On the abundance of calcium in the solar corona
Calcium abundance in solar corona, using measured values for total intensity of continuum and integrated intensities ratio
Fisher, R. R.↗
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Niobium hyperfine structure in crystal calcium tungstate
A study of the niobium hyperfine structure in single crystal calcium tungstate was made by the combination of the technique of electron paramagnetic resonance and electron nuclear double resonance (EPR/ENDOR). The microwave frequency was about 9.4 GHz and the radio frequency from 20MHz to 70 MHz. The rare earth ions Nd(3+), U(3+), or Tm(3+) were added as the charge compensator for Nb(5+). To create niobium paramagnetic centers, the sample was irradiated at 77 deg K with a 10 thousand curie Co-60 gamma source for 1 to 2 hours at a dose rate of 200 K rads per hour and then transferred quickly into the cavity. In a general direction of magnetic field, the spectra showed 4 sets of 10 main lines corresponding to 4 nonequivalent sites of niobium with I = 9/2. These 4 sets of lines coalesced into 2 sets of 10 in the ab-plane and into a single set of 10 along the c-axis. This symmetry suggested that the tungsten ions are substituted by the niobium ions in the crystal.
Tseng, D. L.↗
Interferometric studies of interstellar calcium lines.
Review of interferometric, photoelectric scans of the interstellar calcium K-lines in the spectra of 65 stars. The scans were obtained with a PEPSIOS spectrometer having a passband with a full half-intensity width of 1.0 km/sec or 0.013 A. The fivefold improvement in resolution over that used by Adams reveals numerous line components which correspond very well to those of the interstellar sodium lines, apart from frequent differences in relative intensities.
Marschall, L. A.↗
Comparison of calcium and phosphorus excretion with bone density changes during restraint in immature Macaca nemestrina primates.
Calcium and phosphorus balance data on Macaca nemestrina monkeys during immobilization are presented and correlated with X-ray bone densitometry findings. A positive mineral balance was maintained during the immobilized period. A reduced bone density was observed in most skeletal sites examined with increased density observed in epiphyseal regions. Migration of mineral from one site to another is suggested as a possible explanation for the findings.
Hoffman, R. A.↗
Production of edible carbohydrates from formaldehyde in a spacecraft. pH variations in the calcium hydroxide catalyzed formose reaction
The study of the calcium hydroxide catalyzed condensation of formaldehyde was extended to a batch reactor system. Decreases in pH were observed, often in the acid regime, when using this basic catalyst. This observation was shown to be similar to results obtained by others using less basic catalysts in the batch mode. The relative rates of these reactions are different in a batch reactor than in a continuous stirred tank reactor. This difference in relative rates is due to the fact that at any degree of advancement in the batch system, the products have a history of previous products, pH, and dissolved catalyst. The relative rate differences can be expected to yield a different nature of product sugars for the two types of reactors.
Weiss, A. H.↗
Total body calcium analysis
A technique to quantitate total body calcium in humans is developed. Total body neutron irradiation is utilized to produce argon 37. The radio argon, which diffuses into the blood stream and is excreted through the lungs, is recovered from the exhaled breath and counted inside a proportional detector. Emphasis is placed on: (1) measurement of the rate of excretion of radio argon following total body neutron irradiation; (2) the development of the radio argon collection, purification, and counting systems; and (3) development of a patient irradiation facility using a 14 MeV neutron generator. Results and applications are discussed in detail.
Lewellen, T. K.↗
Parathyroid hormone, calcitonin, and vitamin D 1974: Present status of physiological studies and analysis of calcium homeostasis
The role of parathyroid hormone, calcitonin, and vitamin D in the control of calcium and bone metabolism was studied. Particular emphasis was placed on the physiological adaptation to weightlessness and, as a potential model for this purpose, on the immobilization characteristic of space flight or prolonged bed rest. The biosynthesis, control of secretion, and metabolism of these hormonal agents is considered.
Potts, J. T., Jr.↗
Evidence of charge exchange pumping in calcium-xenon system
A flowing xenon plasma seeded with calcium was used to investigate the population mechanism for the 5s and 4d levels of Ca(+). From the dependence of certain line intensity ratios on electron temperature it was concluded that charge exchange between Xe(+) and Ca is the predominate mechanism for populating the 5s and 4d levels. Comparison with intensity ratios obtained in Ca-Ar and Ca-Kr imply the same conclusion.
Chubb, D. L.↗
Calcium-aluminum-rich inclusions in the Allende meteorite - Evidence for a liquid origin
We have made a detailed examination of the mineralogy, textures, and assemblages of six calcium-aluminum-rich inclusions (CAI) in the Allende meteorite. They can be classified into four types - hibonite-bearing, fassaite- and olivine-bearing, feldspathoid-bearing and fassaite-bearing CAI that are hibonite and olivine free. Examples of each type appear to have crystallized from a liquid rather than by agglomeration of solid nebular condensates. Some lines of evidence for a liquid origin are the presence of spherical and ovoid shapes and rims containing minerals that are more refractory than minerals inside the inclusion. Thermodynamic calculations and comparisons with liquidus phase diagrams indicate that the CAI could have been produced by direct condensation to metastable subcooled liquids that subsequently crystallized or by remelting of an equilibrium high-temperature condensate by impact. The diopside rims in some hibonite-bearing CAI and the paucity of metal in fassaite-olivine-bearing CAI are more consistent with direct condensation of a liquid.
Blander, M.↗
The control of calcium metabolism by parathyroid hormone, calcitonin and vitamin D
Advances in analysis of chemistry and physiology of parathyroid hormone, calcitonin, and Vitamin D are described along with development of techniques in radioassay methods. Emphasis is placed on assessment of normal and abnormal patterns of secretion of these hormones in specific relation to the physiological adaptations of weightlessness and space flight. Related diseases that involve perturbations in normal skeletal and calcium homeostasis are also considered.
Potts, J. T., Jr.↗
A reexamination of solar upper photosphere models, the calcium abundance, and empirical damping parameters
A general iterative method is described for constructing thermal models of the solar photosphere consistent with observed strong and weak lines of Ca I and Ca II. Calibrations of the solar calcium abundance and the van der Waals parameter for important Ca I and Ca II lines are obtained using plane-parallel largely LTE model atmospheres, and these thermal models are modified for better fits to the measured Ca II H and K inner wing shapes. Possible sources of error in this semiempirical approach are evaluated. The derived hydrogen van der Waals broadening is compared with theoretical estimates of that broadening as well as with experimental measurements of the helium broadening
Ayres, T. R.↗
The calcium K-line network in coronal holes
Microphotometry of calcium K-line photographs in the regions of polar coronal holes shows that the chromospheric network exterior to a hole has a slightly broader intensity distribution than that inside the hole itself, a fact which can be attributed to a greater number of bright network elements outside the hole. These bright elements presumably represent the enhanced network resulting from the dispersal of magnetic flux from old active regions, a hypothesis which is consistent with current ideas of coronal-hole formation.
Marsh, K. A.↗
Total body calcium analysis using the Ca-12(n, alpha) Ar-37 reaction
A low dose neutron activation technique was developed to measure total body calcium in vivo. The effort had included development of irradiation and processing facilities and conduction of human studies to determine the accuracy and precision of measurement attainable with the systems.
Lewellen, T. K.↗
Low-dose total-body-calcium analysis
Report details technique for measuring total body calcium by collecting exhaled 37Ar gas after exposure of patients to 14-MeV neutrons. Summary for theoretical basis of technique is presented.
Lewellen, T. K.↗
Study report on a double isotope method of calcium absorption
Some of the pros and cons of three methods to study gastrointestinal calcium absorption are briefly discussed. The methods are: (1) a balance study; (2) a single isotope method; and (3) a double isotope method. A procedure for the double isotope method is also included.
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A brief review of space flight calcium metabolism: Results and methodologies
Space flight induced osteoporosis was described. The techniques that were used to measure and detect the osteoporosis were also described. Areas of calcium metabolism were shown to be very important in the investigation into more sensitive detection and measurement techniques of bone demineralization.
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Preliminary design specifications of a calcium model
A list of objectives, requirements, and guidelines are given for a calcium model. Existing models are reviewed and evaluated in relation to the stated objectives and requirements. The reviewed models were either too abstract or apparently invalidated. A technical approach to the design of a desirable model is identified.
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Reactions of calcium orthosilicate and barium zirconate with oxides and sulfates of various elements
Calcium orthosilicate and barium zirconate were evaluated as the insulation layer of thermal barrier coatings for air cooled gas turbine components. Their reactions with various oxides and sulfates were studied at 1100 C and 1300 C for times ranging up to 400 and 200 hours, respectively. These oxides and sulfates represent potential impurities or additives in gas turbine fuels and in turbine combustion air, as well as elements of potential bond coat alloys. The phase compositions of the reaction products were determined by X-ray diffraction analysis. BaZrO3 and 2CaO-SiO2 both reacted with P2O5, V2O5, Cr2O3, Al2O3, and SiO2. In addition, 2CaO-SiO2 reacted with Na2O, BaO, MgO, and CoO and BaZrO3 reacted with Fe2O3.
Zaplatynsky, I.↗