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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Freezing temperatures of H2SO4/HNO3/H2O mixtures: Implications for polar stratospheric clouds

The freezing temperatures of H2SO4/HNO3/H2O mixtures were systematically documented. Nitric acid was found to affect freezing significantly. Measurements show that nitric acid can cause substantial supercooling over a broad composition range. However, some ternary compositions, like to those in polar stratospheric clouds (PSCs), have high freezing temperatures. The freezing of PSC particles could be controlled by the temperature and vapor pressure of both nitric acid and water in a non-linear way. Formation of polar stratospheric clouds may be forecasted on the basic of conditions of temperature and vapor contents of water and nitric acid.

Song, Naihui↗
NASA NTRS1994

An overview of millimeter-wave spectroscopic measurements of chlorine monoxide at Thule, Greenland, February-March, 1992: Vertical profiles, diurnal variation, and longer-term trends

Measurements of chlorine monoxide in the stratosphere over Thule, Greenland (73.6 N, 68.4 W) were made quasi-continuously during the period February 8 to March 24, 1992, using a high-sensitivity ground based mm-wave spectrometer. These observations give diurnal, short term, and long term changes in the mixing ratio and vertical distribution of ClO. At an equivalent time after the Antarctic winter solstice, very large concentrations (up to approximately 1.5 ppbv) occur in lower stratospheric ClO, resulting in massive ozone destruction. We saw no evidence for large (approximately 1 top 1.5 ppbv) amounts of ClO in the 16-25 km range over Thule in February or March, in agreement with UARS (satellite) observations by the MLS mm-wave spectrometer for this period, and in marked contrast to UARS/MLS and ER-2 aircraft measurements over northern Europe and eastern Canada, respectively, during January, 1992. We have evidence for smaller enhancements (approximately 0.2 to 0.5 ppbv) in the 18-30 km range during late February-early March, which could result from transport of residual low NO2 air following earlier polar stratospheric cloud (PSC) processing (the last of which occurred at least one month earlier, however) or the result of chemical processing by Pinatubo aerosols. Direct influence of Pinatubo aerosols on Arctic ozone during the spring of 1992 has been difficult to assess, and this enhancement of low-altitude ClO might be a significant indicator of aerosol effects.

De Zafra, R. L.↗
NASA NTRS1995

Seasonal variation of atmospheric nitric acid over the South Pole in 1992

We conducted year-around measurements of mid infrared atmospheric emission over the South Pole in 1992. We were able to observe a large seasonal change of the total column of nitric acid (HNO3) vapor. During the summer the HNO3 column abundance was about 2 x 10(exp 16) molecules/sq cm. There was a small increase in the fall. A rapid decrease of 50% was observed in late June, soon after the stratospheric temperature reached the threshold for formation of type I polar stratospheric clouds (PSCs). By early July, the stratospheric temperature was cold enough to form type II PSCs, and the HNO3 column decreased to 7 x 10(exp 15) molecules/sq cm. Measured nitric acid values in the spring remained extremely low even after the stratosphere warmed well above PSC temperatures. This may indicate permanent removal of HNO3 by gravitational settling, or long-term sequestering in large particles. Normal summer values were not observed until the vortex dissipated and allowed the lateral transport of HNO3 to the south polar region.

Allen, Renate Van↗
NASA NTRS1995

UARS MLS observations of lower stratospheric ClO in the 1992-93 and 1993-94 Arctic winter vortices

Upper Atmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS) measurements of lower stratospheric ClO during 1992-93 and 1993-94 Arctic winters are presented. Enhanced ClO in the 1992-93 winter was first observed in early December, and extensively during February when temperatures were continually low enough for polar stratospheric cloud (PSCs). Sporadic episodes of enhanced ClO were observed for most of the 1993-94 winter as minimum temperatures hovered near the PSC threshold, with largest ClO amounts occurring in early March after a sudden deep cooling in late February.

Waters, J. W.↗
NASA NTRS1995

Freezing Behavior of Stratospheric Sulfate Aerosols Inferred from Trajectory Studies

Based on the trajectory analysis presented in this paper, a new mechanism is described for the freezing of the stratospheric sulfate aerosols. Temperature histories based on 10-day back trajectories for six ER-2 flights during AASE-I (1989) and AAOE (1987) are presented. The mechanism requires, as an initial step, the cooling of a H2SO4/H2O aerosol to low temperatures. If a cooling cycle is then followed up by a warming to approximately 196-198 K, the aerosols may freeze due to the growth of the crystallizing embryos formed at the colder temperature. The HNO3 absorbed at colder temperatures may increase the nucleation rate of the crystalling embryos and therefore influence the crystallization of the supercooled aerosols upon warming. Of all the ER-2 flights described, only the polar stratospheric clouds (PSC), observed on the flights of January 24, and 25, 1989 are consistent with the thermodynamics of liquid ternary solutions of H2SO4/HNO3/H2O (type Ib PSCs). For those two days, back trajectories indicate that the air mass was exposed to sulfuric acid tetrahydrate (SAT) melting temperatures about 24 hours prior to being sampled by the ER-2. Temperature histories, recent laboratory measurements, and the properties of glassy solids suggest that stratospheric H2SO4 aerosols may undergo a phase transition to SAT upon warming at approximately 198 K after going through a cooling cycle to about 194 K or lower.

Tabazadeh, A.↗
NASA NTRS1997

A Laboratory Study on the Phase Transition for Polar Stratospheric Cloud Particles

The nucleation and growth of different phases of simulated polar stratospheric cloud (PSC) particles were investigated in the laboratory. Solutions and mixtures of solutions at concentrations 1 to 5 m (molality) of ammonium sulfate, ammonium bisulfate, sodium chloride, sulfuric acid, and nitric acid were supercooled to prescribed temperatures below their equilibrium melting point. These solutions were contained in small diameter glass tubing of volumes ranging from 2.6 to 0.04 ml. Samples were nucleated by insertion of an ice crystal, or in some cases by a liquid nitrogen cooled wire. Crystallization velocities were determined by timing the crystal growth front passages along the glass tubing. Solution mixtures containing aircraft exhaust (soot) were also examined. Crystallization rates increased as deltaT2, where deltaT is the supercooling for weak solutions (2 m or less). The higher concentrated solutions (greater than 3 m) showed rates significantly less than deltaT2. This reduced rate suggested an onset of a glass phase. Results were applied to the nucleation of highly concentrated solutions at various stages of polar stratospheric cloud development within the polar stratosphere.

Teets, Edward H., Jr.↗
NASA NTRS1993

In Situ Measurements of the ClO/HCl Ratio: Heterogeneous Processing on Sulfate Aerosols and Polar Stratospheric Clouds

Simultaneous in situ measurements of stratospheric ClO and HCl have been made for the first time, during numerous flights of the ER-2 aircraft covering latitudes 24-90 deg. N from October 1991 through March 1992. The ClO/HCl ratio is identified as a key indicator of heterogeneous processing both outside and within the Arctic polar vortex. For ClO mixing ratios below about 120 pptv, remarkably constant ClO/HCl values of about 15% characterize the lower stratosphere. The observed values are significantly higher than those derived from a 2-D model using either gas phase photochemistry alone (2%), or including heterogeneous sulfate chemistry (5-10%). During the Arctic early spring, after conversion of HCl into reactive chlorine has taken place, the vortex edge is poorly defined by ClO levels. Loss of HCl and its slow recovery following low-temperature polar heterogeneous chemistry distinguishes HCl as a new and unique dynamical tracer of PSC-processed air.

Webster, C. R.↗
NASA NTRS1993

In Situ Measurements of the ClO/HCl Ratio: Heterogeneous Processing on Sulfate Aerosols and Polar Stratospheric Clouds

Simultaneous in situ measurements of stratospheric ClO and HCl have been made for the first time, during numerous flights of the ER-2 aircraft covering latitudes 24-90 deg N from October 1991 through March 1992. The ClO/HCl ratio is identified as a key indicator of heterogeneous processing both outside and within the Arctic polar vortex. For ClO mixing ratios below about 120 pptv, remarkably constant ClO/HCl values of about 15% characterize the lower stratosphere. The observed values are significantly higher than those derived from a 2-D model using either gas phase photochemistry alone (2%), or including heterogeneous sulfate chemistry (5-10%). During the Arctic early spring, after conversion of HCl into reactive chlorine has taken place, the vortex edge is poorly defined by ClO levels. Loss of HCl and its slow recovery following low-temperature polar heterogeneous chemistry distinguishes HCl as a new and unique dynamical tracer of PSC-processed air.

Webster, C. R.↗
NASA NTRS1993

A Case Study of the Mountain Lee Wave Event of January 6, 1992

A mountain wave event, observed at the southern tip of Greenland on January 6, 1992, was corroborated by three experiments: the Meteorological Measurement System (MMS), the Microwave Temperature Profiler (MTP), and the Reactive Nitrogen Instrument (NO/NO(y)). Gravity wave signatures with classical phase relationship between wind and temperature were observed on both the outbound and inbound legs at different altitudes. The waves showed both vertically propagating and evanescent properties. Characteristics of the dominant wave mode are: wavelength approximately equals 35 km, vertical displacement approximately equals 0.8 km, and peak-to-peak vertical wind approximately equals 6 ms-1. With the prevailing wind at approximately equals 37 m/s, the stratospheric temperature was reduced by 6 K to 195.5 K within 8 minutes. The implication and potential impact of mountain lee waves on the formation of polar stratospheric clouds (PSC's) are discussed.

Chan, K. R.↗
NASA NTRS1993

Stratospheric NO(y) Measurements on the NASA DC-8 during AASE 2

We survey measurements of stratospheric NO(y) on the NASA DC-8 during AASE 2 in early 1992. Emphasis is on correlations with other long-lived species: O3, N2O, and CH4. No cases of extremely high NO(y)/O3 ratios were seen in 1992. This suggests that denitrification at higher altitudes was less pervasive than in 1989. Values of NO(y)/O3 in 1992 are comparable to, though perhaps lower than, those measured in 1989. The correlation of NO(y) with N2O changes over the course of the mission. Relative to the correlation for the whole season, low values of NO(y) occur in February, most notably on the 22nd. The reason for the low NO(y) is unknown It is generally too warm at DC-8 altitudes for the presence of PSC particles, but denitrification at higher altitudes, followed by descent, might account for the low values seen on 22 February. However, this may be unlikely since the NASA ER-2, flying during the same period, saw no evidence of denitrification at higher altitudes.

Weinheimer, A. J.↗
NASA NTRS1998

Stratospheric Cooling and Arctic Ozone Recovery

We present sensitivity studies using the AER( box model for an idealized parcel in the lower stratosphere at 70 N during winter/spring with different assumed stratospheric coolings and chlorine loadings. Our calculations show that stratospheric cooling could further deplete ozone via increased polar stratospheric cloud (PSC) formation and retard its expected recovery even with the projected chlorine loading decrease. We introduce the concept of chlorine-cooling equivalent and show that a 1 K cooling could provide the same local ozone depletion as an increase of chlorine by 0.4-0.7 ppbv for the scenarios considered. Thus, sustained stratospheric cooling could further reduce Arctic ozone content and delay the anticipated ozone recovery in the Northern Hemisphere even with the realization of the Montreal Protocol and its Amendments.

Danilin, Michael Y.↗
NASA NTRS1998

Understanding the Star Formation Process in the Filamentary Dark Cloud GF 9: Near-Infrared Observations

We have performed a near-infrared JHK survey of a dense core and a diffuse filament region within the filamentary dark cloud GF 9 (LDN 1082). The core region is associated with the IRAS point source PSC 20503+6006 and is suspected of being a site of star formation. The diffuse filament region has no associated IRAS point sources and is likely quiescent. We find that neither the core nor the filament region appears to contain a Class I or Class II young stellar object. As traced by the dust extinction, the core and filament regions contain 26 and 22 solar mass, respectively, with an average H2 volume density for both regions of approximately 2500/cu cm. The core region contains a centrally condensed extinction maximum with a peak extinction of A(sub v) greater than or approximately equal to 10 mag that appears to be associated with the IRAS point source. The average H2 volume density of the extinction core is approximately 8000/cu cm. The dust within the filament, however, shows no sign of a central condensation and is consistent with a uniform-density cylindrical distribution.

Ciardi, David R.↗
NASA NTRS1998

Stratospheric Cooling and Arctic Ozone Recovery

We present sensitivity studies using the AER box model for an idealized parcel in the lower stratosphere at 70 deg N during winter/spring with different assumed stratospheric cooling and chlorine loadings. Our calculations show that stratospheric cooling could further deplete ozone via increased polar stratospheric cloud (PSC) formation and retard its expected recovery even with the projected chlorine loading decrease. We introduce the concept of chlorine-cooling equivalent and show that a 1 K Cooling could provide the same local ozone depletion as an increase of chlorine by 0.4-0.7 ppbv for the scenarios considered. Thus, sustained stratospheric cooling could further reduce Arctic ozone content and delay the anticipated ozone recovery in the Northern Hemisphere even with the realization of the Montreal Protocol and its Amendments.

Danilin, Michael Y.↗
NASA NTRS1995

UARS MLS Observations of Lower Stratospheric ClO in the 1992-93 and 1993-94 Arctic Winter Vortices

UARS (Upper Atmosphere Research Satellite) MLS (Microwave Limb Sounder) measurements of lower stratospheric ClO during the 1992-93 and 1993-94 Arctic winters are presented. Enhanced ClO in the 1992-93 winter was first observed in early December, and extensively during February when temperatures were continually low enough for PSCs. Sporadic episodes of enhanced ClO were observed for most of the 1993-94 winter as minimum temperatures hovered near the PSC threshold, with largest ClO amounts occurring in early March after a sudden deep cooling in late February.

Waters, J. W.↗
NASA NTRS1998

Stratospheric Cooling and Arctic Ozone Recovery

We present sensitivity studies using the AER box model for an idealized parcel in the lower stratosphere at 70 deg N during winter/spring with different assumed stratospheric cooling and chlorine loadings. Our calculations show that stratospheric cooling could further deplete ozone via increased polar stratospheric cloud (PSC) formation and retard its expected recovery even with the projected chlorine loading decrease. We introduce the concept of chlorine-cooling equivalent and show that a 1 K cooling could provide the same local ozone depletion as an increase of chlorine by 0.4 - 0.7 ppbv for the scenarios considered. Thus, sustained stratospheric cooling could further reduce Arctic ozone content and delay the anticipated ozone recovery in the Northern Hemisphere even with the realization of the Montreal Protocol and its Amendments.

Danilin, Michael Y.↗
NASA NTRS1995

Freezing Behavior of Stratospheric Sulfate Aerosols Inferred from Trajectory Studies

Temperature histories based on 10-day back growth trajectories for six ER-2 flights during AASE I (1989) and AAOE (1987) are presented. These trajectories along with the properties of the observed PSC (polar stratospheric cloud) particles are used here to infer the physical state of the pre-existing sulfuric acid aerosols. Of all the ER-2 flights described here, only the PSCs observed on the flights of January 24 and 25, 1989 are consistent with the thermodynamics of liquid ternary solutions of H2SO4/HNO3/H2O Ib PSCs). For these two days, back trajectories indicate that the air mass was exposed to SAT (sulfuric acid tetrahydrate) melting temperatures about 24 hours prior to being sampled by the ER-2. For the remaining ER-2 flights (January, 16, 19, and 20 for the AASE I campaign and August 17 for the AAOE campaign), the observed PSCs were probably composed of amorphous solid solutions of HNO3 and H2O (Type Ic PSCs). Formation of such Type Ic PSCs requires the presence of solid H2SO4 aerosols since liquid aerosols yield ternary solutions. The 10-day back trajectories of these flights indicate that the air mass was not exposed to SAT melting temperatures during the past week and had experienced cooling/warming cycles prior to being sampled by the ER-2. These temperature histories, recent laboratory measurements and the properties of glassy solids suggest that stratospheric H2SO4 aerosols may undergo a phase transition to SAT upon warming at approximately 198 K after going through a cooling cycle to about 194 K or lower.

Tabazadeh, A.↗
NASA NTRS1999

The Extraction of the NIRS Point Source Catalogs

The Near Infrared Spectrometer (NIRS) on the Infrared Telescope in Space, IRTS (a Japanese-US collaboration project), surveyed about 7% of the sky during its one month mission. In this work we extracted spectro-photometric point source (PS) data between 1.4 and 4 micron of high quality absolutely calibrated (2% flux uncertainties) and unbiased PS spectra in the near-IR. This database facilitates the study and understanding of a variety of science objectives, including stellar evolution of late type stars, determination of the Cosmic Infrared Background (CIB), and provides unprecedented faint stellar spectral calibrators. The objective of this work was to provide the community with a series of absolutely calibrated NIRS point source catalogs (PSC), with classification and association files. The catalogs will be archived at IRSA/IPAC.

Freund, Minoru M.↗
NASA NTRS2000

HST Studies of the Chromospheres, Wind, and Mass-Loss Rates of Cool Giant and Supergiant Stars

UV spectra of K-M giant and supergiant stars and of carbon stars have been acquired with the Goddard High Resolution Spectrograph (GHRS) on the Hubble Space Telescope (HST). These spectra have been used to measure chromospheric flow and turbulent velocities, study the acceleration of their stellar winds, acquire constraints on their outer atmospheric structure, and enable estimates of their mass-loss rates. Results from our observations of the giant stars Gamma Dra (K5 III hybrid), Alpha Tau (K5 III), Gamma Cru (M3.4 III), Mu Gem (M3 IIIab), and 30 Her (MG III), the supergiants Alpha Ori (M2 Iab) and Lambda Vel (K5 Ib), and the carbon stars TX Psc (NO; C6,2) and TW Hor (NO; C7,2) will be summarized and compared. The high resolution and wavelength accuracy of these data have allowed the direct measurement of the acceleration of the stellar winds in the chromospheres of several of these stars (from initial velocities of 3-9 km/s to upper velocities of 15-25 km/s) and of the chromospheric macroturbulence (-25-35 km/s). The high signal-to-noise and large dynamic range of these spectra have allowed the detection and identification of numerous new emission features, including weak C IV emission indicative of hot transition-region plasma in the non-coronal giant Alpha Tau, many new fluorescent lines of Fe II, and the first detection of fluorescent molecular hydrogen emission and of Ca II recombination lines in the UV spectrum of a giant star. The UV spectrum of two carbon stars have been studied with unprecedented resolution and reveal extraordinarily complicated Mg II lines nearly smothered by circumstellar absorptions. Finally, comparison of synthetic UV emission line profiles computed with the Lamers et al. (1987) Sobolev with Exact Integration (SEI) code with observations of chromospheric emission lines overlain with wind absorption features provides estimates of the mass-loss rates for four of these stars.

Carpenter, Kenneth G.↗