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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Tropospheric UV flux calculations and photolysis rates for use with zonally and diurnally averaged models

A computationally fast and efficient method for calculating solar UV fluxes in the troposphere is developed. Calculated fluxes compare favorably with more rigorous multiple scattering results, and qualitatively correct behavior of the direct and diffuse flux components is maintained. In view of the relatively large uncertainties in other aspects of tropospheric photochemical models, the use of approximate UV flux calculations appears warranted. The technique is applied to the calculation of photolysis rates for twelve significant photolytic reactions of nine species.

Matloff, G. L.↗
NASA NTRS1979

Viking gas exchange reaction - Simulation on UV-irradiated manganese dioxide substrate

The exchange of O2 for H2O, analogous to that recorded on Mars by the Viking GEX experiment, has been observed on humidifying powdered beta-MnO2 (pyrolusite) which had been irradiated by UV in a humidified analog of the Martian atmosphere. Pyrolusite irradiated in a dry atmosphere did not release O2 on humidification. The XPS spectra of Mn and O of the reactive pyrolusite were shifted toward higher binding energies during UV irradiation. These shifts are consistent with the creation of a surface layer of a Mn(V) or Mn(VI) compound. The destruction of such a layer on humidification could account for the observed O2 release. Although manganese has not been identified in the Martian regolith, the upper limit of the Mn concentration is sufficiently high that O2 release from pyrolusite could have been responsible for the results of the Viking GEX experiment.

Blackburn, T. R.↗
NASA NTRS1980

Surface reflectance measurements in the UV from an airborne platform. I

The reflectance of naturally occurring surfaces is measured from a twin engine Cessna 402B aircraft both spectrally (0.29-0.40 micron) with a compact double monochromator and broadband (0.29-1.2 micron) with a UV enhanced photodiode. The measurement system, which is computer controlled and electrically isolated from the aircraft, consists of upward and downward looking hemispheric diffusers, filters, a rotating 90 deg mirror, a focusing lens, and a double monochromator/PMT or the UV photodiode. Measurements are taken at several altitudes enabling the empirical determination of backscatter and attenuation effects on the reflectance. The results are presented for pine forest canopy, green farmland, open ocean, and brown farmland as a function of wavelength and altitude.

Doda, D. D.↗
NASA NTRS1980

IUE observations of the UV spectrum of Comet Bradfield

Comet Bradfield (1979), discovered shortly after perihelion on Christmas day 1979, is characterized by a retrograde orbit of period approximately equal to 250 yr. This orbit was very favorable for observation by the IUE satellite, and the first observations, the preliminary results of which are reported here, were made on 10 and 11 January 1980. Previously, comprehensive vacuum UV cometary spectra were available only for Comet West (1976VI) from rocket observations and Comet Seargent (1978m) with IUE, hence three comets have now been observed in the wavelength region where most of the major constituents are detectable spectroscopically. The UV spectra of these comets are remarkably similar, despite large differences between them in the gas-to-dust ratio and the different heliocentric distances at which the observations were made, and although the statistical basis is still very small, the implication for cosmogony is that nearly all comets have the same primary composition and origin.

Feldman, P. D.↗
NASA NTRS1980

The case against UV photostimulated oxidation of magnetite

The kinetics of magnetite oxidation in O2-bearing atmospheres in the presence of electromagnetic radiation was studied. No perceptible oxidation of magnetite by ultraviolet (UV) photostimulation occurred. These results do not corroborate previous conclusions by Huguenin (1973, 1974) as to the occurrence of this process. Therefore, although the possibility that the process actually occurs cannot be ruled out, it is concluded that there is not yet a basis in laboratory experiments for inferring that UV photostimulated oxidation of magnetite occurs naturally on the surface of Mars.

Morris, R. V.↗
NASA NTRS1980

A magnetic study of spotted UV Ceti flare stars and related late-type dwarfs

A multichannel photoelectric Zeeman analyzer has been used to investigate the magnetic nature of the spotted UV Ceti flare stars. Magnetic observations were obtained on a sample of 19 program objects, of which 5 were currently spotted dKe-dMe stars, 7 were normal dK-dM stars, 7 were UV Ceti flare stars, and 1 was a possible post-T Tauri star. Contrary to most previously published observations and theoretical expectations, no magnetic fields were detected on any of these objects from either the absorption lines or the H-alpha emission line down to an observational uncertainty level of 100-160 gauss (standard deviation).

Vogt, S. S.↗
NASA NTRS1981

Spatial and temporal structures of impulsive bursts from solar flares observed in UV and hard X-rays

New observations are presented of impulsive UV and hard X-rays bursts in two solar flares obtained with instruments on Solar Maximum Mission. The UV bursts were observed in the Si IV and O IV emission lines, whose intensity ratio is density-sensitive. By comparing the spatially resolved Si IV/O IV observations with the corresponding hard X-ray observations, it is possible to study their spatial and temporal relationships. For one flare, the individual component spikes in the multiply peaked hard X-ray burst can be identified with different discrete Si IV/O IV flaring kernels of size 4 arcsec x 4 arcsec or smaller, which brighten up sequentially in time. For the other, many Si IV/O kernels, widely distributed over a large area, show impulsive bursts at the same time, which correlate with the main peak of the impulsive hard X-ray burst. The density of the flaring Si IV/O IV kernels is in the range from 5 x 10 to the 12th-13th/cu cm.

Cheng, C.-C.↗
NASA NTRS1981

Stability of goethite /alpha-FeOOH/ and lepidocrocite /gamma-FeOOH/ to dehydration by UV radiation - Implications for their occurrence on the Martian surface

The geochemistry of the FeOOH polymorphs is an important consideration when evaluating the likelihood of an occurrence of detectable amounts of these minerals on Mars. An investigation is conducted regarding the stability of the FeOOH polymorphs geothite and lepidocrocite to dehydration in the presence of UV radiation. A thorough characterization of the FeOOH powders used in the laboratory experiments is presented, and the irradiational facility and experimental procedures are described. The results obtained in the conducted experiments are discussed. It is found that there is as yet no basis in laboratory experiments for inferring that perceptible UV photodehydration of FeOOH polymorphs will occur naturally on the surface of Mars on a time scale of at least 10-100 years.

Morris, R. V.↗
NASA NTRS1981

Solar UV variability - Effects on stratospheric ozone, trace constituents and thermal structure

The effect of long-term (11-year solar cycle) solar UV variability on stratospheric chemical and thermal structure has been studied using a time-dependent one-dimensional model. Previous studies have suggested substantial variations in local and total ozone, and in stratospheric thermal structure from solar minimum to solar maximum. It is shown that significant variations also occur in some of the trace constituents. Members of the HOx family and N2O exhibit the largest variations, and these changes, if detected, may provide additional means of verifying the presence of solar UV variability and its effects. Some of the species show large phase differences with the assumed solar flux variation. The role of chemical and transport time constants on the time variations of the trace species is examined. Comparisons with reported ozone and temperature data show reasonable agreement for the period 1960 to 1972.

Natarajan, M.↗
NASA NTRS1982

UV radiation from the young sun and oxygen and ozone levels in the prebiological palaeoatmosphere

UV measurements of young T-Tauri stars, resembling the sun at an age of a few million years, have recently been made with the International Ultraviolet Explorer. They indicate that young stars emit up to 10,000 times more UV than the present sun. The implications for the origin and evolution of O2 and O3 in the prebiological palaeoatmosphere are presented here. The results of photochemical calculations indicate that the O2 surface mixing ratio was a factor 10,000-1,000,000 times greater than the standard value of 10 to the -15. This new value reconciles the simultaneous existence of oxidized iron and reduced uranium.

Canuto, V. M.↗
NASA NTRS1982

Atmospheric ozone determination by solar occultation using the UV spectrometer on the Solar Maximum Mission

The UV spectrometer polarimeter instrument on the Solar Maximum Mission spacecraft has been used to measure ozone in the 53-75 km altitude interval by the technique of solar occultation. A 1 x 180 arcsec entrance aperture spectrometer with 0.04-A spectral resolution was employed. Resulting high-quality data are reduced by expressing measured UV attenuation as a Volterra integral equation. Solution of the equation is accomplished by expressing the integral in terms of a series representing the sum of ozone densities contained in concentric shells through tangent points separated by specified altitude increments. Sample ozone vs altitude profiles are presented for the equatorial region. These data show reproducibility to better than 10%. The density at 60 km is 7.3 + or - 0.15 x 10 to the 9th/cu cm for 2.5 deg latitude and longitudes between 81 and 105 deg west in September 1980. Density vs altitude profile exhibits changes in slope between 50 and 75 km.

Aikin, A. C.↗
NASA NTRS1982

Interstellar iron and manganese - UV oscillator strengths and abundances

Observations of 16 UV resonance lines of Fe II and six of Mn II in five stars are used to derive new f-values for the lines of these species at wavelengths lower than 1300 A. Values of forbidden lines Fe/H and Mn/H are derived. These new values are used to reassess mean depletions and range of variations in depletions for several lines of sight. On an integrated line-of-sight basis, depletions of Fe and Mn show larger variations than P, Cl, or Zn. The mean local depletion forbidden line Fe/H is 1.65, in interstellar gas. One Fe II line, 2366.864 A, has never been detected. Its f-value is shown to be much lower than previously thought. This line is therefore not useful for interstellar studies at the present time. It is suggested that the true wavelength of 1142 A of Fe II, from UV multiplet 10, is 1142.285 A.

Lugger, P.↗
NASA NTRS1982

UV eclipse observations of CI Cyg

Low spectral resolution observations were obtained with the IUE during the eclipse phase. Additional data obtained by other IUE groups have been included in the eclipse observations, making it possible to examine the UV spectral properties of CI Cyg over nearly an entire orbit which spans early 1979 through mid 1981. Data obtained over this period suggest an overall decline in UV emission, consistent with the decline of optical emission following the outburst of 1975. The short-wavelength spectrum 1200-2000 A is characterized by numerous intense high-excitation emission lines which become more prominent out of eclipse. The LWR wavelength range 2000-3200 A exhibits a few more additional lines of O III, Mg II, and He II which are superimposed on continuum that rises gradually with increasing wavelength. The observations are consistent with a binary star model which involves mass transfer from the extended cool envelope of the primary to the compact secondary.

Michalitsianos, A. G.↗
NASA NTRS1982

Polarization studies of the Venus UV contrasts - Cloud height and haze variability

The present investigation is concerned with the measurement of differences in the polarization of bright and dark areas on Venus. The differential polarization is matched by simple models in which the cloud height, amount of submicron haze above the clouds, and absorber amount in the clouds are varied. Physical and chemical models consistent with the findings are proposed. The differences in polarization between bright and dark ultraviolet features on Venus are found to have a straightforward interpretation in terms of known constituents of the atmosphere near the cloud tops. The observations of the polarization in four colors over 2 1/2 Venus years imply that the submicron haze and UV absorbers are anticorrelated, and that the clouds lie slightly (approximately 1 km) lower in the dark regions. These findings pose strong constraints on any model for the brightness variations in the UV.

Esposito, L. W.↗
NASA NTRS1983

Discovery of a nitrogen-rich UV-bright star in the globular cluster M5

Observations of a UV bright source in the globular cluster M5 using instrumentation on the Black Brant rocket are reported. Imagery was obtained by two cameras operating at 1540 A and 2360 A and bandpasses of 350 A and 880 A. The instruments are prototypes for cameras to be flown with the Spacelab. The UV-emitting object in the cluster was located off-center. Comparison of the data with data from the IUE for short-wavelength radiation indicated a temperature in the range 25,000-50,000 K, with a dereddened flux for the continuum near 1550 A of 4.2 x 10 to the -13th ergs/sq cm per sec per A. The object is concluded to be a post-AGB star with an envelope which has experienced CNO processing.

Bohlin, R. C.↗
NASA NTRS1984

Determination of the succinonitrile-benzene and succinonitrile-cyclohexanol phase diagrams by thermal and UV spectroscopic analysis

Equilibrium temperature-composition diagrams were determined for the two organic systems, succinonitrile-benzene and succinonitrile-cyclohexanol. Measurements were made using the common thermal analysis methods and UV spectrophotometry. Succinonitrile-benzene monotectic was chosen for its low affinity for water and because UV analysis would be simplified. Succinonitrile-cyclohexanol was chosen because both components are transparent models for metallic solidification, as opposed to the other known succinonitrile-based monotectics.

Kaukler, W. F.↗
NASA NTRS1984

18-months of UV irradiance observations from the Solar Mesosphere Explorer

An instrument on the Solar Mesosphere Explorer has been making daily solar irradiance measurements in the 120-305 nm (UV) spectral interval since October 6, 1981. Calculations of the highest to lowest value of the irradiance within each solar rotation yield percent range values indicative of variations that are useful as input data for model calculations of stratosphere/mesosphere responses to short period solar variability, since solar radiation in the UV is largely responsible for the photochemical interactions and radiative heating of the stratosphere, mesosphere, and lower thermosphere.

London, J.↗
NASA NTRS1984

Absolute measurement of the extreme UV solar flux

A windowless rare-gas ionization chamber has been developed to measure the absolute value of the solar extreme UV flux in the 50-575-A region. Successful results were obtained on a solar-pointing sounding rocket. The ionization chamber, operated in total absorption, is an inherently stable absolute detector of ionizing UV radiation and was designed to be independent of effects from secondary ionization and gas effusion. The net error of the measurement is + or - 7.3 percent, which is primarily due to residual outgassing in the instrument, other errors such as multiple ionization, photoelectron collection, and extrapolation to the zero atmospheric optical depth being small in comparison. For the day of the flight, Aug. 10, 1982, the solar irradiance (50-575 A), normalized to unit solar distance, was found to be 5.71 + or - 0.42 x 10 to the 10th photons per sq cm sec.

Carlson, R. W.↗