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At least 271 records · Page 15

Uncertainty in Tropical Ocean Latent Heat Flux Variability During the Last 25 Years

When averaged over the tropical oceans (30deg N/S), latent heat flux anomalies derived from passive microwave satellite measurements as well as reanalyses and climate models driven with specified seal-surface temperatures show considerable disagreement in their decadal trends. These estimates range from virtually no trend to values over 8.4 W/sq m decade. Satellite estimates also tend to have a larger interannual signal related to El Nino/Southern Oscillation (ENSO) events than do reanalyses or model simulations. An analysis of wind speed and humidity going into bulk aerodynamic calculations used to derive these fluxes reveals several error sources. Among these are apparent remaining intercalibration issues affecting passive microwave satellite 10 m wind speeds and systematic biases in retrieval of near-surface humidity. Likewise, reanalyses suffer from discontinuities in availability of assimilated data that affect near surface meteorological variables. The results strongly suggest that current latent heat flux trends are overestimated.

Robertson, F. R.↗

Burst behavior of nuclear grade FeCrAl and Zircaloy-2 fuel cladding under simulated cyclic dryout conditions

A novel experiment to simulate cyclic dryout in boiling water reactors has been developed to better understand the performance of nuclear grade FeCrAl cladding in a BWR during dryout conditions caused by an Anticipated Operational Occurrence or Anticipated Transient Without SCRAM - both of which are Design Basis Accidents. Internally pressurized C26 M FeCrAl alloy cladding and Zircaloy-2 cladding were subjected to rapid 300°-650 °C thermal cycling in a steam environment; actual maximum temperatures were found to vary between materials but were always above 650 °C. In the range of 32–55 MPa hoop stress, Zircaloy-2 cladding burst within 1–16 cycles (about 100 s of dryout duration above 600 °C), while at 76 MPa hoop stress, C26 M cladding remained virtually undeformed after completing 54 cycles (over 1000 s of dryout duration above 600 °C). Higher temperature 300°-700 °C and 300°C–800 °C cycling experiments had to be performed to induce C26 M burst – failure occurred after 20 cycles in the former and during the first cycle in the latter. Zircaloy-2 and C26 M failure criteria were used to generate hoop stress specific dryout lifetimes. Overall, the simulated cyclic dryout experiments show that nuclear grade C26 M cladding has significantly enhanced survivability under dryout conditions relative to Zircaloy-2.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Optimizing Wear Resistance via Brazing Temperature Adaption: Application into CBN/Cu-Sn-Ti Composites

Cubic boron nitride (CBN)/Cu-Sn-Ti composites as potential superabrasive products are prepared. It is found that as the temperature increases, porosity keeps decreasing from 1123 K to 1223 K but becomes virtually constant afterward, which is inversely coupled to the reaction layer thickness variation. Weight loss arrives at the minimum value at 1223 K. Deep etching over the interfacial region reveals that TiN and TiB{sub 2} compounds have been generated, and their roles in determining wear properties are postulated.

36 MATERIALS SCIENCE↗

Reliable computational design of biological-inorganic materials to the large nanometer scale using Interface-FF

The function of nanomaterials and biomaterials greatly depends on understanding nanoscale recognition mechanisms, crystal growth and surface reactions. The Interface Force Field (IFF) and surface model database are the first collection of transferable parameters for inorganic and organic compounds that can be universally applied to all materials. IFF uses common energy expressions and achieves best accuracy among classical force fields due to rigorous validation of structural and energetic properties of all compounds in comparison to perpetually valid experimental data. This paper summarises key aspects of parameterisation, including atomic charges and transferability of parameters and current coverage. Examples of biomolecular recognition at metal and mineral interfaces, surface reactions of alloys, as well as new models for graphitic materials and pi-conjugated molecules are described. For several metal–organic interfaces, a match in accuracy of computed binding energies between of IFF and DFT results is demonstrated at ten million times lower computational cost. Predictive simulations of biomolecular recognition of peptides on phosphate and silicate surfaces are described as a function of pH. The use of IFF for reactive molecular dynamics is illustrated for the oxidation of Mo3Si alloys at high temperature, showing the development of specific porous silica protective layers. The introduction of virtual pi electrons in graphite and pi-conjugated molecules enables improvements in property predictions by orders of magnitude. The inclusion of such molecule-internal polarity in IFF can reproduce cation–pi interactions, pi-stacking in graphite, DNA bases, organic semiconductors and the dynamics of aqueous and biological interfaces for the first time.

Chemistry↗

Closed-loop Dynamics of In-core Thermionic Reactor Systems

Using a point model of an in-core thermionic converter, alternative schemes for providing closed loop reactor control were investigated. It was found that schemes based on variable gain power regulation buffers which use the reactor current as the control variable provide complete protection from thermionic burnout and also provide a virtually constant voltage to the user. A side benefit is that the emitter temperature transients are small-even for a complete electric load drop the emitter temperature transient is less than 100 deg K. The current regulation scheme was selected for further study with a distributed parameter model which was developed to account for variations in thermionic and heat transfer properties along the length of a cylindrical converter. It was found that even though the emitter temperature distribution is about 200 deg K along the converter length, the dynamic properties are unchanged when using the current control scheme.

Sawyer, C. D.↗

Closed loop dynamics of in-core thermionic reactor systems.

Use of a point model of an in-core thermionic converter to investigate alternative schemes for providing closed-loop reactor control. It was found that schemes based on variable-gain power regulation buffers which use the reactor current as the control variable provide complete protection from thermionic burnout and also provide a virtually constant voltage to the user. A side benefit is that the emitter temperature transients are small; even for a complete electric load drop the emitter temperature transient is less than 100 K. The current regulation scheme was selected for further study with a distributed parameter model which was developed to account for variations in thermionic and heat transfer properties along the length of a cylindrical converter. It was found that, even though the emitter temperature distribution is about 200 K along the converter length, the dynamic properties are unchanged when using the current control scheme.

Sawyer, C. D.↗

Engineering prediction of turbulent skin friction and heat transfer in high-speed flow

A large collection of experimental turbulent-skin-friction and heat-transfer data for flat plates and cones was used to determine the most accurate of six of the most popular engineering-prediction methods; the data represent a Mach number range from 4 to 13 and ratio of wall to total temperature ranging from 0.1 to 0.7. The Spalding and Chi method incorporating virtual-origin concepts was found to be the best prediction method for Mach numbers less than 10; the limited experimental data for Mach numbers greater than 10 were not well predicted by any of the engineering methods except the Coles method.

Cary, A. M., Jr.↗

Studies of hot B subdwarfs. Part 2: Energy distributions of three bright sdB/sdOB stars in the 950-5500 angstrom range

Voyager ultraviolet spectrometer observations of the subdwarf B or OB stars HD 205805, UV 1758+36 and Feige 66 are presented. All three objects display the H I Layman series in absorption. These observations are combined with low dispersion IUE spectrophotometry and with Stroemgren photometry to construct virtually complete energy distributions, which extend over the range 950-5500 angstroms. Effective temperatures based on model atmosphere calculations for high gravity, hydrogen rich stars are determined. Our analyses yield T Sub e 28,200 + or - 1300 K for HD 205805, T sub e 31, 800 + or - 1100 K for UV 1758+36, and T sub e 35,700 + or - 1500 K for Feige 66. The importance of far ultraviolet observations below L sub alpha in reducing the uncertainties associated with the interstellar extinction and the degradation of the IUE sensitivity is emphasized.

Wesemael, F.↗

Studies of hot B subdwarfs. II - Energy distributions of three bright sdB/sdOB stars in the 950-5500 A range

Voyager ultraviolet spectrometer observations of the subdwarf B or OB stars HD 205805, UV 1758+36 and Feige 66 are presented. All three objects display the H I Layman series in absorption. These observations are combined with low dispersion IUE spectrophotometry and with Stromgren photometry to construct virtually complete energy distributions, which extend over the range 950-5500 angstroms. Effective temperatures based on model atmosphere calculations for high gravity, hygrogen rich stars are determined. Our analyses yield T sub e 28,200 + or - 1300 K for HD 205805, T sub e 31, 800 + or - 1100 K for UV 1758+36, and T sub e 35,700 + or 1500 K for Feige 66. The importance of far ultraviolet observations below L sub alpha in reducing the uncertainties associated with the interstellar extinction and the degradation of the IUE sensitivity is emphasized.

Wesemael, F.↗

Quantification and Mitigation of Long-Term Impacts of Urbanization and Climate Change in the Tropical Coastal City of San Juan, Puerto Rico

Urbanization, along with other cases of land cover and land use changes, has significant climate impacts in tropical regions with the added complexity of occurring within the context of global warming. The individual and combined effects of these two factors on the surface energy balance of a tropical city are investigated by use of an integrated atmospheric modeling approach, taking the San Juan Metropolitan Area (SJMA), Puerto Rico as the test case. To achieve this goal, an ensemble of climate and weather simulations is performed, with the climate scenarios combining urban development and sprawl with regional climate change over the past 50 years, and the short-term simulations designed to test the sensitivity to different urban vegetation configurations as mitigating alternatives. As indicator of change, we use the thermal response number (TRN), which is a measure of the sensible heating to the thermal storage of a surface or region, and the Bowen ratio, which is defined as the ratio of sensible to latent heat fluxes. The TRN of the area occupied by the SJMA has decreased as a consequence of replacing the low land coastal plain vegetation with man made materials, indicating that it takes less energy to raise the surface temperature of the urban area, whereas the TRN of forested regions has remained virtually unchanged. The global warming signal also has effects on the thermal response of the SJMA, where dryer current conditions generate lower TRN values. Differences due to global warming are more evident in the Bowen ratio pattern, mostly associated with the drier present conditions observed and its effects on sensible and latent heat fluxes. In terms of testing different mitigation strategies, the short-term simulations show that the urban area is more efficient in partitioning surface energy balance terms when green roofs are specified, as opposed to including vegetation inside the urban core.

Comarazamy, Daniel↗

Data Projection of the High Temperature Electrolysis System in the Dynamic Energy Transport and Integration Laboratory using Dynamic System Scaling

For nuclear power to be flexible in a functioning Integrated Energy System (IES), excess produced heat must be stored or utilized during times of low power demand to ensure a load factor of 1 while load balancing. The Dynamic Energy Transport and Integration Laboratory (DETAIL) is one facility that is under development to emulate IES conditions on the engineering-scale, planned to conduct virtual real time operations with industry-scale facilities, and is currently testing thermal storage and high temperature electrolysis. As part of the study to develop a method to preprocess input signals or postprocess output signals between systems of different scales via Dynamical System Scaling (DSS), the current research is one of the continued efforts branching from the data projection activity conducted for the Thermal Energy Distribution System and currently engages the High Temperature Electrolysis (HTE) System in DETAIL. The HTE SOEC electrical, fluid, and thermal dynamics Figure of Merits (FOM) were identified, governing equations and closure relations were successfully scaled, and relations between FOM scaling ratios were determined. Setting the scaling objectives to reform existing data to project a data set that doubly accelerated the electrolysis process while preserving the produced amount of hydrogen was generated for the full transient. The calculated boundary conditions were inlet temperature, stack current, and inlet steam mass flow rate at 1470 K, 121.1 A, and 1.886 g/s, respectively. The research outcomes demonstrated an output signal postprocessing case accelerating the hydrogen production without changing geometry, number of cells, and partial pressures.

08 HYDROGEN↗

Toward Stabilizing Co 3 O 4 Nanoparticles as an Oxygen Reduction Reaction Catalyst for Intermediate-Temperature SOFCs

The oxygen reduction reaction (ORR) activity of a series of composite cathodes consisting of a porous Gd 0.20 Ce 0.80 O 2-δ (GDC) scaffold infiltrated with Sr-, Co-, and Y-nitrate solutions has been systematically investigated in this study. The results show that such infiltrated cathodes if calcined at low temperatures such as 350°C exhibit low polarization resistance (RP) in the temperature range of 450–700°C, even though XRD analysis reveals that the calcined product is virtually a mixture of Co 3 O 4 and SrCO 3 . A further study by design-of-experiment suggests that the true ORR-active species is Co 3 O 4 , whereas SrCO 3 serves as a sintering inhibitor to preserve the high surface area of Co 3 O 4 . The findings and understanding in this study present a new strategy for future development of active cathodes for intermediate-temperature solid oxide fuel cells (SOFCs).

36 MATERIALS SCIENCE↗

Resolved rotation–vibration non-equilibrium with rotational VIPA-CARS

Simultaneous rotational and vibrational temperatures are measured in an N 2 plasma with rotational coherent anti-Stokes Raman scattering (CARS) resolved with a virtually imaged phased array (VIPA)-based spectrometer. A VIPA spectrally separates rotational transitions for each vibrational state, allowing vibrational populations to be directly measured. VIPA-CARS is shown to provide more accurate measurements of non-equilibrium temperatures than grating-resolved rotational CARS. The general characteristics, limitations, and potential uses of VIPA-CARS are discussed.

Steinmetz, S. A. (ORCID:0000000311014662)↗

A technique for computation of noise temperature due to a beam waveguide shroud

Direct analytical computation of the noise temperature of real beam waveguide (BWG) systems, including all mirrors and the surrounding shroud, is an extremely complex problem and virtually impossible to achieve. Yet the DSN antennas are required to be ultra low-noise in order to be effective, and a reasonably accurate prediction is essential. This article presents a relatively simple technique to compute a real BWG system noise temperature by combining analytical techniques with data from experimental tests. Specific expressions and parameters for X-band (8.45-GHz) BWG noise computation are obtained for DSS 13 and DSS 24, now under construction. These expressions are also valid for various conditions of the BWG feed systems, including horn sizes and positions, and mirror sizes, curvatures, and positions. Parameters for S- and Ka-bands (2.3 and 32.0 GHz) have not been determined; however, those can be obtained following the same procedure as for X-band.

Veruttipong, W.↗

A Revised Calibration Function and Results for the Phoenix Mission TECP Relative Humidity Sensor

The original calibration function of the R(sub H) sensor on the Phoenix Thermal and Electrical Conductivity Sensor (TECP) has been revised in order to extend the range of the valid calibration, and to improve accuracy. The original function returned non-physical R(sub H) values at the lowest temperatures. To resolve this, and because the original calibration was performed against a pair of hygrometers that measured frost point (T(sub f)), the revised calibration equation is also cast in terms of frost point. Because of the complexity of maintaining very low temperatures and high R(sub H) in the laboratory, no calibration data exists at T is greater than 203K. However, sensor response during the mission was smooth and continuous down to 181 K. Therefore we have opted to include flight data in the calibration data set; selection was limited to data acquired during periods when the atmosphere is known to have been saturated. T(sub f) remained below 210 K throughout the mission(P is greater than 0.75 Pa). R(sub H), conversely, ranged from 1 to well under 0.01 diurnally, due to approximately 50 K temperature variations. To first order, both vapor pressure and its variance are greater during daylight hours. Variance in overnight humidity is almost entirely explained by temperature, while atmospheric turbulence contributes substantial variance to daytime humidity. Likewise, data gathered with the TECP aloft reflect higher H2O abundances than at the surface, as well as greater variance. There is evidence for saturation of the atmosphere overnight throughout much of the mission. In virtually every overnight observation, once the atmosphere cooled to T(sub f), water vapor begins to decrease, and tracks air temperature. There is no evidence for substantial decreases in water vapor prior to saturation, as expected for adsorptive exchange. Likewise, there is no evidence of local control of vapor by phases such as perchlorate hydrates hydrated minerals. The daytime average H2O pressure does not change substantially over the course of the mission, although the H2O column abundance varies by a factor of 2. Column abundances calculated from TECP data are lower than orbital measurements if one assumes that H2O is uniformly mixed through a single scale height. These results argue that the vertical distribution of H2O begins to change well in advance of surface concentrations as northern autumn approaches.

Phoenix Thermal and Electrical Conductivity Sensor↗

Exploring thermal state in mixed immersive virtual environments

Combining immersive virtual environment (IVE) with a controlled environment is a potential solution for analyzing human thermal experience during building design. Existing studies in this field have not adequately analyzed scenarios involving stabilized comfortable and uncomfortable temperature conditions using both thermal state votes and physiological responses, or the influence of the seasons. By combining IVE with a climate chamber, called mixed IVE (MIVE) in this study, experiments were conducted to test the hypothesis that participants' virtual experience did not significantly alter their thermal experience compared to their in-situ experience. Response variables were the control temperature distribution, the thermal state vote (at temperature steps 18.3 °C, 23.8 °C, and 29.4 °C), and physiological responses (heart rate and skin temperature). The results show that the first two response variables were not significantly different between the MIVE and in-situ settings (except for one case). Due to the heat development of the head mounted display device, the mean forehead skin temperature in the MIVE experiments was significantly higher than that in the in-situ experiments in most cases. Furthermore, such difference in skin temperature did not seem to affect general thermal state votes. In addition, significant skin temperature differences at some locations were also observed between the MIVE and in-situ settings.

42 ENGINEERING↗

Boundary Layer Diabatic Processes, the Virtual Effect, and Convective Self‐Aggregation

Abstract The atmosphere can self‐organize into long‐lasting large‐scale overturning circulations over an ocean surface with uniform temperature. This phenomenon is referred to as convective self‐aggregation and has been argued to be important for tropical weather and climate systems. Here we present a boundary layer centric framework based on the available potential energy budget of convective self‐aggregation. We show that boundary layer diabatic processes dominate the available potential energy production and are, therefore, essential to convective self‐aggregation. We further show that the enhanced virtual effect of water vapor can lead to convective self‐aggregation.

58 GEOSCIENCES↗