Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Produced Waters”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Synthesis of Yttrium Oxide Particles for Interfacial Water Radiolysis Studies

Radiolysis of water produces hydrogen gas (H2), posing safety issues for nuclear reactors. Metal oxides can impact H2 formation when water is present on metal oxide surfaces. This presentation focuses on the development of a controllable synthesis of spherical yttrium oxide (Y2O3), that later will be tested for H2 production in water radiolysis. Y2O3 was synthesized via hydrothermal hydrolysis precipitation to form yttrium hydroxide (Y(OH)3), followed by high temperature decomposition to form Y2O3. Various synthesis conditions were tested to determine their impact on particle morphology including reaction time, cooling rate, reactant concentration, and inert atmospheres. Through short reaction times and rapid cooling rate, spherical, relatively uniform particles of 350 nm were obtained. Despite inert atmospheres, carbonate formation occurred in all particles. A calcination temperature of 800°C is necessary to remove impurities. Future work will aim to reduce carbonate formation and improve particle uniformity. The synthetic procedure will be translated to other metal ions to study their impact on interfacial radiolysis.

08 - HYDROGEN↗
NASA NTRS2005

Sabatier Methanation Reactor for Space Exploration

The Sabatier Methanation Reactor technology is of vital importance to the success of the human and robotic exploration program. In order to achieve an affordable program, the logistics supply to support the mission must be minimized to the fullest extent possible. One area of potential reduction with high return on investment is the closure of life support loops, particularly oxygen and water. The Sabatier system accomplishes this by utilizing hydrogen and carbon dioxide, waste products from the life support system, to produce water and methane. The recovered water is then recycled back into the life support system to provide oxygen; while the methane can be used for propulsion, or can be broken down further to recover the hydrogen. This technology is applicable not only to transit phases of exploration, but surface habitats as well as in-situ propellant production. The Sabatier Reactor system has been developed for ground based demonstration experiments extensively over the past 30 years. Over the past three years, NASA has funded development of the Sabatier Carbon Dioxide Reduction Assembly (CRA) for use on the ISS. Currently this system is at TRL 5 and it is expected that the system will be flown on the ISS as a flight experiment, The purpose of the flight experiment is to integrate the Sabatier CRA into a synchronized system with the oxygen generation system and the carbon dioxide concentrator. The flight experiment will verify the integration of the different systems working together plus it will verify the capability of the system to operate, and effectively separate its products in a micro-gravity environment. Subsequent to design validation, the flight experiment can remain onboard the ISS providing valuable water to offset logistics re-supply requirements. Some of the challenges facing the development of the Sabatier system include handling vibration induced particulates, microgravity phase separation and containment of hazardous gases. Plans for adequately addressing these issues will be presented. The Sabatier carbon dioxide reduction process will greatly benefit any of the extended duration human exploration missions because of the tremendous savings of consumables realized. Any of these mission scenarios, be they transit or surface based, must consider closing the life support loops in order to make the mission achievable, let alone affordable. Carbon dioxide reduction technology will be necessary for future outpost habitats, and the technology needs to be proven viable in a space application. The Sabatier methanation reaction is also a desirable method for producing propellant from the Mars atmosphere. The common system could be designed to accept carbon dioxide from an indoor air revitalization loop concentrator, or from an outdoor atmosphere compressor. Carbon dioxide reduction validation is but one step in the spiral development of the in-situ propellant production system desired for future planetary exploration.

Murdoch, Karen↗
NASA NTRS1969

Device separates hydrogen from solution in water at ambient temperatures

Separator decreases the partial pressure of hydrogen gas dissolved in the water produced by fuel cells containing an alkaline electrolyte. The unit eliminates the hazards associated with the release of hydrogen from water solution when the hydrostatic pressure is rapidly decreased.

Albright, C. F.↗
NASA NTRS2009

Chemically Assisted Photocatalytic Oxidation System

The chemically assisted photocatalytic oxidation system (CAPOS) has been proposed for destroying microorganisms and organic chemicals that may be suspended in the air or present on surfaces of an air-handling system that ventilates an indoor environment. The CAPOS would comprise an upstream and a downstream stage that would implement a tandem combination of two partly redundant treatments. In the upstream stage, the air stream and, optionally, surfaces of the air-handling system would be treated with ozone, which would be generated from oxygen in the air by means of an electrical discharge or ultraviolet light. In the second stage, the air laden with ozone and oxidation products from the first stage would be made to flow in contact with a silica-titania photocatalyst exposed to ultraviolet light in the presence of water vapor. Hydroxyl radicals generated by the photocatalytic action would react with both carbon containing chemicals and microorganisms to eventually produce water and carbon dioxide, and ozone from the first stage would be photocatalytically degraded to O2. The net products of the two-stage treatment would be H2O, CO2, and O2.

Andino, Jean↗
DOE OSTI2024

Numerical Simulations in Support of a Long-Term Test of Gas Production From Hydrate Accumulations on the Alaska North Slope: Water Production and Associated Design and Management Issues

Here, we investigated numerical simulation strategies for a long-term test of depressurization-induced gas production from the B1 Sand of Unit B at the Hydrate-01 Stratigraphic Test Well. The main objective of this study was to estimate fluid production rates (with emphasis on water production) under a variety of conditions and production scenarios and contribute new insights to the design and management of the field test. In the first part of the study, we investigated the system response to a three-step depressurization process using two limiting sets of flow properties─the expected maximum and minimum intrinsic and effective permeabilities─for the very heterogeneous reservoir. In the second part, we investigated the effect of the production interval length and placement within the formation relative to the boundaries of the hydrate-bearing unit. The best performing well configuration was used in the third part of the study, which used the most representative subsurface flow properties to investigate the effect of the depressurization strategy on the production performance. The best overall performance (largest gas production with modest water production and a strong response at the observation wells) was obtained with a 10 m-long well situated 3 m below the top of the formation and a three-step depressurization scheme at 15-day intervals to a terminal bottomhole pressure of 2.8 MPa. The overall production performance was enhanced by a faster rate of depressurization. Estimated water production rates in all cases were limited and easily manageable. None of the tested well configurations or depressurization strategies significantly reduced water production without also severely reducing gas production. In all the investigated cases, 95% of the long-term fraction of produced water was replenished by inflows from the boundaries and could not be reduced. These substantial water inflows are an unavoidable feature of HU-B and cannot be easily mitigated by a hydraulic control.

02 PETROLEUM↗
DOE OSTI2021

Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation

Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER, to manipulate the spin ordering of ferromagnetic OER catalysts (e.g., by magnetization) can reduce the kinetic barrier. However, most active OER catalysts are not ferromagnetic, which makes the spin manipulation challenging. In this work, we report a strategy with spin pinning effect to make the spins in paramagnetic oxyhydroxides more aligned for higher intrinsic OER activity. The spin pinning effect is established in oxideFM/oxyhydroxide interface which is realized by a controlled surface reconstruction of ferromagnetic oxides. Under spin pinning, simple magnetization further increases the spin alignment and thus the OER activity, which validates the spin effect in rate-limiting OER step. The spin polarization in OER highly relies on oxyl radicals (O∙) created by 1 st dehydrogenation to reduce the barrier for subsequent O-O coupling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2019

Waste Water Brine Purification through Electrodialysis Ion Exchange

Reutilizing resources onboard the International Space Station (ISS) and for future deep space missions are critical for mission longevity and sustainability. Waste water brine produced from water recovery systems contain chemical species that could be processed into a potential fertilizer for future plant systems.Fertilizer production can be achieved through a process called electrodialysis ion exchange. Waste water containing inorganic salt components are fed through a series of ion exchange membranes to produce fertilizer (a phosphate rich stream), electrolysis-grade water, and other useful commodities.A test bed was constructed to conduct controlled experiments and an experimental design procedure developed to determine the feasibility of the process. Conductivity and pH probes were utilized to determine the ion concentration in each of the product streams, along with ion chromatography (IC) to define the exact concentration of each ion in every stream throughout the experiment. This is crucial in order to convey the effectiveness of ion removal from the incoming waste water stream.The waste water and electrolyte streams were prepared in the lab prior to experimentation. Additionally, the ion exchange membrane configurations were developed and Opto 22 data analysis software incorporated to conduct measurements in real time.Ions successfully diffused across their respective membranes into the concentrate, acid, and base streams. This resulted in pure water, a phosphate rich stream, and a separate anion/hydrogen and cation/hydroxide stream.

Hancock, Matthew L.↗
NASA NTRS2003

Seasonal/Diurnal Mapping of Ozone and Water in the Martian Atmosphere

Ozone and water are key species for understanding the stability and evolution of Mars atmosphere; they are closely linked (along with CO, H, OH, and O) through photochemistry. Photolysis of water produces the OH radical (thought to catalyze reformation of CO2 from CO and O2) and atomic hydrogen (which reacts with O3 forming OH and O2). Atomic hydrogen also reacts with O2 (forming HO2), thereby reducing the amount of O2 available to reform O3 from collisions between O and O2. Hence ozone and water should be anti-correlated on Mars. Photolysis of O3 produces O2(a(sup 1) delta g) with 90% efficiency, and the resulting emission band system near 1.27 mm traces the presence and abundance of ozone. This approach was initially used to study ozone on Earth and then applied to Mars. In 1997, we measured several lines of the O2(a(sup 1) delta g) emission using CSHELL at the NASA IRTF; the O2(a(sup 1) delta g) state is also quenched by collisions with CO2. This quenching dominates at lower altitudes so that the detected emissions are used to detect ozone column densities above ~20 km. The slit was positioned N-S along Mars' central meridian resulting in a one-dimensional map of ozone. Nearly simultaneous maps may be made of water using CSHELL by detecting the v1 fundamental band of HDO near 3.67 microns and using the D/H ratio for Mars. This technique was used by DiSanti and Mumma. With CSHELL, measurements for both O2(a(sup 1) delta g) emissions and HDO absorptions can be made during the day or night. Since January, 1997, we have repeated these measurements at different times during the Martian year. For all of these dates, we have positioned the slit N-S along the central meridian; for some of these dates, we have also stepped the slit across the planet at 1 arc-sec intervals generating a 2-dimensional map. We have also positioned the slit E-W on Mars thus providing diurnal variations of ozone and water along the slit.

Novak, R. E.↗
DOE OSTI2025

Enhancing water and oxygen transport through electrode engineering for AEM water electrolyzers

Anion-exchange membrane water electrolyzers (AEMWEs) can accelerate the deployment of more efficient and affordable hydrogen production solutions. Here, electrode structure is shown to affect water back-diffusion and oxygen transport, which, in return, governs overpotential behaviors in AEMWEs. Measurements indicate that electrode with copious catalytic sites produces water close to the AEM, creating a higher water gradient and driving water back-diffusion, which improves membrane hydration and mass transport. In situ measurement reveals a high pH gradient near the anode surface, which affects anode kinetics. Operando measurement shows reduced oxygen accumulation when decoupling oxygen production and transport on anode. Catalyst ink rheology and stability are tuned with additives to realize scalable fabrication of electrodes with enhanced transport features, allowing AEMWE to operate at 2 A cm−2 for over 1,000+ h at a 2.3 μV h−1 degradation rate. Analysis during and post-durability provides insights into degradation mechanisms. This work demonstrates an electrode design strategy for efficient and durable AEMWEs.

AEM↗
DOE OSTI2023

Prediction of alkaline earth metal ion adsorption on goethite for various background electrolytes with the CD-MUSIC model

As water scarcity drives the use of more saline water sources, contaminant fate and transport models must capture the impact of high concentrations of alkaline earth metal ions (AEMs) and background electrolytes in these more complex waters. By utilizing macroscopic adsorption data from various electrolyte systems, a Charge Distribution – Multisite Complexation (CD-MUSIC) model, capable of incorporating electrolyte adsorption, was able to accurately simulate the adsorption behavior of alkaline earth metal ions onto goethite. The modeling effort was guided by previous spectroscopic and surface complexation modeling of alkaline earth metal adsorption and built on previous CD-MUSIC modeling that accounted for changes in crystal face contributions to the surface site density as a function of specific surface area. Further, the model was constrained to consider only two dominant surface complex species for each metal ion adsorption reaction. These two species were selected from 44 possible species through objective curve fitting of single-solute macroscopic adsorption data. While most of the alkaline earth metal surface complexes formed outer-sphere complexes at the goethite surface, an inner-sphere species was utilized for Mg 2+ . With the surface complex species and equilibrium constants obtained from this study, the calibrated model successfully predicted alkaline earth metal ion adsorption over a wide range of solution and surface conditions; the model predictions encompassed a wide range of pH (5–11), solute/solid ratio (1.37 × 10 -5 – 8.33 × 10 -4 mol -solute /g -solid ), ionic strengths (0.01 M – 0.7 M), and background electrolytes (Na + , Cs + , Rb + , Cl - , and NO 3 - ) using the same crystal face contribution methodology for site density, capacitance values, and surface acidity constants adopted for proton and cadmium adsorption in previous work (Han and Katz, 2019). Model simulations for a range of background water chemistries demonstrated the potential for Mg 2+ to reduce Cd 2+ adsorption to goethite in model seawater and oil- and gas-produced waters.

42 ENGINEERING↗
NASA NTRS1973

Domestic wash-water reclamation using an aerospace-developed water recovery subsystem

A prototype aerospace distillation water recovery subsystem was tested to determine its capability to recover potable water from domestic wash water. A total of 0.0994 cu m (26.25 gallons) of domestic wash water was processed over a 7-day period at an average process rate of 0.0146 cu m per day (3.85 gallons per day). The subsystem produced water that met all United States Public Health Standards for drinking water with the exception of two standards which could not be analyzed at the required sensitivity levels. Average energy consumption for this evaluation to maintain both the recovery process and microbial control in the recovered water was approximately 3366 kilowatt-hours per cubic meter (12.74 kilowatt-hours per gallon) of water recovered. This condition represents a worst case energy consumption since no attempt was made to recover heat energy in the subsystem. An ultraviolet radiation cell installed in the effluent line of the subsystem was effective in controlling coliform micro-organisms within acceptable levels for drinking water. The subsystem recovered virtually 100 percent of the available water in the waste-water process. In addition, the subsystem removed 99.6 percent and 98.3 percent of the surfactants and phosphate, respectively, from the wash water.

Hall, J. B., Jr.↗
NASA NTRS2008

Production of Methane and Water from Crew Plastic Waste

Recycling is a technology that will be key to creating a self sustaining lunar outpost. The plastics used for food packaging provide a source of material that could be recycled to produce water and methane. The recycling of these plastics will require some additional resources that will affect the initial estimate of starting materials that will have to be transported from earth, mainly oxygen, energy and mass. These requirements will vary depending on the recycling conditions. The degredation products of these plastics will vary under different atmospheric conditions. An estimate of the the production rate of methane and water using typical ISRU processes along with the plastic recycling will be presented.

Captain, Janine↗
DOE OSTI2023

Tradeoffs in life cycle water use and greenhouse gas emissions of hydrogen production pathways

Hydrogen has been promoted as a key component of global decarbonization efforts, with various past studies estimating carbon emissions for several production pathways, but little past work has considered its water resource needs. This life cycle analysis considers hydrogen production on a per-kilogram basis for 11 pathways, fossil and non-fossil. It also includes impacts of treating water to the required quality for hydrogen production. Greenhouse gas emissions results were in a range of –15 to +31 kg CO 2 e/kg H 2 produced. Water consumption varied more widely, from about 7 to 55 kg water/kg H 2 for fossil-based pathways and 530 to 3400 kg water/kg H 2 for biomass-based pathways. Electrolysis with various renewable electricity scenarios were also modeled. Altogether, there are challenging tradeoffs to be navigated to achieve a low carbon and water footprint in hydrogen economy.

08 HYDROGEN↗
DOE OSTI2021

Kinetics of Direct Olefin Synthesis from Syngas over Mixed Beds of Zn–Zr Oxides and SAPO-34

A packed bed containing a physical mixture of both Zn–Zr mixed oxide catalyst and SAPO-34 converts syngas directly into a mixture of C 2 –C 5 olefins and paraffins. Specifically, the mixed oxide catalyst is responsible for intermediate oxygenate synthesis from syngas while the molecular sieve catalyzes olefin synthesis from the oxygenate intermediates. Kinetic measurements with cofed propylene over each catalyst independently confirm olefin hydrogenation activity over both components of the composite bed. The addition of either water or CO to the feed drops the activity of propylene hydrogenation over the Zn–Zr oxide. In sum, under reaction conditions of syngas feed and produced water, olefin hydrogenation predominantly occurs over the SAPO-34 catalyst, rather than over the catalyst responsible for hydrogenating CO into oxygenate intermediates. Here, a developed kinetic model consistent with this conclusion describes measurements at differing feed compositions, temperatures, space velocities, and bed catalyst mixing ratios. Technoeconomic analysis of the process indicates that the olefin-to-paraffin ratio is a key performance metric for commercial scale syngas conversion and highlights the importance of considering olefin hydrogenation rates over the molecular sieve component.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2003

Alternative Electrochemical Systems for Ozonation of Water

Electrochemical systems that are especially well suited for the small-scale generation of ozone and ozonated water for local use have been invented. These systems can operate with very little maintenance, and the only inputs needed during operation are electric power and water. Ozonated water produced by these systems can be used in diverse industrial applications: A few examples include sterilization in the brewing industry, general disinfection, and treatment of sewage and recycled water. The basic principle of operation admits of several alternative system configurations. The heart of the system is a stack of electrolytic cells, each containing a proton-exchange membrane (which serves as a solid electrolyte) sandwiched between a catalytic anode and a catalytic cathode. Preferably, the proton-exchange membrane is made of a perfluorinated sulfonic acid polymer. During electrolysis, a mixture of O2 and O3 gases is generated at the anode and H2 is generated at the cathode. Some of the O3 generated at the anode becomes dissolved in the water. The proportion of O3 in the O2/O3 mixture can be maximized by the selection of suitable electrode materials and the use of a high overpotential. Although the proton-exchange membrane conducts protons, it does not conduct electrons. It is also impermeable by gases; consequently, it maintains separation between the O2/O3 mixture evolved at the anode and the H2 evolved at the cathode.

Andrews, Craig C.↗
NASA NTRS2011

Software Architecture to Support the Evolution of the ISRU RESOLVE Engineering Breadboard Unit 2 (EBU2)

The In-Situ Resource Utilization (ISRU) Regolith & Environmental Science and Oxygen & Lunar Volatiles Extraction (RESOLVE) software provides operation of the physical plant from a remote location with a high-level interface that can access and control the data from external software applications of other subsystems. This software allows autonomous control over the entire system with manual computer control of individual system/process components. It gives non-programmer operators the capability to easily modify the high-level autonomous sequencing while the software is in operation, as well as the ability to modify the low-level, file-based sequences prior to the system operation. Local automated control in a distributed system is also enabled where component control is maintained during the loss of network connectivity with the remote workstation. This innovation also minimizes network traffic. The software architecture commands and controls the latest generation of RESOLVE processes used to obtain, process, and quantify lunar regolith. The system is grouped into six sub-processes: Drill, Crush, Reactor, Lunar Water Resource Demonstration (LWRD), Regolith Volatiles Characterization (RVC) (see example), and Regolith Oxygen Extraction (ROE). Some processes are independent, some are dependent on other processes, and some are independent but run concurrently with other processes. The first goal is to analyze the volatiles emanating from lunar regolith, such as water, carbon monoxide, carbon dioxide, ammonia, hydrogen, and others. This is done by heating the soil and analyzing and capturing the volatilized product. The second goal is to produce water by reducing the soil at high temperatures with hydrogen. This is done by raising the reactor temperature in the range of 800 to 900 C, causing the reaction to progress by adding hydrogen, and then capturing the water product in a desiccant bed. The software needs to run the entire unit and all sub-processes; however, throughout testing, many variables and parameters need to be changed as more is learned about the system operation. The Master Events Controller (MEC) is run on a standard laptop PC using Windows XP. This PC runs in parallel to another laptop that monitors the GC, and a third PC that monitors the drilling/ crushing operation. These three PCs interface to the process through a CompactRIO, OPC Servers, and modems.

Moss, Thomas↗
NASA NTRS2004

A chemical route to the formation of water in circumstellar envelopes around carbon-rich asymptotic branch stars: Fischer-Tropsch catalysis

Fischer-Tropsch catalysis has been suggested as a means of driving hydrocarbon chemistry in oxygen rich regions such as the protosolar nebula. In addition to producing hydrocarbons, Fischer-Tropsch catalysis also produces water, and it is therefore possible that such processes could account for the recent observations of water in the circumstellar envelope of asymptotic giant branch star IRC +10216.

astrochemistry molecular data giant branch stars↗