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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Effect of rhenium on the structure and properties of the weld metal of a molybdenum alloy

The structure and properties of welds made in molybdenum alloy VM-1 as a function of rhenium concentrations in the weld metal were studied. Rhenium was introduced into the weld using rhenium wire and tape or wires of Mo-47Re and Mo-52Re alloys. The properties of the weld metal were studied by means of metallographic techniques, electron microscopy, X-ray analysis, and autoradiography. The plasticity of the weld metal sharply was found to increase with increasing concentration of rhenium up to 50%. During welding, a decarburization process was observed which was more pronounced at higher concentrations of rhenium.

Dyachenko, V. V.↗
NASA NTRS1984

Constraints on the origin of the Moon from molybdenum and other siderophile elements

New data on the concentration of molybdenum in the mantle of the Earth and in lunar rocks confirm that most siderophile elements in lunar crustal rocks and lunar basalts derived from the interior have significantly lower concentrations than in the Earth's mantle and much lower concentrations compared to chrondritic meteorites. Different but correlated depletions of Co and P have been found in different lunar samples. The Mo data appear to be correlated with the P and Co depletions. The variations siderophile contents may be explained by small variations in the segregation of the siderophile element data which are consistent with theories for either a terrestrial gran independent origin for the Moon. It is suggested that the Moon formed from the Earth's mantle (depleted in siderophile elements) and segregation of metal within the Moon further lowered the concentrations compared to the Earth's mantle. The Mo data support evidence from other siderophile elements that the Moon almost certainly contains a metal core or pools of segregated metal.

Newsom, H. E.↗
NASA NTRS1985

Overheated Open Coronal Regions

The physics of compact, hydrostatic coronal shells formed from the collapse of overheated coronae is addressed. A large number of hydrostatic shells was computed for the usual exponential heating law with constant damping length. The boundary conditions were that on both sides of a shell the conductive flux at chromospheric temperatures is small. The boundary value problem was solved with a shooting technique. The main goal of the calculations was to determine the dependence of the shells on coronal heating flux (F sub Mo) and damping length (L); and in particular, to localize the boundary line in the parameter space (F sub Mo, L) that separates normal extended coronae from coronal shells.

Hammer, R.↗
NASA NTRS1985

Iron rich low cost superalloys

An iron-rich low-cost superalloy was developed. The alloy, when processed by conventional chill casting, has physical and mechanical properties that compare favorably with existing nickel and cobalt based superalloys while containing significantly lower amounts of strategic elements. Studies were also made on the properties of Cr(20)-Mn(10)-C(3.4)-Fe(bal.), a eutectic alloy processed by chill casting and directional solidification which produced an aligned microstructure consisting of M7C3 fibers in a gamma-Fe matrix. Thermal expansion of the M7C3 (M = Fe, Cr, Mn) carbide lattice was measured up to 800 C and found to be highly anisotropic, with the a-axis being the predominant mode of expansion. Repetitive impact sliding wear experiments performed with the Fe rich eutectic alloy showed that the directionally solidified microstructure greatly improved the alloy's wear resistance as compared to the chill cast microstructure and conventional nickel base superalloys. Studies on the molybdenum cementite phase prove that the crystal structure of the xi phase is not orthorhombic. The crystal structure of the xi phase is made up of octahedra building elements consisting of four Mo and two Fe atoms and trigonal prisms consisting of four Fe and two Mo atoms. The voids are occupied by carbon atoms. The previous chemical formula for the molybdenum cementite MoFe2C is now clearly seen to be Mo12Fe22C10.

Wayne, S. F.↗
NASA NTRS1984

MOD silver metallization for photovoltaics

The development of flat plate solar arrays is reported. Photovoltaic cells require back side metallization and a collector grid system on the front surface. Metallo-organic decomposition (MOD) silver films can eliminate most of the present problems with silver conductors. The objectives are to: (1) identify and characterize suitable MO compounds; (2) develop generic synthesis procedures for the MO compounds; (3) develop generic fabrication procedures to screen printable MOD silver inks; (4) optimize processing conditions to produce grid patterns and photovoltaic cells; and (5) develop a model which describes the adhesion between the fired silver film and the silicon surface.

Vest, G. M.↗
NASA NTRS1984

Metal-support interactions during the adsorption of CO on thin layers and islands of epitaxial palladium

Islands and continuous layers of palladium were grown in an ultrahigh vacuum on substrates of Mo(110)c(14 x 7)-O, designated MoO(x), and of clean Mo(110). It was found that as-deposited islands and layers exhibited bulk palladium adsorption properties for CO when deposited at room temperature and for palladium thicknesses in excess of about 3 monolayers. CO adsorption was drastically reduced, however, on annealing. For islands, annealing temperatures of as low as 400 K led to some reduction in CO adsorption whereas more severe reductions were found to occur at 600 K for islands and at 800 K for continuous multilayers. The deactivation depended on the palladium thickness, the substrate species and the extent of thermal treatments. Auger electron spectroscopy, temperature-programmed desorption and Delta-Phi measurements were combined to interpret the deactivation behavior in terms of substrate-support interactions involving the diffusion of substrate species towards the palladium surface.

Park, C.↗
NASA NTRS1984

Corrosion behavior of magnetron sputter-deposited (Mo/0.6/Ru/0.4/)82B18 and Mo82B18 amorphous metal films

Amorphous metallic films of Mo49Ru33B18 and Mo82B18 have been prepared by magnetron sputtering, and their corrosion behavior was investigated and compared with amorphous liquid-quenched Mo49Ru33B18 and crystalline Mo i acidic and basic solutions. Sputtered Mo49Ru33B18 showed lower corrosion rates compared with liquid-quenched Mo49Ru33B18, owing to the superior surface smoothness and uniformity of the former. Amorphous Mo82B18 showed low corrosion rates in both acidic and basic aqueous solutions. Comparison of the corrosion properties of Mo49Ru33B18 with Mo82B18 and Mo demonstrates the roles of the alloys' constituents. Ru significantly extends the passive region to high-anodic potentials, but, at less-anodic potentials, Mo82B18 has the lowest corrosion rate.

Williams, R. M.↗
NASA NTRS1984

Factors which influence directional coarsening of gamma-prime during creep in nickel-base superalloy single crystals

Changes in the morphology of the gamma prime precipitate were examined as a function of the time during creep at 982 C in 001 oriented single crystals of a Ni-Al-Mo-Ta superalloy. In this alloy, which has a large negative misfit of -0.80 pct., the gamma prime particles link together during creep to form platelets, or rafts, which are aligned with their broad faces perpendicular to the applied tensile axis. The effects of initial microstructure and alloy composition of raft development and creep properties were investigated. Directional coarsening of gamma prime begins during primary creep and continues well after the onset of second state creep. The thickness of the rafts remains constant up through the onset of tertiary creep, a clear indication of the stability of the finely-spaced gamma/gamma prime lamellar structure. The thickness of the rafts which formed was equal to the initial gamma prime size which was present prior to testing. The single crystals with the finest gamma prime size exhibited the longest creep lives, because the resultant rafted structure had a larger number of gamma/gamma prime interfaces per unit volume of material. Reducing the Mo content by only 0.73 wt. pct. increased the creep life by a factor of three, because the precipitation of a third phase was eliminated.

Mackay, R. A.↗
NASA NTRS1984

Osseous adaptation to continuous loading of rigid endosseous implants

The effect of loading on etched Ti implants in the femurs of young (3 mo) and adult (6 mo) rabbits is investigated experimentally. The results are presented in photographs, fluorescence and polarization micrographs, radiographs, and drawings and discussed. Implantation is followed by formation of coarse woven bone within 3 d and mature lamellar bone by 6 wks, with nonspecific subperiosteal bony hypertrophy in the young rabbits only. Spring loading at 100 g produces spontaneous spiral-type fractures when applied immediately, but the implants remain rigid when loads are applied after 6-12 wks of healing. The mechanisms of bone formation involved are examined, and the potential of endosseous implants as anchors in orthodontics or dentofacial-orthopedics is confirmed.

Roberts, W. E.↗
NASA NTRS1986

Development of a potentiometric EDTA method for determination of molybdenum. Use of the analysis for molybdenite concentrates

Based on considerations of principles and experimental data, the interference of sulfate ions in poteniometric titration of EDTA with FeCl3 was confirmed. The method of back complexometric titration of molybdenum of Nonova and Gasheva was improved by replacing hydrazine sulfate with hydrazine hydrochloride for reduction of Mo(VI) to Mo(V). The method can be used for one to tenths of mg of molybdenum with 0.04 mg standard deviation. The specific method of determination of molybdenum in molybdenite concentrates is presented.

Khristova, R.↗
NASA NTRS1984

Substrate heating rates for planar and cylindrical-post magnetron sputtering sources

Results are presented for the substrate heating energy/atom required in the planar magnetron sputtering of Al, Cr, Ni, Cu, Mo, In, Ta, W, and Pt in Ar, as well as Al and Cr in O2. Data are also obtained for cylindrical magnetron sputtering of Nb, Ag, Ta, W, and Pb-Sn in Ar, and Mo sputtered in Ne, Ar, Kr, and Xe. Planar and cylindrical magnetron heating rates were comparable. Special experiments were conducted to examine the contributions to substrate heating of plasma species and ion neutralization and reflection at the cathode; the results obtained indicate that charged plasma species do not significantly contribute to the heating, but that neutralized and reflected ions play a significant role in the planar as well as cylindrical cases despite the differences in cathode geometry.

Thornton, J. A.↗
NASA NTRS1985

Electron temperature and average density in spherical laser-produced plasmas - Ultraviolet plasma spectroscopy

The average values of the electron temperature Te and the electron density Ne in the corona plasmas of spherically irradiated high-Z targets have been estimated. Targets composed of the elements Cu through Br, Rb, and Mo were irradiated using the fundamental (1.06 microns) and the frequency-tripled (351 nm) output of the Omega laser system. Spectra were recorded in the wavelength region 15-200 A. Using various extreme ultraviolet spectroscopic techniques, it is found that for the case of a Mo plasma produced by frequency-tripled laser irradiation, Te = 2600 + or - 600 eV and Ne is greater than 6 x 10 to the 20th/cu cm. This is consistent with a 'flux limit' smaller than 0.1. The estimated values of Te and Ne are lower in the corona plasmas produced using the fundamental (1.06 micron) irradiation.

Goldsmith, S.↗
NASA NTRS1986

Mars Observer orbital accuracy analysis

Attention is given to the orbital accuracy of the Mars Observer (MO) spacecraft throughout its 687 days of mapping (scheduled to commence in 1991). The MO's short period and near circular orbit necessitate a multiorbit analysis in which the spacecraft's motion is strongly perturbed by the local and global gravity field of Mars. This analysis attests to the feasibility of achieving an orbital position accuracy at the level of 2-3 km within the data interval. It is found that Very Long Baseline Interferometric data can rectify a situation in which the position accuracy degrades significantly.

Esposito, P. B.↗
NASA NTRS1987

Advanced powder metallurgy aluminum alloys via rapid solidification technology, phase 2

Marko's rapid solidification technology was applied to processing high strength aluminum alloys. Four classes of alloys, namely, Al-Li based (class 1), 2124 type (class 2), high temperature Al-Fe-Mo (class 3), and PM X7091 type (class 4) alloy, were produced as melt-spun ribbons. The ribbons were pulverized, cold compacted, hot-degassed, and consolidated through single or double stage extrusion. The mechanical properties of all four classes of alloys were measured at room and elevated temperatures and their microstructures were investigated optically and through electron microscopy. The microstructure of class 1 Al-Li-Mg alloy was predominantly unrecrystallized due to Zr addition. Yield strengths to the order of 50 Ksi were obtained, but tensile elongation in most cases remained below 2 percent. The class 2 alloys were modified composition of 2124 aluminum alloy, through addition of 0.6 weight percent Zr and 1 weight percent Ni. Nickel addition gave rise to a fine dispersion of intermetallic particles resisting coarsening during elevated temperature exposure. The class 2 alloy showed good combination of tensile strength and ductility and retained high strength after 1000 hour exposure at 177 C. The class 3 Al-Fe-Mo alloy showed high strength and good ductility both at room and high temperatures. The yield and tensile strength of class 4 alloy exceeded those of the commercial 7075 aluminum alloy.

Ray, Ranjan↗
NASA NTRS1986

Simulations of the gross solar magnetic field during sunspot cycle 21

Regarding new bipolar magnetic regions as sources of flux, the evolution of the radial component of the solar photospheric magnetic field during 1976-1984 has been simulated with a spatial resolution of about 34,000 km, and the corresponding evolution of its absolute value averaged over the visible disk is derived. For nominal values of the transport parameters, this simulated gross field is in close, though imperfect, agreement with the observed gross field and its associated indices of solar activity. By analyzing the response of the simulated gross field to variations in the transport parameters and the source properties, it is found that the simulated field originates in newly erupted bipolar regions. The lifetimes of these regions are almost always less than three mo. Consequently, the strength of the simulated gross field is a measure of the current level of solar activity, and any recurrent patterns with lifetimes in excess of six mo must reflect the continuing eruption of new flux at 'active longitudes' rather than the persistence of old flux in long-lived magnetic structures.

Sheeley, Neil R., Jr.↗
NASA NTRS1987

Core formation in the shergottite parent body and comparison with the earth

Abundances of elements in shergottite, nakhlite, and Chassigny meteorites which originated on a single planet, the shergottite parent body (SPB), were examined with the aim of elucidating the chemical conditions of metal separation and core formation in the SPB and of testing present models of planetary core formation. Using partition coefficients and the SPB mantle composition determined in earlier studies, the abundances of Ag, Au, Co, Ga, Mo, Ni, P, Re, S, and W were modeled, with free parameters being oxygen fugacity, proportion of solid metal formed, proportion of metallic liquid formed, and proportion of silicate that is molten. It is shown that the abundances of all elements (except Mo) could be reproduced using models with these four free parameters. In contrast to the SPB, an equivalent model used to predict element abundances in the earth's mantle was shown by Jones and Drake (1986) to be inadequate; there is at present no hypothesis capable of quantitatively reproducing the elemental abundances of the earth's mantle. The contrast suggests that these two terrestrial planets (assuming that the SPB is Mars) may have accreted or differentiated differently.

Treiman, Allan H.↗
NASA NTRS1987

Chill block melt spinning of nickel-molybdenum alloys

Samples of Ni-Mo alloys ranging in composition from pure nickel to Ni-40 at. pct molybdenum were cast by the chill block melt-spinning rapid solidification technique and examined by optical metallography, X-ray diffraction, and microhardness testing. Casting difficulties were encountered with lean alloys, but richer alloys spread more readily on the casting wheel. Alloy microstructures for 5 to 37.5 at. pct molybdenum ribbons were primarily cellular/dendritic; microstructure feature size decreased with increasing molybdenum content. Extended solubility of molybdenum in gamma-nickel, with fcc lattice parameter increasing with composition to the 1.05 power, was observed up to 37/5 at. pct molybdenum. Substoichiometric Ni-Mo (delta) nucleated on the wheel side of the ribbons of compositions 35, 37.5, and 40 at. pct molybdenum. The amount of partitionless delta-phase thus formed increased with increasing molybdenum content and quench rate. This substoichiometric delta transformed readily to a fine structure gamma-delta mixture.

Hemker, Kevin J.↗
NASA NTRS1987

Effect of alloy composition on the sodium-sulfate induced hot corrosion attack of cast nickel-base superalloys at 900 C

The effects of Cr, Al, Ti, Mo, Ta, Nb, and W content on the hot corrosion of Ni-base alloys were examined experimentally. The superalloys were tested for 300 1-hr cycles at 900 C in a Mach 0.3 burner rig flame containing 0.5 ppmw sodium. The data reveal that the best corrosion resistance is obtained when the Cr content is greater than 12 percent; however, good resistance is detected in some alloys with Cr content less than 10 percent provided that the Al content is less than 2.5 wt pct and the Ti content is less than 4 wt pct. It is observed that the influence of W, Ta, Mo, and Nb content on resistance is dependent on Al and Ti contents. The derivation of an equation for estimating hot corrosion attack as a function of alloy composition using multiple linear regression analysis is described. The applicability of the equation is tested using various data sets of alloys. It is noted that the equation can be used to explain the effects of alloy composition on attack rates.

Stearns, C. A.↗