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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Gallium-bearing sphalerite in a metal-sulfide nodule of the Qingzhen (EH3) chondrite

The composition and possible history of the Qingshen (EH3) chondrite is presented. The chondrite contains a population of spheroidal metal-sulfide nodules, which display textural evidence of reheating and melting. Evidence of metal sulfuration is also present, suggesting replacement of metal by sulfide during melting. This process has led to the nucleation of perryite along metal-sulfide interfaces. The Ga-bearing sphalerite that was found may have formed by injection of molten sulfide droplets into the metal followed by subsolidus diffusion of Ga from the metal into the sulfide. The latter may occur because of Ga supersaturation in the metal during progressive sulfuration and its decreased affinity for the metal phase during cooling below the taenite-kamacite transition point.

Rambaldi, E. R.↗
NASA NTRS1987

On Lipschitz continuity of nonlinear differential operators

In connection with approximations for nonlinear evolution equations, it is standard to assume that nonlinear terms are at least locally Lipschitz continuous. However, it is shown here that f = f(X,del sub u(X)) is Lipschitz continuous from the subspace W sup 1, infinity is a subset of L sub 2 into W sup 1,2, and maps W sup 2, infinity into W sup 1, infinity, if and only if f is affine with W sup 1, infinity coefficients. In fact, a local version of this claim is proved.

Keeling, Stephen L.↗
NASA NTRS1986

Teleparallelism as a universal connection on null hypersurfaces in general relativity

It is shown that a close relationship between the inner geometry of a null hypersurface N3 and the Newman-Penrose (NP) (1962, 1963) spin coefficient formalism exists. Projecting the null complex NP tetrad onto N3, two triads of basis vectors in N3 are obtained. The inner geometry of N3 is based on the assumption that these vectors are parallelly transported along the surface; this gives rise to the teleparallel connection as a metric nonsymmetric affine connection. The gauge freedom for the choice of the basis triads is given by the isotropy subgroup of the local Lorentz group leaving invariant the direction of the null generators of N3, and teleparallelism is determined by the equivalence class of the basis triads with respect to the global gauge group. Nine of the twelve NP coefficients are identified as the triad components of the torsion and the second fundamental form of N3. The resulting generalized Gauss-Codazzi equations are identical to nine of the NP equations, i.e., to the half of the Ricci identities. This result gives a geometrical meaning to the entire formalism. Finally a general proof of Penrose's theorem that the shear of the null generators of N3 is the only initial null datum for a gravitational field on N3 is presented.

Mazur, P. O.↗
NASA NTRS1986

Differential partition of virulent Aeromonas salmonicida and attenuated derivatives possessing specific cell surface alterations in polymer aqueous-phase systems

Two-polymer aqueous-phase systems in which partitioning of biological matter between the phases occurs according to surface properties such as hydrophobicity, charge, and lipid composition are used to compare the surface properties of strains of the fish pathogen Aeromonas salmonicida. The differential ability of strains to produce a surface protein array crucial to their virulence, the A layer, and to produce smooth lipopolysaccharide is found to be important in the partitioning behavior of Aeromonas salmonicida. The presence of the A layer is shown to decrease the surface hydrophilicity of the pathogen, and to increase specifically its surface affinity for fatty acid esters of polyethylene glycol. The method has application to the analysis of surface properties crucial to bacterial virulence, and to the selection of strains and mutants with specific surface characteristics.

Van Alstine, J. M.↗
NASA NTRS1986

Brans-Dicke-type models with nonmetricity

A scalar-tensor-nonmetric theory of gravity without matter fields is shown to be equivalent to the scalar-tensor-torsion theory proposed by German, the only difference being in the source of the Weyl vector or torsion vector (for equivalently the scalar field) which remains arbitrary in the theory. General extended conformal transformations, which leave the curvature tensor invariant, are presented and their implications for metric-affine theories and scalar-tensor theories are discussed.

Smalley, L. L.↗
NASA NTRS1987

Large-scale fluctuations in the interplanetary medium

Power spectra of measurements of the magnetic field strength in the heliosphere obtained by Voyager 1 between 1 AU and 9 AU have the form of a power law f exp -a from periods of several hours to at least 6 days. The exponent was a = 2.0 + or - 0.05 for all of the spectra considered, which is the exponent for a series of steps and for Burgers' (1971) turbulence. Spectra of large-scale speed fluctuations also have the form f exp - b from a period of a few hours to periods greater than 13 days in the region from 1 AU to 8.9 AU. The exponent b is generally somewhat larger than b = 2, implying some 'persistence' of the speed fluctuations. The low-frequency cutoff (outer cutoff) of the power law increases from a period of 6.5 days at 1 AU to 26 days at (6.1-8.9) AU, which can be attributed to: (1) the coalescence of interaction regions and (2) a transfer of energy from the spectrum of large-scale speed fluctuations. The outer cutoff of the spectrum of speed fluctuations increases from a period of 13 days at 1 AU to 26 days between a few AU and 8.9 AU. Both the magnetic field strength fluctuations and the speed fluctuations have fractal behavior, suggesting that they are self affine rather than dominated by a few large discontinuities.

Burlaga, L. F.↗
NASA NTRS1987

On the presolar origin of the 'normal planetary' noble gas component in meteorites

Several components of planetary noble gases, including CCFXe (Xe-X), s-process Kr and Xe, and Ne-E, are now thought to have had a presolar origin. It is proposed that the 'normal planetary' noble gas component, which contains most of the planetary Ar, Kr, and Xe, is also presolar. This component was trapped in carbonaceous mantles as the mantles formed on grain surfaces in the molecular cloud. The presolar dust grains and their carbonaceous mantles were then incorporated into primitive meteorites. This model naturally explains: (1) the affinity of 'normal planetary' noble gases for carbonaceous material in primitive chondrites; (2) the near absence of He and Ne in the 'normal planetary' component; (3) the elemental fractionation patterns of the 'exotic' and 'normal planetary' components; (4) the similarity of the isotopic compositions of 'normal planetary' and trapped solar Ar, Kr, and Xe; (5) the high noble gas content of the 'normal planetary' gas carrier; (6) several aspects of the chemistry of the 'normal planetary' gas carrier; (7) the correlation of planetary noble gases with the fine-grained material in primitive chondrites; and (8) the widespread occurrence of the planetary fractionation pattern throughout the solar system.

Huss, Gary R.↗
NASA NTRS1987

Mixed Cu-simple metal dimers and trimers - CuLi, CuLi2, CuNa, CuK, CuBe, CuBe2, Cu2Be, CuAl, and CuAl2

Theoretical studies of selected diatomic and triatomic molecules containing copper and the simple metals Li, Na, K, Be, and Al are presented, with emphasis on elucidating the nature of the bonding in mixed transition metal-simple metal systems. Large Gaussian basis sets are used in the diatomic calculations, and are used to calibrate the triatomic calculations, in which somewhat smaller Gaussian basis sets are employed. Electron correlation is incorporated using both the single-reference singles plus doubles configuration interaction and coupled pair functional methods. It is found that alkali atoms form very polar sigma bonds with copper, and that the ionicity increases with the inclusion of higher excitations because they improve the electron affinity of copper, which in turn allows a larger negative charge on copper. Aluminum is found to form stronger bonds than beryllium, since it does not have to undergo sp hybridization. Some of the trimers bond by forming three-center three-electron bonds. These multicenter bonds are quite strong even when compared to the two-electron bonds in the dimers or to other bonding mechanisms in the trimers.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1987

Cell model and elastic moduli of disordered solids - Low temperature limit

The cell theory has been previously employed to compute the equation of state of a disordered condensed system. It is now generalized to include anisotropic stresses. The condition of affine deformation is adopted, transforming an orginally spherical into an ellipsoidal cell. With a Lennard-Jones n-m potential between nonbonded centers, the formal expression for the deformational free energy is derived. It is to be evaluated in the limit of the linear elastic range. Since the bulk modulus in this limit is already known, it is convenient to consider a uniaxial deformation. To begin with, restrictions are made to the low-temperature limit in the absence of entropy contributions. Young's modulus and Poisson's ratio then follow.

Peng, S. T. J.↗
NASA NTRS1987

The biogeochemical cycle of the adsorbed template. I - formation of the template

Experimental results are presented for the verification of the first adsorption step of the 'adsorbed template' biogeochemical cycle, a simple model for a primitive prebiotic replication system. The adsorption of Poly-C, Poly-U, Poly-A, Poly-G, and 5'-AMP, 5'-GMP, 5'-CMP and 5'-UMP onto gypsum was studied. It was found that under the conditions of the experiment, the polymers have a very high affinity for the mineral surface, while the monomers adsorb much less efficiently.

Lazard, Daniel↗
NASA NTRS1987

Physical properties of immiscible polymers

The demixing of immiscible polymers in low gravity is discussed. Applications of knowledge gained in this research will provide a better understanding of the role of phase segregation in determining the properties of polymer blends made from immiscible polymers. Knowledge will also be gained regarding the purification of biological materials by partitioning between the two liquid phases formed by solution of the polymers polyethylene glycol and dextran in water. Testing of new apparatus for space flight, extension of affinity phase partitioning, refinement of polymer chemistry, and demixing of isopycnic polymer phases in a one gravity environment are discussed.

Harris, J. Milton↗
NASA NTRS1987

Monte Carlo modeling and meteor showers

Prediction of short lived increases in the cosmic dust influx, the concentration in lower thermosphere of atoms and ions of meteor origin and the determination of the frequency of micrometeor impacts on spacecraft are all of scientific and practical interest and all require adequate models of meteor showers at an early stage of their existence. A Monte Carlo model of meteor matter ejection from a parent body at any point of space was worked out by other researchers. This scheme is described. According to the scheme, the formation of ten well known meteor streams was simulated and the possibility of genetic affinity of each of them with the most probable parent comet was analyzed. Some of the results are presented.

Kulikova, N. V.↗
NASA NTRS1988

Nature and origin of mineral coatings on volcanic rocks of the Black Mountain, Stonewall Mountain, and Kane Springs Wash volcanic centers, Southern Nevada

Comparative lab spectra and Thematic Mapper imagery investigations at 3 Tertiary calderas in southern Nevada indicate that desert varnish is absorbant relative to underlying host rocks below about 0.7 to 1.3 microns, depending on mafic affinity of the sample, but less absorbant than mafic host rocks at higher wavelengths. Desert varnish occurs chiefly as thin impregnating films. Distribution of significant varnish accumulations is sparse and localized, occurring chiefly in surface recesses. These relationships result in the longer wavelength bands and high 5/2 values over felsic units with extensive desert varnish coatings. These lithologic, petrochemical, and desert varnish controlled spectral responses lead to characteristic TM band relationships which tend to correlate with conventionally mappable geologic formations. The concept of a Rock-Varnish Index (RVI) is introduced to help distinguish rocks with a potentially detectable varnish. Felsic rocks have a high RVI, and those with extensive desert varnish behave differently, spectrally, from those without extensive varnish. The spectrally distinctive volcanic formations at Stonewall Mountain provide excellent statistical class segregation on supervised classification images. A binary decision rule flow-diagram is presented to aid TM imagery analysis over volcanic terrane in semi-arid environments.

Taranik, James V.↗
NASA NTRS1988

The electrokinetic behavior of calcium oxalate monohydrate in macromolecular solutions

Electrophoretic mobilities were measured for calcium oxalate monohydrate (COM) in solutions containing macromolecules. Two mucopolysaccharides (sodium heparin and chrondroitin sulfate) and two proteins (positively charged lysozyme and negatively charged bovine serum albumin) were studied as adsorbates. The effects of pH, calcium oxalate surface charge (varied by calcium or oxalate ion activity), and citrate concentration were investigated. All four macromolecules showed evidence for chemical adsorption. The macromolecule concentrations needed for reversing the surface charge indicated that the mucopopolysacchrides have greater affinity for the COM surface than the proteins. The amount of proteins that can chemically adsorb appears to be limited to approximately one monomolecular layer. When the surface charge is high, an insufficient number of proteins can chemically adsorb to neutralize or reverse the surface charge. The remaining surface charge is balanced by proteins held near the surface by longer range electrostatic forces only. Citrate ions at high concentrations appear to compete effectively with the negative protein for surface sites but show no evidence for competing with the positively charged protein.

Curreri, P. A.↗
NASA NTRS1988

Two puzzling aspects of protein crystal growth

A study is presented of several mechanisms which may reduce crystal growth rates and or terminate crystal growth. It is found that salt gradients which change the local chemical potential of the protein are insufficient to account for the slow crystal growth rates which have been reported. Contaminants which adsorb protein from solution may reduce the effective protein concentration, but the impurity's concentration and its affinity for protein are unknown. Association of protein molecules in bulk solution can reduce the monomer concentration significantly, but extant theory and experiment are not sensitive enough to determine the actual concentration of aggregates in solution. For systems of interest, shear-induced effects were found to be too weak to interfere with normal binding of incoming protein molecules. Although we found that most crystal growth occurs in a regime where both interfacial kinetics and diffusion influence crystal growth, the role of mass transfer rates on the terminal size of crystals is unknown, primarily because no data exist which cover the size range of interest (0.1 mm to 1 mm in length).

Grant, M. L.↗
NASA NTRS1984

Separation of cells from the rat anterior pituitary gland

Data concerned with analyzing the cellular organization of the rat anterior pituitary gland are examined. The preparation of the cell suspensions and the methods used to separate pituitary cell types are described. Particular emphasis is given to velocity sedimentation at unit gravity, density gradient centrifugation, affinity methods, fluorescence activated cell sorting, and density gradient and continuous-flow electrophoresis. The difficulties encountered when attempting to compare data from different pituitary cell separation studies are discussed, and results from various experiments are presented. The functional capabilities of the separated cell populations can be tested in various culture systems.

Hymer, W. C.↗
NASA NTRS1988

Similarity for high angle-of-attack subsonic/transonic slender-body aerodynamics

The work of Sychev (1960) is extended to sharp-edged wings and smooth bodies. A simple fit to the correlations based on the Polhamus (1966) suction analogy is shown for several affine families of bodies with elliptical cross sections. The results suggest that simple models for nonlinear subsonic/transonic flows over not-so-slender wings and bodies can be obtained from a combination of well-known linear-theory models for the attached flow and slender-body concepts for the vortical flow.

Hemsch, M. J.↗
NASA NTRS1987

Compositional evidence regarding the origins of rims on Semarkona chondrules

This paper presents results on neutron activation analyses of the interiors and the abraded surfaces of seven chondrules from Semarkona chondrite. The results showed that six of seven chondrule rims have enhanced contents of siderophiles and chalcophiles relative to chondrule interiors, indicating that, during chondrule formation, metal/sulfide melts migrated to the exterior of the chondrule; later reheating caused this material to spread out into fine-grained rim material. For nonvolatile elements, the lithophile and siderophile element abundance patterns in the surfaces are generally similar to those in the corresponding interiors, indicating that the surface and the interior metal might have originated from a single precursor. The volatile to moderately-volatile elements K, As, and Zn tend to be enriched in the surface, compared with other elements of similar mineral affinity.

Grossman, Jeffrey N.↗