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At least 271 records · Page 15

Development of a Technique for Separating Raman Scattering Signals from Background Emission with Single-Shot Measurement Potential

Raman scattering is a powerful technique for quantitatively probing high temperature and high speed flows. However, this technique has typically been limited to clean hydrogen flames because of the broadband fluorescence interference which occurs in hydrocarbon flames. Fluorescence can also interfere with the Raman signal in clean hydrogen flames when broadband UV lasers are used as the scattering source. A solution to this problem has been demonstrated. The solution to the fluorescence interference lies in the fact that the vibrational Q-branch Raman signal is highly polarized for 90 deg. signal collection and the fluorescence background is essentially unpolarized. Two basic schemes are available for separating the Raman from the background. One scheme involves using a polarized laser and collecting a signal with both horizontal and vertical laser polarizations separately. The signal with the vertical polarization will contain both the Raman and the fluorescence while the signal with the horizontal polarization will contain only the fluorescence. The second scheme involves polarization discrimination on the collection side of the optical setup. For vertical laser polarization, the scattered Q-branch Raman signal will be vertically polarized; hence the two polarizations can be collected separately and the difference between the two is the Raman signal. This approach has been used for the work found herein and has the advantage of allowing the data to be collected from the same laser shot(s). This makes it possible to collect quantitative Raman data with single shot resolution in conditions where interference cannot otherwise be eliminated.

Hartfield, Roy↗

Polycyclic Aromatic Hydrocarbons

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Salama, Farid↗

Demonstration of a Fiber Optic Regression Probe in a High-Temperature Flow

The capability to provide localized, real-time monitoring of material regression rates in various applications has the potential to provide a new stream of data for development testing of various components and systems, as well as serving as a monitoring tool in flight applications. These applications include, but are not limited to, the regression of a combusting solid fuel surface, the ablation of the throat in a chemical rocket or the heat shield of an aeroshell, and the monitoring of erosion in long-life plasma thrusters. The rate of regression in the first application is very fast, while the second and third are increasingly slower. A recent fundamental sensor development effort has led to a novel regression, erosion, and ablation sensor technology (REAST). The REAST sensor allows for measurement of real-time surface erosion rates at a discrete surface location. The sensor is optical, using two different, co-located fiber-optics to perform the regression measurement. The disparate optical transmission properties of the two fiber-optics makes it possible to measure the regression rate by monitoring the relative light attenuation through the fibers. As the fibers regress along with the parent material in which they are embedded, the relative light intensities through the two fibers changes, providing a measure of the regression rate. The optical nature of the system makes it relatively easy to use in a variety of harsh, high temperature environments, and it is also unaffected by the presence of electric and magnetic fields. In addition, the sensor could be used to perform optical spectroscopy on the light emitted by a process and collected by fibers, giving localized measurements of various properties. The capability to perform an in-situ measurement of material regression rates is useful in addressing a variety of physical issues in various applications. An in-situ measurement allows for real-time data regarding the erosion rates, providing a quick method for empirically anchoring any analysis geared towards lifetime qualification. Erosion rate data over an operating envelope could also be useful in the modeling detailed physical processes. The sensor has been embedded in many regressing media to demonstrate the capabilities in a number of regressing environments. In the present work, sensors were installed in the eroding/regressing throat region of a converging-diverging flow, with the working gas heated to high temperatures by means of a high-pressure arc discharge at steady-state discharge power levels up to 500 kW. The amount of regression observed in each material sample was quantified using a later profilometer, which was compared to the in-situ erosion measurements to demonstrate the efficacy of the measurement technique in very harsh, high-temperature environments.

Korman, Valentin↗

Wake Measurement Probe

A probe includes a stem having a tip that measures a wake produced by an object moving through a fluid. The probe includes temperature and pressure sensors co-located in the tip.

Tavares, Matthew R.↗

Absorption Efficiencies of Forsterite. I: DDA Explorations in Grain Shape and Size

We compute the absorption efficiency (Q(sub abs)) of forsterite using the discrete dipole approximation (DDA) in order to identify and describe what characteristics of crystal grain shape and size are important to the shape, peak location, and relative strength of spectral features in the 8 - 40 micron wavelength range. Using the DDSCAT code, we compute Q(sub abs) for non-spherical polyhedral grain shapes with a(sub eff) = 0.1 micron. The shape characteristics identified are: 1) elongation/reduction along one of three crystallographic axes; 2) asymmetry, such that all three crystallographic axes are of different lengths; and 3) the presence of crystalline faces that are not parallel to a specific crystallographic axis, e.g., non-rectangular prisms and (di)pyramids. Elongation/reduction dominates the locations and shapes of spectral features near 10, 11, 16, 23.5, 27, and 33.5 micron, while asymmetry and tips are secondary shape effects. Increasing grain sizes (0.1 - 1.0 micron) shifts the 10, 11 micron features systematically towards longer wavelengths and relative to the 11 micron feature increases the strengths and slightly broadens the longer wavelength features. Seven spectral shape classes are established for crystallographic a-, b-, and c-axes and include columnar and platelet shapes plus non-elongated or equant grain shapes. The spectral shape classes and the effects of grain size have practical application in identifying or excluding columnar, platelet or equant forsterite grain shapes in astrophysical environs. Identification of the shape characteristics of forsterite from 8 - 40 micron spectra provides a potential means to probe the temperatures at which forsterite formed.

circumstellar matter↗

Temperature structure in the lower atmosphere of Venus - New results derived from Pioneer Venus entry probe measurements

The Pioneer Venus Small-Probe Net Flux Radiometer temperature sensor and its calibration, the thermal model of the sensor head, the procedure for deriving atmospheric temperature from the sensor temperatures, and the new temperature results for each entry probe are reported. The new results are compared with those of the Small-Probe Atmospheric Structure experiment and with simple models of diurnal and latitudinal temperature contrasts. A dynamical inconsistency between these results and low-latitude measurements by the Sounder probe is described, and possible ways to resolve it are considered.

Sromovsky, L. A.↗

Heated Surface Temperatures Measured by Infrared Detector in a Cascade Environment

Investigators have used infrared devices to accurately measure heated surface temperatures. Several of these applications have been for turbine heat transfer studies involving film cooling and surface roughness, typically, these measurements use an infrared camera positioned externally to the test section. In cascade studies, where several blades are used to ensure periodic flow, adjacent blades block the externally positioned camera's views of the test blade. To obtain a more complete mapping of the surface temperatures, researchers at the NASA Glenn Research Center fabricated a probe with an infrared detector to sense the blade temperatures. The probe size was kept small to minimize the flow disturbance. By traversing and rotating the probe, using the same approach as for total pressure surveys, one can find the blade surface temperatures. Probe mounted infrared detectors are appropriate for measuring surface temperatures where an externally positioned infrared camera is unable to completely view the test object. This probe consists of a 8-mm gallium arsenide (GaAs) lens mounted in front of a mercury-cadmium-zinc-tellurium (HgCdZnTe) detector. This type of photovoltaic detector was chosen because of its high sensitivity to temperature when the detector is uncooled. The particular application is for relatively low surface temperatures, typically ambient to 100 C. This requires a detector sensitive at long wavelengths. The detector is a commercial product enclosed in a 9-mm-diameter package. The GaAs lens material was chosen because of its glass-like hardness and its good long-wavelength transmission characteristics. When assembled, the 6.4-mm probe stem is held in the traversing actuator. Since the entire probe is above the measurement plane, the flow field disturbance in the measurement plane is minimized. This particular probe body is somewhat wider than necessary, because it was designed to have replaceable detectors and lenses. The signal for the detector is fed through the hollow probe body. The detector's signal goes to an externally mounted preamplifier. The detector assembly, along with a preamplifier, is calibrated as a function of the surface temperature for various detector temperatures. The output voltage is a function of both the detector and object temperatures.

Boyle, Robert J.↗

Plasma Measurements in an Integrated-System FARAD Thruster

Pulsed inductive plasma accelerators are spacecraft propulsion devices in which energy is stored in a capacitor and then discharged through an inductive coil. The device is electrodeless, inducing a current sheet in a plasma located near the face of the coil. The propellant is accelerated and expelled at a high exhaust velocity (order of 10 km/s) through the interaction of the plasma current and the induced magnetic field. The Faraday Accelerator with RF-Assisted Discharge (FARAD) thruster[1,2] is a type of pulsed inductive plasma accelerator in which the plasma is preionized by a mechanism separate from that used to form the current sheet and accelerate the gas. Employing a separate preionization mechanism allows for the formation of an inductive current sheet at much lower discharge energies and voltages than those used in previous pulsed inductive accelerators like the Pulsed Inductive Thruster (PIT). A benchtop FARAD thruster was designed following guidelines and similarity performance parameters presented in Refs. [3,4]. This design is described in detail in Ref. [5]. In this paper, we present the temporally and spatially resolved measurements of the preionized plasma and inductively-accelerated current sheet in the FARAD thruster operating with a Vector Inversion Generator (VIG) to preionize the gas and a Bernardes and Merryman circuit topology to provide inductive acceleration. The acceleration stage operates on the order of 100 J/pulse. Fast-framing photography will be used to produce a time-resolved, global view of the evolving current sheet. Local diagnostics used include a fast ionization gauge capable of mapping the gas distribution prior to plasma initiation; direct measurement of the induced magnetic field using B-dot probes, induced azimuthal current measurement using a mini-Rogowski coil, and direct probing of the number density and electron temperature using triple probes.

Polzin, K. A.↗

Variability of dayside electron temperature at Venus

Langmuir probe measurements on Pioneer Venus Orbiter show that electron temperature (Te) profiles exhibit two distinct regions. The lower, but more extended region is in the main ionosphere where Te increases slowly with altitude. The other, less extended region is in the ionopause, where Te rise sharply with altitude. If horizontal magnetic fields and flux ropes in the ionosphere inhibit vertical thermal conductivity sufficiently, then the observed Te profile could be explained with EUV as the major heat source (Cravens et al., 1980). The rise in Te in the ionopause region has generally been attributed to solar wind heating (Brace and Kliore, 1991). We suggest that this sharp rise in Te is due primarily to the steep fall in electron density, Ne. If the heating rate is essentially unchanged and heat conduction is not of primary importance, then a steep rise in Te will maintain a constant electron cooling rate for a steeply falling Ne. We have observed large orbit to orbit variations in Te in the ionopause region which are found to be inversely related to changes in Ne. Variations in solar wind dynamic pressure do not seem to have a direct effect on Te, rather the effect is indirect coming through the sharp decrease in Ne.

Mahajan, K. K.↗

High Temperature Antenna Measurement System with GSG or GS Contact Probing Capability

Applications that require data transmission at high temperatures are becoming more common due to growing commercial and military needs. Antennas are an indispensable part of these systems and the ability to characterize them at elevated temperatures is quite complicated with little or no information being reported on the subject [1]. This paper describes a measurement system that can characterize planar antennas up 600 C with ground-signal-ground (GSG) or ground-signal (GS) probe contacts. The return loss and radiation patterns of a folded slot antenna (FSA), designed to operate at 5 GHz (no ground plane on back side) and fabricated on an alumina substrate, are presented at room temperature (RT) and 250 C [2]. All measurements were made with Agilent's Precision Network Analyzer (PNA) E8361. The return loss and radiation patterns were also measured on a Styrofoam chuck to illustrate the effect the high temperature measurement system has on the patterns.

Jordan, Jennifer L.↗

Optimization of single-base-pair mismatch discrimination in oligonucleotide microarrays

The discrimination between perfect-match and single-base-pair-mismatched nucleic acid duplexes was investigated by using oligonucleotide DNA microarrays and nonequilibrium dissociation rates (melting profiles). DNA and RNA versions of two synthetic targets corresponding to the 16S rRNA sequences of Staphylococcus epidermidis (38 nucleotides) and Nitrosomonas eutropha (39 nucleotides) were hybridized to perfect-match probes (18-mer and 19-mer) and to a set of probes having all possible single-base-pair mismatches. The melting profiles of all probe-target duplexes were determined in parallel by using an imposed temperature step gradient. We derived an optimum wash temperature for each probe and target by using a simple formula to calculate a discrimination index for each temperature of the step gradient. This optimum corresponded to the output of an independent analysis using a customized neural network program. These results together provide an experimental and analytical framework for optimizing mismatch discrimination among all probes on a DNA microarray.

NASA Discipline Life Sciences Technologies↗

Effect of an isotropic nonequilibrium plasma on electron temperature measurements.

The electron temperatures that would be determined (using the conventional single-temperature analysis) by the electrostatic probe, the diffuse resonance, and the radar backscatter techniques in an isotropic two-temperature plasma are presented. Plasma models corresponding to the addition of a minor component of energetic electrons and models corresponding to a process that cools a fraction of the ionospheric electrons are considered. The diffuse resonance temperature is found to lie between the probe and radar backscatter temperatures. The isotropic models corresponding to the addition of energetic electrons cannot support the reported discrepancies between radio wave and probe electron temperature measurements. Temperature differences similar to the observed differences can be produced by models with a fraction of the electrons at a temperature cooler than that of the main component of electrons. These models, however, are difficult to explain in terms of present understanding of the ionospheric plasma.

Benson, R. F.↗

Extreme Environment Technologies for Space and Terrestrial Applications

Over the next decades, NASA's planned solar system exploration missions are targeting planets, moons and small bodies, where spacecraft would be expected to encounter diverse extreme environmental (EE) conditions throughout their mission phases. These EE conditions are often coupled. For instance, near the surface of Venus and in the deep atmospheres of giant planets, probes would experience high temperatures and pressures. In the Jovian system low temperatures are coupled with high radiation. Other environments include thermal cycling, and corrosion. Mission operations could also introduce extreme conditions, due to atmospheric entry heat flux and deceleration. Some of these EE conditions are not unique to space missions; they can be encountered by terrestrial assets from the fields of defense,oil and gas, aerospace, and automotive industries. In this paper we outline the findings of NASA's Extreme Environments Study Team, including discussions on state of the art and emerging capabilities related to environmental protection, tolerance and operations in EEs. We will also highlight cross cutting EE mitigation technologies, for example, between high g-load tolerant impactors for Europa and instrumented projectiles on Earth; high temperature electronics sensors on Jupiter deep probes and sensors inside jet engines; and pressure vessel technologies for Venus probes and sea bottom monitors. We will argue that synergistic development programs between these fields could be highly beneficial and cost effective for the various agencies and industries. Some of these environments, however, are specific to space and thus the related technology developments should be spear headed by NASA with collaboration from industry and academia.

extreme environments↗