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NASA NTRS2016

Abundant Solar Nebula Solids in Comets

Comets have been proposed to consist of unprocessed interstellar materials together with a variable amount of thermally annealed interstellar grains. Recent studies of cometary solids in the laboratory have shown that comets instead consist of a wide range of materials from across the protoplanetary disk, in addition to a minor complement of interstellar materials. These advances were made possible by the return of direct samples of comet 81P/Wild 2 coma dust by the NASA Stardust mission and recent advances in microscale analytical techniques. Isotopic studies of 'cometary' chondritic porous interplanetary dust particles (CP-IDPs) and comet 81P/Wild 2 Stardust samples show that preserved interstellar materials are more abundant in comets than in any class of meteorite. Identified interstellar materials include sub-micron-sized presolar silicates, oxides, and SiC dust grains and some fraction of the organic material that binds the samples together. Presolar grain abundances reach 1 weight percentage in the most stardust-rich CP-IDPs, 50 times greater than in meteorites. Yet, order of magnitude variations in presolar grain abundances among CP-IDPs suggest cometary solids experienced significant variations in the degree of processing in the solar nebula. Comets contain a surprisingly high abundance of nebular solids formed or altered at high temperatures. Comet 81P/Wild 2 samples include 10-40 micron-sized, refractory Ca- Al-rich inclusion (CAI)-, chondrule-, and ameboid olivine aggregate (AOA)-like materials. The O isotopic compositions of these refractory materials are remarkably similar to their meteoritic counterparts, ranging from 5 percent enrichments in (sup 16) O to near-terrestrial values. Comet 81P/Wild 2 and CP-IDPs also contain abundant Mg-Fe crystalline and amorphous silicates whose O isotopic compositions are also consistent with Solar System origins. Unlike meteorites, that are dominated by locally-produced materials, comets appear to be composed of materials that were formed across a wide swath of the early protoplanetary disk.

Messenger, S.↗

NASA NTRS2017

Ion Microprobe Measurements of Comet Dust and Implications for Models of Oxygen Isotope Heterogeneity in the Solar System

The oxygen isotopic compositions of anhydrous minerals in carbonaceous chondrites reflect mixing between a O-16-rich and O-17, O18-rich reservoir. The UV photodissociation of CO (i.e. selfshielding) has been proposed as a mass-independent mechanism for producing these isotopically distinct reservoirs. Self-shielding models predict the composition for the CO gas reservoir to be O-16-rich, and that the accreting primordial dust was in isotopic equilibrium with the gaseous reservoir [1, 2]. Self-shielding also predicts that cometary water, presumed to represent the O-17, O-18-rich reservoir, should be enriched in O-17 and O-18, with compositions of 200 -1000per mille, and that the interaction with this O-17, O-18-rich H2O reservoir altered the compositions of the primordial dust toward planetary values. The bulk composition of the solar nebula, which may be an approximation to the 16O-rich gaseous reservoir, has been constrained by the Genesis results [3]. However, material representing the O-17, O-18-rich end-member is rare [4], and dust representing the original accreting primordial dust has been challenging to conclusively identify in current collections. Anhydrous dust from comets, which accreted in the distal cold regions of the nebula at temperatures below approximately 30K, may provide the best opportunity to measure the oxygen isotope composition of primordial dust. Chondritic porous interplanetary dust particles (CP-IDPs) have been suggested as having cometary origins [5]; however, until direct comparisons with dust from a known comet parent body were made, link between CP-IDPs and comets remained circumstantial. Oxygen isotope analyses of particles from comet 81P/Wild 2 collected by NASA's Stardust mission have revealed surprising similarities to minerals in carbonaceous chondrites which have been interpreted as evidence for large scale radial migration of dust components from the inner solar nebula to the accretion regions of Jupiter- family comets [6]. These studies have been largely focused on the coarse-grained terminal particles extracted from aerogel collectors; hypervelocity capture into aerogel resulted in fine-grained material that was melted and intimately mixed with the SiO2 capture medium. Hypervelocity impacts into Al foils surrounding the aerogel tiles produced impact craters that captured material from the impactor without significant oxygen contamination, allowing for analysis of both the coarse and fine-grained components of the Wild 2 dust. To date, no particles with definitive hydrated mineralogy have been observed in Stardust samples, though this may be a result of alteration due to hypervelocity capture. High-carbon hydrated CS-IDPs have been suggested as resulting from the aqueous alteration of CP-IDPs [7], and may retain evidence for interaction with O-17, O-18-enriched "cometary" water predicted by CO self-shielding. Here we present results of oxygen isotope measurements of twelve Stardust foil craters and four C-rich hydrated IDPs [8, 9], and discuss implications for models of oxygen isotope heterogeneity in the early solar system.

Snead, C. J.↗

NASA NTRS2013

Organic Nano-Grains in Comet 103P/Hartley 2: The Organic Glue of Porous Aggregate Grains?

The GNIRS instrument on the Gemini 8-‐m telescope observed comet 103P/Hartley on 2010-‐ Dec-‐04UT, a month after the EPOXI Mission encounter, and detected the 3.3 and 3.4 um bands in emission. The 3.3/3.4 ratio and the broad band widths are consistent with experiments of heated (approximately 600 K) aliphatic carbon (-CH3, -CH2) thin films. For the 3.4 micron band to be in emission, the aliphatic bonds must be attached to a carrier possessing the strongly UV-‐absorbing C=C aromatic rings, and these rings have to be less than 50-‐100 carbon atoms (4-6 Angstrom) for attached -CH bonds to also generate a 3.3 micron-band in emission. Slightly larger (≥10Å) Very Small Grains (VSGs) can absorb single UV photons comparable to or exceeding their heat capacity, thermally fluctuate and release IR photon(s). The 3.3 micron and 3.4 micron bands observed by GNIRS suggest that organic macromolecules/ nano-‐grains with both aliphatic and aromatic bonds are fluorescing/thermally fluctuating in the coma. Aliphatic and aromatic materials have been seen in Stardust samples and the primitive carbonaceous chondrite 'Tagish Lake'. The larger the ratio of the -CH2/-CH3 components of the aliphatic 3.4 micron band, the more 'primitive' the organic material. In a Stardust organic globule, some aliphatic bonds were transformed into aromatic bonds during the low dosage of Transmission Electron Microscope imaging. Conversely, lab experiments show irradiation of ices containing small PAHs generates aliphatic organics. Photo-‐processing of ices also likely forms the ubiquitous aliphatic coatings that appear on the surfaces of all silicate subgrains constituting nine cometary interplanetary dust particles. The aliphatic coatings, dominated by -CH2, likely were important in sticking the aggregates together, and existed prior to incorporation of dust aggregates into comet nuclei. These comet aliphatics may be some of the sought-‐after precursors to the more robust and complex organics studied as Insoluble Organic Matter in carbonaceous chondrites. Aliphatic coatings on submicron grains, however, will not be observable in absorption because they are fairly transparent, nor do the aliphatic carbonaceous coatings produce the 3.4 micron emission band because the particles they are attached to are too large (too many vibration modes). We must probe the nano-‐sized organic carriers that undergo substantive thermal fluctuations in cometary comae and emit at 3.3 3.4 micron. Observations of the 3.3 and 3.4 micron emission features contribute to characterizing the evolution of organics prior to their incorporation into cometary nuclei as well as their rapid evolution in cometary comae, which in turn contributes to deepening our understanding of the evolution of organics on the surfaces of asteroids and outer icy bodies in our solar system. Studying organics in comets contributes to understanding the formation and evolution pathways of ISM organics through to the formation of the robust insoluble organic matter in meteorites. A'Hearn, M.F., et al. 2011, Science, 332, 1396; Bockelee-‐Morvan, D. et al. 1995, Icarus, 116, 18; De Gregorio, B.T., et al. 2010, GCA, 74, 4454; Dello Russo, N., et al. 2011, ApJ, 734, L8; Dischler et al. 1983, Solid State Communications, 48, 105; Flynn, G., et al. 2010a, LPSC, 41, #1079; Flynn, G., et al. 2010b, COSPAR, 38, F31-‐0012-‐10; Flynn, G., Wirick, S. 2011, LPSC, 42, #1856; Fomenkova, et al. 1994, GCA 58, 4503; Matrajt, G., et al. 2013, ApJ, 765, 145; Schutte, et al. 1993, ApJ, 415, 397; Wooden, D.H. et al. 2011, EPSC-‐DPS, 1557; Wooden, D.H. et al. 2013, submitted.

Stardust samples↗

DOE OSTI2025

Impact of T - and ρ -dependent decay rates and new (n, γ ) cross-sections on the s process in low-mass asymptotic giant branch stars

Aims. We study the impact of nuclear input related to weak-decay rates and neutron-capture reactions on predictions for the slow neutron-capture process (s process) in asymptotic giant branch (AGB) stars. We provide the first database of surface abundances and stellar yields of the isotopes heavier than iron from the Monash models. Methods. We ran nucleosynthesis calculations with the Monash post-processing code for seven stellar structure evolution models of low-mass AGB stars with three different sets of nuclear inputs. The reference set has constant decay rates and represents the set used in the previous Monash publications. The second set contains the temperature and density dependence of β decays and electron captures based on the default rates of nuclear NETwork GENerator (NETGEN). In the third set, we further update 92 neutron-capture rates based on re-evaluated experimental cross sections from the ASTrophysical Rate and rAw data Library. We compare and discuss the predictions of the sets relative to each other in terms of isotopic surface abundances and total stellar yields. We also compare the results to isotopic ratios measured in presolar stardust silicon carbide (SiC) grains from AGB stars. Results. The new sets of models result in a ∼66% solar s-process contribution to the p-nucleus 152 Gd, confirming that this isotope is predominantly made by the s process. The nuclear input updates result in predictions for the 80 Kr/ 82 Kr ratio in the He intershell and surface 64 Ni/ 58 Ni, 94 Mo/ 96 Mo, and 137 Ba/ 136 Ba ratios that are more consistent with the corresponding ratios measured in stardust; however, the new predicted 138 Ba/ 136 Ba ratios are higher than the typical values of the SiC grains. The W isotopic anomalies are in agreement with data from the analyses of other meteoritic inclusions. We confirm that the production of 176 Lu and 205 Pb is affected by too large uncertainties in their decay rates from NETGEN.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2025

Acoustic Observations of the OSIRIS-REx Sample Return Capsule Re-Entry from Wendover Airport

The Origins, Spectral Interpretation, Resource Identification, and Security‐Regolith Explorer sample return capsule (SRC) re‐entered the Earth’s atmosphere at hypersonic speeds from interplanetary space on 24 September 2023. The current work reports on 18 ground‐based acoustic sensors deployed at Wendover Airport, the same location that the Genesis and Stardust SRC re‐entries were recorded. Four different sensors (Chaparral Physics, Gem, Wilson Engineering Research and Development [WERD], and RedVox) were deployed in close proximity to compare their performance. All the sensors captured an N‐wave signal associated with the SRC re‐entry shock wave followed by a broadband coda. The Chaparral Physics array served as the high‐fidelity reference measurement. The N‐wave signal had a peak‐to‐peak amplitude of 4.07 Pa with a fundamental frequency of 4.98 Hz from 167.5° measured clockwise from north, nearly perpendicular to the SRC trajectory. In addition, high coherence in the coda was shown to be associated reflections from the surrounding mountains. In general, the more economical sensors (Gem, WERD, and RedVox) produced results that were consistent with these observations and sensor specifications. Beamforming with these single sensors arranged as an array showed agreement with the high‐fidelity array to within a couple of degrees. Furthermore, the current high‐fidelity results were compared with the measurements during the Genesis and Stardust SRC re‐entries. All three entries produced a broadband fundamental peak at a frequency that was inversely related to the SRC diameter as well as evidence of reflections from the surrounding topography.

KC, Real J. [Oklahoma State University, Stillwater↗

NASA NTRS1986

Composition, structure and chemistry of interstellar dust

The observational constraints on the composition of the interstellar dust are analyzed. The dust in the diffuse interstellar medium consists of a mixture of stardust (amorphous silicates, amorphous carbon, polycyclic aromatic hydrocarbons, and graphite) and interstellar medium dust (organic refractory material). Stardust seems to dominate in the local diffuse interstellar medium. Inside molecular clouds, however, icy grain mantles are also important. The structural differences between crystalline and amorphous materials, which lead to differences in the optical properties, are discussed. The astrophysical consequences are briefly examined. The physical principles of grain surface chemistry are discussed and applied to the formation of molecular hydrogen and icy grain mantles inside dense molecular clouds. Transformation of these icy grain mantles into the organic refractory dust component observed in the diffuse interstellar medium requires ultraviolet sources inside molecular clouds as well as radical diffusion promoted by transient heating of the mantle. The latter process also returns a considerable fraction of the molecules in the grain mantle to the gas phase.

Tielens, Alexander G. G. M.↗

NASA NTRS1994

Grain destruction in shocks in the interstellar medium

Destruction of interstellar dust occurs predominantly in supernova shock waves in the warm neutral/ionized medium (density approximately = 0.25/cu cm, temperature approximately = 10(exp 4) K). Recent theoretical developments and laboratory data for sputtering processes and grain-grain collisional vaporization allows us to better evaluate the grain destruction rate in interstellar shocks in the warm medium. We find that, independent of composition, grain denstruction in supernova blast waves is dominated by nonthermal sputtering for shock velocities greater than 50 km/s and less than or equal to 150 km/s and thermal sputtering at higher shock velocities. We use a detailed scheme for the vaporization of grains colliding at high velocities (v(sub s) greater than or equal to 20 km/s) and show that the grain-grain collision destruction process is only dominant for shock velocities of less than or equal to 50-80 km/s and is less important than previously assumed. Nevertheless, the grain-grain destruction rates are of order 30%-90% of the sputtering rates at v(sub s) greater than 100 km/s and less than 200 km/s and are important in vaporizing the cores of grains. Detailed results for grain destruction as a function of grain size and composition are presented. We also present results for silicon carbide, iron, ice, and porous test particles. For carbonaceous grains we find that the fractional destruction is less than or equal to 0.29, and for silicate it is less than or equal to 0.45, for v(sub s) less than or equal to 200 km/s. We have calculated grain lifetimes, using the three-phase model of the interstellar medium, and find lifetimes of 4 x 10(exp 8) yr for carbonaceous grains and 2.2 x 10(exp 8) yr for silicate grains. Given that the typical stardust injection timescale of 2.5 x 10(exp 9) yr, we conclude that efficient mechanisms for grain growth in the interstellar medium must exist in order that a significant fraction of the refractory elements be incorporated in dust, as observed. Therefore, although our improved model has less vaporization of dust due to grain-grain collisions, sputtering still destroys dust efficiently and grain mantle growth in the interstellar medium is required, a conclusion reached in previous models of grain destruction in the interstellar medium. Carbonaceous mantles on silicate grains can protect the silicate cores from sputtering destruction in interstellar shock waves, provided that the protective mantles can efficiently reform in the interstellar medium. Also, if the grains are porous the postshock grain velocities are lower than for solid particles, and grain destruction is reduced. Porosity and mantling may increase the grain lifetime by factors of approximately 3 and approximately 3-4, respectively. The fraction of interstellar silicon in silicate stardust is therefore less than or equal to 0.25, but more silicon might be depleted in the form of a grain mantle.

Jones, A. P.↗

NASA NTRS1998

Physics of Interplanetary Dust Collection with Aerogel

This report presents the results of research undertaken to study various problems associated with hypervelocity capture of dust particles in aerogel. The primary topics investigated were the properties of shocked aerogel and the requirements for reliable capture of particles on the STARDUST mission. In particular, the viscosity of shocked aerogel has been an open question. The results presented here suggest that the viscosity of aerogel at high impact velocities is negligible, although there remains some uncertainty about lower velocities. The model adopted for viscosity treats the mixture of polymeric silica and decomposition products and finds that, for particle velocities of 6-7 km/s, the viscosity is similar to that typical of light gasses at STP. Expressions for the Hugoniot of aerogel as a function of density were also obtained from the available data. All aerogels of interest for cosmic dust collectors have very similar shock velocity-particle velocity Hugoniot curves. The strength behavior of aerogel for low-speed penetration was measured, but further work is needed to study the proper way to apply this to the issue of terminal deceleration of a dust particle. Preliminary calculations designed to maximize the penetration depths were performed to determine the required density of aerogel to reliably stop a particle in a 3 cm thickness of aerogel (the path length expected for a normal impact into the STARDUST collector). In order to stop a particle of density rho(sub p) and diameter d(sub p), the mean density of the aerogel collector should be no less than that given by the expression bar rho(sub 0) = 1.085 X 10(exp -4 )rho(sub p)d(sub p), for densities measured in g/ cu cm and the particle diameter measured in micrometers.

Anderson, William W.↗

NASA NTRS1999

Asteroids and Comets Outreach Compilation

Contents include various different animations in the area of Asteroids and Comets. Titles of the short animated clips are: STARDUST Mission; Asteroid Castallia Impact Simulation; Castallia, Toutatis and the Earth; Simulation Asteroid Encounter with Earth; Nanorover Technology Task; Near Earth Asteroid Tracking; Champollian Anchor Tests; Early Views of Comets; Exploration of Small Bodies; Ulysses Resource Material from ESA; Ulysses Cometary Plasma Tail Animation; and various discussions on the Hale-Bopp Comet. Animation of the following are seen: the Stardust aerogel collector grid collecting cometary dust particles, comet and interstellar dust analyzer, Wiper-shield and dust flux monitor, a navigation camera, and the return of the sample to Earth; a comparison of the rotation of the Earth to the Castallia and Tautatis Asteroids; an animated land on Tautatis and the view of the motion of the sky from its surface; an Asteroid collision with the Earth; the USAF Station in Hawaii; close-up views of asteroids; automatic drilling of the Moon; exploding Cosmic Particles; and the dropping off of the plasma tail of a comet as it travels near the sun.

Source record↗

NASA NTRS1999

The Return of Astromaterials to Earth Over the Next Decade

We are entering a new and golden age of sample return missions. In the coming decade we will harvest samples from Comet P/Wild II and interstellar dust courtesy of the STARDUST Mission (Brownlee et al., 1997), an asteroid (probably 4660 Nereus or 1989ML) by the ISAS MUSES-C Mission (ISAS, 1997), and solar wind by the Genesis Mission. A sample return from Mars is also envisioned as early as 2008, and possibly one from the two moons of Mars. It is, however, sobering to realize that MUSES-C aims to return 3-10 g of sample, STARDUST will provide micrograms of comet and interstellar dust, and Genesis will harvest only few micrograms of atoms. The diminutive size of the returning samples may be a source of concern for petrologists used only to looking at hefty lunar rocks and meteorites. How much sample is really needed to achieve prime science objectives, while maintaining a cost effective mission? The range of geological processes that we will want to address with these samples is staggering, encompassing not merely the entire history of the Solar system, but the history of the elements themselves. The interstellar processes include element formation, production and interactions with radiation, formation of organics, grain condensation and evolution, and interactions with magnetic fields. In the pre-accretionary (nebular) environment we wish to understand grain condensation, evaporation and recondensation, shock, radiation processing, solar energetic particle implantation, gas composition, the magnetic environment, and the evolution of organics. Finally, for solid bodies we wish to examine accretion history, shock, brecciation, impact gardening, metamorphism, aqueous alteration, weathering, exposure history, volcanism, fumarolic activity, differentiation, the magnetic environment, atmosphere evolution, and the evolution of organics. Since 1981, NASA has supported asteroid and comet science by collecting dust grains from these bodies in the stratosphere, and making them available for analysis in laboratories worldwide (Warren and Zolensky, 1994). Over the succeeding 17 years, many new techniques have been developed for these painstaking analyses, by at least 24 different laboratories across the globe. Despite the fact that the particle supply has always exceeded the demand, the painstaking efforts required for most of the nano-scale analyses have resulted in only 1520 grains having been analyzed, with a total mass of only 0.52 micrograms. Thus we really require less sample for analysis than one might imagine.

Zolensky, Michael E.↗

NASA NTRS1997

Characteristics of Interstellar and Circumstellar Dust

This paper will review our current knowledge of circumstellar and interstellar dust from an astronomical point of view. About half of the interstellar dust volume consists of amorphous silicates. The remainder has to be made up of an carbonaceous component such as graphite, amorphous carbon (i.e., soot), Polycyclic Aromatic Hydrocarbon molecules (PAHs), and/or organic grain mantles (i.e., mixed polymers). The observational evidence for these components will be reviewed and their relative importance assessed. The emphasis will be on recent observations using the Infrared Space Observatory. Most of these dust components are formed in the outflows from stars in the late stages of their evolution (i.e., red giants, planetary nebulae, novae, supergiants, Wolf Rayet stars, and supernovae). Indeed, observation of such objects indicate an even richer spectrum of stardust components, including also SiC, MgS, and aluminates and crystalline silicates. These observations will be briefly discussed. The stardust budget of the galaxy will be reviewed and the relative importance of the various birth sites assessed. Finally, in recent years, isotopic composition studies have shown that some circumstellar and interstellar dust grains have been incorporated into solar system bodies such as planetary dust particles and meteorites without totally losing their identity. Among the components identified are SiC, graphite, diamonds, PAHs, aluminum oxides, as well as various trace element carbides. Studies of this kind have opened up a new window on the composition and structure of interstellar dust. These different sources of information on interstellar and circumstellar dust will be briefly contrasted.

Tielens, A. G. G. M.↗

NASA NTRS2003

The Nature of Interstellar Dust

The STARDUST mission is designed to collect dust the coma of comet Wild 2 and to collect interstellar dust on a second set of collectors. We have a reasonable idea of what to expect from the comet dust collection because the research community has been studying interplanetary dust particles for many years. It is less clear what we should expect from the interstellar dust. This presentation discusses what we might expect to find on the STARDUST interstellar dust collector.

Huss, G. R.↗

NASA NTRS2003

Robust Extraction and Multi-Technique Analysis of Micrometeoroids Captured in Low Earth Orbit

The use of low-density silica aerogel as the primary capture cell technology for the NASA Discovery mission Stardust to Comet Wild-2 [1] is a strong motivation for researchers within the Meteoritics community to develop techniques to handle this material. The unique properties of silica aerogel allow dust particles to be captured at hypervelocity speeds and to remain partially intact. The same unique properties present difficulties in the preparation of particles for analysis. Using tools borrowed from microbiologists, we have developed techniques for robustly extracting captured hypervelocity dust particles and their residues from aerogel collectors[2-3]. It is important not only to refine these extraction techniques but also to develop protocols for analyzing the captured particles. Since Stardust does not return material to Earth until 2006, researchers must either analyze particles that are impacted in the laboratory using light-gasgun facilities [e.g. 41 or examine aerogel collectors that have been exposed in low-Earth orbit (LEO) [5]. While there are certainly benefits in laboratory shots, i.e. accelerating known compositions of projectiles into aerogel, the LEO capture particles offer the opportunity to investigate real particles captured under real conditions. The aerogel collectors used in this research are part of the NASA Orbital Debris Collection Experiment that was exposed on the MIR Space Station for 18 months [5]. We have developed the capability at the UCB Space Sciences Laboratory to extract tiny volumes of aerogel that completely contain each impact event, and to mount them on micromachined fixtures so that they can be analyzed with no interfering support (Fig.1). These aerogel keystones simultaneously bring the terminal particle and the particle track to within 10 m (15 g cm- ) of the nearest aerogel surface. The extracted aerogel wedges containing both the impact tracks and the captured particles have been characterized using the synchrotron total external reflection X-ray fluorescence (TXRF) microprobe at SSRL, the Nuclear Microprobe at LLNL, synchrotron infrared microscopy at the ALS facility at LBL and the NSLS at BNL, and the Total Reflection X-ray Fluorescence (TXRF) facility at SLAC.

Westphal, A. J.↗

NASA NTRS2003

An Extraction and Curation Technique for Particles Captured in Aerogel Collectors

In 2006, the STARDUST mission will return samples of cometary, interplanetary and interstellar dust captured in aerogel collectors. The curation strategy (or strategies) for STARDUST remain to be defined. Here we present a technique for curation of particles captured in aerogel which will simultaneously preserve the entire particle track, and could allow for the elemental in situ analysis of both the particle residue at the terminus of the track and any particle residues located along the track. This builds on work that we have previously reported elsewhere.

Westphal, A. J.↗

NASA NTRS2004

Insight into Primordial Solar System Oxygen Reservoirs from Returned Cometary Samples

The recent successful rendezvous of the Stardust spacecraft with comet Wild-2 will be followed by its return of cometary dust to Earth in January 2006. Results from two separate dust impact detectors suggest that the spacecraft collected approximately the nominal fluence of at least 1,000 particles larger than 15 micrometers in size. While constituting only about one microgram total, these samples will be sufficient to answer many outstanding questions about the nature of cometary materials. More than two decades of laboratory studies of stratospherically collected interplanetary dust particles (IDPs) of similar size have established the necessary microparticle handling and analytical techniques necessary to study them. It is likely that some IDPs are in fact derived from comets, although complex orbital histories of individual particles have made these assignments difficult to prove. Analysis of bona fide cometary samples will be essential for answering some fundamental outstanding questions in cosmochemistry, such as (1) the proportion of interstellar and processed materials that comprise comets and (2) whether the Solar System had a O-16-rich reservoir. Abundant silicate stardust grains have recently been discovered in anhydrous IDPs, in far greater abundances (200 5,500 ppm) than those in meteorites (25 ppm). Insight into the more subtle O isotopic variations among chondrites and refractory phases will require significantly higher precision isotopic measurements on micrometer-sized samples than are currently available.

Brownlee, D. E.↗

NASA NTRS2004

Acquisition of a High-resolution Inductively Coupled Plasma Mass Spectrometer for Cosmochemical and Geochemical Research

The primary goal of our research in this program is to develop new techniques for the analysis of volatile trace elements in very small samples using inductively coupled plasma mass spectrometry (ICP-MS) in preparation for samples returned by the Stardust mission. The instrument that will serve as the basis of our experiments is the ELEMENT2 high-resolution ICP-MS. We have spent the past year designing the laboratory to house this instrument as well as space to store and prepare samples returned by the Stardust mission. Unfortunately, the location that we had initially selected for the instrument turned out to be insufficient for our needs. This was determined almost eight months into the first year of our funding cycle, after extensive work including the production of engineering drawings. However, during this time the Lunar and Planetary Laboratory was selected to lead Phoenix, the first Mars Scout mission. As a result of this award LPL purchased a new, 50,000 square foot building. We have acquired 1400 square feet of laboratory space in this new facility. Four-hundred square feet will be used for a class-100 clean room. This area is designated for storage and preparation of extraterrestrial materials. The additional 1000 square feet will house the ELEMENT2 ICP-MS and peripheral devices. This is an enormous amount of space for this instrument, but it provides plenty of room for expansion in the future. The ICP-MS and the clean room facilities have been purchased. The instrument has been delivered. The startup time for this instrument is relatively short and we expect to be collecting our first data by mid-summer.

Lauretta, D. S.↗

NASA NTRS2006

Mineralogy and Petrology of COMET WILD2 Nucleus Samples

The sample return capsule of the Stardust spacecraft will be recovered in northern Utah on January 15, 2006, and under nominal conditions it will be delivered to the new Stardust Curation Laboratory at the Johnson Space Center two days later. Within the first week we plan to begin the harvesting of aerogel cells, and the comet nucleus samples they contain for detailed analysis. By the time of the LPSC meeting we will have been analyzing selected removed grains for more than one month. This presentation will present the first results from the mineralogical and petrological analyses that will have been performed.

Zolensky, Michael↗

NASA NTRS2006

Constraints from Comets

Crystalline silicates identified in the laboratory examinations of cometary interplanetary dust particles, in Stardust particles, and in the IR spectra of comets and protoplanetary disks typically have high Mg and low Fe contents. In contrast, the amorphous silicates in IDPs and comets are predominantly Fe-rich. Mg-rich crystalline silicates are hypothesized to form by heating of amorphous silicates at temperatures above 1000 K. Annealing does not change the stoichiometry, i.e., the chemistry of the grains. Therefore, annealing is not expected to change an Fe-bearing amorphous silicate into a Mg-rich crystal. We discuss this challenge to the annealing scenario, review the condensation scenarios, and discuss the possibility that Fe reduction, a process thought to contribute in chondrule-formation, is the missing link between Fe-rich amorphous silicates and Mg rich crystalline silicates. We discuss the time scales for these processes in terms of time dependent 2D models of disks (by Gail & collaborators) and in terms of shocks. We mention the Stardust sample return results on Mg-rich crystalline silicates.

Wooden, Diane H.↗