh S enrichment. In combination, these two effects may be able to account for much of the chemical variation among various types of chondrites. Opaque, fine grained matrix in unequilibrated chondrites, which is thought to derive from dust, has indeed been found to have a volatile element abundance complementary to chondrules.
A transformation of TM-waveband reflectance-factor data which provides features related as directly as possible to the corresponding TM Tasseled Cap brightness, greennes, and wetness features is presented. The reflectance factor transformation is based on spectrometer data integrated over the prelaunch composite-detector response functions of the Landsat-4 Thematic Mapper. A description, in general terms, of the approach for adjusting the transformation matrix to other types of reflectance factor data (different instrument or band response) is given.
The dependence of the nitrogen distribution in thermally nitrided SiO2 films on the nitridation time and temperature has been studied by means of X-ray photoelectron spectroscopy (XPS). The photoelectron peak intensities were measured by fitting Voigt profiles to the XPS spectra and were used to calculate the film composition as a function of film depth, applying an analytical method described in detail. The times of appearance of the maxima in interfacial nitrogen concentration are shown for 800, 1000, and 1150 C, and the data are related to a kinetic model of Vasquez and Madhukar (1985), which considers the effect of interfacial strain on the nitridation kinetics. In addition, the intensity of a fluorine marker (from the HF used in the etching step) was found to correlate with the nitrogen concentration. It is postulated that the F bonds preferentially to defects. This hypothesis and the measured F intensities are consistent with the proposed strain-dependent energy of defect formation.
The Giotto heavy ion analyzer RPA2-PICCA was designed to identify the composition and distribution of heavy thermal positive ions in the coma of comet Halley. The instrument is an electrostatic analyzer which takes advantage of the large relative flyby velocity and the fact that the ions in the inner coma should be cold and predominantly singly charged. A method of deconvolving E/Q measurements to yield ion mass composition, temperature, and flow velocity is presented. The measurements are used to investigate the dynamic behavior of the ions and variations in mass composition as a function of cometary distance.
This paper examines the occurrence of white evaporitic deposits on Antarctic meteorites from the U.S. collection, as a function of meteorite compositional group and weathering category. Evaporites occur with unusual frequency on carbonaceous chondrites. Almost two-thirds of all evaporite-bearing meteorites belong to weathering categories A, A/B, and B. Where chemical data were available, surficial evaporite deposits could be associated with elemental anomalies in meteorite interiors.
Part of the University of Wisconsin study of the feasibility of recovering He-3 from the moon is selection and evaluation of potential mining sites. Selection and evaluation are based primarily on salient findings by investigators: (1) Regoliths from areas underlain by highland materials contain less than 20 wppm He; (2) Regoliths of certain maria or parts of maria also contain less than 20 wppm He, but mare regoliths at the Apollo 11 and 17 sites contain 25 to 49 wppm He; (3) The helium content of a regolith is a function of its composition; and (4) Helium is concentrated in the -50 micron size fractions of regoliths. In site selection, the concern is with the compositions of lunar regoliths, in particular with their titanium contents. It is widely accepted that compositions of mare regoliths are controlled by the nature of the underlying basalts from which the regoliths are largely derived. The distribution and extent of the three groups of basalts and the regoliths derived from them are the first basis for site selection and evaluation. Other considerations are briefly discussed.