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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Tunable topological Dirac surface states and van Hove singularities in kagome metal GdV 6 Sn 6

Transition-metal-based kagome materials at van Hove filling are a rich frontier for the investigation of novel topological electronic states and correlated phenomena. To date, in the idealized two-dimensional kagome lattice, topologically Dirac surface states (TDSSs) have not been unambiguously observed, and the manipulation of TDSSs and van Hove singularities (VHSs) remains largely unexplored. Here, we reveal TDSSs originating from a $\mathbb{Z}_2$ bulk topology and identify multiple VHSs near the Fermi level (E F ) in magnetic kagome material GdV 6 Sn 6 . Using in situ surface potassium deposition, we successfully realize manipulation of the TDSSs and VHSs. The Dirac point of the TDSSs can be tuned from above to below E F , which reverses the chirality of the spin texture at the Fermi surface. These results establish GdV 6 Sn 6 as a fascinating platform for studying the nontrivial topology, magnetism, and correlation effects native to kagome lattices. They also suggest potential application of spintronic devices based on kagome materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Sequential multidimensional heteroepitaxy of chalcogen-sharing 3D ZnSe and 2D MoSe 2 with quasi van der Waals interface engineering

Two-dimensional (2D) materials are emerging as a promising platform for epitaxial growth, largely free from the constraints of lattice constant and thermal expansion coefficient mismatches. Among them, transition metal dichalcogenides (TMDs), known for their superior electrical properties, are ideal for ultrathin semiconductor applications. Their unique epitaxial characteristics enable seamless integration with 3D materials, facilitating the development of gate stacks and heterojunction devices. In this regard, developing a process for growing high-quality 3D epitaxial materials before and after the growth of 2D TMDs and understanding the 2D/3D interface are crucial. This study demonstrates the sequential growth of fully epitaxial ZnSe/MoSe 2 /ZnSe heterostructures using metal-organic chemical vapor deposition. ZnSe and MoSe 2 , sharing chalcogen elements, enable large-area quasi van der Waals epitaxy with sharp interfaces without intermediate phase. Multiscale analysis involving transmission electron microscopy and density functional theory calculation reveals lattice commensurability, van der Waals gaps, termination, and interfacial reconstruction. Understanding these interactions is crucial for advancing multidimensional integration of 2D and 3D materials.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Dependence of Van-Vleck paramagnetism on the size of nanocrystals in superstoichiometric TiO{sub y}

In situ measurements of the magnetic susceptibility of titanium monoxide nanocrystals with superstoichiometric composition TiO{sub y} (y > 1) in the 300–1200 K temperature range showed that this value depends not only on the structural state of a sample, but also on the size of crystals. Analysis of data obtained for both ordered and disordered TiO{sub y} showed that the Van-Vleck paramagnetism is inversely proportional to the nanocrystal size because of breakage of the symmetry of local environment of the near-surface atoms of titanium and oxygen. The Van-Vleck paramagnetism contribution due to atomic-vacancy disorder in superstoichiometric titanium monoxide nanocrystals, as well as in the stoichiometric composition, is proportional to a deviation of the degree of long-range order from its maximum value.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

Effect of collisions on Van Kampen waves

The time evolution of Van Kampen waves is analyzed by solving the kinetic equation for the plasma particle distribution function. The damping law for Van Kampen waves, ∝Bexp(−C(Ωt){sup 3}), obtained earlier from qualitative considerations, is confirmed. The values of the constants B and C are found, and comparison with the previous analysis is made.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2011

Shubnikov-de-Haas and de-Haas-van-Alphen oscillations in silicon nanostructures

The dependences of the longitudinal resistance and the static magnetic susceptibility on the magnetic field applied perpendicularly to the plane of an ultranarrow silicon quantum well confined by {delta} barriers heavily doped with boron demonstrate the high-temperature Shubnikov-de-Haas and de-Haas-van-Alphen oscillations in low magnetic fields. The results are indicative of the implementation of the high-field approximation {mu}B Much-Greater-Than 1 under these conditions due to the small effective mass of two-dimensional heavy holes, which is confirmed by measurements of temperature dependences of the de-Haas-van-Alphen oscillations.

36 MATERIALS SCIENCE↗
DOE OSTI2026

AmeriFlux FLUXNET-1F US-NR3 Niwot Ridge Alpine (T-Van West)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-NR3 Niwot Ridge Alpine (T-Van West). This is the FLUXNET version of the carbon flux data for the site US-NR3 Niwot Ridge Alpine (T-Van West) produced by applying the standard ONEFlux (1F) software. Site Description - Snow-scoured alpine tundra; Dry meadow vegetation; 3-m tower located 50 m W of US-NR4, 420 m SW of US-xNW, and 28 km west of Boulder, CO, USA. Nearby reliable daily precipitation data (NWT D1) can be found at: https://doi.org/10.6073/pasta/63b912a406254df036e89c84a1b59230.

Knowles, John [USDA ARS Southwest Watershed Resear↗
DOE OSTI2024

Resonant Metasurfaces with Van Der Waals Hyperbolic Nanoantennas and Extreme Light Confinement

This work reports on a metasurface based on optical nanoantennas made of van der Waals material hexagonal boron nitride. The optical nanoantenna made of hyperbolic material was shown to support strong localized resonant modes stemming from the propagating high-k waves in the hyperbolic material. An analytical approach was used to determine the mode profile and type of cuboid nanoantenna resonances. An electric quadrupolar mode was demonstrated to be associated with a resonant magnetic response of the nanoantenna, which resembles the induction of resonant magnetic modes in high-refractive-index nanoantennas. The analytical model accurately predicts the modes of cuboid nanoantennas due to the strong boundary reflections of the high-k waves, a capability that does not extend to plasmonic or high-refractive-index nanoantennas, where the imperfect reflection and leakage of the mode from the cavity complicate the analysis. In the reported metasurface, excitations of the multipolar resonant modes are accompanied by directional scattering and a decrease in the metasurface reflectance to zero, which is manifested as the resonant Kerker effect. Van der Waals nanoantennas are envisioned to support localized resonances and can become an important functional element of metasurfaces and transdimensional photonic components. By designing efficient subwavelength scatterers with high-quality-factor resonances, this work demonstrates that this type of nanoantenna made of naturally occurring hyperbolic material is a viable substitute for plasmonic and all-dielectric nanoantennas in developing ultra-compact photonic components.

Chemistry↗
DOE OSTI2018

Magnetosphere dynamics during the 14 November 2012 storm inferred from TWINS, AMPERE, Van Allen Probes, and BATS-R-US–CRCM

During the 14 November 2012 geomagnetic storm, the Van Allen Probes spacecraft observed a number of sharp decreases ("dropouts") in particle fluxes for ions and electrons of different energies. In this paper, we investigate the global magnetosphere dynamics and magnetosphere–ionosphere (M–I) coupling during the dropout events using multipoint measurements by Van Allen Probes, TWINS, and AMPERE together with the output of the two-way coupled global BATS-R-US–CRCM model. We find different behavior for two pairs of dropouts. For one pair, the same pattern was repeated: (1) weak nightside Region 1 and 2 Birkeland currents before and during the dropout; (2) intensification of Region 2 currents after the dropout; and (3) a particle injection detected by TWINS after the dropout. The model predicted similar behavior of Birkeland currents. TWINS low-altitude emissions demonstrated high variability during these intervals, indicating high geomagnetic activity in the near-Earth tail region. For the second pair of dropouts, the structure of both Birkeland currents and ENA emissions was relatively stable. The model also showed quasi-stationary behavior of Birkeland currents and simulated ENA emissions with gradual ring current buildup. We confirm that the first pair of dropouts was caused by large-scale motions of the OCB (open–closed boundary) during substorm activity. We show the new result that this OCB motion was associated with global changes in Birkeland (M–I coupling) currents and strong modulation of low-altitude ion precipitation. The second pair of dropouts is the result of smaller OCB disturbances not related to magnetospheric substorms. The local observations of the first pair of dropouts result from a global magnetospheric reconfiguration, which is manifested by ion injections and enhanced ion precipitation detected by TWINS and changes in the structure of Birkeland currents detected by AMPERE. This study demonstrates that multipoint measurements along with the global model results enable the reconstruction of a more complete system-level picture of the dropout events and provides insight into M–I coupling aspects that have not previously been investigated.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

Primary and secondary particle contributions to the depth dose distribution in a phantom shielded from solar flare and Van Allen protons

Calculations have been made using the nucleon-meson transport code NMTC to estimate the absorbed dose and dose equivalent distributions in astronauts inside space vehicles bombarded by solar flare and Van Allen protons. A spherical shell shield of specific radius and thickness with a 30-cm-diam. tissue ball at the geometric center was used to simulate the spacecraft-astronaut configuration. The absorbed dose and the dose equivalent from primary protons, secondary protons, heavy nuclei, charged pions, muons, photons, and positrons and electrons are given as a function of depth in the tissue phantom. Results are given for solar flare protons with a characteristic rigidity of 100 MV and for Van Allen protons in a 240-nautical-mile circular orbit at 30 degree inclination angle incident on both 20-g/sq cm-thick aluminum and polyethylene spherical shell shields.

Santoro, R. T.↗
NASA NTRS1978

Baseline tests of the Volkswagen transporter electric delivery van

The Volkswagen Transporter, an electric delivery van, was tested as part of an Energy Research and Development Administration (ERDA) project to characterize the state of the art of electric vehicles. The Volkswagen Transporter is a standard Volkswagen van that has been converted to an electric vehicle. It is powered by a 144-volt traction battery. A direct current (dc) chopper controller, actuated by a conventional accelerator pedal, regulates the voltage or power applied to the 16-kilowatt (21-hp) motor. The braking system uses conventional hydraulic braking in combination with an electric regenerative braking system. The Volkswagen vehicle performance test results are presented.

Soltis, R. F.↗
NASA NTRS1980

Curves of growth for van der Waals broadened spectral lines

Curves of growth are evaluated for a spectral line broadened by the van der Waals interactions during collisions. The growth of the equivalent widths of such lines is shown to be dependent on the product of the perturber density and the 6/10 power of the van der Waals potential coefficient. When the parameter is small, the widths grow as the 1/2 power of the optical depth as they do for the Voigt profile: but when the parameter is large, they grow as 2/3 power and, hence, faster than the Voigt profile. An approximate analytical expression for the computed growth characteristics is given.

Park, C.↗
NASA NTRS1983

Results from tests, with van-mounted sensor, of magnetic leader cable for aircraft guidance during roll-out and turnoff

Tests were conducted with a van mounted experimental magnetic leader cable sensor to evaluate its potential for measuring aircraft displacement and heading with respect to the leader cable during roll out and turnoff. Test results show that the system may be usable in measuring displacement but the heading measurement contains errors introduced by distortion of the magnetic field by the metal van or aircraft.

Young, J. C.↗
NASA NTRS1990

Infrared spectra of van de Waals complexes of importance in planetary atmospheres

It has been suggested that (CO2)2 and Ar-CO2 are important constituents of the planetary atmospheres of Venus and Mars. Recent results on the laboratory spectroscopy of CO2 containing van der Waals complexes which may be of use in the modeling of the spectra of planetary atmospheres are presented. Sub-Doppler infrared spectra were obtained for (CO2)2, (CO2)3, and rare-gas-CO2 complexes in the vicinity of the CO2 Fermi diad at 2.7 micrometers using a color-center-laser optothermal spectrometer. From the spectroscopic constants the geometries of the complexes have been determined and van der Waals vibrational frequencies have been estimated. The equilibrium configurations are C2h, C3h, and C2v, for (CO2)2, (CO2)3, and the rare-gas-CO2 complexes, respectively. Most of the homogeneous linewidths for the revibrational transitions range from 0.5 to 22 MHz, indicating that predissociation is as much as four orders of magnitude faster than radiative processes for vibrational relaxation in these complexes.

Fraser, G. T.↗
NASA NTRS1990

Microwave spectra of van der Waals complexes of importance in planetary atmospheres

The Fourier-transform Fabry-Perot pulsed-molecular-beam microwave spectrometer at NIST was used to study the microwave spectra of a number of molecular dimers and trimers that may be present in planetary atmospheres. The weak van der Waals bonds associated with these species usually give rise to rotational-tunneling splittings in the microwave spectra. The microwave spectrum of the water dimer species was used to illustrate the complications that can arise in the study of the rotational spectra of these loosely bound species. In addition to the water dimer species, the microwave spectra of the following hydrogen-bonded and van der Waals complexes were studied: (CO2)2-H2O, CO2-(H2O)2, CO2-H2S, N2-H2O, CO-H2O, SO2-H2O, and O3-H2O.

Suenram, R. D.↗
NASA NTRS1992

A high-pressure van der Waals compound in solid nitrogen-helium mixtures

A detailed diamond anvil-cell study using synchrotron X-ray diffraction, Raman scattering, and optical microscopy has been conducted for the He-N system, with a view to the weakly-bound van der Waals molecule interactions that can be formed in the gas phase. High pressure is found to stabilize the formation of a stoichiometric, solid van der Waals compound of He(N2)11 composition which may exemplify a novel class of compounds found at high pressures in the interiors of the outer planets and their satellites.

Vos, W. L.↗
NASA NTRS2004

A Polarimetric Extension of the van Cittert-Zernike Theorem for Use with Microwave Interferometers

The van Cittert-Zernike theorem describes the Fourier-transform relationship between an extended source and its visibility function. Developments in classical optics texts use scalar field formulations for the theorem. Here, we develop a polarimetric extension to the van Cittert-Zernike theorem with applications to passive microwave Earth remote sensing. The development provides insight into the mechanics of two-dimensional interferometric imaging, particularly the effects of polarization basis differences between the scene and the observer.

Piepmeier, J. R.↗
NASA NTRS2015

Relativistic Electron Response to the Combined Magnetospheric Impact of a Coronal Mass Ejection Overlapping with a High-Speed Stream: Van Allen Probes Observations

During early November 2013, the magnetosphere experienced concurrent driving by a coronal mass ejection (CME) during an ongoing high-speed stream (HSS) event. The relativistic electron response to these two kinds of drivers, i.e., HSS and CME, is typically different, with the former often leading to a slower buildup of electrons at larger radial distances, while the latter energizing electrons rapidly with flux enhancements occurring closer to the Earth. We present a detailed analysis of the relativistic electron response including radial profiles of phase space density as observed by both Magnetic Electron and Ion Sensor (MagEIS) and Relativistic Electron Proton Telescope instruments on the Van Allen Probes mission. Data from the MagEIS instrument establish the behavior of lower energy (<1 MeV) electrons which span both intermediary and seed populations during electron energization. Measurements characterizing the plasma waves and magnetospheric electric and magnetic fields during this period are obtained by the Electric and Magnetic Field Instrument Suite and Integrated Science instrument on board Van Allen Probes, Search Coil Magnetometer and Flux Gate Magnetometer instruments on board Time History of Events and Macroscale Interactions during Substorms, and the low-altitude Polar-orbiting Operational Environmental Satellites. These observations suggest that during this time period, both radial transport and local in situ processes are involved in the energization of electrons. The energization attributable to radial diffusion is most clearly evident for the lower energy (<1 MeV) electrons, while the effects of in situ energization by interaction of chorus waves are prominent in the higher-energy electrons.

Magnetosphere↗
NASA NTRS2016

Prompt Injections of Highly Relativistic Electrons Induced by Interplanetary Shocks: A Statistical Study of Van Allen Probes Observations

We conduct a statistical study on the sudden response of outer radiation belt electrons due to interplanetary (IP) shocks during the Van Allen Probes era, i.e., 2012 to 2015. Data from the Relativistic Electron-Proton Telescope instrument on board Van Allen Probes are used to investigate the highly relativistic electron response (E greater than 1.8 MeV) within the first few minutes after shock impact. We investigate the relationship of IP shock parameters, such as Mach number, with the highly relativistic electron response, including spectral properties and radial location of the shock-induced injection. We find that the driving solar wind structure of the shock does not affect occurrence for enhancement events, 25% of IP shocks are associated with prompt energization, and 14% are associated with MeV electron depletion. Parameters that represent IP shock strength are found to correlate best with highest levels of energization, suggesting that shock strength may play a key role in the severity of the enhancements. However, not every shock results in an enhancement, indicating that magnetospheric preconditioning may be required.

Schiller, Q.↗