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At least 271 records · Page 15

Assessment of Reduced-Kinetics Mechanisms for Combustion of Jet Fuel in CFD Applications

A computational effort was undertaken to analyze the details of fluid flow in Lean-Direct Injection (LDI) combustors for next-generation LDI design. The National Combustor Code (NCC) was used to perform reacting flow computations on single-element LDI injector configurations. The feasibility of using a reduced chemical-kinetics approach, which optimizes the reaction rates and species to model the emissions characteristics typical of lean-burning gas-turbine combustors, was assessed. The assessments were performed with Reynolds- Averaged Navier-Stokes (RANS) and Time-Filtered Navier Stokes (TFNS) time-integration, with a Lagrangian spray model with the NCC code. The NCC predictions for EINOx and combustor exit temperature were compared with experimental data for two different single-element LDI injector configurations, with 60deg and 45deg axially swept swirler vanes. The effects of turbulence-chemistry interaction on the predicted flow in a typical LDI combustor were studied with detailed comparisons of NCC TFNS with experimental data.

Ajmani, Kumud↗

Recent Biomass Burning in the Tropics and Related Changes in Tropospheric Ozone

Biomass burning is an important source of chemical precursors of tropospheric ozone. In the tropics, biomass burning produces ozone enhancements over broad regions of Indonesia, Africa, and South America including Brazil. Fires are intentionally set in these regions during the dry season each year to clear cropland and to clear land for human/industrial expansion. In Indonesia enhanced burning occurs during dry El Nino conditions such as in 1997 and 2006. These burning activities cause enhancement in atmospheric particulates and trace gases which are harmful to human health. Measurements from the Aura Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) from October 2004-November 2008 are used to evaluate the effects of biomass burning on tropical tropospheric ozone. These measurements show sizeable decreases approx.15-20% in ozone in Brazil during 2008 compared to 2007 which we attribute to the reduction in biomass burning. Three broad biomass burning regions in the tropics (South America including Brazil, western Africa, and Indonesia) were analyzed in the context of OMI/MLS measurements and the Global Modeling Initiative (GMI) chemical transport model developed at Goddard Space Flight Center. The results indicate that the impact of biomass burning on ozone is significant within and near the burning regions with increases of approx.10-25% in tropospheric column ozone relative to average background concentrations. The model suggests that about half of the increases in ozone from these burning events come from altitudes below 3 km. Globally the model indicates increases of approx.4-5% in ozone, approx.7-9% in NO, (NO+NO2), and approx.30-40% in CO.

Ziemke↗

A new interpretation of luminous blue stars

A major revision of current theoretical ideas about the brightest blue stars must be made if Carson's (1976) radiative opacities are adopted in stellar models. Unlike earlier opacities, these exhibit a large 'bump' due to CNO ionization, which leads to very strong central condensation, convective instability, and pulsational instability in hot diffuse stellar envelopes. Despite a number of theoretical uncertainties, the new picture of the structure of very luminous stars is reasonably successful in accounting for a variety of previously unexplained observations. The stellar models for the phase of core hydrogen burning predict large radii and rather cool effective temperatures for O stars and a spreading out of the main-sequence band in the H-R diagram toward luminous cool supergiants for masses higher than about 20 solar masses. In massive X-ray binary systems, circular orbits and supergiant-like visual companions are expected to be quite common. Long-period variability is predicted to exist for massive blue supergiants of luminosity class Ia. The models for helium stars predict large radii and rather cool effective temperatures for Wolf-Rayet stars, as well as multimodal pulsational instability and, possibly, surface turbulence for these stars.

Stothers, R.↗

Conditions for accretion-induced collapse of white dwarfs

Recent discovery of an unexpectedly large number of low-mass binary pulsars (LMBPs) in globular clusters has instigated active discussions on the evolutionary origin of binary pulsars. Prompted by the possibility that at least some of LMBPs originate from accretion-induced collapse (AIC) of white dwarfs, a reexamination is conducted as to whether or not AIC occurs for the new models of O + Ne + Mg white dwarfs and solid C + O white dwarfs that can ignite explosive nuclear burning at significantly lower central densities than in the previous models. Even with low critical densities, AIC is still much more likely than explosion for both types of white dwarfs. Possible regions for AIC are presented in a diagram of mass accretion rate vs initial mass of the white dwarfs.

Nomoto, Ken'ichi↗

Combustion of Metals in Reduced-Gravity and Extra Terrestrial Environments

The combustion of metals is a field with important practical applications in rocket propellants, high-temperature flames, and material synthesis. Also, the safe operation of metal containers in high-pressure oxygen systems and with cryogenic fuels and oxidizers remains an important concern in industry. The increasing use of metallic components in spacecraft and space structures has also raised concerns about their flammability properties and fire suppression mechanisms. In addition, recent efforts to embark on unmanned and manned planetary exploration, such as on Mars, have also renewed the interest in metal/carbon-dioxide combustion as an effective in situ resource utilization technology. In spite of these practical applications, the understanding of the combustion properties of metals remains far behind that of the most commonly used fuels such as hydrocarbons. The lack of understanding is due to the many problems unique to metal- oxidizer reactions such as: low-temperature surface oxidation prior to ignition, heterogeneous reactions, very high combustion temperatures, product condensation, high emissivity of products, and multi-phase interactions. Very few analytical models (all neglecting the influence of gravity) have been developed to predict the burning characteristics and the flame structure details. Several experimental studies attempting to validate these models have used small metal particles to recreate gravity-free conditions. The high emissivity of the flames, rapid reaction, and intermittent explosions experienced by these particles have made the gathering of any useful information on burning rates and flame structure very difficult. The use of a reduced gravity environment is needed to clarify some of the complex interactions among the phenomena described above. First, the elimination of the intrusive buoyant flows that plague all combustion phenomena is of paramount importance in metal reactions due to the much higher temperatures reached during combustion. Second, a low-gravity environment is absolutely essential to remove the destructive effect of gravity on the shape of a molten metal droplet in order to study a spherically symmetric condition with large bulk samples. The larger size of the spherical metal droplet and the longer burning times available in reduced gravity extend the spatial and temporal dimensions to permit careful probing of the flame structure and dynamics. Third, the influence of the radiative heat transfer from the solid oxides can be studied more carefully by generating a stagnant spherical shell of condensed products undisturbed by buoyancy.

Branch, M.C.↗

Carbon Emissions from Deforestation in the Brazilian Amazon Region

A simulation model based on satellite observations of monthly vegetation greenness from the Moderate Resolution Imaging Spectroradiometer (MODIS) was used to estimate monthly carbon fluxes in terrestrial ecosystems of Brazilian Amazon and Cerrado regions over the period 2000-2002. The NASA-CASA (Carnegie Ames Stanford Approach) model estimates of annual forest production were used for the first time as the basis to generate a prediction for the standing pool of carbon in above-ground biomass (AGB; gC/sq m) for forested areas of the Brazilian Amazon region. Plot-level measurements of the residence time of carbon in wood in Amazon forest from Malhi et al. (2006) were interpolated by inverse distance weighting algorithms and used with CASA to generate a new regional map of AGB. Data from the Brazilian PRODES (Estimativa do Desflorestamento da Amazonia) project were used to map deforested areas. Results show that net primary production (NPP) sinks for carbon varied between 4.25 Pg C/yr (1 Pg=10(exp 15)g) and 4.34 Pg C for the region and were highest across the eastern and northern Amazon areas, whereas deforestation sources of CO2 flux from decomposition of residual woody debris were higher and less seasonal in the central Amazon than in the eastern and southern areas. Increased woody debris from past deforestation events was predicted to alter the net ecosystem carbon balance of the Amazon region to generate annual CO2 source fluxes at least two times higher than previously predicted by CASA modeling studies. Variations in climate, land cover, and forest burning were predicted to release carbon at rates of 0.5 to 1 Pg C/yr from the Brazilian Amazon. When direct deforestation emissions of CO2 from forest burning of between 0.2 and 0.6 Pg C/yr in the Legal Amazon are overlooked in regional budgets, the year-to-year variations in this net biome flux may appear to be large, whereas our model results implies net biome fluxes had actually been relatively consistent from year to year during the period 2000-2002. This is the first study to use MODIS data to model all carbon pools (wood, leaf, root) dynamically in simulations of Amazon forest deforestation from clearing and burning of all kinds.

Potter, C.↗

The Carbon Monoxide Tape Recorder

Using Aura MLS data we have identified the stratospheric tape recorder in carbon monoxide (CO). Unlike the water vapor tape recorder, which is controlled by upper troposphere processes, the CO tape recorder is linked to seasonal biomass burning. Since CO has a lifetime of only a few months, the CO tape recorder barely extends above 20 km. The tape head for CO appears to be close to 360K near the same location as the water vapor tape head [Read et al, 20041. Both tape heads are below the equatorial cold point tropopause but above the base of the tropical tropopause layer. The tape recorder signal becomes more distinct from 360K to 380K suggesting that convective detrainment of plays a decreasingly important role with altitude. The Global Modeling Initiative chemical transport model forced by the climatology of biomass burning reproduces the CO tape recorder.

Schoeberl, M. R.↗

Predicting the velocity and azimuth of fragments generated by the range destruction or random failure of rocket casings and tankage

A calculational method is described which provides a powerful tool for predicting solid rocket motor (SRM) casing and liquid rocket tankage fragmentation response. The approach properly partitions the available impulse to each major system-mass component. It uses the Pisces code developed by Physics International to couple the forces generated by an Eulerian-modeled gas flow field to a Lagrangian-modeled fuel and casing system. The details of the predictive analytical modeling process and the development of normalized relations for momentum partition as a function of SRM burn time and initial geometry are discussed. Methods for applying similar modeling techniques to liquid-tankage-overpressure failures are also discussed. Good agreement between predictions and observations are obtained for five specific events.

Eck, Marshall↗

An Inversion Analysis of Recent Variability in Natural CO2 Fluxes Using GOSAT and In Situ Observations

About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks, and their location and year-to-year variability are, however, not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations and interannually varying meteorology. We also use measurement-based ocean flux estimates and two sets of fixed fossil CO2 emissions. Here, our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, filtered and bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3 x 3.75 weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM atmospheric transport model driven by meteorology from the MERRA reanalysis. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble those from other studies. For example, the results indicate that the terrestrial biosphere is a net CO2 sink, and a GOSAT-only inversion suggests a shift in the global sink from the tropics south to the north relative to the prior and to an in-situ-only inversion. We also find a smaller terrestrial sink in higher-latitude northern regions in boreal summer of 2010 relative to 2009.

Carbon dioxide↗

Biomass Burning Emissions from Fire Remote Sensing

Knowledge of the emission source strengths of different (particulate and gaseous) atmospheric constituents is one of the principal ingredients upon which the modeling and forecasting of their distribution and impacts depend. Biomass burning emissions are complex and difficult to quantify. However, satellite remote sensing is providing us tremendous opportunities to measure the fire radiative energy (FRE) release rate or power (FRP), which has a direct relationship with the rates of biomass consumption and emissions of major smoke constituents. In this presentation, we will show how the satellite measurement of FRP is facilitating the quantitative characterization of biomass burning and smoke emission rates, and the implications of this unique capability for improving our understanding of smoke impacts on air quality, weather, and climate. We will also discuss some of the challenges and uncertainties associated with satellite measurement of FRP and how they are being addressed.

Ichoku, Charles↗

Ignition and Burn in a Hybrid Nuclear Fuel for a Pulsed Rocket Engine

This work explores the parameter space of a cylindrical hybrid nuclear fuel in support of a z-pinch driven pulsed fission-fusion (PuFF) engine. 0D power balance and 1D burn wave calculations have been performed to explore the parameter space of hybrid cylindrical nuclear fuels. The boundary of minimal initial conditions needed to reach breakeven are found within the context of the model. The effects of initial conditions upon the yield at the end of burn wave expansion are also determined. The model is used to examine the minimum initial energies predicted to result in yields of a few MJ. The goal of this work is to guide fuel design, inform future models and experiments as well as look for the most efficient parameter space for ignition in a z-pinch driven hybrid nuclear reaction. The impact of initial parameters upon ignition, burn, and gain are discussed. It is found that a hybrid cylindrical target may breakeven with initial energy near the axis of approximately 4 to 6 MJ in lithium deuteride/uranium 235 fuel. It is also found that magnetic field can lower the threshold further of which the magnitude changes across the parameter space. The dual fusion/fission reactions are found to boost each other leading to lower initial driving energies needed to reach breakeven in the hybrid cylindrical nuclear fuel.

fission↗

Radiative Heating Rate Profiles over the Southeast Atlantic Ocean during the 2016 and 2017 Biomass Burning Seasons

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. Further uncertainties in the cloud structure arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean where biomass burning aerosol is transported from the African continent. As the aerosol plume progresses across the southeast Atlantic Ocean, radiative heating within the aerosol layer has the potential to alter the thermodynamic environment and therefore the cloud structure; however, limited work has been done to quantify this along the trajectory of the aerosol plume in the region. The deployment of the First Atmospheric Radiation Measurement Mobile Facility in support of the Layered Atlantic Smoke Interactions with Clouds field campaign provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96 °S, 14.35 °W). Using observed profiles of temperature, humidity, and clouds from the field campaign, alongside aerosol optical properties from MERRA-2 as input for the Rapid Radiation Transfer Model, profiles of the radiative heating rate due to aerosols and clouds were computed. Radiative heating is also assessed across the southeast Atlantic Ocean using an ensemble of back trajectories from the Hybrid Single Particle Lagrangian Integrated Trajectory Model. Idealized experiments using the Rapid Radiation Transfer Model with and without aerosols and a range of values for the single scattering albedo demonstrate that shortwave heating within the aerosol layer above Ascension Island can locally range between 2 and 8 K per day depending on the aerosol optical properties, though impacts of the aerosol can be felt elsewhere in the atmospheric column. When considered under clear conditions, the aerosol has a cooling effect at the TOA and based on the observed cloud properties at Ascension Island, the cloud albedo is not large enough to overcome this. Shortwave radiative heating due to biomass burning aerosol is not balanced by additional longwave cooling, and the net radiative impact results in a stabilization of the lower troposphere. However, these results are extremely sensitive to the single scattering albedo assumptions in models.

Allison B. Marquardt Collow↗

Combustion theory for liquids with a free surface. 3: Special problems

Two special problems concerning the combustion of liquids with a free surface, i.e., flame quenching during the mixing of a burning liquid inside a container and liquid burnout from a porous layer, are analyzed using a quasi-one-dimensional model. The critical parameters corresponding to the quenching of a burning fluid with a free surface are determined. Determinations are also made of the limiting pressure gradients corresponding to the transition from the combustion mode where the liquid evaporates from the surface of a porous layer to the mode where the phase transition surface lies inside the porous layer.

Milkov, S. N.↗

The Distribution of Snow Black Carbon observed in the Arctic and Compared to the GISS-PUCCINI Model

In this study, we evaluate the ability of the latest NASA GISS composition-climate model, GISS-E2- PUCCINI, to simulate the spatial distribution of snow BC (sBC) in the Arctic relative to present-day observations. Radiative forcing due to BC deposition onto Arctic snow and sea ice is also estimated. Two sets of model simulations are analyzed, where meteorology is linearly relaxed towards National Centers for Environmental Prediction (NCEP) and towards NASA Modern Era Reanalysis for Research and Applications (MERRA) reanalyses. Results indicate that the modeled concentrations of sBC are comparable with presentday observations in and around the Arctic Ocean, except for apparent underestimation at a few sites in the Russian Arctic. That said, the model has some biases in its simulated spatial distribution of BC deposition to the Arctic. The simulations from the two model runs are roughly equal, indicating that discrepancies between model and observations come from other sources. Underestimation of biomass burning emissions in Northern Eurasia may be the main cause of the low biases in the Russian Arctic. Comparisons of modeled aerosol BC (aBC) with long-term surface observations at Barrow, Alert, Zeppelin and Nord stations show significant underestimation in winter and spring concentrations in the Arctic (most significant in Alaska), although the simulated seasonality of aBC has been greatly improved relative to earlier model versions. This is consistent with simulated biases in vertical profiles of aBC, with underestimation in the lower and middle troposphere but overestimation in the upper troposphere and lower stratosphere, suggesting that the wet removal processes in the current model may be too weak or that vertical transport is too rapid, although the simulated BC lifetime seems reasonable. The combination of observations and modeling provides a comprehensive distribution of sBC over the Arctic. On the basis of this distribution, we estimate the decrease in snow and sea ice albedo and the resulting radiative forcing. We suggest that the albedo reduction due to BC deposition presents significant space-time variations, with highest mean reductions of 1.25% in the Russian Arctic, which are much larger than those in other Arctic regions (0.39% to 0.64 %). The averaged value over the Arctic north of 66degN is 0.4-0.6% during spring, leading to regional surface radiative forcings of 0.7, 1.1 and 1.0Wm(exp−2) in spring 2007, 2008 and 2009, respectively.

Dou, T.↗

Error analysis for pulsed maneuvers of a dual-spin spacecraft

The Galileo is a dual-spin interplanetary spacecraft which is scheduled for launch toward Jupiter in October of 1989. The spacecraft has twelve thrusters, located on the rotor, which can be operated in continuous or pulsed modes. In this paper probabilistic error models are presented for the pulsed maneuvers which are used to change the spacecraft's velocity. These models take into account all error sources which might affect the maneuver accuracies, such as wobble, nutation, plume impingement, thrust level variation and misalignment, gyro drift, burn timing errors and mass property uncertainties. The analytic models are sufficiently general so that they may be applied to all spin and dual-spin stabilized spacecraft. When these models are applied to the case of the Galileo spacecraft, the numerical results demonstrate that the spacecraft can achieve the maneuver accuracies required in order to successfully reach Jupiter and perform its scientific mission.

Longuski, James M.↗

Combustion of Interacting Droplet Arrays in a Microgravity Environment

This research program involves the study of single droplets and linear arrays of droplets in weakly-buoyant and non-bouyant environments. The primary purpose of the single droplet work was to (1) provide a data base from which to compare droplet array results and (2) to correlate the effects of buoyancy on flame shape. Traditionally convective effects in droplet combustion are represented in terms of the Reynolds number, Re, for forced convection and the Grashof number, Gr, for natural convection. Typically, corrections to the burning rate constant for convective effects are written in terms of Re or Gr(exp 1). The Stefan velocity is not included in these correlations, even though from purely physical reasons, one would expect it to be important, especially at higher burning rates. The flame distortion due to convective effects is less documented quantitatively. Kumagai and Isoda do predict flame shape in natural and forced convective flow fields. Their focus, however, was to predict the actual flame dimensions. Law and co-workers used reduced pressure, high oxidizer ambients to obtain spherical flames. This implies that buoyant flows were reduced at the low pressures, as indicated by a very small Grashof number. Ross et al, however, using scaling arguments showed that reducing the pressure does not have a large effect on the magnitude of the buoyant velocity. Struk et al showed elongated flame shapes during simulated (porous sphere) droplet combustion. The elongation of the flames was due to residual gravity levels aboard the reduced gravity aircraft on which the experiments were conducted. These flame shapes, as well as some data from the literature were interpreted based on a dimensionless grouping called the sphericity parameter, Sp. Sp is the ratio of a characteristic computed buoyant velocity to the Stefan velocity at the flame front. One purpose of the droplet arrays work is to extend the database and theories that exist for single droplets into the regime where droplet interactions are important. The eventual goal being to use the results of this work as inputs to models on spray combustion where droplets seldom burn individually; instead the combustion history of a droplet is strongly influenced by the presence of the neighboring droplets. Recently, Annamali and Ryan have summarized he current status of droplet array, cloud and spray combustion. A number of simplified theories led numerical studies of droplet vaporization/combustion where multiple droplet effects are present are now available. These theories all neglect the effect of buoyancy. Experimentally, most studies to date suffer the effects of buoyancy. It is the dominant transport mechanism in the problem. Only the works of Law and co-worker and more recently by Mikami et al were performed in an environment where buoyancy effects were small. Law and co-workers were limited to high oxygen index, low pressure ambient environments since there studies were conducted in normal gravity.

Dietrich, Daniel L.↗

Parameterization of Aerosol Sinks in Chemical Transport Models

The modelers point of view is that the aerosol problem is one of sources, evolution, and sinks. Relative to evolution and sink processes, enormous attention is given to the problem of aerosols sources, whether inventory based (e.g., fossil fuel emissions) or dynamic (e.g., dust, sea salt, biomass burning). On the other hand, aerosol losses in models are a major factor in controlling the aerosol distribution and lifetime. Here we shine some light on how aerosol sinks are treated in modern chemical transport models. We discuss the mechanisms of dry and wet loss processes and the parameterizations for those processes in a single model (GEOS-5). We survey the literature of other modeling studies. We additionally compare the budgets of aerosol losses in several of the ICAP models.

Colarco, Peter↗

Sensitivity of Mesoscale Modeling of Smoke Direct Radiative Effect to the Emission Inventory: a Case Study in Northern Sub-Saharan African Region

An ensemble approach is used to examine the sensitivity of smoke loading and smoke direct radiative effect in the atmosphere to uncertainties in smoke emission estimates. Seven different fire emission inventories are applied independently to WRF-Chem model (v3.5) with the same model configuration (excluding dust and other emission sources) over the northern sub-Saharan African (NSSA) biomass-burning region. Results for November and February 2010 are analyzed, respectively representing the start and end of the biomass burning season in the study region. For February 2010, estimates of total smoke emission vary by a factor of 12, but only differences by factors of 7 or less are found in the simulated regional (15degW-42degE, 13degS-17degN) and monthly averages of column PM(sub 2.5) loading, surface PM(sub 2.5) concentration, aerosol optical depth (AOD), smoke radiative forcing at the top-of-atmosphere and at the surface, and air temperature at 2 m and at 700 hPa. The smaller differences in these simulated variables may reflect the atmospheric diffusion and deposition effects to dampen the large difference in smoke emissions that are highly concentrated in areas much smaller than the regional domain of the study. Indeed, at the local scale, large differences (up to a factor of 33) persist in simulated smoke-related variables and radiative effects including semi-direct effect. Similar results are also found for November 2010, despite differences in meteorology and fire activity. Hence, biomass burning emission uncertainties have a large influence on the reliability of model simulations of atmospheric aerosol loading, transport, and radiative impacts, and this influence is largest at local and hourly-to-daily scales. Accurate quantification of smoke effects on regional climate and air quality requires further reduction of emission uncertainties, particularly for regions of high fire concentrations such as NSSA.

Sahel and sub-Saharan African region↗