Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Mid infraRed Instruments”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Mid-IR interband cascade lasers

Efficient mid-IR interband cascade (IC) lasers are developed based on 111-V semiconductor materials to cover wavelength range from 2.7 to 5.6 (mu)m. These IC lasers reuse injected electrons in cascade stages for photon generation with high quantum efficiency to achieve high output powers. Also, IC lasers have low threshold current density with very efficient use of applied voltage, resulting in reduced power consumptions. Single-mode distributed feedback lasers have been made, and integrated into aircraft and balloon instrument which made measurements of CH4 and HCI. In this work, the characteristics of IC lasers and their recent development are reviewed.

mid - infrared↗
NASA NTRS2018

The Origins Space Telescope

The Universe has never been seen like this before. The window into the infrared opens only above Earth's atmosphere, and humanity has barely glimpsed outside. About half of the light emitted by stars, planets, and galaxies over the lifetime of the Universe emerges in the infrared. With an unparalleled sensitivity increase — up to a factor of 1,000 more than any previous or planned mission — the advance offered by the Origins Space Telescope (OST) is akin to that from the naked eye to humanity's first telescope, or from Galileo's first telescope to the first telescope in space. While key path-finding missions have glimpsed a rich infrared cosmos, extraordinary discovery space awaits; the time for a far-infrared revolution has begun.Are we alone or is life common in the Universe? OST will directly address this long-standing question by searching for signs of life in the atmospheres of potentially habitable terrestrial planets transiting M dwarf stars. How do planets become habitable? OST will trace the trail of cold water from the interstellar medium, through protoplanetary disks and into the outer reaches of our own Solar System. How do stars, galaxies, black holes and the elements of life form, from the cosmic dawn to today? With broad wavelength coverage and fast mapping speeds, OST will map millions of galaxies, simultaneously measuring star formation rates and black hole growth across cosmic time, peering deeper into the far reaches of the Universe than ever before.OST will be maintained at a temperature of 4 K, enabling its tremendous sensitivity gain, and will operate from 5 m to 600 m, encompassing the mid- and far-infrared. OST has two Mission Concepts: Concept 1 with a 9.1-m deployed off-axis primary, and Concept 2, described here, a non-deployed 5.9-m on-axis telescope with the equivalent collecting area of the James Webb Space Telescope (JWST). Concept 2 includes four instruments with capabilities for imaging (large surveys and pointed), spectroscopy (survey and high-resolution modes) and polarimetry, as well as an instrument for high-precision spectroscopy of transiting exoplanets. Concept 2 is optimized for maximum science return and minimal complexity, and offers fast mapping (approximately 60 arcseconds per second). We describe here the three key science themes for OST and the basic mission specifications.

Battersby, Cara↗
NASA NTRS2022

MODIS TEB Electronic Crosstalk Correction Update and Impact on L1B Product Uncertainty

The MODIS instruments onboard the Terra and Aqua satellites have been in operation for over22 and 20 years, respectively. The instruments’ calibration accuracy has been maintained, even with instrument degradation. Electronic crosstalk in the thermal emissive bands (TEB) is a known issue with an increasing impact on the calibration and product. The Terra MODIS photovoltaic (PV) longwave infrared (LWIR) bands crosstalk corrections have been applied in Collection 6.1 (C6.1). However, the electronic crosstalk contamination for some detectors in the mid-wave infrared (MWIR) bands and the Aqua PVLWIR bands affect the Level-1B (L1B) product’s measurement accuracy and image quality. In Collection 7 (C7), crosstalk corrections for select detectors in the Terra and Aqua MWIR and Aqua PV LWIR bands are applied. The entire mission crosstalk coefficients for the select detectors and bands are derived from scheduled lunar observations and populated in the form of look-up tables (LUTs). The Aqua PV-LWIR bands exhibit similar downward crosstalk trends as the Terra PV-LWIR bands, especially in recent years. The crosstalk coefficients and their trends provide a guideline for the correction application. Earth measurement analyses before and after the correction provide contamination and correction assessments. It has been shown that the product quality is enhanced with the crosstalk correction applied in C7. For C7, the crosstalk coefficient uncertainty is derived from the fit residuals between the measured values and a linear fit over a three-year sliding window. The uncertainty propagation is modeled and applied in the total uncertainty calculation intheL1B product. The TEB electronic crosstalk LUTs have been processed over the entire Terra and Aqua MODIS missions. This paper presents the C7 crosstalk correction, as well as its assessment and uncertainty propagation algorithm to the TEB uncertainty.

Tiejun Chang↗
NASA NTRS2022

Modis TEB Electronic Crosstalk Correction Update and Impact on L1B Product Uncertainty

The MODIS instruments on board the Terra and Aqua satellites have been in operation for over 22 and 20 years, respectively. The instruments’ calibration accuracy has been maintained, even with instrument degradation. Electronic crosstalk in the thermal emissive bands (TEB) is a known issue with an increasing impact on the calibration and product. The Terra MODIS photovoltaic (PV) longwave infrared (LWIR) bands crosstalk corrections have been applied in Collection 6.1 (C6.1). However, the electronic crosstalk contamination for some detectors in the mid-wave infrared(MWIR) bands and the Aqua PVLWIR bands affect the Level-1B(L1B) product’s measurement accuracy and image quality. In Collection 7 (C7), crosstalk corrections for select detectors in the Terra and Aqua MWIR and Aqua PV LWIR bands are applied. The entire mission crosstalk coefficients for the select detectors and bands are derived from scheduled lunar observations and populated in the form of look-up tables (LUTs). The Aqua PV-LWIR bands exhibit similar downward crosstalk trends as the Terra PV-LWIR bands, especially in recent years. The crosstalk coefficients and their trends provide a guideline for the correction application. Earth measurement analyses before and after the correction provide contamination and correction assessments. It has been shown that the product quality is enhanced with the crosstalk correction applied in C7. For C7, the crosstalk coefficient uncertainty is derived from the fit residuals between the measured values and a linear fit over a three-year sliding window. The uncertainty propagation is modeled and applied in the total uncertainty calculation intheL1B product. The TEB electronic cross talk LUT shave been processed over the entire Terra and Aqua MODIS missions. This paper presents the C7 crosstalk correction, as well as its assessment and uncertainty propagation algorithm to the TEB uncertainty.

Tiejun Chang↗
NASA NTRSDate not supplied

Seasonal Surface Spectral Emissivity Derived From MODIS Data

Surface emissivity is essential for many remote-sensing applications including the retrieval of surface skin temperature from satellite-based infrared measurements, the determination of cloud detection thresholds, and the estimation of the surface longwave radiation emission, an important component of the energy budget of the surface-atmosphere interface. The CERES (Clouds and the Earth’s Radiant Energy System) Project is measuring broadband shortwave and longwave radiances and deriving cloud properties from the MODIS on Terra and Aqua and from the VIIRS on NOAA-19 and NOAA-20 orbiters to produce combined global radiation and cloud property data sets. Zhou et al. (IEEE Trans. Geosci. Remote Sens., 49, 2011) used Infrared Atmospheric Sounding Interferometer (IASI) data to create a high spectral resolution surface emissivity atlas for remote sensing and modeling applications. The IASI measures spectral radiances between 3.62 and 15.5 μm. The VIIRS I4 channel width is from 3.55 to 3.93 μm, while MODIS Band 20 is from 3.66 to 3.84 m. Comparisons of top-of-atmosphere (TOA) radiance calculations with MODIS and VIIRS observations for these bands relative to bands in the mid-infrared suggest that the IASI emissivity atlas near 3.7 µm may not be suitable for CERES cloud retrievals. In this paper, the IASI emissivities for the VIIRS and MODIS bands centered near 11m are used to derive surface skin temperature from nighttime MODIS/VIIRS data. The Goddard Earth Observing System for Instrument Teams (GEOS-IT) numerical weather analyses provide temperature and water vapor profiles fused to correct the observed radiances for atmospheric absorption and emission. Global seasonal emissivity maps are then derived for the VIIRS and MODIS 3.7-m bands that are consistent with the derived skin temperatures and the observed TOA radiances. These seasonal climatology maps are validated and will be used in CERES Edition 5 and other CERES-related cloud retrieval algorithms to provide improved clear-sky radiances and derived cloud properties.

Surface Emissivity↗
NASA NTRS1982

Methods of editing cloud and atmospheric layer affected pixels from satellite data

Subvisible cirrus clouds (SCi) were easily distinguished in mid-infrared (MIR) TIROS-N daytime data from south Texas and northeast Mexico. The MIR (3.55-3.93 micrometer) pixel digital count means of the SCi affected areas were more than 3.5 standard deviations on the cold side of the scene means. (These standard deviations were made free of the effects of unusual instrument error by factoring out the Ch 3 MIR noise on the basis of detailed examination of noisy and noise-free pixels). SCi affected areas in the IR Ch 4 (10.5-11.5 micrometer) appeared cooler than the general scene, but were not as prominent as in Ch 3, being less than 2 standard deviations from the scene mean. Ch 3 and 4 standard deviations and coefficients of variation are not reliable indicators, by themselves, of the presence of SCi because land features can have similar statistical properties.

Nixon, P. R.↗
NASA NTRS1990

Tunable diode laser IR spectrometer for in situ measurements of the gas phase composition and particle size distribution of Titan's atmosphere

A new instrument, the Probe Infrared Laser Spectrometer (PIRLS), is described for in situ sensing of the gas composition and particle size distribution of Titan's atmosphere on the NASA/ESA Cassini mission. For gas composition measurements, several narrow-band (0.0001/cm) tunable lead-salt diode lasers operating near 80 K at selected mid-IR wavelengths are directed over a path length defined by a small reflector extending over the edge of the probe spacecraft platform; volume mixing ratios of 10 to the -9th should be measurable for several species of interest. A cloud-particle-size spectrometer using a diode laser source at 780 nm shares the optical path and deployed reflector; a combination of imaging and light scattering techniques is used to determine sizes of haze and cloud particles and their number density as a function of altitude.

Webster, Christopher R.↗
NASA NTRS1978

First comparison of simultaneous IRIS, BUV, and ground-based measurements of total ozone

In the present paper, the zonally-averaged global distribution of total ozone obtained simultaneously from different measurements are compared with respect to differences in the measured latitudinal and seasonal variations of total ozone. Emphasis is placed on systematic discrepancies that appear to be related to differences in the sensing methodologies or instruments. While the zonal averages of the IRIS and BUV satellite techniques agree quite well at low latitudes, the results are consistently higher for IRIS than for BUV above mid-latitudes in both the Northern and Southern Hemispheres. The BUV and ground-based ultraviolet averages agree better with each other than with infrared IRIS measurements.

Prior, E. J.↗
NASA NTRS1981

Spectral mapping of Jupiter and the Galilean satellites in the near infrared

A near-infrared mapping spectrometer is included in the science complement of the Galileo Mission, which will explore Jupiter and its satellites in the mid-1980s. The objectives of the infrared mapping spectrometer experiment are to map compositional units on the surfaces of the Jovian satellites and to characterize the mineral content of these units. For Jupiter's atmosphere, this experiment will investigate such areas as cloud properties and the spatial and temporal variability of minor species. The instrument consists of a telescope, a plane grating spectrometer, a Si and InSb detector array, and a passive radiative cooler. The spectral range is 0.7-5.2 microns, covered with a resolution of 0.025 micron. A wobbling secondary mirror in the telescope provides one dimension of spatial scanning, while the other dimension is provided by motion of the spacecraft scan platform.

Carlson, R. W.↗
NASA NTRS2018

Space-Based Infrared Interferometry to Study Exoplanetary Atmospheres

The quest for other habitable worlds and the search for life among them are major goals of modern astronomy. One way to make progress towards these goals is to obtain high-quality spectra of a large number of exoplanets over a broad range of wavelengths. While concepts currently investigated in the United States are focused on visible/NIR wavelengths, where the planets are probed in reflected light, a compelling alternative to characterize planetary atmospheres is the mid-infrared waveband (5-20 um). Indeed, mid-infrared observations provide key information on the presence of an atmosphere, the surface conditions (e.g., temperature, pressure, habitability), and the atmospheric composition in important species such as H2O,CO2, O3, CH4, and N2O. This information is essential to investigate the potential habitability of exoplanets and to make progress towards the search for life in the Universe. Obtaining high-quality mid-infrared spectra of exoplanets from the ground is however extremely challenging due to the overwhelming brightness and turbulence of the Earth's atmosphere. In this paper, we present a concept of space-based midinfrared interferometer that can tackle this observing challenge and discuss the maintechnological developments required to launch such a sophisticated instrument.

Defrère, D.↗
NASA NTRS1997

Diffuse Reflectance Mid-Infrared Spectroscopy as a Tool for the Identification of Surface Contamination on Sandblasted Metals

The SOC 400 Surface Inspection Machine/Infrared (SIMIR) is a small, ruggedized Fourier transform infrared spectrometer having dedicated diffuse reflectance optics. The SOC 400 was designed for the purpose of detecting (qualitatively and quantitatively) oil stains on the inside surface of solid rocket motor casings in the as-sandblasted and cleaned condition at levels approaching 1 mg. sq ft. The performance of this instrument is described using spectral mapping techniques.

G. Louis Powell↗
NASA NTRS1995

Remote sensing of smoke, clouds, and radiation using AVIRIS during SCAR experiments

During the past two years, researchers from several institutes joined together to take part in two SCAR experiments. The SCAR-A (Sulfates, Clouds And Radiation - Atlantic) took place in the mid-Atlantic region of the United States in July, 1993. remote sensing data were acquired with the Airborne Visible Infrared Imaging Spectrometer (AVIRIS), the MODIS Airborne Simulator (MAS), and a RC-10 mapping camera from an ER-2 aircraft at 20 km. In situ measurements of aerosol and cloud microphysical properties were made with a variety of instruments equipped on the University of Washington's C-131A research aircraft. Ground based measurements of aerosol optical depths and particle size distributions were made using a network of sunphotometers. The main purpose of SCAR-A experiment was to study the optical, physical and chemical properties of sulfate aerosols and their interaction with clouds and radiation. Sulfate particles are believed to affect the energy balance of the earth by directly reflecting solar radiation back to space and by increasing the cloud albedo. The SCAR-C (Smoke, Clouds And Radiation - California) took place on the west coast areas during September - October of 1994. Sets of aircraft and ground-based instruments, similar to those used during SCAR-A, were used during SCAR-C. Remote sensing of fires and smoke from AVIRIS and MAS imagers on the ER-2 aircraft was combined with a complete in situ characterization of the aerosol and trace gases from the C-131A aircraft of the University of Washington and the Cesna aircraft from the U.S. Forest Service. The comprehensive data base acquired during SCAR-A and SCAR-C will contribute to a better understanding of the role of clouds and aerosols in global change studies. The data will also be used to develop satellite remote sensing algorithms from MODIS on the Earth Observing System.

Gao, Bo-Cai↗
NASA NTRS2002

Optical Testing of Diamond Machined, Aspheric Mirrors for Groundbased, Near-IR Astronomy

The Infrared Multi-Object Spectrometer (IRMOS) is a facility-class instrument for the Kitt Peak National Observatory 4 and 2.1 meter telescopes. IRMOS is a near-IR (0.8-2.5 micron) spectrometer and operates at approximately 80 K. The 6061-T651 aluminum bench and mirrors constitute an athermal design. The instrument produces simultaneous spectra at low- to mid-resolving power (R=lambda/delta lambda= 300-3000) of approximately 100 objects in its 2.8 x 2.0 arcmin field. We describe ambient and cryogenic optical testing of the IRMOS mirrors across a broad range in spatial frequency (figure error, mid-frequency error, and microroughness). The mirrors include three rotationally symmetric, off-axis conic sections, one off-axis biconic, and several flat fold mirrors. The symmetric mirrors include convex and concave prolate and oblate ellipsoids. They range in aperture from 94x86 mm to 286x269 mm and in f-number from 0.9 to 2.4. The biconic mirror is concave and has a 94x76 mm aperture, R(sub x)=377 mm, k(sub x)=0.0778, R(sub y)=407 mm, and k(sub y)=0.1265 and is decentered by -2 mm in X and 227 mm in Y. All of the mirrors have an aspect ratio of approximately 6:1. The surface error fabrication tolerances are less than 10 nm RMS microroughness, 'best effort' for mid-frequency error, and less than 63.3 nm RMS figure error. Ambient temperature (approximately 293 K) testing is performed for each of the three surface error regimes, and figure testing is also performed at approximately 80 K. Operation of the ADE Phaseshift MicroXAM white light interferometer (micro-roughness) and the Bauer Model 200 profilometer (mid-frequency error) is described. Both the sag and conic values of the aspheric mirrors make these tests challenging. Figure testing is performed using a Zygo GPI interferometer, custom computer generated holograms (CGH), and optomechanical alignment fiducials. Cryogenic CGH null testing is discussed in detail. We discuss complications such as the change in prescription with temperature and thermal gradients. Correction for the effect of the dewar window is also covered. We discuss the error budget for the optical test and alignment procedure. Data reduction is accomplished using commercial optical design and data analysis software packages. Results from CGH testing at cryogenic temperatures are encouraging thus far.

Chambers, V. John↗
NASA NTRS2015

Principle Component Analysis of AIRS and CrIS Data

Synthetic Eigen Vectors (EV) used for the statistical analysis of the PC reconstruction residual of large ensembles of data are a novel tool for the analysis of data from hyperspectral infrared sounders like the Atmospheric Infrared Sounder (AIRS) on the EOS Aqua and the Cross-track Infrared Sounder (CrIS) on the SUOMI polar orbiting satellites. Unlike empirical EV, which are derived from the observed spectra, the synthetic EV are derived from a large ensemble of spectra which are calculated assuming that, given a state of the atmosphere, the spectra created by the instrument can be accurately calculated. The synthetic EV are then used to reconstruct the observed spectra. The analysis of the differences between the observed spectra and the reconstructed spectra for Simultaneous Nadir Overpasses of tropical oceans reveals unexpected differences at the more than 200 mK level under relatively clear conditions, particularly in the mid-wave water vapor channels of CrIS. The repeatability of these differences using independently trained SEV and results from different years appears to rule out inconsistencies in the radiative transfer algorithm or the data simulation. The reasons for these discrepancies are under evaluation.

infrared↗
NASA NTRS2021

MODIS Thermal Emissive Bands Calibration Improvements for Collection 7

The MODIS thermal emissive bands (TEB) radiometric calibration uses a quadratic function for the instrument response, and the calibration coefficients look-up tables (LUTs) are updated using the response of an on-board blackbody (BB). After more than 21 and 19 years on-orbit, the TEB performances for Terra and Aqua MODIS have been generally stable. However, contamination from electronic crosstalk, a known issue since prelaunch, has affected the L1B image quality and measurement accuracy. In addition to the photovoltaic (PV) longwave infrared (LWIR) bands crosstalk correction included in Terra MODIS Collection 6.1 (C6.1), a crosstalk correction for select detectors in the Terra and Aqua mid-wave infrared (MWIR) and Aqua PV LWIR bands are applied in C7. The mission-long crosstalk coefficients for the selected detectors are derived and populated in the form of LUTs. The crosstalk correction is applied to both on-orbit calibration and the algorithm used to generate Earth-view L1B products. Among these detectors, the Aqua MODIS band 24 detector 1 crosstalk has the largest impact on image quality, with striping observed over cold scenes for both Terra and Aqua MODIS. The images of C7 L1B and C6.1 are compared to assess the impact of the correction. Additional assessments using Earthview measurements and inter-comparison also revealed the need for improvement of calibration stability and consistence for select bands. Additional improvements for long-term stability and mirror side consistence were developed using quasideep convective clouds (qDCC), Dome-C, ocean, desert, and inter-comparison with other instruments.

MODIS↗
NASA NTRS1990

Infrared spectroscopic remote sensing from the Cassini orbiter

An infrared spectroscopy instrument for infrared remote sensing from the Cassini orbiter is being breadboarded in the laboratory. The Composite Infrared Spectrometer (CIRS) consists of a pair of Fourier Transform Spectrometers (FTS) which together cover the range from 10 - 1400/cm with a spectral resolution up to 0.5/cm. The far-infrared FTS is a polarizing interferometer covering the 10 - 300/cm range. The mid-infrared FTS is a conventional Michelson FTS covering 200 - 1400/cm in three spectral channels. CIRS will retrieve information on the atmospheres of Titan and Saturn with good vertical resolution, from deep in their tropospheres to high in their stratospheres, and into the upper few centimeters of the regoliths of icy objects. The science objectives and design of CIRS are discussed.

Kunde, V.↗
NASA NTRS1992

On the Retrieval and Analysis of Multilevel Clouds

An accurate satellite retrieval of cloud properties depends upon the detection and analysis of multilayered, overlapping cloud systems that surface observations show to be common. Multiple cloud layers are often found, for instance, in frontal situations, where cirrus overlays boundary layer convective cloud or low-to mid-level stratus cloud. Surface observers (Hahan et al., 1982) indicate that over ocean in the Northern Hemisphere between 30 deg. N and 60 deg. N, 51 percent of observations are of multilevel clouds. A satellite analysis by Coakley (1983) over the Pacific Ocean finds that more than 50 percent of 500 (250 sq km) frames exhibit evidence of multilayered cloud systems. The questions addressed in this study are the following: What error is introduced when inferring the cloud pressure from a Field-Of-View (FOV) that contains some arbitrary amount of transparent cloud overlaying a lower-level black cloud, such as stratus, by making the assumption that there is only a single cloud layer in the FOV, and what may be done to improve the cloud retrieval? The CO2 slicing methods (e.g. McCleese and Wilson, 1976; Smith and Platt, 1978; Chahine, 1974) have been shown to provide accurate means of inferring cirrus cloud altitude from passive infrared radiance measurements. The CO2 techniques have been applied to radiometric data from several instruments, notably the High Resolution Infrared Radiometric Sounder (HIRS/2, hereafter referred to as HIRS), the VISSR Atmospheric Sounder (VAS) (e.g., Menzel et al., 1983; Wylie and Menzel, 1989), and most recently to the High Resolution Interferometer Sounder (HIS) (Smith and Frey, 1990). The methods take advantage of the fact that infrared CO2 sounding channels spaced closely in wavenumber each have varying opacity to CO2, thereby causing each channel to be sensitive to a different level in the atmosphere. The techniques have been shown to be effective for single-layered, nonblack, mid- to high-level clouds such as cirrus, but are generally applied operationally to any given cloud occurrence. The CO2 slicing algorithms are most accurate for clouds than occur in a single, well-defined layer, or for multi-layered cloud cases in which the uppermost cloud layer is nearly black. Significant cloud height retrieval errors may ensue if the HIRS Field-Of-View (FOV) is cotaminated with low cloud. McCleese and Wilson (1976) have shown that the retrieved cloud height for the case of multiple cloud layers is a weighted average of the cloud heights actually present. The weight is approximately proportional to the product of the cloud heigt and the effective cloud amount. The effect of their result is that the uppermost cloud layer dominates the cloud pressure retrieval. Beyond stating that the higher cloud dominates the cloud pressure retrieval, there is no quantitative information to provide a way of estimating the errors in cloud pressure retrieval one should expect for certain common multilevel cloud situations or any suggestions on how to reduce the errors. In this paper we estimate the magnitude of the errors and use a simple algorithm to reduce the errors in optically thin cloud height retrival.

Baum, Bryan A.↗
DOE OSTI2023

A Spectroscopic Study of Mars-analog Materials with Amorphous Sulfate and Chloride Phases: Implications for Detecting Amorphous Materials on the Martian Surface

The Chemistry and Mineralogy X-ray diffraction (XRD) instrument aboard the Curiosity rover consistently identifies amorphous material at Gale Crater, which is compositionally variable, but often includes elevated sulfur and iron, suggesting that amorphous ferric sulfate (AFS) may be present. Understanding how desiccating ferric sulfate brines affect the spectra of Martian material analogs is necessary for interpreting complex/realistic reaction assemblages. Visible and near-infrared reflectance (VNIR), mid-infrared attenuated total reflectance (MIR, FTIR-ATR), and Raman spectra, along with XRD data are presented for basaltic glass, hematite, gypsum, nontronite, and magnesite, each at three grain sizes (<25, 25–63, and 63–180 μm), mixed with ferric sulfate (+/–NaCl), deliquesced, then rapidly desiccated in 11% relative humidity or via vacuum. All desiccated products are partially or completely XRD amorphous; crystalline phases include starting materials and trace precipitates, leaving the bulk of the ferric sulfate in the amorphous fraction. Due to considerable spectral masking, AFS detectability is highly dependent on spectroscopic technique and minerals present. This has strong implications for remote and in situ observations of Martian samples that include an amorphous component. AFS is only identifiable in VNIR spectra for magnesite, nontronite, and gypsum samples; hematite and basaltic glass samples appear similar to pure materials. Sulfate features dominate Raman spectra for nontronite and basaltic glass samples; the analog material dominates Raman spectra of hematite and gypsum samples. MIR data are least affected by masking, but basaltic glass is almost undetectable in MIR spectra of those mixtures. NaCl produces similar FTIR-ATR and Raman features, regardless of analog material.

58 GEOSCIENCES↗