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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Protective coating for lithium-containing electrode and methods of making the same

A lithium-containing electrode with a protective coating and lithium-containing electrochemical cells including the same are provided herein. The protective coating has a first layer including a first fluoropolymeric matrix and Li—F compounds and a second layer including a second fluoropolymeric matrix. Methods of preparing the protective coating on the lithium-containing electrode by applying a first fluoropolymer and/or a first fluoropolymer precursor and a second fluoropolymer and/or a second fluoropolymer precursor are also provided herein.

Xiao, Xingcheng↗
DOE OSTI2021

Electrically Conductive and Protective Coating Compatibility with LSCF Cathodes

Ferritic stainless-steel interconnect materials are used in intermediate or high-temperature SOFCs because of their oxidation resistance, high formability, and low cost. Their corrosion resistance is due to the formation of a protective chromium oxide scale during operation. However, the protective oxide layer produces Cr-containing volatile species at SOFC operating temperatures and conditions, which can cause cathode poisoning. Spinel coatings have been developed to prevent cathode poisoning while maintaining an electrically conductive pathway through SOFC stacks. Generally, Mn-Co-O spinel has been the material of choice, but PNNL has developed an Mn-Cu-O spinel protective coating to remove the costly Co and enhance the electrical conductivity. This paper will focus on the electrically conductive coating’s compatibility with LSCF in high-temperature operating environments.

Choi, Jung-Pyung↗
DOE OSTI2021

Deposition of integrated protective material into zirconium cladding for nuclear reactors by high-velocity thermal application

A zirconium alloy nuclear reactor cylindrical cladding has an inner Zr substrate surface, an outer volume of protective material, and an integrated middle volume of zirconium oxide, zirconium and protective material, where the protective material is applied by impaction at a velocity greater than 340 meters/second to provide the integrated middle volume resulting in structural integrity for the cladding.

Mazzoccoli, Jason P.↗
DOE OSTI2022

Protective coatings for lithium metal electrodes

Double-layered protective coatings for lithium metal electrodes, as well as methods of formation relating thereto, are provided. The negative electrode assembly includes an electroactive material layer including lithium metal and a protective dual-layered coating. The protective dual-layered coating includes a polymeric layer disposed on a surface of the electroactive material layer and an inorganic layer disposed on an exposed surface of the polymeric layer. The polymeric layer has an elastic modulus of greater than or equal to about 0.01 GPa to less than or equal to about 410 GPa. The inorganic layer has an elastic modulus of greater than or equal to about 10 GPa to less than or equal to about 1000 GPa.

Xiao, Xingcheng↗
DOE OSTI2022

Systems and Implementation: Integrating Unmanned Aircraft Systems into Physical Protection Systems at Fixed Sites and During Transportation

Physical protection systems, and response forces in particular, are designed to prevent an adversary from successfully completing a malevolent act against a facility or transport operations. Timely detection and assessment of any potential adversary action against a target is an essential element of materials security. The timely detection and assessment must then be followed-up by a capable and timely response that might be enhanced with the additional situational awareness provided by unmanned aircraft systems (UAS). The United States Department of Energy’s National Nuclear Security Administration Office of International Nuclear Security has been exploring capabilities provided by UAS to support response force operations within the physical protection system. UAS have the potential to provide response force commanders and operators with situational awareness in assessing adversary locations and actions as well as the locations of responders. UAS may be utilized for area searches ahead of responder pathways to identify potential threats and to provide situational awareness of areas not normally covered by cameras (such as areas outside the fence line outside at fixed facilities). In addition, UAS can provide real-time information to transportation convoy teams that pass through constantly changing public access environments. This paper will provide operational recommendations to be addressed when integrating UAS into existing physical protection systems at fixed sites and during transport. Recommendations will include aspects of the following: needs analysis; tactics and techniques to support detection and assessment as well as response force deployment; remote pilot selection, qualifications, training, and currency; UAS selection criteria; UAS laws and regulations; possible cost sharing with other facility operations; and on-scene emergency management.

Stockwell, Brandon↗
DOE OSTI2023

Methods and materials for protection of sulfide glass solid electrolytes

A sulfide glass solid electrolyte sheet can be protected from reaction with moisture by a thin metal layer coating converted to a thin electrochemically functional and protective compound layer. The converted protective compound layer is electrochemically functional in that it allows for through transport of lithium ions.

Visco, Steven J.↗
DOE OSTI2023

Protective layers for metal electrode batteries

Hybrid electrodes for batteries are disclosed having a protective electrochemically active layer on a metal layer. Other hybrid electrodes include a silicon salt on a metal electrode. The protective layer can be formed directly from the reaction between the metal electrode and a metal salt in a pre-treatment solution and/or from a reaction of the metal salt added in an electrolyte so that the protective layer can be formed in situ during battery formation cycles.

Archer, Lynden A.↗
DOE OSTI2024

Feasibility Study for Cathodic Protection of Waste Tanks at Hanford

The Hanford Nuclear Reservation site contains approximately 211 million liters of radioactive and chemically hazardous waste arising from nuclear weapons production, beginning with World War II, and continuing through the Cold War. The waste is stored in 177 carbon-steel underground storage tanks, of which 149 are single-shell tanks (SSTs) and the remaining are double-shell tanks (DSTs). The mission of an ongoing River Protection Project is to retrieve the waste from the underground storage tanks and then treat and immobilize (i.e., vitrify) it for disposal. Waste from the older SSTs is being progressively retrieved into the newer DSTs for storage pending treatment, immobilization, and disposal. Waste chemistry controls are in place to mitigate general corrosion, pitting corrosion, and stress corrosion cracking (SCC) and minimize corrosion risks to the carbon steel tank liners of DST at the Hanford Site. The chemistry control program focuses on preserving liner integrity while balancing the need for caustic/nitrite additions that have large downstream impacts on vitrification. Some of the DSTs store salt cake or sludge waste layers contain out-of-specification interstitial liquids that contact the primary tank bottom or sidewall. Remediation of such layers through chemical additions is not practical. At the present time, the most significant leak integrity concern at Hanford is for corrosion of the tank bottoms of DSTs where the solids layer is out of specification because of hydroxide ion depletion and consequently, pH values that are less than 12. Cathodic protection (CP) has been proposed as a possible way to protect the liners of such tanks against corrosion. The objective of this project was to investigate the feasibility of applying CP to Hanford DSTs to mitigate internal corrosion of the carbon steel tank primary liners. The scope of the project included (1) a literature review on the application of CP to storage tank systems, in general, and to waste tanks at the Savannah River Site (SRS) and Hanford, (2) a review of the finite element analysis (FEA) model recently developed to evaluate potentials for a DST, and (3) the development of a boundary element analysis (BEA) model for CP for a DST. Tank AN-107, one of the Hanford DSTs, was selected for this work because (1) the bottommost waste layer in the tank is out-of-specification, and (2) electrochemical and resistivity data, based on recent waste sampling and testing, are available for this tank. The overarching conclusion of this study is that, based on the available information, it is feasible to apply CP to mitigate internal corrosion of the primary liners of the Hanford DSTs. However, significant additional information and work are required before a CP system can be designed. Recommendations for next steps in the design of the CP system will be presented.

WIERSMA, BRUCE↗
DOE OSTI2024

3D printable polymeric lightning strike protection system for fiber reinforced composites

The current embodiments include all-polymeric protective material for mitigating lightning strike damage. The protective material includes a hybrid matrix comprising PANI and MXene dispersed within a thermosetting epoxy resin. This hybrid matrix can be painted, printed, or applied as a conductive polymeric layer to a FRCP structure, for example an aircraft fuselage, wing, empennage, control surface (aileron, flap, slats, rudder, elevator) or a wind turbine blade. The protective material not only withstands lightning strikes, but also functions as shielding against electromagnetic interference and is corrosion-resistant and lightweight.

Kumar, Vipin↗
DOE OSTI2024

Methods and materials for protection of sulfide glass solid electrolytes

A sulfide glass solid electrolyte sheet can be protected from reaction with moisture by a thin metal layer coating converted to a thin electrochemically functional and protective compound layer. The converted protective compound layer is electrochemically functional in that it allows for through transport of lithium ions.

Source record↗
DOE OSTI2021

Variable frequency response testbed to validate protective relays up to 20 kHz☆

Microgrids operate in islanding or utility grid mode. In islanding mode, distributed energy sources with power electronics inverters can generate fault currents over a wide range of frequencies. To gain a better understanding of the nature of these events, it is crucial to measure currents at frequencies of up to 20 kHz at transient states with protective relays. Protective relays at these frequency responses should be tested prior to being installed in microgrids. However, testing at high-frequency currents cannot be done with Relay Test Equipment (RTE) that generate signals up to 50th Harmonic for 60 Hz (3 kHz). In this study, a frequency response method and testbed for high-frequency currents of up to 20.16 kHz was developed and tested. The testbed utilized a RTE and High-Frequency Power Source/ Amplifier. Furthermore, frequency relay experiments were run at frequencies of up to 1 and 20.16 kHz at a current magnitude of 0.1 and 0.5 A, respectively. The events were collected, and the current magnitude and frequency were plotted at time and frequency domain, respectively. The study of current magnitude and frequencies of up to 20.16 kHz for two overcurrent relays was performed and validated the variable frequency testbed and methodology.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Searching for Grid-Forming Technologies That Do Not Impact Protection Systems: A promising technology

The design of legacy-line protection elements has been guided by the behavior of synchronous machines during faults. Because of the significant field-winding inductance and rotating mass, the magnitude, angular frequency, and phase angle of the back-electromotive force (EMF) voltage waveforms of synchronous machines remain practically constant for several hundreds of milliseconds after a fault occurs. Furthermore this has facilitated the engineering of the memory-polarization technique in mho distance elements, which has been effective for machine-dominant power grids. However, this assumption is no longer held for inverter-based resources (IBRs) because of the lack of field winding and moment of inertia in power electronics devices. Notably, the negative-sequence directional overcurrent protection and the quadrilateral distance elements have been impacted by early IBRs with grid-following (GFL) controls because they did not inject negative-sequence currents during asymmetrical faults.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

A Time-Domain Protection Approach for AC Transmission Systems With Grid-Forming Resources

Ac transmission protection must reliably detect, classify, and locate short-circuit faults from voltage and current measurements. At present, these functionalities, which have been classically engineered using phasors approaches, are being challenged by the dynamic behavior and fault-current limits of converter-based generation. This paper tackles these challenges by engineering a time-domain protection approach that leverages the classical Bergeron model in a new manner. Low- and high-impedance faults are detected and classified by ascertaining how well line voltage and current measurements match the Bergeron equations. Faults are located by posing a novel one-variable optimization problem, whereas voltage and current waveforms at the fault location are estimated by unveiling rigorous relationships. The proposed elements are secure against external faults, measurement errors, and variation of line parameters and sampling time. Furthermore, these advances are tested via electromagnetic transient simulations and are significant to satisfy IEEE and North American Electric Reliability Corporation requirements.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

CCE Phase 4: Mitigations and Protections

During the first three phases, the CCE Team identified any instances of unverified trust in the organization’s technologies, processes, and procedures, any or all of which could be used to adversely impact the system. In Phase 4, the primary goal is to remove the possibility of the end effect—that is, to develop means or mechanisms that will ensure an adversary cannot achieve their Objective (identified in Phase 1) via cyber means. Such measures are known as “protections.” In some cases, this may not be possible, or the implementation of protections may not be desirable due to other considerations. In such cases, means and mechanisms should be developed that focus on putting an organization in a better position to identify adversary activities directed against it, increasing the cost of cyber-enabled sabotage for the adversary (including making things more difficult for the adversary and attempting to lower the chances an adversary may succeed), or decreasing the recovery cost of a victim organization. These measures are known as “mitigations.”

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2022

High Current-Density-Charging Lithium Metal Batteries Enabled by Double-Layer Protected Lithium Metal Anode

The practical application of lithium (Li) metal anode (LMA) is still hindered by non-uniformity of solid electrolyte interphase (SEI), formation of "dead" Li, and continuous consumption of electrolyte although LMA has an ultrahigh theoretical specific capacity and a very low electrochemical redox potential. Herein, we report a facile protection strategy for LMA using a double layer (DL) coating that consists of a polyethylene oxide (PEO)-based bottom layer which is highly stable with LMA and promotes uniform ion flux, and a cross-linked polymer-based top layer which prevents solvation of PEO layer in electrolytes. Li deposited on DL-coated Li (DL@Li) exhibits a smoother surface and much larger size than that deposited on bare Li. The LiF/Li 2 O enriched SEI layer generated by the salt decomposition on top of DL@Li further suppresses the side reactions between Li and electrolyte. Driven by the abovementioned advantageous features, the DL@Li||LiNi 0.6 Mn 0.2 Co 0.2 O 2 cells demonstrate capacity retention of 92.4% after 220 cycles at a current density of 2.1 mA cm -2 (C/2 rate) and stability at a high charging current density of 6.9 mA cm -2 (1.5C rate). These results indicate that the DL protection is promising to overcome the rate limitation of LMAs and high energy-density Li metal batteries.

25 ENERGY STORAGE↗
DOE OSTI2021

Thickness threshold study of polyaniline-based lightning strike protection coating for carbon/glass fiber reinforced polymer composites

Different polyaniline (PANI) based lightning strike protection (LSP) coating thicknesses were tested against simulated lightning strike tests to evaluate the threshold thickness of the coating. A series of lightning strike tests were performed on carbon/glass fiber reinforced polymer (CFRP/GFRP) composites subjected to simulated lightning currents ranging from 40 to 100 kA. Five LSP-coated specimens were considered herein: two CFRP and three GFRP composites. A minimum of ~ 345 μm thick PANI-based LSP coating on CFRP and GFRP composites under a 40 kA peak current retained 83 % and 100 % residual strength, respectively. Additionally, GFRP specimens tested against 60 and 100 kA peak currents exhibited 100 % residual strength. Finally, this study proposes that a PANI-based LSP coating is suitable for protecting GFRP composites, while the careful design is necessary for CFRP composites to avoid any catastrophic failure.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Enhancing operational safety: The NSTX-U Shorted Turn Protection (STP) system

The NSTX-U Shorted Turn Protection (STP) system is a vital safety feature designed to protect the tokamak’s coils during operations. It employs a Kalman filter-based algorithm to monitor coil currents and detect faults in real-time. If an anomaly is detected, the system swiftly terminates the tokamak pulse to prevent damage. Developed with Matlab and Simulink, the STP system has been validated through real-time simulations, ensuring its effectiveness for the upcoming upgrades of the NSTX-U facility. In conclusion, this article presents the theory for implementation of the STP algorithm and the results from simulation and real-time implementation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Broadly neutralizing anti-S2 antibodies protect against all three human betacoronaviruses that cause deadly disease

Pan-betacoronavirus neutralizing antibodies may hold the key to developing broadly protective vaccines against novel pandemic coronaviruses and to more effectively respond to SARS-CoV-2 variants. The emergence of Omicron and subvariants of SARS-CoV-2 illustrates the limitations of solely targeting the receptor-binding domain (RBD) of the spike (S) protein. Here, we isolated a large panel of broadly neutralizing antibodies (bnAbs) from SARS-CoV-2 recovered-vaccinated donors, which targets a conserved S2 region in the betacoronavirus spike fusion machinery. Select bnAbs showed broad in vivo protection against all three deadly betacoronaviruses, SARS-CoV-1, SARS-CoV-2, and MERS-CoV, which have spilled over into humans in the past two decades. Structural studies of these bnAbs delineated the molecular basis for their broad reactivity and revealed common antibody features targetable by broad vaccination strategies. These bnAbs provide new insights and opportunities for antibody-based interventions and for developing pan-betacoronavirus vaccines.

60 APPLIED LIFE SCIENCES↗