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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

A Composite Damage Tolerance Simulation Technique to Augment the Building Block Approach

Aerospace structures comprised of composite materials are traditionally certified empirically via the Building Block Approach (BBA). While this approach has been performed successfully in the past, it is expensive and time consuming. One means to improve the overall efficiency of composite structural certification is to reduce the cost of the BAA by eliminating the need for some tests by incorporating damage analysis tools. For an analysis to replace a given test, the tool must first be validated using other similar test data. The subject of this paper is a description of an analysis technique for simulating compression after damage strength of a solid laminate. The analysis technique is one that is practical for use in an applied engineering context due to efforts to minimize necessary computational resources and complexity of the model.

McElroy, Mark↗
NASA NTRS2019

A Composite Damage Tolerance Simulation Technique to Augment the Building Block Approach

Aerospace structures comprised of composite materials are traditionally certified empirically via the Building Block Approach (BBA). While this approach has been performed successfully in the past, it is expensive and time-consuming. One means to improve the overall efficiency of composite structural certification is to reduce the cost of the BBA by eliminating the need for some tests by incorporating damage analysis tools. For an analysis to replace a given test, the tool must first be validated using other similar test data. The subject of this paper is a description of an efficient analysis technique for simulating compression after damage strength of a solid laminate. The analysis technique is one that is practical for use in an applied engineering context due to efforts to minimize necessary computational resources and complexity of the model.

McElroy, Mack↗
DOE OSTI2023

ATRP Enhances Structural Correlations In Polymerization–Induced Phase Separation**

Synthetic methods to control the structure of materials at sub–micron scales are typically based on the self–assembly of structural building blocks with precise size and morphology. On the other hand, many living systems can generate structure across a broad range of length scales in one step directly from macromolecules, using phase separation. Here, we introduce and control structure at the nano– and microscales through polymerization in the solid state, which has the unusual capability of both triggering and arresting phase separation. In particular, we show that atom transfer radical polymerization (ATRP) enables control of nucleation, growth, and stabilization of phase–separated poly–methylmethacrylate (PMMA) domains in a solid polystyrene (PS) matrix. ATRP yields durable nanostructures with low size dispersity and high degrees of structural correlations. Furthermore, we demonstrate that the length scale of these materials is controlled by the synthesis parameters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Preliminary results in implementing a model of the world economy on the CYBER 205: A case of large sparse nonsymmetric linear equations

A brief description of the Model of the World Economy implemented at the Institute for Economic Analysis is presented, together with our experience in converting the software to vector code. For each time period, the model is reduced to a linear system of over 2000 variables. The matrix of coefficients has a bordered block diagonal structure, and we show how some of the matrix operations can be carried out on all diagonal blocks at once.

Szyld, D. B.↗
DOE OSTI2025

Structural complexity in the f -block: small deviations of the complexation of lanthanides by O,Oʹ -diethylmonothiophosphate

Dithiophosphinic acids undergo radiolytic degradation during the extraction of actinides in used nuclear fuel. These will degrade into monothiophosphinic acids and then to phosphinic acids. To elucidate how the complexes that are formed during these radioactive separations change as the ligand degrades, the mixed donor ligand O,O′- diethylmonothiophosphate is chosen as an analog for the monothiophosphinic intermediate. Herein, the monothiophosphate complexes Ln 2 (OPS(OEt) 2 ) 6 (H 2 O) 8 (Ln = La) (La 2 L 6 H 2 O), Ln 2 (OPS(OEt) 2 ) 6 (EtOH) 4 (Ln = La) (La 2 L 6 EtOH), K 2 [Ln(OPS(OEt) 2 ) 5 (H 2 O) 2 ]·H 2 O·CH 2 Cl 2 , (Ln = Ce) (CeL 5 -α), K 2 [Ln(OPS(OEt) 2 ) 5 (H 2 O) 2 ]·H 2 O·CH 2 Cl 2 , (Ln = Pr) (PrL 5 -β), K[Ln(OPS(OEt) 2 ) 4 (H 2 O) 3 ], (Ln = Pr, Sm-Er) (ML 4 ), and K 3 [Ln(OPS(OEt) 2 ) 6 ], (Ln = Dy) (DyL 6 ) were synthesized and characterized using single-crystal X-ray diffraction and optical spectroscopy. Although the lanthanides contract in a nearly linear fashion, the structural changes observed as the f-block is traversed in these compounds are not necessarily a hard line but more so a blend of different structure types possible for each f-element. Furthermore, comparison of the Ln−O bond lengths shows a nearly linear contraction, but the Ln−S bond lengths do not monotonically decrease because of the hard Lewis acidity of the Ln 3+ cations.

37 - INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL C↗
NASA NTRS1997

Bayesian Blocks: A New Method to Analyze Photon Counting Data

A Bayesian analysis of photon-counting data leads to a new time-domain algorithm for detecting localized structures (bursts), revealing pulse shapes, and generally characterizing intensity variations. The raw counting data -- time-tag events (TTE), time-to-spill (TTS) data, or binned counts -- is converted to a maximum likelihood segmentation of the observation into time intervals during which the photon arrival rate is perceptibly constant -- i.e. has a fixed intensity without statistically significant variations. The resulting structures, Bayesian Blocks, can be thought of as bins with arbitrary spacing determined by the data. The method itself sets no lower limit to the time scale on which variability can be detected. We have applied the method to RXTE data on Cyg X-1, yielding information on this source's short-time-scale variability.

Scargle, Jeffrey D.↗
NASA NTRS1995

Surface Micro-Machining: Progress Towards Micro-Electro Mechanical Systems

Surface micromachining is a technique for building electromechanical systems in silicon. A number of electromechanical systems have been implemented in miniature using the fundamental structural building blocks of tensile and non-tensile springs, differential capacitance sensing cells, and electrostatic drive. The integration of complicated mechanical structures and electrical circuits onto a single chip is expected to improve reliability and testability of systems. Reduction in interconnect wiring, the increased use of automation, and the inherent reliability of integrated circuits will all contribute to increased reliability of systems.

Doscher, James↗
DOE OSTI2023

Areal interpolation of population projections consistent with different SSPs from 1-km resolution to block level based on USA Structures dataset

Population data are normally collected at various census administrative levels, and areal interpolation of population is often required to transform population to the desired spatial resolution. Building footprint datasets, such as Microsoft building footprints, have proven to be useful in estimating population distribution and can therefore be used for areal interpolation of population. In addition to Microsoft building footprints, the recently released USA Structures dataset provides additional information such as building type and building height for some regions, which may provide valuable information for a better depiction of population distribution and improved population areal interpolation accuracy. In this study, we have conducted areal interpolation of population projections consistent with three different Shared Socioeconomic Pathways (SSP2, SSP3, and SSP5) from 1-km grid cells to block level in Washington state for every ten years from 2020 to 2040 based on USA Structures. We assessed USA Structures-based population downscaling accuracy using U.S. decennial survey data in 2020 under three different downscaling schemes, including population downscaling from census tracts to block groups, from census tracts to blocks, and from block groups to blocks. The resulting accuracies were compared with those based on Microsoft building footprints. The comparison showed that USA Structures achieved higher accuracies across different population density regions and areas with different urbanization extent within our study area.

99 GENERAL AND MISCELLANEOUS↗
NASA NTRS1989

Energetics examination of winter blocking simulations in the Northern Hemisphere

Four numerical simulations of the global atmosphere for January 1979 are analyzed to study the formation of blocking in terms of Northern Hemisphere energetics. The Goddard Laboratory for Atmospheres (GLA) 4 x 5 deg latitude-longitude grid general circulation model (GCM) and 2 x 2.5 deg grid GCM are employed with the GLA and Geophysical Fluid Dynamics Laboratory initial datasets. Among four simulations, the simulations by the high resolution GCM produce realistically strong blockings with compatible spectral energetics as in the observed blockings episodes. The latitude-height cross sections of the energy variables of wavenumber 1 is presented to describe the dipole structure of blockings. Blocking development is also examined in time series of barotropic and baroclinic components of energy and associated conversions.

Kung, Ernest C.↗
NASA NTRS1989

Kinematics and mechanics of tectonic block rotations

Paleomagnetic, structural geology, and rock mechanics data are combined to explore the validity of the block rotation concept and its significance. The analysis is based on data from (1) Northern Israel, where fault slip and spacing are used to predict block rotation; (2) the Mojave Desert, with well-documented strike-slip fault sets, organized in at least three major domains; (3) the Lake Mead, Nevada, fault system with well-defined sets of strike-slip faults, which, in contrast to the Mojave region, are surrounded with domains of normal faults; and (4) the San Gabriel Mountains domain with a multiple set of strike-slip faults. It is found that block rotations can have a profound influence on the interpretation of geodetic measurements and the inversion of geodetic data, especially the type collected in GPS surveys. Furthermore, block rotations and domain boundaries may be involved in creating the heterogeneities along active fault systems which are responsible for the initiation and termination of earthquake rupture.

Nur, Amos↗
DOE OSTI2021

A medium-range structure motif linking amorphous and crystalline states

Amorphous materials have no long-range order, but there are ordered structures at short range (2–5 Å), medium range (5–20 Å) and even longer length scales. While regular and semiregular polyhedra are often found as short-range ordering in amorphous materials, the nature of medium-range order has remained elusive. Consequently, it is difficult to determine whether there exists any structural link at medium range or longer length scales between the amorphous material and its crystalline counterparts. Moreover, an amorphous material often crystallizes into a phase of different composition, with very different underlying structural building blocks, further compounding the issue. Here, we capture an intermediate crystalline cubic phase in a Pd-Ni-P amorphous alloy and reveal the structure of the medium-range order, a six-membered tricapped trigonal prism cluster (6M-TTP) with a length scale of 12.5 Å. We find that the 6M-TTP can pack periodically to several tens of nanometres to form the cube phase. Our experimental observations provide evidence of a structural link between the amorphous and crystalline phases in a Pd-Ni-P alloy at the medium-range length scale and suggest that it is the connectivity of the 6M-TTP clusters that distinguishes the crystalline and amorphous phases. These findings will shed light on the structure of amorphous materials at extended length scales beyond that of short-range order.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Reversible Changes in the Grain Structure and Conductivity in a Block Copolymer Electrolyte

Here, we study the phase behavior of a triblock organic–inorganic hybrid copolymer, poly(polyhedral oligomeric silsesquioxane)-b-poly(ethylene oxide)-b-poly(polyhedral oligomeric silsesquioxane) (POSS-PEO-POSS)/lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt mixture, as a function of temperature. The polymer exhibits a lamellar morphology both in the neat state and in the presence of salt. However, the average grain size increases substantially when the electrolyte is heated above 113 °C. The grain structure of this sample changes reversibly with temperature, that is, smaller grains reappear when the electrolyte is cooled below 113 °C. While annealing block copolymers at high temperatures often leads to an increase in the grain size, this change is generally irreversible. The reason for the reversible change in the grain structure of the POSS-PEO-POSS/LiTFSI electrolyte is discussed. The ionic conductivity of the electrolyte also exhibits reversible changes in this temperature window. Knowledge of the grain structure is crucial for understanding ion transport in nanostructured electrolytes.

25 ENERGY STORAGE↗
NASA NTRS1993

Photogeological analysis of Europan tectonic features

Preliminary photogeological analyses of the Pelorus Linea and Sidon Flexus regions of Europa were conducted to explore the proposal by Schenk that lateral motion of crustal blocks has occurred in a 'rift zone' including possible strike-slip, tension fracturing, and geometric plate rotation about an Euler pole. These analyses revealed features interpreted as tensional structures and block rotation in a strike-slip regime consistent with the Schenk hypotheses and implied the presence of at least two stages of crustal deformation consistent with a chronology developed by Lucchitta. Confirmation of regional scale Euler pole rotation was ambiguous, however. Up to 80 kilometers of possible extension was identified in the rift zone; to accommodate this, 'cryosubduction' is speculatively proposed as a mechanism for recycling Europan 'ice lithosphere'. The cumulative width of wedge-shaped bands included in the rift zone was measured and plotted versus distance from the inferred rotation pole. Three sharp decreases in the total width were noted. These occur roughly where certain triple bands cross the rift zone suggesting that the bands are structural features that predate and influence the zone. While the curve hints at one or more sinusoidal relationships consistent with rotation geometry, given the low photographic resolution and the preliminary nature of this examination the question of whether the observations represent coherent regional rotation modified by crosscutting structures or instead imply independent local rotations separated by these structures is unanswered by this analysis.

Tufts, B. R.↗
NASA NTRS1988

The CSM testbed matrix processors internal logic and dataflow descriptions

This report constitutes the final report for subtask 1 of Task 5 of NASA Contract NAS1-18444, Computational Structural Mechanics (CSM) Research. This report contains a detailed description of the coded workings of selected CSM Testbed matrix processors (i.e., TOPO, K, INV, SSOL) and of the arithmetic utility processor AUS. These processors and the current sparse matrix data structures are studied and documented. Items examined include: details of the data structures, interdependence of data structures, data-blocking logic in the data structures, processor data flow and architecture, and processor algorithmic logic flow.

Regelbrugge, Marc E.↗
NASA NTRS2022

Atomic-Scale Structure and Non-Stoichiometry of Meteoritic Hibonite: A Transmission Electron Microscope Study

Hibonite (CaAl_12O_19) is a common refractory mineral in Ca-Al-rich inclusions (CAIs) in primitive meteorites. Transmission electron microscope (TEM) studies have identified enigmatic planar defects in different occurrences of hibonite in the Allende meteorite that give rise to strong streaking along c* in electron diffraction patterns. Atomic resolution high-angle annular dark-field (HAADF) imaging and energy-dispersive X-ray (EDX) analyses were used to determine the nature and origin of these planar features. HAADF images of hibonite grains reveal lamellar intergrowths of common 1.6 nm spacing, and less commonly 2.0 and 2.5 nm spacings, interspersed in stoichiometric hibonite showing 1.1 nm (002) spacing. Stoichiometric hibonite consists of alternating Ca-containing (“R”) and spinel-structured (“S”) blocks stacked in a sequence RS. In contrast, the 1.6 nm layers result from a doubled S block such that the stacking sequence is RSS, while in the widest defect observed, the stacking sequence is RSSSS. These intergrowths are epitaxial and have coherent, low-strain boundaries with the host hibonite Meteoritic hibonite shows common Ti and Mg substitution for Al in its structure. Atomic-resolution EDX maps of hibonite grains in the Allende CAI confirm the preferred site occupancy of Mg on tetragonal M3 sites in S blocks and of Ti on trigonal bipyramidal M2 and octahedral M4 sites in R blocks. Mg is highly concentrated, but Ti is absent in the planar defects where wider S blocks show Al-rich compositions compared to stoichiometric MgAl_2O_4 spinel. Therefore, Mg likely played the major role in the formation and metastability of planar defects in hibonite. Electron energy loss spectroscopy data from the Ti L_2,3 edge show the presence of mixed Ti oxidation states with ~ 15–20% of Ti as Ti^(3+) in hibonite, suggesting a direct substitution of Ti^(3+) ↔ Al^(3+) in hibonite. The remaining ~ 80–85% of Ti is present as Ti^(4+) and corresponding EDX analyses are consistent with the well-known coupled substitution 2Al^(3+) ↔ Ti^(4+) + Mg^(2+) being the major mechanism for Ti and Mg substitution in hibonite. The formation of planar defects in hibonite occurred during high-temperature nebular condensation or melting/crystallization processes. The occurrence of non-stoichiometric hibonite in the Allende CAI deviates from the mineral formation sequence predicted from equilibrium condensation models. Overall, our atomic resolution TEM observations signify non-equilibrium, kinetic-controlled crystal growth during the high-temperature formation of refractory solids in the early solar nebula.

hibonite↗
DOE OSTI2023

Thermodynamic Basis for the Stabilization of Helical Peptoids by Chiral Sidechains

Peptoids are a class of highly customizable biomimetic foldamers that retain properties from both proteins and polymers. It has been shown that peptoids can adopt peptide-like secondary structures through the careful selection of sidechain chemistries, but the underlying conformational landscapes that drive these assemblies at the molecular level remain poorly understood. Given the high flexibility of the peptoid backbone, it is essential that methods applied to study peptoid secondary structure formation possess the requisite sensitivity to discriminate between structurally similar yet energetically distinct microstates. In this work, a generalizable simulation scheme is used to robustly sample the complex folding landscape of various 12mer polypeptoids, resulting in a predictive model that links sidechain chemistry with preferential assembly into one of 12 accessible backbone motifs. Using a variant of the metadynamics sampling method, four peptoid dodecamers are simulated in water: sarcosine, N-(1-phenylmethyl)glycine (Npm), (S)-N-(1-phenylethyl)glycine (Nspe), and (R)-N-(1-phenylethyl)glycine (Nrpe)–to determine the underlying entropic and energetic impacts of hydrophobic and chiral peptoid sidechains on secondary structure formation. Our results indicate that the driving forces to assemble Nrpe and Nspe sequences into polyproline type-I helices in water are found to be enthalpically driven, with small benefits from an entropic gain for isomerization and steric strain due to the presence of the chiral center. The minor entropic gains from bulky chiral sidechains in Nrpe- and Nspe-containing peptoids can be explained through increased configurational entropy in the cis state. However, overall assembly into a helix is found to be overall entropically unfavorable. Furthermore, these results highlight the importance of considering the many various competing interactions in the rational design of peptoid secondary structure building blocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2000

Parameterization of Model Validating Sets for Uncertainty Bound Optimizations

Given measurement data, a nominal model and a linear fractional transformation uncertainty structure with an allowance on unknown but bounded exogenous disturbances, easily computable tests for the existence of a model validating uncertainty set are given. Under mild conditions, these tests are necessary and sufficient for the case of complex, nonrepeated, block-diagonal structure. For the more general case which includes repeated and/or real scalar uncertainties, the tests are only necessary but become sufficient if a collinearity condition is also satisfied. With the satisfaction of these tests, it is shown that a parameterization of all model validating sets of plant models is possible. The new parameterization is used as a basis for a systematic way to construct or perform uncertainty tradeoff with model validating uncertainty sets which have specific linear fractional transformation structure for use in robust control design and analysis. An illustrative example which includes a comparison of candidate model validating sets is given.

Lim, K. B.↗