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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Evaluating the Impacts of Coordination for Cascaded Hydropower Plants on the Mid-Columbia

The Mid-Columbia region in the U.S. Pacific Northwest includes seven large, cascaded hydropower plants with a combined nameplate capacity of nearly 14 GW. These plants have several different operators, and there is currently limited coordination among the operators. We develop a detailed model of the Mid-Columbia system that captures both river flow constraints and power system operations. We then place this detailed model within a production cost model of a 2030 system of the Western Interconnection to evaluate how coordination of the Mid-Columbia hydropower plants might impact operations throughout the interconnection. We find that coordination of the Mid-Columbia plants leads to more generation from the Mid-Columbia plants and increased revenues for the Mid-Columbia operators. This benefit is achieved primarily through better utilization of the storage reservoirs and decreased spill through the cascade. We also evaluate the impacts of look-ahead on production costs and find that longer look-ahead values result in lower system-wide production costs.

13 HYDRO ENERGY↗

Design of a bifunctional TEMPO-tertiary amine mesoporous silica catalyst for the three-step cascade synthesis of a chromene derivative

A key challenge is design of materials and processes whereby competing reagents or conditions do not harm the multi-step sequence, thus allowing for more efficient chemical synthesis with elimination of work-up and separation steps. In this work, a three-step reaction cascade is performed using a porous bifunctional dimethylpropylamine-TEMPO-MCM41 catalyst, converting the commodity chemicals benzyl alcohol, sodium hypochlorite, and malononitrile to a biologically active anti-cancer, and anti-malarial 2-amino-chromene derivative. The cascade first utilizes a TEMPO-catalyzed oxidation of benzyl alcohol to benzaldehyde with NaOCl as the terminal oxidant. This is followed by a two-step, dual base catalyzed Knoevenagel condensation with malononitrile followed by a Michael addition with lawsone. Optimal conditions converting benzyl alcohol to 2-amino-5,10-dioxo-4-phenyl-5,10-dihydro-4H-benzo[g]chromene-3-carbonitrile include the delayed addition of malononitrile and lawsone during the three-step reaction sequence, which results in a 2-amino-chromene yield of over 80%. The importance of stepwise reagent addition is rationalized due to the unfavorable adsorption of acidic lawsone on the surface-grafted base catalyst. Tertiary Brønsted base sites of dimethylpropylamine outperform the more Lewis basic primary propylamine functionalized catalyst. This work outlines a simple and effective method for generating mesoporous materials with two types of active sites via co-condensation and thiol-ene coupling procedures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Cascade Effectiveness of 3-Terminal Tandem Photocathode Architectures as Applied to CO 2 Reduction

Cascade catalysis for photoelectrochemical CO 2 reduction (CO 2 R) decouples the overall reaction into sequential steps occurring on separately optimized catalysts (for example, Ag and Cu) between which an intermediate species such as CO is transferred. A 3-terminal tandem (3TT) photovoltaic architecture advantageously holds two different catalytic regions at different potentials under a single illumination source, but its overall efficiency is low. Using a stochastic reaction-diffusion model, we have examined 3TT photocathode design principles, focusing on the coupling of surface chemistry and transport of CO both inside the boundary layer and outward, into the bulk electrolyte. We find that ensuring that the lateral diffusion distance within the boundary layer is short compared to the boundary layer thickness and controlling bulk flow are key, with interdigitated designs showing an overall conversion efficiency improvement by 2 orders of magnitude compared to the side-by-side case without flow. These findings can be adapted for other cascaded architectures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tunable Metasurface External-Cavity Quantum Cascade Lasers up to 5.74 THz

Vertical-external-cavity surface-emitting lasers based on amplifying quantum-cascade metasurfaces are demonstrated in the 5–6 THz range for the first time. Enhanced parasitic coupling to lossy surface modes requires updated design guidelines, while elevated losses and lower available material gain limit the scaling of the metasurface period from previous designs. A series of metasurface devices with varying periods employing both uniform and focusing metasurfaces is fabricated and characterized. Reducing the metasurface period below 70% of the free-space wavelength enables devices with superior performance, achieving pulsed operation up to 5.74 THz with peak output powers of 1.3 mW, maximum operating temperatures up to 83 K, and continuous-wave operation up to 54 K with 23 μW of output power. In the best case, single-mode tuning from 5.23–5.73 THz, which corresponds to a 9.1% fractional tuning, is realized with near-Gaussian far-field profiles maintained across the entire range. Finally, these results establish quantum cascade vertical-external-cavity surface-emitting lasers as promising candidates for high-frequency local oscillator applications in heterodyne spectroscopy.

gallium arsenide↗

Highly Stable Fe/Co-TPY-MIL-88(NH 2 ) Metal–Organic Framework (MOF) in Enzymatic Cascade Reactions for Chemiluminescence-Based Detection of Extracellular Vesicles

Metal-Organic Frameworks (MOFs) can deliver many advantages when acting as enzyme mimics to assist with signal amplification in molecular detection: they have abundant active catalytic sites per unit volume of the material; their structures and elemental compositions are highly tunable, and their high specific surface area and porous property can assist with target separation and enrichment. In the present work, we have demonstrated that, by adding the pore partition agent, 2,4,6-tris(4-pyridyl)pyridine (TPY) during synthesis of the bimetallic Fe/Co-MIL-88(NH 2 ) MOF to block the open metal sites, a highly porous MOF of Fe/Co-TPY-MIL-88(NH 2 ) can be produced. This material also exhibits high stability in basic solutions and biofluids and possesses high peroxidase-mimicking activity, which can be utilized to produce long-lasting chemiluminescence (CL) from luminol and H 2 O 2 . Moreover, acting as the peroxidase-mimic, the Fe/Co-TPY-MIL-88(NH 2 ) MOF can form the enzymatic cascade with glucose oxidase (GOx) for biomarker detection. Further, when applied to detect extracellular vesicles (EVs), the MOF material and GOx are brought to the proximity on the EVs through two surface proteins, which triggers the enzyme cascade to produce high CL from glucose and luminol. EVs within the concentration range of 5 × 10 5 - 4 ×10 7 particles/mL can be detected, and the method can be used to analyze EV contents in human serum without sample preparation and EV purification. Overall, our work demonstrates that the high versatility and tunability of the MOF structures could bring in significant benefits to biosensing and enable ultrasensitive detection of biomarkers with judicious material designs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Suppression of pair beam instabilities in a laboratory analogue of blazar pair cascades

The generation of dense electron–positron pair beams in the laboratory can enable direct tests of theoretical models of γ-ray bursts and active galactic nuclei. We have successfully achieved this using ultrarelativistic protons accelerated by the Super Proton Synchrotron at (CERN). In the first application of this experimental platform, the stability of the pair beam is studied as it propagates through a meter-length plasma, analogous to TeV γ-ray-induced pair cascades in the intergalactic medium. It has been argued that pair beam instabilities disrupt the cascade, thus accounting for the observed lack of reprocessed GeV emission from TeV blazars. If true, this would remove the need for a moderate strength intergalactic magnetic field to explain the observations. We find that the pair beam instability is suppressed if the beam is not perfectly collimated or monochromatic, hence the lower limit to the intergalactic magnetic field inferred from γ-ray observations of blazars is robust.

blazar jets↗

Density-Matrix Model for Photon-Driven Transport in Quantum Cascade Lasers

In this report we develop a time-dependent density-matrix model to study photon-assisted (PA) electron transport in quantum cascade lasers. The Markovian equation of motion for the density matrix in the presence of an optical field is solved for an arbitrary field amplitude. Level-broadening terms emerge from microscopic Hamiltonians and supplant the need for empirical parameters that are often employed in related approaches. We show that, in quantum cascade lasers with diagonal design, photon resonances have a pronounced impact on electron dynamics around and above the lasing threshold, an effect that stems from the large spatial separation between the upper and lower lasing states. With the inclusion of PA tunneling, the calculated current density and output power are in good agreement with experiment.

36 MATERIALS SCIENCE↗

Submodule-Level Decentralized Control for Cascaded Quadruple Active Bridge-Based Medium-Voltage Converters

High-power, low-voltage DC (LVDC) loads, such as AI data centers, electric vehicle fast-charging hubs, and hydrogen electrolyzers, are accelerating the deployment of solid-state transformers (SSTs) that directly interface medium-voltage AC (MVAC) to LVDC, streamlining power delivery. This paper proposes a submodule-level decentralized control strategy for an SST comprising a cascaded H-bridge (CHB) active rectifier on the MVAC side and per-module quadruple-active-bridge (QAB) converters on the LVDC side with local controllers. The proposed strategy eliminates the need for high-fidelity, real-time cross-isolation communication by synchronizing all active bridges to a common heartbeat signal and enabling the primary- and secondary-side controllers to generate independent local control signals (phase shifts). The resultant phase shifts naturally govern average and double-line frequency power transfer between active bridges, enabling each side to meet its control objectives using only local measurements. Detailed controller design considerations are presented based on a stability analysis. Comprehensive electromagnetic-transient simulations demonstrate tight DC-link voltage regulation, high-quality grid currents, and robust operation under load transients and grid disturbances, without real-time communication among the submodule controllers. These results indicate that the proposed scheme can significantly enhance the reliability, scalability, and flexibility of cascaded bridge-based medium-voltage converters.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Big Data Analytic for Cascading Failure Analysis

With the challenges of increased grid dynamics and more variability of power generation from renewable energy sources, rapidly increasing complexity in the grid model, and abundant data from measurements and simulations, the requirements for computational analysis have also increased dramatically. Power system operators and engineers need to analyze more scenarios, extract meaningful information from a larger set of data, and respond more quickly when faced with these new challenges for large-scale applications, such as contingency analysis. This paper proposes a novel big data analysis approach for power system cascading analysis, prevention, and remediation. The developed techniques will be capable of cascading analysis, better assessment of the system’s vulnerability level, as well as proposing potential remediation. Case studies using IEEE 118-bus system and a 500-bus system, with a comparison against a commercial tool, validate the advantages of the developed big data approach: accurate prediction, and more importantly, faster and effective correction actions.The developed techniques could be further used for other power system applications.

big data, cascading analysis, corrective action, m↗

Comparison of NACA 65-series compressor-blade pressure distributions and performance in a rotor and in cascade

An investigation has been conducted to compare the performance of NACA 65-series compressor blades in two-dimensional cascade with that in an axial flow compressor. Blade pressure distributions were obtained by the use of a mercury-seal pressure-transfer device. The comparison indicated that cascade data accurately predicted the turning angle and blade pressure distribution obtained in the compressor at design conditions.

CASCADES↗

Cascade Error Projection Learning Algorithm

A detailed mathematical analysis is presented for a new learning algorithm termed cascade error projection (CEP) and a general learning frame work. This frame work can be used to obtain the cascade correlation learning algorithm by choosing a particular set of parameters.

learning algorithm neural network cascade error pr↗

Complementary Aerodynamic Performance Datasets for Variable Speed Power Turbine Blade Section from Two Independent Transonic Turbine Cascades

Two independent experimental studies were conducted in linear cascades on a scaled, two-dimensional mid-span section of a representative Variable Speed Power Turbine (VSPT) blade. The purpose of these studies was to assess the aerodynamic performance of the VSPT blade over large Reynolds number and incidence angle ranges. The influence of inlet turbulence intensity was also investigated. The tests were carried out in the NASA Glenn Research Center Transonic Turbine Blade Cascade Facility and at the University of North Dakota (UND) High Speed Compressible Flow Wind Tunnel Facility. A large database was developed by acquiring total pressure and exit angle surveys and blade loading data for ten incidence angles ranging from +15.8deg to −51.0deg. Data were acquired over six flow conditions with exit isentropic Reynolds number ranging from 0.05×106 to 2.12×106 and at exit Mach numbers of 0.72 (design) and 0.35. Flow conditions were examined within the respective facility constraints. The survey data were integrated to determine average exit total-pressure and flow angle. UND also acquired blade surface heat transfer data at two flow conditions across the entire incidence angle range aimed at quantifying transitional flow behavior on the blade. Comparisons of the aerodynamic datasets were made for three "match point" conditions. The blade loading data at the match point conditions show good agreement between the facilities. This report shows comparisons of other data and highlights the unique contributions of the two facilities. The datasets are being used to advance understanding of the aerodynamic challenges associated with maintaining efficient power turbine operation over a wide shaft-speed range.

Cascade↗

Complementary Aerodynamic Performance Datasets for Variable Speed Power Turbine Blade Section from Two Independent Transonic Turbine Cascades

Two independent experimental studies were conducted in linear cascades on a scaled, two-dimensional mid-span section of a representative Variable Speed Power Turbine (VSPT) blade. The purpose of these studies was to assess the aerodynamic performance of the VSPT blade over large Reynolds number and incidence angle ranges. The influence of inlet turbulence intensity was also investigated. The tests were carried out in the NASA Glenn Research Center Transonic Turbine Blade Cascade Facility and at the University of North Dakota (UND) High Speed Compressible Flow Wind Tunnel Facility. A large database was developed by acquiring total pressure and exit angle surveys and blade loading data for ten incidence angles ranging from +15.8deg to −51.0deg. Data were acquired over six flow conditions with exit isentropic Reynolds number ranging from 0.05×106 to 2.12×106 and at exit Mach numbers of 0.72 (design) and 0.35. Flow conditions were examined within the respective facility constraints. The survey data were integrated to determine average exit total-pressure and flow angle. UND also acquired blade surface heat transfer data at two flow conditions across the entire incidence angle range aimed at quantifying transitional flow behavior on the blade. Comparisons of the aerodynamic datasets were made for three "match point" conditions. The blade loading data at the match point conditions show good agreement between the facilities. This report shows comparisons of other data and highlights the unique contributions of the two facilities. The datasets are being used to advance understanding of the aerodynamic challenges associated with maintaining efficient power turbine operation over a wide shaft-speed range.

Turbine↗

Flow Reconstruction in A Transonic Turbine Cascade Using Physics-Informed Neural Networks (PINNS)

This paper investigates the application of Physics-Informed Neural Networks (PINNs) for the analysis of turbine blades in a transonic cascade. The 2-D flow field in a transonic turbine cascade is reconstructed in three ways: the traditional forward approach (PINN not trained on experimental data), by training the PINN using discrete sets of experimentally measured pressure at midspan, and in the inverse sense where no inlet or outlet pressure boundary conditions are applied. Comparisons between the PINN solutions to measured data are made. This is repeated for three different turbine blades with distinct loading characteristics. Good agreement is shown between a CFD calculation of the CMC7 blade, and the PINN model trained with all data. The PINN is trained utilizing all available data, half the available data, data from only the leading edge region, and data from only the trailing edge region. The forward problem results deviate the most from experimental data but show promise. Solutions from the assisted training cases show that the PINN can reconstruct the flow field with acceptable accuracy when trained on measurements along the entire blade. In the inverse case, it is shown that to simultaneously achieve acceptable errors for inlet Mach number and outlet isentropic Mach number, the PINN must be trained on the static pressure data along the entire blade.

Machine Learning↗

GT2024-128885: Flow Reconstruction in a Transonic Turbine Cascade using Physics-Informed Neural Networks (PINNs)

This presentation investigates the application of Physics-Informed Neural Networks (PINNs) for the analysis of turbine blades in a transonic cascade. PINNs are a machine learning method trained on losses calculated from reconstructed governing equations, assigned boundary/initial conditions, and measured data. We reconstruct the 2-D flow field in a transonic turbine cascade in two ways: the traditional forward approach (without training/experimental data) and by training the PINN using experimental data. We then compare the PINN solutions to measured data. This is repeated for three different turbine blades with distinct loading characteristics. The experimental data used for training is the static pressure measurements along the suction and pressure sides of each blade. The PINN is trained utilizing all available data, half the available data, data from only the leading edge region, and data from only the trailing edge region. It's shown that the PINN can reconstruct the flow field in all cases with acceptable errors. Cases where the PINN is trained on all the data, and even half the data, resulted in the lowest errors. The exit Mach number is inferred for each case and compared to the experimentally calculated value.

Machine Learning↗

Submodule-Level Decentralized Control for Cascaded Quadruple Active Bridge-Based Medium-Voltage Converters: Preprint

High-power, low-voltage DC (LVDC) loads, such as AI data centers, electric vehicle fast-charging hubs, and hydrogen electrolyzers, are accelerating the deployment of solid-state transformers (SSTs) that directly interface medium-voltage AC (MVAC) to LVDC, streamlining power delivery. This paper proposes a submodule-level decentralized control strategy for an SST comprising a cascaded H-bridge (CHB) active rectifier on the MVAC side and per-module quadruple-active-bridge (QAB) converters on the LVDC side with local controllers. The proposed strategy eliminates the need for high-fidelity, real-time cross-isolation communication by synchronizing all active bridges to a common heartbeat signal and enabling the primary- and secondary-side controllers to generate independent local control signals (phase shifts). The resultant phase shifts naturally govern average and double-line frequency power transfer between active bridges, enabling each side to meet its control objectives using only local measurements. Detailed controller design considerations are presented based on a stability analysis. Comprehensive electromagnetic-transient simulations demonstrate tight DC-link voltage regulation, high-quality grid currents, and robust operation under load transients and grid disturbances, without real-time communication among the submodule controllers. These results indicate that the proposed scheme can significantly enhance the reliability, scalability, and flexibility of cascaded bridge-based medium-voltage converters.

24 POWER TRANSMISSION AND DISTRIBUTION↗