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At least 271 records · Page 15

Boundary Conditions for the Paleoenvironment: Chemical and Physical Processes in Dense Interstellar Clouds: Summary of Research

The basic theme of this program was the study of molecular complexity and evolution for the biogenic elements and compounds in interstellar clouds and in primitive solar system objects. Research included the detection and study of new interstellar and cometary molecules and investigation of reaction pathways for astrochemistry from a comparison of theory and observed molecular abundances. The latter includes studies of cold, dark clouds in which ion-molecule chemistry should predominate, searches for the effects of interchange of material between the gas and solid phases in interstellar clouds, unbiased spectral surveys of particular sources, and systematic investigation of the interlinked chemistry and physics of dense interstellar clouds. In addition, the study of comets has allowed a comparison between the chemistry of such minimally thermally processed objects and that of interstellar clouds, shedding light on the evolution of the biogenic elements during the process of solar system formation. One PhD dissertation on this research was completed by a graduate student at the University of Massachusetts. An additional 4 graduate students at the University of Massachusetts and 5 graduate students from other institutions participated in research supported by this grant, with 6 of these thus far receiving PhD degrees from the University of Massachusetts or their home institutions. Four postdoctoral research associates at the University of Massachusetts also participated in research supported by this grant, receiving valuable training.

Irvine, William M.↗

The Equilibrium Response of Climate and Composition to Lightning

Climate change can affect atmospheric composition through perturbation of natural processes, leading to complex feedbacks. The primary atmospheric oxidants OH and ozone are very sensitive to emissions of nitrogen oxides (NO x ) from lightning, and therefore so are the subsequent chemical perturbations to long-lived greenhouse gases (e.g., methane) and aerosol chemistry and physics. Meanwhile, cloud electrification responds to both meteorology and composition (aerosol particles). Key to understanding the ultimate impact of lightning on air quality and climate is the long-term methane feedback. Here, we present simulations from the GISS ModelE2.1 chemistry-climate model in which we isolate the response of Earth’s radiative budget and composition to lightning NO x in the present day and at the end of this century by allowing the model to re-equilibrate following removal of the source. Whereas lightning initially contributes to surface ozone enhancements, longer-term responses amplified by the methane lifetime feedback reduce surface ozone on multi-decadal time scales in the northern midlatitudes. Lightning consequently contributes a strong negative radiative effect in the present day (-0.5 W m -2 ), stronger than that estimated for the anthropogenic NOx source. In addition to influencing tropospheric composition, we find significant changes in stratospheric dynamics and composition. We test the sensitivity of our results to multiple parameterizations for global lightning activity.

Lightning↗

Collisional rate coefficients of C3H2 and the determination of physical conditions in molecular clouds

Collisional excitation rates for C3H2, calculated using the coupled states approximation at temperatures of 10-30 K, are presented. C3H2 produces a number of spectral line pairs whose members are close together in frequency but arise from levels with different excitation energies. The rates are used in statistical equilibrium calculations to illustrate the excitation properties and density-dependent behavior of various C3H2 line ratios.

Avery, L. W.↗

First results from Goddard High-Resolution Spectrograph - C I, S I, and CO toward Xi Persei and the physical conditions in diffuse clouds

Observations made by the Goddard High Resolution Spectrograph of the cool, neutral interstellar gas in the line of sight to Xi Per are reported. Heliocentric velocities and equivalent widths were measured for absorption lines of C I and S I. Synthetic spectra were computed and fitted to the observed CO(2-0) and (3-0) bands in the A IPi - X 1Sigma(+) system. Derived populations of the C I ground-state fine-structure levels and the CO ground-state rotational levels were used to derive densities of two of the three, and possibly four, detected cloud components. The velocity component displaying the strongest C I absorption reveals extraordinarily high pressure.

Smith, Andrew M.↗

CGILS: Results from the First Phase of an International Project to Understand the Physical Mechanisms of Low Cloud Feedbacks in Single Column Models

1] CGILS-the CFMIP-GASS Intercomparison of Large Eddy Models (LESs) and single column models (SCMs)-investigates the mechanisms of cloud feedback in SCMs and LESs under idealized climate change perturbation. This paper describes the CGILS results from 15 SCMs and 8 LES models. Three cloud regimes over the subtropical oceans are studied: shallow cumulus, cumulus under stratocumulus, and well-mixed coastal stratus/stratocumulus. In the stratocumulus and coastal stratus regimes, SCMs without activated shallow convection generally simulated negative cloud feedbacks, while models with active shallow convection generally simulated positive cloud feedbacks. In the shallow cumulus alone regime, this relationship is less clear, likely due to the changes in cloud depth, lateral mixing, and precipitation or a combination of them. The majority of LES models simulated negative cloud feedback in the well-mixed coastal stratus/stratocumulus regime, and positive feedback in the shallow cumulus and stratocumulus regime. A general framework is provided to interpret SCM results: in a warmer climate, the moistening rate of the cloudy layer associated with the surface-based turbulence parameterization is enhanced; together with weaker large-scale subsidence, it causes negative cloud feedback. In contrast, in the warmer climate, the drying rate associated with the shallow convection scheme is enhanced. This causes positive cloud feedback. These mechanisms are summarized as the "NESTS" negative cloud feedback and the "SCOPE" positive cloud feedback (Negative feedback from Surface Turbulence under weaker Subsidence-Shallow Convection PositivE feedback) with the net cloud feedback depending on how the two opposing effects counteract each other. The LES results are consistent with these interpretations

Single Column Models↗

The physical properties of giant molecular cloud complexes in the outer Galaxy - Implications for the ratio of H2 column density to (C-12)O intensity

The physical properties of 35 giant molecular cloud complexes in the outer Galaxy were derived from the Goddard-Columbia surveys of the Galactic plane region (Dame et al., 1987). The spatial and radial velocity boundaries for the individual cloud complexes were estimated by analyzing the spatial and velocity structure of emission features in the (C-12)O surveys, and the distance to each cmplex was determined kinematically on the assumption of a flat rotation curve. The ratio of the H2 column density to the (C-12)O intensity for the outer Galaxy complexes was found to be about 6.0 x 10 to the 20th molecules/sq cm K per km/sec, which is by a factor of 2-3 greater than the value derived by other auhtors for the inner Galaxy complexes. This increase in the H2 column density/(C-12)O intensity with the distance from with the Galactic center is consistent with predictions of the optically thick cloudlet model of giant molecular cloud complexes.

Sodroski, T. J.↗

Protostars and planets II

Various papers on the formation of stars and planets are presented. The general topics addressed include: molecular clouds and star formation, young stellar objects and circumstellar disks, chemistry and grains in molecular clouds and the solar nebula, formation of giant planets, and models of the solar nebula and other planetary systems. Individual papers address: molecular cloud cores, physical conditions in isolated dark globules, rotation in dark clouds, and turbulence in molecular clouds. Also discussed are: fragmentation and hierarchical structure in the interstellar medium, formation of bound stellar clusters, ambient radiation field of young solar systems, and magnetic fields.

Black, D. C.↗

Comets in the post-Halley era. Vols. 1 & 2

The present volume on comets in the post-Halley era discusses observing techniques and intepretation, laboratory studies and simulations, the origin and evolution of comets, the cometary nucleus and coma, cometary dust, and plasmas and fields. Attention is given to IR techniques for comet observations, UV spectroscopy of cometary comae, radio interferometric imaging of comets, and irradiation effects on comets and cometary debris. Topics addressed include laboratory simulation of cometary structures, chemical theories on the origin of comets, biological implications of organic compounds in comets, the dynamic history of the Oort cloud, and physical aspects of the evolution of cometary debris. Also discussed are possible mechanisms of cometary outbursts, isotopic ratios in comets, the hydrogen clouds of comets, and physical and optical properties of cometary dust.

Newburn, R. L., Jr.↗

Boundary conditions for the paleoenvironment: Chemical and Physical Processes in dense interstellar clouds

The present research includes searches for important new interstellar constituents; observations relevant to differentiating between different models for the chemical processes that are important in the interstellar environment; and coordinated studies of the chemistry, physics, and dynamics of molecular clouds which are the sites or possible future sites of star formation. Recent research has included the detection and study of four new interstellar molecules; searches which have placed upper limits on the abundance of several other potential constituents of interstellar clouds; quantitative studies of comparative molecular abundances in different types of interstellar clouds; investigation of reaction pathways for astrochemistry from a comparison of theory and the observed abundance of related species such as isomers and isotopic variants; studies of possible tracers of energenic events related to star formation, including silicon and sulfur containing molecules; and mapping of physical, chemical, and dynamical properties over extended regions of nearby cold molecular clouds.

Irvine, W. M.↗

Utilization of Streamtubes to Analyze the Physical Interaction of a Dispersed Cloud with the CRM65 Hybrid Midspan Model

Recently there have been numerous efforts to identify the relevant icing physics related to the formation of complex three dimensional features, sometimes referred to as ’scallops’, on swept wings. However, much of the physics is still not well understood. This paper computationally investigates the interaction of the icing cloud with the 65 percent Common Research Model (CRM65). Both the interaction with an uniced model, and the interaction with a representative simulated three dimensional ice accretion are analyzed. Preliminary results suggest that the liquid water content increases near the aerodynamic body. For small droplets on the uniced geometry, the particle velocity vector becomes nearly parallel with the aerodynamic model resulting in a low value of collection efficiency. When a three dimensional feature with a length scale much smaller than the leading edge of the airfoil is introduced into the flow, the impingement of small particles can become significantly more perpendicular to the particle velocity vector in the region of these features. Since the liquid water content near the body has increased due to the interaction with the larger scale features of the aerodynamic model, i.e. the leading edge of the swept wing, extremely high collection efficiency is observed. These results suggest that three dimensional features are likely a significant physical driver that should be modeled in some capacity when simulating the impingement of a cloud on an aerodynamic model.

Icing↗

Utilization of Streamtubes to Analyze the Physical Interaction of a Dispersed Cloud with the CRM65 Hybrid Midspan Model

Recently there have been numerous efforts to identify the relevant icing physics related to the formation of complex three dimensional features, sometimes referred to as ’scallops’, on swept wings. However, much of the physics is still not well understood. This paper computationally investigates the interaction of the icing cloud with the 65 percent Common Research Model (CRM65). Both the interaction with an uniced model, and the interaction with a representative simulated three dimensional ice accretion are analyzed. Preliminary results suggest that the liquid water content increases near the aerodynamic body. For small droplets on the uniced geometry, the particle velocity vector becomes nearly parallel with the aerodynamic model resulting in a low value of collection efficiency. When a three dimensional feature with a length scale much smaller than the leading edge of the airfoil is introduced into the flow, the impingement of small particles can become significantly more perpendicular to the particle velocity vector in the region of these features. Since the liquid water content near the body has increased due to the interaction with the larger scale features of the aerodynamic model, i.e. the leading edge of the swept wing, extremely high collection efficiency is observed. These results suggest that three dimensional features are likely a significant physical driver that should be modeled in some capacity when simulating the impingement of a cloud on an aerodynamic model.

Icing↗

Cloud containment by a flux of particles

It is generally believed that relatively dense gas clouds must be present in the broad-line-emitting regions of Seyfert galaxies and quasars. A possible mechanism for the containment of these dense clouds is investigated in which momentum transfer from a flux of particles produces the hydrostatic equilibrium. Using a slab geometry and requiring ionization, energy, and force balance at each point in the cloud, the physical conditions are determined as a function of position in the cloud. The calculation describes equally well the confinement by ram pressure of a cloud moving rapidly through a thin gas. An important result is that the initial relative velocity of the incident particles and the cloud must be at least 20,000 km/s in the absence of a magnetic field parallel to its surface.

Rowe, D.↗

Lower mass limit of an evolving interstellar cloud and chemistry in an evolving oscillatory cloud

Simultaneous solution of the equation of motion, equation of state and energy equation including heating and cooling processes for interstellar medium gives for a collapsing cloud a lower mass limit which is significantly smaller than the Jeans mass for the same initial density. The clouds with higher mass than this limiting mass collapse whereas clouds with smaller than critical mass pass through a maximum central density giving apparently similar clouds (i.e., same Av, size and central density) at two different phases of its evolution (i.e., with different life time). Preliminary results of chemistry in such an evolving oscillatory cloud show significant difference in abundances of some of the molecules in two physically similar clouds with different life times. The problems of depletion and short life time of evolving clouds appear to be less severe in such an oscillatory cloud.

Tarafdar, S. P.↗

Measuring the Internal Structure and Physical Conditions in Star and Planet Forming Clouds Cores: Towards a Quantitative Description of Cloud Evolution

This grant funds a research program to use infrared extinction measurements to probe the detailed structure of dark molecular cloud cores and investigate the physical conditions which give rise to star and planet formation. The goals of this program are to acquire, reduce and analyze deep infrared and molecular-line observations of a carefully selected sample of nearby dark clouds in order to determine the detailed initial conditions for star formation from quantitative measurements of the internal structure of starless cloud cores and to quantitatively investigate the evolution of such structure through the star and planet formation process.

Lada, Charles J.↗

Measuring the Internal Structure and Physical Conditions in Star and Planet Forming Clouds Core: Toward a Quantitative Description of Cloud Evolution

This grant funds a research program to use infrared extinction measurements to probe the detailed structure of dark molecular cloud cores and investigate the physical conditions which give rise to star and planet formation. The goals of this program are to acquire, reduce and analyze deep infrared and molecular-line observations of a carefully selected sample of nearby dark clouds in order to internal structure of starless cloud cores and to quantitatively investigate the evolution of such structure through the star and planet formation process. During the second year of this grant, progress toward these goals is discussed.

Lada, Charles J.↗

Cloud Thickness from Offbeam Returns (THOR) Validation Campaign on NASA's P3B Over the ARM/SGP

Physical thickness of a cloud layer, sometimes multiple cloud layers, is a crucial controller of solar heating of the Earth- atmosphere system, which drives the convective processes that produce storm systems. Yet clouds of average optical thickness are opaque to conventional lidar, so their thickness is well estimated only by combining a lidar above and another below cloud, or a radar and lidar on the same side, dual facilities not widely available. Here we report initial observations of a new airborne multiple field of view lidar, capable of determining physical thickness of cloud layers from time signatures of off-beam returns from a I kHz micropulse lidar at 540 rim. For a single layer, the time delay of light returning from the outer diffuse halo of light surrounding the beam entry point, relative to the time delay at beam center, determines the cloud physical thickness. The delay combined with the pulse stretch gives the optical thickness. This halo method requires cloud optical thickness exceeding 2, and improves with cloud thickness, thus complimenting conventional lidar, which cannot penetrate thick clouds. Results are presented from March 25, 2002, when THOR flew a butterfly pattern over the ARM site at 8.3 km, above a thin ice cloud at 5 km, and a thick boundary-layer stratus deck with top at 1.3 km, as shown by THOR channel 1, and a base at about 0.3 km as shown by the ground-based MPL. Additional information is included in the original extended abstract.

Cahalan, R. F.↗