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At least 271 records · Page 15

Kinematic and Microphysical Control of Lightning Flash Rate over Northern Alabama

The Deep Convective Clouds and Chemistry (DC3) experiment seeks to examine the relationship between deep convection and the production of nitrogen oxides (NO (sub x)) via lightning (LNO (sub x)). A critical step in estimating LNO (sub x) production in a cloud-resolving model (CRM) without explicit lightning is to estimate the flash rate from available model parameters that are statistically and physically correlated. As such, the objective of this study is to develop, improve and evaluate lightning flash rate parameterizations in a variety of meteorological environments and storm types using radar and lightning mapping array (LMA) observations taken over Northern Alabama from 2005-2012, including during DC3. UAH's Advanced Radar for Meteorological and Operational Research (ARMOR) and the Weather Surveillance Radar - 1988 Doppler (WSR 88D) located at Hytop (KHTX) comprises the dual-Doppler and polarimetric radar network, which has been in operation since 2004. The northern Alabama LMA (NA LMA) in conjunction with Vaisala's National Lightning Detection Network (NLDN) allow for a detailed depiction of total lightning during this period. This study will integrate ARMOR-KHTX dual Doppler/polarimetric radar and NA LMA lightning observations from past and ongoing studies, including the more recent DC3 results, over northern Alabama to form a large data set of 15-20 case days and over 20 individual storms, including both ordinary multicell and supercell convection. Several flash rate parameterizations will be developed and tested, including those based on 1) graupel/small hail volume; 2) graupel/small hail mass, and 3) convective updraft volume. Sensitivity of the flash rate parameterizations to storm intensity, storm morphology and environmental conditions will be explored.

Carey, Lawrence D.↗

The Fiber Optic System for the Advanced Topographic Laser Altimeter System (ATLAS) Instrument

The Advanced Topographic Laser Altimeter System (ATLAS) Instrument has been in integration and testing over the past 18 months in preparation for the Ice, Cloud and Land Elevation Satellite - 2 (ICESat-2) Mission, scheduled to launch in 2017. ICESat-2 is the follow on to ICESat which launched in 2003 and operated until 2009. ATLAS will measure the elevation of ice sheets, glaciers and sea ice or the "cryosphere" (as well as terrain) to provide data for assessing the earth's global climate changes. Where ICESat's instrument, the Geo-Science Laser Altimeter (GLAS) used a single beam measured with a 70 m spot on the ground and a distance between spots of 170 m, ATLAS will measure a spot size of 10 m with a spacing of 70 cm using six beams to measure terrain height changes as small as 4 mm. The ATLAS pulsed transmission system consists of two lasers operating at 532 nm with transmitter optics for beam steering, a diffractive optical element that splits the signal into 6 separate beams, receivers for start pulse detection and a wavelength tracking system. The optical receiver telescope system consists of optics that focus all six beams into optical fibers that feed a filter system that transmits the signal via fiber assemblies to the detectors. Also included on the instrument is a system that calibrates the alignment of the transmitted pulses to the receiver optics for precise signal capture. The larger electro optical subsystems for transmission, calibration, and signal receive, stay aligned and transmitting sufficiently due to the optical fiber system that links them together. The robust design of the fiber optic system, consisting of a variety of multi fiber arrays and simplex assemblies with multiple fiber core sizes and types, will enable the system to maintain consistent critical alignments for the entire life of the mission. Some of the development approaches used to meet the challenging optical system requirements for ATLAS are discussed here.

global climate changes↗

A satellite-based radar wind sensor

The objective is to investigate the application of Doppler radar systems for global wind measurement. A model of the satellite-based radar wind sounder (RAWS) is discussed, and many critical problems in the designing process, such as the antenna scan pattern, tracking the Doppler shift caused by satellite motion, and backscattering of radar signals from different types of clouds, are discussed along with their computer simulations. In addition, algorithms for measuring mean frequency of radar echoes, such as the Fast Fourier Transform (FFT) estimator, the covariance estimator, and the estimators based on autoregressive models, are discussed. Monte Carlo computer simulations were used to compare the performance of these algorithms. Anti-alias methods are discussed for the FFT and the autoregressive methods. Several algorithms for reducing radar ambiguity were studied, such as random phase coding methods and staggered pulse repitition frequncy (PRF) methods. Computer simulations showed that these methods are not applicable to the RAWS because of the broad spectral widths of the radar echoes from clouds. A waveform modulation method using the concept of spread spectrum and correlation detection was developed to solve the radar ambiguity. Radar ambiguity functions were used to analyze the effective signal-to-noise ratios for the waveform modulation method. The results showed that, with suitable bandwidth product and modulation of the waveform, this method can achieve the desired maximum range and maximum frequency of the radar system.

Xin, Weizhuang↗

Neutron Stars and Black Holes in the Small Magellanic Cloud: The SMC NuSTAR Legacy Survey

We present a source catalog from the first deep hard X-ray (E > 10 keV) survey of the Small Magellanic Cloud (SMC), the Nuclear Spectroscopic Telescope Array (NuSTAR) Legacy Survey of the SMC. We observed three fields, for a total exposure time of 1 Ms, along the bar of this nearby star-forming galaxy. Fields were chosen for their young stellar and accreting binary populations. We detected 10 sources above a 3σ significance level (4–25 keV) and obtained upper limits on an additional 40 sources. We reached a 3σ limiting luminosity in the 4–25 keV band of ∼10(exp 35) erg s(exp −1), allowing us to probe fainter X-ray binary (XRB) populations than has been possible with other extragalactic NuSTAR surveys. We used hard X-ray colors and luminosities to constrain the compact-object type, exploiting the spectral differences between accreting black holes and neutron stars at E > 10 keV. Several of our sources demonstrate variability consistent with previously observed behavior. We confirmed pulsations for seven pulsars in our 3σ sample. We present the first detection of pulsations from a BeXRB, SXP 305 (CXO J005215.4–73191), with an X-ray pulse period of 305.69 ± 0.16 s and a likely orbital period of ∼1160–1180 days. Bright sources (≳5 × 10(exp 36) erg s(exp −1) ) in our sample have compact-object classifications consistent with their previously reported types in the literature. Lower-luminosity sources (≲5 × 10(exp 36) erg s(exp −1) ) have X-ray colors and luminosities consistent with multiple classifications. We raise questions about possible spectral differences at low luminosity between SMC pulsars and the Galactic pulsars used to create the diagnostic diagrams

Lazzarini, M.↗

A Case Study on the Challenges and Opportunities for the Deployment of PHM Capabilities in Existing Engineering Systems

The field of Prognostics and Health Management (PHM) of engineering systems has experienced considerable growth over the last decade. From benefits associated with faster and more powerful hardware in the form of wireless sensors, edge devices, and general computing capabilities (GPU’s and cloud computing), to development of powerful algorithms for anomaly detection and remaining useful life (RUL) estimation, the number of engineering systems featuring advanced diagnostics and prognostics capabilities continues to grow at an increasingly faster pace. However, the deployment of PHM capabilities as part of the upgrade of existing engineering systems presents multiple challenges to the PHM practitioner charged with retrofitting such systems. Issues include a lack of specific instrumentation needed to capture the signals of interest; insufficient data and sampling rates required for fault detection and diagnosis, and for detection of failure/degradation indicators; and difficulties in the identification of a system’s nominal behavior as a result of age induced degradation. Today’s PHM practitioner must be able to quickly identify and assess these types of issues to effectively evaluate and select the optimal PHM strategies required to achieve the desired results. This paper presents results from the preliminary evaluation of the High-Pressure Gas Facility (HPGF) infrastructure at NASA’s Stennis Space Center in Hancock County, Mississippi. This evaluation is part of a feasibility study conducted prior to the deployment of prognostics and diagnostics capabilities in the pumps skids of the liquid nitrogen (LN2) system of the HPGF.

Condition Based Maintenance↗

Comets and the origin of the solar system - Reading the Rosetta Stone

It is argued that, from the measured volatile abundances, comets formed at temperatures near or below about 60 K and possibly as low as about 25 K. Grains in Comet Halley were found to be of two types: silicates and organics. Isotopic evidence shows that Comet Halley formed from material with the same compositional mix as the rest of the solar system, and is consistent with comets having been a major contributor to the volatile reservoirs on the terrestrial planets. A variety of processes have been shown to modify and reprocess the outer layers of comets both during their long residence time in the Oort cloud and following their entry back into the planetary system. The most likely formation site for comets is in the Uranus-Neptune zone or just beyond, with dynamical ejection by the growing protoplanets to distant orbits to form the Oort cloud. A substantial flux of interstellar comets was likely created by the same process, and may be detectable if cometary formation is common in planetary systems around other stars.

Mumma, Michael J.↗

Interstellar grain chemistry and organic molecules

The detection of prominant infrared absorption bands at 3250, 2170, 2138, 1670 and 1470 cm(-1) (3.08, 4.61, 4.677, 5.99 and 6.80 micron m) associated with molecular clouds show that mixed molecular (icy) grain mantles are an important component of the interstellar dust in the dense interstellar medium. These ices, which contain many organic molecules, may also be the production site of the more complex organic grain mantles detected in the diffuse interstellar medium. Theoretical calculations employing gas phase as well as grain surface reactions predict that the ices should be dominated only by the simple molecules H2O, H2CO, N2, CO, O2, NH3, CH4, possibly CH3OH, and their deuterated counterparts. However, spectroscopic observations in the 2500 to 1250 cm(-1)(4 to 8 micron m) range show substantial variation from source reactions alone. By comparing these astronomical spectra with the spectra of laboratory-produced analogs of interstellar ices, one can determine the composition and abundance of the materials frozen on the grains in dense clouds. Experiments are described in which the chemical evolution of an interstellar ice analog is determined during irradiation and subsequent warm-up. Particular attention is paid to the types of moderately complex organic materials produced during these experiments which are likely to be present in interstellar grains and cometary ices.

Allamandola, L. J.↗

Dim Prospects for Transmission Spectra of Ocean Earths Around M Stars

The search for water-rich Earth-sized exoplanets around low-mass stars is rapidly gaining attention because they represent the best opportunity to characterize habitable planets in the near future. Understanding the atmospheres of these planets and determining the optimal strategy for characterizing them through transmission spectroscopy with our upcoming instrumentation is essential in order to constrain their environments. For this study, we present simulated transmission spectra of tidally locked Earth-sized ocean-covered planets around late-M to mid-K stellar spectral types, utilizing GCM modeling results previously published by Kopparapu et al. (2017) as inputs for our radiative transfer calculations performed using NASA's Planetary Spectrum Generator (psg.gsfc.nasa.gov; Villanueva et al. (2018)). We identify trends in the depth of H2O spectral features as a function of planet surface temperature and rotation rate. These trends allow us to calculate the exposure times necessary to detect water vapor in the atmospheres of aquaplanets through transmission spectroscopy with the upcoming James Webb Space Telescope (JWST) as well as several future flagship space telescope concepts under consideration (LUVOIR and OST) for a target list constructed from the TESS Input Catalog (TIC). Our calculations reveal that transmission spectra for water-rich Earth-sized planets around low-mass stars will be dominated by clouds, with spectral features < 20 ppm, and only a small subset of TIC stars would allow for the characterization of an ocean planet in the Habitable Zone. We thus present a careful prioritization of targets that are most amenable to follow-up characterizations with next-generation instrumentation, in order to assist the community in efficiently utilizing precious telescope time.

exoplanet atmospheres↗

Detecting Thin Cirrus in Multiangle Imaging Spectroradiometer Aerosol Retrievals

Thin cirrus clouds (optical depth (OD) < 03) are often undetected by standard cloud masking in satellite aerosol retrieval algorithms. However, the Mu]tiangle Imaging Spectroradiometer (MISR) aerosol retrieval has the potential to discriminate between the scattering phase functions of cirrus and aerosols, thus separating these components. Theoretical tests show that MISR is sensitive to cirrus OD within Max{0.05 1 20%l, similar to MISR's sensitivity to aerosol OD, and MISR can distinguish between small and large crystals, even at low latitudes, where the range of scattering angles observed by MISR is smallest. Including just two cirrus components in the aerosol retrieval algorithm would capture typical MISR sensitivity to the natural range of cinus properties; in situations where cirrus is present but the retrieval comparison space lacks these components, the retrieval tends to underestimate OD. Generally, MISR can also distinguish between cirrus and common aerosol types when the proper cirrus and aerosol optical models are included in the retrieval comparison space and total column OD is >-0.2. However, in some cases, especially at low latitudes, cirrus can be mistaken for some combinations of dust and large nonabsorbing spherical aerosols, raising a caution about retrievals in dusty marine regions when cirrus is present. Comparisons of MISR with lidar and Aerosol Robotic Network show good agreement in a majority of the cases, but situations where cirrus clouds have optical depths >0.15 and are horizontally inhomogeneous on spatial scales shorter than 50 km pose difficulties for cirrus retrieval using the MISR standard aerosol algorithm..

Pierce, Jeffrey R.↗

Supernova 1987A in the Large Magellanic Cloud; Proceedings of the Fourth George Mason Astrophysics Workshop, George Mason University, Fairfax, VA, Oct. 12-14, 1987

Papers concerning SN 1987A are presented, covering topics such as images and spectrograms of the SN 1987A progenitor, a linear polarimetric study of SN 1987A, the energetics, nature, and uniqueness of the supernova, comparison of the SN 1987A light curve with other type II supernovae, P-Cygni features and photospheric velocities, the neutrino burst from SN 1987A, mass determination of neutrinos, neutrino transport, energetics, and oscillations. Additional papers discuss supernovae light echoes, the UV interstellar spectrum of SN 1987A, theoretical models of SN 1987A, circumstellar and interstellar interaction, the supernova as a stripped asymptotic-branch giant in a binary system, pulsar formation and the fall back mass fraction, the signals of particle acceleration at SN 1987A, the effects of the mixing of the ejecta on the hard X-ray emissions from the supernova, possible s-process gamma-ray lines in supernovae, detectability of early thermal radiation from a neutron star in SN 1987A, NASA studies of the supernova, and information exchange for SN 1987A. Observational studies presented include optical, IR, radio, and UV observations, IR speckle-interferometry, coded mask X-ray observations, broad band X-ray imaging spectrophotometry, gamma-ray and thermal X-ray observations, and reports from several observatories.

Kafatos, Minas↗

ROSAT Observations of a New X-ray Transient in the Small Magellanic Cloud

We describe ROSAT observations of a new X-ray transient and its probable optical companion in the Small Magellanic Cloud, The transient, designated RX J0117.6-7330, appeared at a position approx. 5 southeast of the X-ray pulsar, SMC X-1, in 1992 October 1-2 PSPC observations centered on the pulsar. It was detected again in a similar observation 246 days later at a counting rate diminished by a factor of 270, which corresponds to an average e-folding decay time of 44 days. No periodic pulsations have been detected. The average 1992 flux level would be produced by a source radiating isotropically with a luminosity of 1.6 x 10(exp 37) (D/50 kpc)(exp 2) ergs 1/s in the energy range 0.2-2.5 keV. The 5 radius positional error circle includes the probable optical counterpart in the form of a magnitude V = 14.2 star with the spectral characteristics of type Be.

Clark, George W.↗

Scattering Properties and Brightness Temperatures Associated with Solid Precipitation

In the past few years, early solid precipitation detection and retrieval algorithms have been developed and shown to be applicable for snowing clouds and blizzards. NOAA has an operational snow versus rain classifier based on AMSU-B observations. Solid precipitation retrieval algorithms reported in the literature over the past two years include those that rely on neural nets, statistics, or physical relationships. All of the algorithms require the use of millimeter-wave radiometer observations. The millimeter-wave frequencies are especially sensitive to the scattering and emission properties of frozen particles due to the ice particle refractive index. Passive radiometric channels respond to both the integrated particle mass throughout the volume and field of view, and to the amount, location, and size distribution of the frozen (and liquid) particles with the sensitivity varying for different frequencies and hydrometeor types. This investigation probes the sensitivity of scattering and absorption coefficients, and hence computed brightness temperatures, resulting from variations in solid precipitation cloud profiles. The first study compares the single scattering, absorption, and asymmetry parameters associated with snow particles in clouds. Several methodologies are used to convert the physical characteristics (e.g., shape, size distributions, ice-air-water ratios) of ice particles to electromagnetic properties (e.g., absorption, scattering, and asymmetry factors). These methodologies include: conversion to solid ice particles, homogeneous dielectric mixing, or discrete dipole approximation. Changes in the conversion methodology can produce computed brightness temperature differences greater than 50 Kelvin.

Skofronick-Jackson, Gail M.↗

Space-Based Lidar Systems

An overview of space-based lidar systems is presented. from the first laser altimeter on APOLLO 15 mission in 1971 to the Mercury Laser Altimeter on MESSENGER mission currently in orbit, and those currently under development. Lidar, which stands for Light Detection And Ranging, is a powerful tool in remote sensing from space. Compared to radars, lidars operate at a much shorter wavelength with a much narrower beam and much smaller transmitter and receiver. Compared to passive remote sensing instruments. lidars carry their own light sources and can continue measuring day and night. and over polar regions. There are mainly two types of lidars depending on the types of measurements. lidars that are designed to measure the distance and properties of hard targets are often called laser rangers or laser altimeters. They are used to obtain the surface elevation and global shape of a planet from the laser pulse time-of-night and the spacecraft orbit position. lidars that are designed to measure the backscattering and absorption of a volume scatter, such as clouds and aerosols, are often just called lidars and categorized by their measurements. such as cloud and aerosol lidar, wind lidar, CO2 lidar, and so on. The advantages of space-based lidar systems over ground based lidars are the abilities of global coverage and continuous measurements.

Sun, Xiaoli↗

ROSAT Observations of a New X-ray Transient in the Small Magellanic Cloud

We describe ROSAT observations of a new X-ray transient and its probable optical companion in the Small Magellanic Cloud. The transient, designated RX J0117.6-7330, appeared at a position approximately 5 min southeast of the X-ray pulsar, SMC X-1, in 1992 October 1-2 PSPC observations centered on the pulsar. It was detected again in a similar observation 246 days later at a counting rate diminished by a factor of 270, which corresponds to an average epsilon-folding decay time of 44 days. No periodic pulsations have been detected. The average 1992 flux level would be produced by a source radiating isotropically with a luminosity of 1.6 X 10(exp 37)(D/50 kpc)(exp 2) ergs/s in the energy range 0.2-2.5 keV. The 5 sec radius positional error circle includes the probable optical counterpart in the form of a magnitude V = 14.2 star with the spectral characteristics of type Be.

Clark, George W.↗

Generating Land Surface Reflectance for the New Generation of Geostationary Satellite Sensors with the MAIAC Algorithm

The latest generation of geostationary satellite sensors, including the GOES-16/ABI and the Himawari 8/AHI, provide exciting capability to monitor land surface at very high temporal resolutions (5-15 minute intervals) and with spatial and spectral characteristics that mimic the Earth Observing System flagship MODIS. However, geostationary data feature changing sun angles at constant view geometry, which is almost reciprocal to sun-synchronous observations. Such a challenge needs to be carefully addressed before one can exploit the full potential of the new sources of data. Here we take on this challenge with Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm, recently developed for accurate and globally robust applications like the MODIS Collection 6 re-processing. MAIAC first grids the top-of- atmosphere measurements to a fixed grid so that the spectral and physical signatures of each grid cell are stacked (“remembered”) over time and used to dramatically improve cloud/shadow/snow detection, which is by far the dominant error source in the remote sensing. It also exploits the changing sun-view geometry of the geostationary sensor to characterize surface BRDF with augmented angular resolution for accurate aerosol retrievals and atmospheric correction. The high temporal resolutions of the geostationary data indeed make the BRDF retrieval much simpler and more robust as compared with sun-synchronous sensors such as MODIS. As a prototype test for the geostationary-data processing pipeline on NASA Earth Exchange (GEONEX), we apply MAIAC to process 18 months of data from Himawari 8/AHI over Australia. We generate a suite of test results, including the input TOA reflectance and the output cloud mask, aerosol optical depth (AOD), and the atmospherically-corrected surface reflectance for a variety of geographic locations, terrain, and land cover types. Comparison with MODIS data indicates a general agreement between the retrieved surface reflectance products. Furthermore, the geostationary results satisfactorily capture the movement of clouds and variations in atmospheric dust/aerosol concentrations, suggesting that high quality land surface and vegetation datasets from the advanced geostationary sensors can help complement and improve the corresponding EOS products.

geostationary satellite sensors↗

Cubespark: A New Satellite-Based 3d Lightning Observing Concept

Legacy and current space-based optical lightning detectors are insensitive to small and dim pulses that make up much of the lightning activity produced by severe storms. Moreover, lightning flashes produced at low altitudes within optically thick clouds are severely under-detected by current optical detectors. Lastly, there is currently no capability to characterize the 3D structure of lightning both day and night at the global scale, yet this information is critical for identifying lightning produced in updraft regions, including lightning occurring in overshooting tops, which is a distinctive signature of severe weather. Global 3D lightning information is also critical for understanding the vertical distribution of NOx production and identifying anomalously electrified storms. Furthermore, the vertical distribution of lightning has implications for how microphysical (e.g., ice-based) and thermodynamical (e.g., latent heat release) processes vary regionally, as well as seasonally – e.g., winter lightning typically occurs at lower altitudes than summer lightning and is often associated with tall, man-made structures. Finally, global-scale 3D lightning observations would directly provide flash type (i.e., CG or IC) information that is very useful in all of the studies mentioned in this paragraph and is fundamental in identifying/documenting deleterious CG-caused impacts (e.g., wildfires, power-outages, crop and property damage, and associated insurance claims). A new, satellite mission concept called CubeSpark is being designed to address these shortcomings and fill this measurement gap by providing novel 3D observations of total lightning activity. CubeSpark will utilize a constellation of low-Earth orbiting small satellites that make radio frequency (RF) and bi-spectral optical measurements of lightning. Two options for combining these measurements to retrieve the 3D location of lightning are considered with corresponding measurement simulators built to understand the level of detail and viability of each approach. Although the level of detail varies for each combined measurement approach, results indicate that a 3D location accuracy of < 1-2 km in each dimension is feasible across 300-500 km wide swaths, which suggests that CubeSpark can resolve the charge structure of thunderclouds from the tropics to the mid- and high-latitudes.

lightning↗

The Characteristics of Total Lightning Activity in Severe Florida Thunderstorms

Severe thunderstorms are defined by specific exceedance criteria regarding either wind speed (greater than or equal to 50 kts), hailstone diameter (greater than or equal to 3/4 inch), the occurrence of a tornado, or any combination thereof. Although traditional radar signatures of severe thunderstorms have been well documented, the characteristics of associated total lightning activity (both intracloud and cloud-to-ground) of severe thunderstorms remain poorly established. The reason for this are (1) less than 1% of all storms are actually severe, (2) intracloud lightning, which is typically the dominant form of electrical discharge within thunderstorms, is not routinely measured or recorded, (3) direct visual observations of intracloud lightning are obscured during the daytime, and (4) the migratory nature of many severe thunderstorms can make the accurate detection and mapping of intracloud lightning difficult when using fixed-location sensors. The recent establishment of LISDAD (Lightning Imaging Sensor Data Acquisition and Display - discussed in Goodman et al, this Meeting) has substantially addressed these limitations in east central Florida (ECFL). Analysis of total lightning flash Count histories using the LDAR (Lightning Detection And Ranging) system for known severe thunderstorms (currently irrespective of seasonal aspects and severe storm-type) has revealed flash rates exceeding 1 per second. This appears to be a necessary, but not sufficient,condition for most ECFL severe storm cases. The differences in radar-observed storm structure for high flash rate storms (to include both severe and non-severe categories) will be described together with the timing of peak flash rate vs. the timing of the severe weather manifestation. Comparisons with the satellite-bases OTD (Optical Transient Detector) overhead passes will also be presented when possible.

Williams, E.↗

New detections of interstellar HNO at 2 and 1.2 millimeters: More N-O bonds

The 2(sub 02) to 1(sub 01) and 3(sub 03) to 2(sub 02) transitions of HNO at 163 and 244 GHz have been detected toward several molecular clouds. In conjunction with previous measurements of the 1(sub 01) to 0(sub 00) line at 81 GHz, these observations secure the identification of interstellar HNO. The 2(sub 02) to 1(sub 01) transition of this species has been detected toward NGC 2024, Sgr B2 (NW), W51M, and Dr 21 (OH), while the 3(sub 03) to 2(sub 02) line at 1.2 mm was observed only in NGC 2024. Typical column densities of HNO observed toward these sources are N(sub tot) approximately 10(exp 12) to 10(exp 14)/sq cm, corresponding to fractional abundances of f(sub HNO) approximately 10(exp -11) to 10(exp -10). These values imply NO/HNO ratios of approximately 100 to 800. Both the HNO fractional abundances and NO/HNO ratios are in reasonable agreement with predictions of ion-molecule-type models of interstellar chemistry, provided early-time calculations are used. Such behavior contrasts with that of other nitrogen compounds, whose observed abundances are best duplicated by steady-state calculations. The chemistries of HNO and NO are thus likely to be related. These observations also suggest that interstellar N-O bonds may be more common than previously thought.

Ziurys, L. M.↗