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At least 271 records · Page 15

Graphene-based Yagi-Uda antenna with reconfigurable radiation patterns

This paper presents a radiation pattern reconfigurable Yagi-Uda antenna based on graphene operating at terahertz frequencies. The antenna can be reconfigured to change the main beam pattern into two or four different radiation directions. The proposed antenna consists of a driven dipole radiation conductor, parasitic strips and embedded graphene. The hybrid graphene-metal implementation enables the antenna to have dynamic surface conductivity, which can be tuned by changing the chemical potentials. Therefore, the main beam direction, the resonance frequency, and the front-to-back ratio of the proposed antenna can be controlled by tuning the chemical potentials of the graphene embedded in different positions. The proposed two-beam reconfigurable Yagi-Uda antenna can achieve excellent unidirectional symmetrical radiation pattern with the front-to-back ratio of 11.9 dB and the10-dB impedance bandwidth of 15%. The different radiation directivity of the two-beam reconfigurable antenna can be achieved by controlling the chemical potentials of the graphene embedded in the parasitic stubs. The achievable peak gain of the proposed two-beam reconfigurable antenna is about 7.8 dB. Furthermore, we propose a four-beam reconfigurable Yagi-Uda antenna, which has stable reflection-coefficient performance although four main beams in reconfigurable cases point to four totally different directions. The corresponding peak gain, front-to-back ratio, and 10-dB impedance bandwidth of the four-beam reconfigurable antenna are about 6.4 dB, 12 dB, and 10%, respectively. Therefore, this novel design method of reconfigurable antennas is extremely promising for beam-scanning in terahertz and mid-infrared plasmonic devices and systems.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Exploring leakage in dielectric films via automated experiments in scanning probe microscopy

Here electronic conduction pathways in dielectric thin films are explored using automated experiments in scanning probe microscopy (SPM). In this study, we use large field of view scanning to identify the position of localized conductive spots and develop an SPM workflow to probe their dynamic behavior at higher spatial resolution as a function of time, voltage, and scanning process in an automated fashion. Using this approach, we observe the variable behaviors of the conductive spots in a 20-nm-thick ferroelectric Hf 0.54 Zr 0.48 O 2 film, where conductive spots disappear and reappear during continuous scanning. There are also fresh conductive spots that develop during scanning. The automated workflow is universal and can be integrated into a wide range of microscopy techniques, including SPM, electron microscopy, optical microscopy, and chemical imaging.

36 MATERIALS SCIENCE↗

Constraints on a split superconducting transition under uniaxial strain in Sr 2 RuO 4 from scanning SQUID microscopy

More than two decades after the discovery of superconductivity in Sr 2 RuO 4 , it is still unclear whether the order parameter has a single component or two degenerate components. For any two-component scenario, application of uniaxial strain is expected to lift the degeneracy, generating two distinct phase transitions. The presence of a second (lower-temperature) transition may be observable by probes that are sensitive to changes in the London penetration depth, λ, as a function of temperature, T. Furthermore, we use scanning SQUID microscopy combined with a uniaxial strain device to test for a second transition under strain. We only observe a single transition. Within the temperature range where a second transition has been suggested by μSR measurements, we further place a tight upper bound of less than 1% on the change in the zero temperature superfluid density n s ∝ λ –2 (0) due to a second transition, suggesting that such a transition does not occur. These results constrain theories of the order parameter in Sr 2 RuO 4 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Low-temperature etching of silicon oxide and silicon nitride with hydrogen fluoride

Etching of high aspect ratio features into alternating SiO 2 and SiN layers is an enabling technology for the manufacturing of 3D NAND flash memories. In this paper, we study a low-temperature or cryo plasma etch process, which utilizes HF gas together with other gas additives. Compared with a low-temperature process that uses separate fluorine and hydrogen gases, the etching rate of the SiO 2 /SiN stack doubles. Both materials etch faster with this so-called second generation cryo etch process. Pure HF plasma enhances the SiN etching rate, while SiO 2 requires an additional fluorine source such as PF 3 to etch meaningfully. Further, the insertion of H 2 O plasma steps into the second generation cryo etch process boosts the SiN etching rate by a factor of 2.4, while SiO 2 etches only 1.3 times faster. We observe a rate enhancing effect of H 2 O coadsorption in thermal etching experiments of SiN with HF. Ammonium fluorosilicate (AFS) plays a salient role in etching of SiN with HF with and without plasma. AFS appears weakened in the presence of H 2 O. Density functional theory calculations confirm the reduction of the bonding energy when NH 4 F in AFS is replaced by H 2 O.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multiscale spectral nanoscopy

A system and method for non-invasively tracking a particle in a sample is disclosed. The system includes a 2-photon or confocal laser scanning microscope (LSM) and a particle-holding device coupled to a stage with X-Y and Z position control. The system also includes a tracking module having a tracking excitation laser, X-Y and Z radiation-gathering components configured to detect deviations of the particle in an X-Y and Z directions. The system also includes a processor coupled to the X-Y and Z radiation gathering components, generate control signals configured to drive the stage X-Y and Z position controls to track the movement of the particle. The system may also include a synchronization module configured to generate LSM pixels stamped with stage position and a processing module configured to generate a 3D image showing the 3D trajectory of a particle using the LSM pixels stamped with stage position.

42 ENGINEERING↗

Probing plasmons in three dimensions by combining complementary spectroscopies in a scanning transmission electron microscope

The nanoscale optical response of surface plasmons in three-dimensional metallic nanostructures plays an important role in many nanotechnology applications, where precise spatial and spectral characteristics of plasmonic elements control device performance. Electron energy loss spectroscopy (EELS) and cathodoluminescence (CL) within a scanning transmission electron microscope have proven to be valuable tools for studying plasmonics at the nanoscale. Each technique has been used separately, producing three-dimensional reconstructions through tomography, often aided by simulations for complete characterization. Here we demonstrate that the complementary nature of the two techniques, namely that EELS probes beam-induced electronic excitations while CL probes radiative decay, allows us to directly obtain a spatially- and spectrally-resolved picture of the plasmonic characteristics of nanostructures in three dimensions. Furthermore, the approach enables nanoparticle-by-nanoparticle plasmonic analysis in three dimensions to aid in the design of diverse nanoplasmonic applications.

36 MATERIALS SCIENCE↗

Final report: Mapping Interactions in Hybrid Systems with Active Scanning Probes

This project aimed to study and map interactions between components of hybrid nanodevices using a novel scanning probe approach. To enable this work, we initially constructed a flexible experimental apparatus allowing for simultaneous scanning probe and confocal optical microscopy measurements. This setup was first used for all-optical measurements of nanostructures, with the focus then shifting to hybrid devices in which single coherent electron spins are coupled to micron-scale ferromagnetic elements, which may prove useful for addressing single spins, enhanced sensing, or spin-wave-mediated coupling of spins for quantum information applications. A significant breakthrough was the realization that it is not necessary to fabricate a magnetic structure on a scanning probe – instead a ferromagnetic vortex core can act as an integrated, solid state, scanning probe. The core of the vortex produces a very strong, localized fringe field which can be used analogously to an MFM tip. Unlike a traditional MFM tip, however, the vortex core is scanned within an integrated device (eliminating drift), and can be moved on vastly faster timescales. This approach allows the detailed investigation of interactions between single spins and complex driven ferromagnetic dynamics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Growth, structural, and magnetic properties of single-crystal full-Heusler Co 2 TiGe thin films

This paper presents the growth, structural characterization, and measurement of magnetic properties of Co 2 TiGe thin films grown by molecular beam epitaxy on insulating MgO (001) substrates and conductive lattice matched InAlAs/InGaAs/InAlAs epitaxial layers grown on n-InP (001) substrates. A GdAs diffusion barrier was used to minimize interfacial reactions during Co 2 TiGe growth on InAlAs. The surface morphology, structural quality, and magnetic behavior were examined by reflection high-energy electron diffraction, scanning tunneling microscopy, X-ray diffraction, and superconducting quantum interference device magnetometry. The results reveal high quality Co 2 TiGe thin films with a saturation magnetization of ~1.8 μ B /formula unit and a Curie temperature of ~375 K. Finally, the magnetic easy axis was found to lie in the [110] direction but magnetometry also reveals that there is only a small difference in energy between the [110] and [010] magnetization directions.

36 MATERIALS SCIENCE↗

Simultaneous translational temperature measurements of different atomic species in plasma flows using scanning Fabry-Perot interferometry

A revised scientific instrument to measure simultaneously kinetic temperatures of different atoms from their optical emission profile is reported. Emission lines are simultaneously detected using one single scanning Fabry-Perot-interferometer (FPI) for a combined spectroscopic setup to acquire different emission lines simultaneously. The setup consists in a commercial Czerny-Turner spectrometer configuration which is combined with a scanning Fabry-Perot interferometer. The fast image acquisition mode of an intensified charge coupled device camera allows the detection of a wavelength interval of interest continuously while acquiring the highly resolved line during the scan of the FPI ramp. Results using this new setup are presented for the simultaneous detection of atomic nitrogen and oxygen in a high enthalpy air plasma flow as used for atmospheric re-entry research and their respective kinetic temperatures derived from the measured line profiles. The paper presents the experimental setup, the calibration procedure, and an exemplary result. The determined temperatures are different, a finding that has been published so far as due to a drawback of the experimental setup of sequential measurements, and which has now to be investigated in more detail.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Crickets{sup TM} and Curies: Lessons Learned from the Steel Industry - 18221

The global nuclear power industry, and to a lesser extent, the decommissioning and demolition of old nuclear weapons plants, obviously present challenges to those in the radioactive waste management field. Some if not many of these challenges have already been dealt with, and resolved, in the steel industry, including its recycling component. This paper presents proven state-of-the-art radiation detection systems used in steel and related recycling facilities, emphasizing current, reliable and flexible technologies for characterization, volume reduction, and remote handling of recyclable solid wastes contaminated and, just as important, not contaminated, with a wide range of radioactive isotopes. It will also cover features of remotely operated waste handling equipment effective in reducing or eliminating exposure of workers engaged in decontamination and demolition work on active and/or inactive nuclear installations. The industry group identified above has a long-standing policy regarding any radioactivity in potentially recyclable as well as waste materials it receives: if it is detected, it is rejected. The US Steel Manufacturers Association (SMA) put it this way in one of their Public Policy Statements: 'SMA members have not, and will not, accept scrap that is known to be radioactively contaminated' (emphasis included in the original) (1). This policy, adopted around the globe, obviously has major implications for decommissioning and demolition projects. To put it bluntly, if rad-contaminated metal, concrete, or other materials are sent to a facility for possible recycling, reuse or even disposal, they may well be rejected. If so, the materials will be returned to the generator--at the generator's cost-and a new solution will have to be found. This also results in additional costs for the generator. Facilities in the steel making and metal recycling industries have access to, and routinely count on, a wide range of proven detection technologies and techniques for monitoring incoming shipments and sorting the materials in them. The approaches range from using sensitive handheld instruments for pinpointing and isolating small devices such as isotope-containing gauges and radium dials all the way up to technologies effective for large volumes and weights of contaminated construction and demolition material. In this latter realm, the most suitable, robust, and field-proven system for decommissioning and demolition work is a radiation detection system fitted to a grappling and/or magnetic device, known as the Crickets{sup TM} technology, which automatically scans bulk material with no added effort or time in material handling operations. Highly versatile, a Crickets{sup TM} system can be put to work on any material-handling system, including grapples handling volumes ranging from 1 up to 18 cubic yards, while detecting radioactivity in real-time over a very wide dose range, from nSv to Sv levels. Other field-proven real-time measuring radiation detection devices can be fixed to conveyor belts with traverse speeds up 3 meters/second, also measuring in real time and over the same dose range, allowing both recyclable and waste materials with a pre-set level of radioactivity to be diverted off the belt. Finally, there are highly sensitive radiation portal installations for detecting radiation from materials being transported by vehicles, including those with roll-offs, dump trailers, and other containers, again in real-time and for the same dose ranges. For vehicles, the speed must be carefully controlled-the vehicles need to travel from 5 to 10 km/h through the scanning zone to ensure that maximum detection capability is maintained. When radiation detection systems at recycling and steel making facilities detect radioactive material in an incoming shipment, these facilities have a zero tolerance for accepting the cargo. Therefore, it is imperative that material from a demolition operation that is slated to be sent for recycling or other reuse be checked at the point of demolition at similar detection levels to avoid possible rejection later of a shipment because of its radioactivity. In addition to measuring overall radiation levels (for example, total gamma), when necessary, combinations of different radiation detection media can be used to detect the presence and intensities of specific isotopes such as U-235, Cs-137, Co-60, Am-241, etc., again in real-time and over a similar dose range. These detection technologies can be fixed or transportable. More important for the rad-waste management profession, this overall systems approach can be tailored and adapted during use on-site in any dismantling, demolition or remediation project, to allow materials to be thoroughly scanned before being released to the recycling stream for reuse, or to appropriate long-term storage and disposal facilities. Potentially recyclable materials with contamination such as steel beams and rebar will set off alarms at recycling facilities, resulting in unnecessary added expenses to the generator, primarily due to increased transportation costs, time delays and additional rad-waste handling and disposal charges. Additionally, there are situations where relatively lightly contaminated materials, once identified and appropriately characterized, can be reused in new construction applications, such as concrete from demolition being used in the base layer for roads or recycled steel used for repair or construction of bridges. In other cases, specific smaller volumes can be sent to specialized rad-waste disposal sites. These radiation detection systems can also be custom tailored to ensure proper handling and disposition of contaminated materials destined for reuse in specific applications where, for example, acceptable levels of radioactivity in NORM or TENORM can be reused or safely disposed of. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Solid-state electrochemistry on the nanometer and atomic scales: the scanning probe microscopy approach

Energy technologies of the 21st century require an understanding and precise control over ion transport and electrochemistry at all length scales – from single atoms to macroscopic devices. Our short review provides a summary of recent studies dedicated to methods of advanced scanning probe microscopy for probing electrochemical transformations in solids at the meso-, nano- and atomic scales. In this discussion we present the advantages and limitations of several techniques and a wealth of examples highlighting peculiarities of nanoscale electrochemistry.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Functionalization of Scanning Probe Tips with Epitaxial Semiconductor Layers

Functionalized scanning probe tips hold great promise for the controlled delivery of signals from and to selected nanoscale volumes. Here, a new nanotechnological approach for the functionalization of scanning probe tips is presented, targeting the transfer of the optical, electrical, thermal, or chemical properties of precisely characterized epitaxial semiconductor layers to the nanoscale probe tip. Homogeneously doped, strain‐relaxed heteroepitaxial germanium layers, several micrometers thick, are first grown on silicon wafers by low‐energy plasma‐enhanced chemical vapor deposition and then employed to functionalize the probe apex. This choice of materials and growth technique enables the future scalability of the tip functionalization process toward high production volumes. The fabricated probe tips are investigated in a transmission electron microscope, revealing that the crystal structure and the homogeneous doping level of the epitaxial layers are unchanged after the probe‐tip functionalization process. These doped‐germanium tips are also tested as nanoemitters of light at telecom wavelengths (1.55 µm) and applied as scattering probes for near‐field mid‐infrared microscopy. The reported combination of heteroepitaxial growth and a nanofabrication approach can be extended to a variety of epitaxial materials, thus enabling a new generation of scanning probes for the investigation of nanostructured materials and devices.

Giliberti, Valeria↗

magnetoARPES: Angle Resolved Photoemission Spectroscopy with magnetic field control

Angle-Resolved Photoemission Spectroscopy (ARPES) is a premier technique for understanding the electronic excitations in conductive, crystalline matter, in which the induced photocurrent is collected and dispersed in energy and angle of emission to reveal the energy- and momentum-dependent single particle spectral function A (k,ω). So far, ARPES in a magnetic field has been precluded due to the need to preserve the electron paths between the sample and detector. Here, in this paper we report progress towards “magnetoARPES”, a variant of ARPES that can be conducted in a magnetic field. It is achieved by applying a microscopic probe beam (≲10 μm) to a thinned sample mounted upon a special sample holder that generates magnetic field confined to a thin layer near the sample surface. In this geometry we could produce ARPES in magnetic fields up to around ±100 mT. The magnetic fields can be varied from purely in-plane to nearly purely out-of-plane, by scanning the probe beam across different parts of the device. We present experimental and simulated data for graphene to explore the aberrations induced by the magnetic field. These results demonstrate the viability of the magnetoARPES technique for exploring symmetry breaking effects in weak magnetic fields.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Analysis of Interpretable Data Representations for 4D-STEM Using Unsupervised Learning

Abstract Understanding the structure of materials is crucial for engineering devices and materials with enhanced performance. Four-dimensional scanning transmission electron microscopy (4D-STEM) is capable of mapping nanometer-scale local crystallographic structure over micron-scale field of views. However, 4D-STEM datasets can contain tens of thousands of images from a wide variety of material structures, making it difficult to automate detection and classification of structures. Traditional automated analysis pipelines for 4D-STEM focus on supervised approaches, which require prior knowledge of the material structure and cannot describe anomalous or deviant structures. In this article, a pipeline for engineering 4D-STEM feature representations for unsupervised clustering using non-negative matrix factorization (NMF) is introduced. Each feature is evaluated using NMF and results are presented for both simulated and experimental data. It is shown that some data representations more reliably identify overlapping grains. Additionally, real space refinement is applied to identify spatially distinct sample regions, allowing for size and shape analysis to be performed. This work lays the foundation for improved analysis of nanoscale structural features in materials that deviate from expected crystallographic arrangement using 4D-STEM.

Bruefach, Alexandra (ORCID:0000000209323477)↗

Electrochemical Strain Microscopy: Probing Electrochemical Transformations in Nanoscale Volumes

Electrochemical and electrocatalytic phenomena underpin a broad spectrum of energy, chemical, and information technologies. Examples range from electrocatalytic activation of oxygen reduction reactions in fuel cells, gas-solid reactions, and ionic transport in gas sensors and oxygen pumps, to a wide gamut of electrochemical and transport phenomena in primary and secondary batteries. Equally important is the role of ionic phenomena in information technologies, as exemplified by a recent wave of interest in memristive and electroresisitive information storage and logic devices. Finally, this article examines a new type of scanning probe microscopy (SPM), referred to as electrochemical strain microscopy (ESM), that can provide a better understanding of these complex phenomena.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of Zr{sup 4+} substitution on ferroelectric and dielectric properties of BaTiO{sub 3} ceramics

A lead-free system, BaTi{sub (1−x)}Zr{sub x}O{sub 3}, with x varying from 0.00 to 0.15 (in steps of 0.05), were prepared by solid state reaction method. X-ray diffraction study confirms the perovskite-type tetragonal structure with, a = 4.003 Å and c = 3.998 Å for pure BaTiO{sub 3} and a = 4.027 Å and c = 4.023 Å for pure BaTi{sub 0.85}Zr{sub 0.15}O{sub 3}. Microstructure changes, with Zr{sup 4+} in BaTi{sub (1−x)}Zr{sub x}O{sub 3}, are studied using scanning electron microscopy (SEM). Dielectric constant measurements show the maximum dielectric constant value (~ 9445) for a composition, BaTi{sub 0.85}Zr{sub 0.15}O{sub 3}. P-E loop measurements support ferroelectric nature for all the samples and maximum polarization value (~10.55 µC/cm{sup 2}) with squareness ratio ~0.6, at electric field 7.11 kV/cm, is obtained for BaTi{sub 0.85}Zr{sub 0.15}O{sub 3} composition. All the measured properties suggest that the BaTi{sub 0.85}Zr{sub 0.15}O{sub 3} may be suitable for memory device applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Imaging collective behavior in an rf-SQUID metamaterial tuned by DC and RF magnetic fields

In this study, we examine the collective behavior of two-dimensional nonlinear superconducting metamaterials using a non-contact spatially resolved imaging technique. The metamaterial is made up of sub-wavelength nonlinear oscillators in a strongly coupled 27x27 planar array of radio-frequency Superconducting QUantum Interference Devices (rf SQUIDs). By using low-temperature laser scanning microscopy we image microwave currents in the driven SQUIDs while in non-radiating dark modes and identify the clustering and uniformity of like-oscillating meta-atoms. We follow the rearrangement of coherent patterns due to meta-atom resonant frequency tuning as a function of external dc and rf magnetic flux bias. We find that the rf current distribution across the SQUID array at zero dc flux and small rf flux reveals a low degree of coherence. By contrast, the spatial coherence improves dramatically upon increasing of rf flux amplitude, in agreement with simulation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗