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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Adaptive critic design-based reinforcement learning approach in controlling virtual inertia-based grid-connected inverters

In this report, an adaptive critic design (ACD) approach is proposed to control the phase and voltage of a grid-connected virtual synchronous generator (VSG). The penetration of fast responding inertia-less power converters significantly affect the stability of the power system, especially weak systems such as micro grids. The concept of virtual inertia addresses this concern by virtually emulating the behavior of a synchronous generator. However, the conventional VSG is designed based on two conditions: (i) fixed operating point and (ii) inductive grid connections. The performance of VSGs in low-voltage semi-resistive microgrids is far from optimal. To overcome the aforementioned concerns, a heuristic dynamic programing (HDP) approach is proposed to optimally control grid-connected VSGs. The neural-network-based inherence of the HDP enables the proposed technique to adapt to any impedance angle. The HDP controller includes two subnetworks: (i) the action network that controls the system optimally and (ii) the critic network, which evaluates the effectiveness of the action network. The simulation and experimental results are provided to evaluate the effectiveness of the proposed technique. As shown, the HDP-based approach illustrates a better performance in comparison with the conventional PI-based VSG in various operating conditions.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

High-Gradient Wien Spin Rotators at Jefferson Lab

Nuclear physics experiments performed in the Continuous Electron Beam Accelerator Facility (CEBAF) at Jefferson Laboratory (JLab) require spin manipulation of electron beams. Two Wien spin rotators in the injector keV region are essential at CEBAF to establish longitudinal polarization at the end station target, and to flip the polarization direction by ? rad to rule out false asymmetries. In a Wien filter, the homogeneous and independent electric and magnetic fields, along with the velocity vectors of the electrons that traverse it, form a mutually orthogonal system. The magnitude of the electrostatic field, established by biasing two highly-polished electrodes, defines the desired spin angle at the target yet deviates the beam trajectory due to the Lorentz force. The beam trajectory in the Wien is then re-established by adjusting the magnetic field, induced by an electromagnet encasing the device vacuum chamber. This contribution describes the evolution design and high voltage testing of Wien filters for spin manipulation at increased beam energies in the keV injector region, required by high precision parity violation experiments like MOLLER.

Palacios Serrano, G. G.↗
DOE OSTI2022

High-Gradient Wien Spin Rotators at Jefferson Lab

Nuclear physics experiments performed in the Continuous Electron Beam Accelerator Facility (CEBAF) at Jefferson Laboratory (JLab) require spin manipulation of electron beams. Two Wien spin rotators in the injector keV region are essential at CEBAF to establish longitudinal polarization at the end station target, and to flip the polarization direction by ? rad to rule out false asymmetries. In a Wien filter, the homogeneous and independent electric and magnetic fields, along with the velocity vectors of the electrons that traverse it, form a mutually orthogonal system. The magnitude of the electrostatic field, established by biasing two highly-polished electrodes, defines the desired spin angle at the target yet deviates the beam trajectory due to the Lorentz force. The beam trajectory in the Wien is then re-established by adjusting the magnetic field, induced by an electromagnet encasing the device vacuum chamber. This contribution describes the evolution design and high voltage testing of Wien filters for spin manipulation at increased beam energies in the keV injector region, required by high precision parity violation experiments like MOLLER.

Palacios Serrano, G. G.↗
DOE OSTI2023

Synergizing a Large Ordinary Nernst Effect and Axis‐Dependent Conduction Polarity in Flat Band KMgBi Crystals

The exploration of quantum materials in which an applied thermo/electrical/magnetic field along one crystallographic direction produces an anisotropic response has led to unique functionalities. Along these lines, KMgBi is a layered, narrow gap semiconductor near a critical state between multiple Dirac phases due to the presence of a flat band near the Fermi level. The valence band is highly anisotropic with minimal cross-plane dispersion, which, in combination with an isotropic conduction band, enables axis-dependent conduction polarity. Thermopower and Hall measurements indicate dominant p-type conduction along the cross-plane direction, and n-type conduction along the in-plane direction, leading to a significant zero-field transverse thermoelectric response when the heat flux is at an angle to the principal crystallographic directions. Additionally, a large Ordinary Nernst effect (ONE) is observed with an applied field. It arises from the ambipolar term in the Nernst effect, whereby the Lorentz force on electrons and holes makes them drift in opposite directions so that the resulting Nernst voltage becomes a function of the difference between their partial thermopowers, greatly enhancing the ONE. It is proven that axis-dependent polarity can synergistically enhance the ONE, in addition to leading to a zero-field transverse thermoelectric performance.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Voltage waveform tailoring for high aspect ratio plasma etching of SiO 2 using Ar/CF 4 /O 2 mixtures: Consequences of low fundamental frequency biases

The use of non-sinusoidal waveforms in low pressure capacitively coupled plasmas intended for microelectronics fabrication has the goal of customizing ion and electron energy and angular distributions to the wafer. One such non-sinusoidal waveform uses the sum of consecutive harmonics of a fundamental sinusoidal frequency, f 0 , having a variable phase offset between the fundamental and even harmonics. In this paper, we discuss results from a computational investigation of the relation between ion energy and DC self-bias when varying the fundamental frequency f 0 for capacitively coupled plasmas sustained in Ar/CF 4 /O 2 and how those trends translate to a high aspect ratio etching of trenches in SiO 2 . The fundamental frequency, f 0 , was varied from 1 to 10 MHz and the relative phase from 0° to 180°. Two distinct regimes were identified. Average ion energy onto the wafer is strongly correlated with the DC self-bias at high f 0 , with there being a maximum at φ = 0° and minimum at φ = 180°. In the low frequency regime, this correlation is weak. Average ion energy onto the wafer is instead dominated by dynamic transients in the applied voltage waveforms, with a maximum at φ = 180° and minimum at φ = 0°. The trends in ion energy translate to etch properties. In both, the high and low frequency regimes, higher ion energies translate to higher etch rates and generally preferable final features, though behaving differently with phase angle.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Tailoring P2/P3‐Intergrowth in Manganese‐Based Layered Transition Metal Oxide Positive Electrodes via Sodium Content for Na‐Ion Batteries

High-manganese content sodium-ion positive electrodes have received heightened interest as an alternative to contemporary Li-ion chemistries due to their high abundance, low toxicity, and even geographical distribution. However, these materials typically suffer from poor capacity, unstable cycling performance, and sluggish Na + kinetics. Herein, we explore a manganese-based layered transition metal oxide (Na x N 0.25 Mn 0.75 O 2 ) and show by X-ray diffraction (XRD) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) that careful variation of the sodium content can instigate the formation of a biphasic intergrowth. This intergrown P2/P3 material offered a higher capacity than its monophasic P2 counterpart due to the P3 structure having greater low-voltage Mn 3+/4+ redox. Further, the intergrowth material offers greatly enhanced kinetics and cycling stability when compared to single-phase P3 material, due to the stabilizing nature of the P2 structure, elucidated by galvanostatic intermittent titration technique (GITT) and operando synchrotron X-ray diffraction. These results highlight the beneficial effect that the intergrowth structure has on the electrochemical performance of high-manganese content positive electrode for future sodium-ion batteries.

25 ENERGY STORAGE↗
NASA NTRS1987

The design and operating characteristics of an advanced 30-kW ammonia arcjet engine

Experimental investigations were conducted to evaluate the effects of a contoured nozzle and modified cathode shape on ammonia arcjet engine performance. The contoured nozzle performance data were compared to the performance data of an arcjet which had a 38-deg included-angle, conical nozzle. Thrust improvements of up to 10 percent were demonstrated which corresponded to 3 percent improvements in specific impulse and 10 percent improvements in thrust efficiency. Performance characterizations for the modified cathode tip were conducted with the contoured nozzle arcjet. A uniform 15 percent decrease in arc voltage was demonstrated over a mass flow range of 0.175 to 0.350 g/s. A 4 percent improvement in thrust efficiency was noted at 22.0 kW.

Deininger, William D.↗
NASA NTRS1980

Propagation of charge-exchange plasma produced by an ion thruster

A charge-exchange plasma is produced downstream of ion thrusters by collisions between energetic ions and neutrals escaping through the ion optics. The charge-exchange ions flow radially from the thruster beam due to electric fields produced by its density gradient. The propagation of the charge-exchange plasma after it leaves the thruster beam is the subject of this paper. Under the proper conditions there is an 'end-effect' of a long, cylindrical Langmuir probe which allows a significant increase in collected ion current when the probe is aligned with a flowing plasma. This effect is used to determine the charge-exchange plasma flow direction at various locations relative to the ion thruster. A portion of the charge-exchange plasma flows upstream of the ion thruster and can represent a contamination source to electrically propelled spacecraft. The ion current collected by the probe as a function of its angle with respect to the plasma flow allows determination of the plasma density and plasma flow velocity at the probe's location upstream of the ion thruster optics. The density value obtained from the ion current agree to within a factor of two of density values obtained by typical voltage-current Langmuir probe characteristics.

Carruth, M. R., Jr.↗
NASA NTRS1981

Propagation of charge-exchange plasma produced by an ion thruster

Under the proper conditions there is an end-effect of a long, cylindrical Langmuir probe which allows a significant increase in collected ion current when the probe is aligned with a flowing plasma. This effect was used to determine the charge-exchange plasma flow direction at various locations relative to the ion thruster. The ion current collected by the probe as a function of its angle with respect to the plasma flow allows determination of the plasma density and plasma flow velocity at the probe's location upstream of the ion thruster optics. The density values obtained from the ion current agreed to within a factor of two of density values obtained by typical voltage-current Langmuir probe characteristics.

Carruth, M. R., Jr.↗
NASA NTRS1987

New techniques for the detection and capture of micrometeoroids

In order to understand the origin and distribution of the biogenic elements and their compounds in the solar system, it will be necessary to study materials from many classes of objects. Chemical, elemental, and isotopic measurements of returned samples of comets, asteroids, and possibly extra-solar system dust clouds would provide information on a particularly important class: primitive objects. Extraterrestrial micron-sized particles in the vicinity of Earth are one source of such materials that might otherwise be inaccessible. The Space Station appears to be an eminently suitable platform from which to collect and detect these various particles. The primary challenge, however, is to collect intact, uncontaminated particles which will be encountered at tens of kilometers per seconds. A concept for a micrometeoroid detector that could be deployed from the Space Station was developed which uses a large area detector plate implanted with acoustic transducers. When an impact event occurs, the resulting signal is subjected to spectral analysis providing positive detection, momentum information, and angle of incidence. The primary advantage of this detector is the large area which increases the probability of measuring events. A concept of a nondestuctive micrometeoroid collector for use from a Space Station was also developed. The collector utilizes input port charging of the incoming particle followed by staged high voltage deceleration for nondestructive capture. Low velocity particles (local contamination) would be rejected due to insufficient energy and only uncontaminated micrometeoroids would be collected.

Wolfe, J. H.↗
NASA NTRS1992

The formation and structure of plasma wakes behind large high-voltage space platforms in ionosphere

Theory and particle simulation results are presented for ionospheric plasma flow over space platforms in the large-dimension and high-voltage range. Both the transient formation of the space-charge wake and its steady state structure are studied. The wake-side ion impact and current collection are obtained. It is found that the wake behind a high-voltage plate is characterized by two ion-rich sheaths embedded in a quasi-neutral background wake. The embedded sheath is formed by the ions passing through the sheath around the plate edge and serves as their trajectory path. Depending on the surface potential, the plate dimension, and the angle of attack, the embedded sheath may either extend downstream or curve back to the plate causing a high, localized ion flux density at the location it strikes.

Wang, J.↗
DOE OSTI2026

Detecting the full photoemission cone from laser-based ARPES experiments by leveraging deflector technology

Angle-resolved photoemission spectroscopy (ARPES) provides a direct access to the electronic band structure of solid and molecular systems. The momentum range accessible by this technique depends directly on the photon energy used, and low-photon-energy sources are insufficient to photoemit electrons over the full Brillouin zone of most quantum materials. In addition, while electrons are emitted over a 2π solid angle, conventional hemispherical analyzers only collect a small subset of those electrons. A previous work [Gauthier et al., Rev. Sci. Instrum. 92, 123907 (2021)] demonstrated that electrons emitted over a larger field-of-view can be acquired in one fixed configuration by accelerating them toward the analyzer with a bias voltage. Here, in this study, we extend this work by leveraging the deflector technology of novel ARPES hemispherical analyzers. We demonstrate the ability to detect all 2π photoemitted electrons in a fixed configuration for various materials, such as gold, cuprates, and transition-metal dichalcogenides. This approach is especially advantageous for time-resolved ARPES, as electron dynamics over a large momentum range can be accessed with identical measurement conditions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Electrically switchable metallic polymer metasurface device with gel polymer electrolyte

Abstract We present an electrically switchable, compact metasurface device based on the metallic polymer PEDOT:PSS in combination with a gel polymer electrolyte. Applying square-wave voltages, we can reversibly switch the PEDOT:PSS from dielectric to metallic. Using this concept, we demonstrate a compact, standalone, and CMOS compatible metadevice. It allows for electrically controlled ON and OFF switching of plasmonic resonances in the 2–3 µm wavelength range, as well as electrically controlled beam switching at angles up to 10°. Furthermore, switching frequencies of up to 10 Hz, with oxidation times as fast as 42 ms and reduction times of 57 ms, are demonstrated. Our work provides the basis towards solid state switchable metasurfaces, ultimately leading to submicrometer-pixel spatial light modulators and hence switchable holographic devices.

36 MATERIALS SCIENCE↗
NASA NTRS2000

Arc-Tangent Circuit for Continuous Linear Output

A device suitable for determining arc-tangent of an angle θ is provided. Circuitry generates a first square wave at a frequency ωt and a second square wave at the frequency ωt but shifted by a phase difference equal to the angle θ. A pulse width modulation signal generator processes the first and second square waves to generate a pulse width modulation signal having a frequency of rot and having a pulse width that is a function of the phase difference θ. The pulse width modulation signal is converted to a DC voltage that is a linear representation of the phase difference θ.

Dean C Alhorn↗
DOE OSTI2024

Voltage-induced modulation of interfacial ionic liquids measured using surface plasmon resonant grating nanostructures

We have used surface plasmon resonant metal gratings to induce and probe the dielectric response (i.e., electro-optic modulation) of ionic liquids (ILs) at electrode interfaces. Here, the cross-plane electric field at the electrode surface modulates the refractive index of the IL due to the Pockels effect. This is observed as a shift in the resonant angle of the grating (i.e., Δϕ), which can be related to the change in the local index of refraction of the electrolyte (i.e., Δnlocal). The reflection modulation of the IL is compared against a polar (D2O) and a non-polar solvent (benzene) to confirm the electro-optic origin of resonance shift. The electrostatic accumulation of ions from the IL induces local index changes to the gratings over the extent of electrical double layer (EDL) thickness. Finite difference time domain simulations are used to relate the observed shifts in the plasmon resonance and change in reflection to the change in the local index of refraction of the electrolyte and the thickness of the EDL. Simultaneously using the wavelength and intensity shift of the resonance enables us to determine both the effective thickness and Δn of the double layer. We believe that this technique can be used more broadly, allowing the dynamics associated with the potential-induced ordering and rearrangement of ionic species in electrode–solution interfaces.

Chemistry↗
DOE OSTI2020

Water Freezes at Near-Zero Temperatures Using Carbon Nanotube-Based Electrodes under Static Electric Fields

Although static electric fields have been effective in controlling ice nucleation, the highest freezing temperature ( T f ) of water that can be achieved in an electric field ( E ) is still uncertain. In this study, we performed a systematic study of the effect of an electric field on water freezing by varying the thickness of a dielectric layer and the voltage across it in an electrowetting system. Results show that T f first increases sharply with E and then reaches saturation at –3.5 °C after a critical value E of 6 × 10 6 V/m. Using classical heterogeneous nucleation theory, it is revealed that this behavior is due to saturation in the contact angle of the ice embryo with the underlying substrate. Finally, we show that it is possible to overcome this freezing saturation by controlling the uniformity of the electric field using carbon nanotubes. We achieve a T f of –0.6 °C using carbon nanotube-based electrodes with an E of 3 × 10 7 V/m. This work sheds new light on the control of ice nucleation and has the potential to impact many applications ranging from food freezing to ice production.

25 ENERGY STORAGE↗
NASA NTRS2002

A Statistical Analysis of Laser Ablated Ba(Sub 0.50)Sr(Sub 0.50)TiO(Sub 3)/LaAlO(Sub 3) Films for Microwave Applications

The NASA Glenn Research Center is constructing a 616 element scanning phased array antenna using thin film Ba(sub x)Sr(sub 1-x)TiO(sub 3) based phase shifters. A critical milestone is the production of 616 identical phase shifters at 19 GHz with [asymptotically equal to]4 dB insertion loss and at least 337.5 deg phase shift with 3 percent bandwidth. It is well known that there is a direct relationship between dielectric tuning and loss due to the Kramers-Kronig relationship and that film crystallinity and strain, affected by the substrate template, play an important role. Ba(sub 0.50)Sr(sub 0.50)TiO (sub 3) films, nominally 400 nm thick, were deposited on 48 0.25 mm thick, 5 cm diameter LaAlO(sub 3) wafers. Although previous results suggested that Mn-doped films on MgO were intrinsically superior in terms of phase shift per unit loss, for this application phase shift per unit length was more important. The composition was selected as a compromise between tuning and loss for room temperature operation (e.g. crystallinity progressively degrades for Ba concentrations in excess of 30 percent). As a prelude to fabricating the array, it was necessary to process, screen, and inventory a large number of samples. Variable angle ellipsometry was used to characterize refractive index and film thickness across each wafer. Microstructural properties of the thin films were characterized using high resolution X-ray diffractometry. Finally, prototype phase shifters and resonators were patterned on each wafer and RE probed to measure tuning as a function of dc bias voltage as well as peak (0 field) permittivity and unloaded Q. The relationship among film quality and uniformity and performance is analyzed. This work presents the first statistically relevant study of film quality and microwave performance and represents a milestone towards commercialization of thin ferroelectric films for microwave applications.

Ferroelectric thin films↗
NASA NTRS2001

Preliminary Study of Electron Emission for Use in the PIC Portion of MAFIA

This memorandum summarizes a study undertaken to apply the program MAFIA to the modeling of an electron gun in a traveling wave tube (TWT). The basic problem is to emit particles from the cathode in the proper manner. The electrons are emitted with the classical Maxwell-Boltzmann (M-B) energy distribution; and for a small patch of emitting surface; the distribution with angle obeys Lambert's law. This states that the current density drops off as the cosine of the angle from the normal. The motivation for the work is to extend the analysis beyond that which has been done using older codes. Some existing programs use the Child-Langmuir, or 3/2 power law, for the description of the gun. This means the current varies as the 3/2 power of the anode voltage. The proportionality constant is termed the perveance of the gun. This is limited, however, since the 3/2 variation is only an approximation. Also, if the cathode is near saturation, the 3/2 law definitely will not hold. In most of the older codes, the electron beam is decomposed into current tubes, which imply laminar flow in the beam; even though experiments show the flow to be turbulent. Also, the proper inclusion of noise in the beam is not possible. These older methods of calculation do, however, give reasonable values for parameters of the electron beam and the overall gun, and these values will be used as the starting point for a more precise particle-in-cell (PIC) calculation. To minimize the time needed for a given computer run, all beams will use the same number of particles in a simulation. This is accomplished by varying the mass and charge of the emitted particles (macroparticles) in a certain manner, to be consistent with the desired beam current.

Freeman, Jon C.↗