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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

The Trans-Heliospheric Survey - Radial Trends in Plasma Parameters Across the Heliosphere

Context. Though the solar wind is characterized by spatial and temporal variability across a wide range of scales, long-term averages of in situ measurements have revealed clear radial trends: changes in average values of basic plasma parameters (e.g., density, temperature, and speed) and a magnetic field with a distance from the Sun. Aims. To establish our current understanding of the solar wind's average expansion through the heliosphere, data from multiple spacecraft needed to be combined and standardized into a single dataset. Methods. In this study, data from twelve heliospheric and planetary spacecraft - Parker Solar Probe (PSP), Helios 1 and 2, Mariner 2 and 10, Ulysses, Cassini, Pioneer 10 and 11, New Horizons, and Voyager 1 and 2 - were compiled into a dataset spanning over three orders of magnitude in heliocentric distance. To avoid introducing artifacts into this composite dataset, special attention was given to the solar cycle, spacecraft heliocentric elevation, and instrument calibration. Results. The radial trend in each parameter was found to be generally well described by a power-law fit, though up to two break points were identified in each fit. Conclusions. These radial trends are publicly released here to benefit research groups in the validation of global heliospheric simulations and in the development of new deep-space missions such as Interstellar Probe.

Bennett A Maruca↗
DOE OSTI2020

Local characterization of a heavy-fermion superconductor via sub-Kelvin magnetic force microscopy

Using magnetic force microscopy operating at sub-Kelvin temperatures, we characterize the heavy fermion superconductor CeCoIn5. We pinpoint the absolute London penetration depth of λ(0)=435 ± 20 nm and report its temperature dependence, which is closely linked to the symmetry of the superconducting gap. In addition, we directly measure the pinning force of individual Abrikosov vortices and estimate the critical current density of jc=9×104 A/cm2. In contrast to the related, well-established tunnel diode oscillator technique, our method is capable of resolving inhomogeneities locally on the micrometer scale at ultra-low temperature.

Wulferding, Dirk (ORCID:0000000342792109)↗
NASA NTRS1997

Lepidocrocite to Maghemite to Hematite: A way to have Magnetic and Hematitic Martian Soil

We examined decomposition products of lepidocrocite, which were produced by heating the phase in air at temperatures up to 525 C for 3 and 300 hr, by XRD, TEM, magnetic methods, and reflectance spectroscopy (visible and near-IR). Single-crystal lepidocrocite particles dehydroxilated to polycrystalline particles of disordered maghemite which subsequently transformed to polycrystalline particles of hematite. Essentially pure maghemite was obtained at 265 and 223 C for the 3 and 300 hr heating experiments, respectively. Its saturation magnetization (J(sub s)) and mass specific susceptibility are approximately 50 A(sq m)/kg and approximately 40 cubic micrometers/kg, respectively. Because hematite is spectrally dominant, spectrally-hematitic samples (i.e., characterized bv a minimum near 860 nm and a maximum near 750 nm) could also be strongly magnetic (J(sub s) up to approximately 30 A(sq m)/kg) from the masked maghemite component. TEM analyses showed that individual particles are polycrystalline with respect to both maghemite and hematite. The spectrally-hematitic and magnetic Mh+Hm particles can satisfy the spectral and magnetic constraints for Martian surface materials over a wide range of values of Mh/(Mh+Hm) and as either pure oxide powders or (within limits) as components of multiphase particles. These experiments are consistent with lepidocrocite as the precursor of Mh+Hm assemblages on Mars, but other phases (e.g., magnetite) that decompose to Mh and Hm are also possible precursors. Simulations done with a copy of the Mars Pathfinder Magnet Array showed that spectrally hematitic Mh+Hm powders having J(sub s) equal to 20.6 A(sq m)/kg adhered to all five magnets.

Morris, Richard V.↗
NASA NTRS2013

Mode Transitions in Hall Effect Thrusters

Mode transitions have been commonly observed in Hall Effect Thruster (HET) operation where a small change in a thruster operating parameter such as discharge voltage, magnetic field or mass flow rate causes the thruster discharge current mean value and oscillation amplitude to increase significantly. Mode transitions in a 6-kW-class HET called the H6 are induced by varying the magnetic field intensity while holding all other operating parameters constant and measurements are acquired with ion saturation probes and ultra-fast imaging. Global and local oscillation modes are identified. In the global mode, the entire discharge channel oscillates in unison and azimuthal perturbations (spokes) are either absent or negligible. Downstream azimuthally spaced probes show no signal delay between each other and are very well correlated to the discharge current signal. In the local mode, signals from the azimuthally spaced probes exhibit a clear delay indicating the passage of "spokes" and are not well correlated to the discharge current. These spokes are localized oscillations propagating in the ExB direction that are typically 10-20% of the mean value. In contrast, the oscillations in the global mode can be 100% of the mean value. The transition between global and local modes occurs at higher relative magnetic field strengths for higher mass flow rates or higher discharge voltages. The thrust is constant through mode transition but the thrust-to-power decreased by 25% due to increasing discharge current. The plume shows significant differences between modes with the global mode significantly brighter in the channel and the near-field plasma plume as well as exhibiting a luminous spike on thruster centerline. Mode transitions provide valuable insight to thruster operation and suggest improved methods for thruster performance characterization.

interplanetary exploration↗
DOE OSTI2020

Restoration and Modification of Magnetosome Biosynthesis by Internal Gene Acquisition in a Magnetotactic Bacterium

We report that the Integration of a large-sized DNA fragment into a chromosome is an important strategy for characterization of cellular functions in microorganisms. Magnetotactic bacteria synthesize intracellular organelles comprising membrane-bound single crystalline magnetite, also referred to as magnetosomes. Magnetosomes have gained interest in both scientific and engineering sectors as they can be utilized as a material for biomedical and nanotechnological applications. Although genetic engineering of magnetosome biosynthesis mechanism has been investigated, the current method requires cumbersome gene preparation processes. Here, the chromosomal integration of a plasmid containing ≈27 magnetosome genes (≈26 kbp region) in a non-magnetic mutant of Magnetospirillum magneticum AMB-1 using a broad-host-range plasmid is shown. The genome sequencing of gene-complemented strains reveals the chromosomal integration of the plasmid with magnetosome genes at a specific site, most likely by catalysis of an endogenous transposase. Magnetosome production is successfully enhanced by integrating a variation of magnetosome gene operons in the chromosome. This chromosomal integration mechanism will allow the design of functional magnetosomes de novo and M. magneticum AMB-1 may be used as a chassis for the designed magnetosome production.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Solvothermal synthesis and solid-state characterization of metal-metal bonded tetracarboxylatoditechnetium(II,III) polymers

Investigations of solvothermal reactions with pertechnetate, [TcO 4 ] - , have produced four new low-valent Tc extended metal atom chain (EMAC) complexes with multiple metal-metal bonds. The thermal reaction of potassium pertechnetate with glacial acetic acid, under in-situ hydrogen production from the decomposition of sodium borohydride, yields purple elongated crystals determined to be tetraacetato ditechnetium (II,III) acetate (1), [Tc 2 (O 2 CCH 3 ) 4 (μ-O 2 CCH 3 ] n . Compound 1 was characterized by single crystal X-ray diffraction and its magnetic properties recorded between 10 and 300 K. Single crystal X-ray diffraction analysis of 1 indicates the Tc 2 +5 tetraacetato unit is linked by the carboxylate oxygens of the bridging acetate, similar to known chloride and bromide linkage polymers of composition [Tc 2 (μ-O 2 CCH 3 ) 4 Cl] n , and [Tc 2 (μ-O 2 CCH 3 ) 4 Br] n . Here, using the same synthetic method three similar compounds have been synthesized from propionic, benzoic and pivalic acid.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2003

Can MARSIS Measure the Low-Altitude Components of the Mars Magnetic Field?

Measuring the magnetic field anomaly of Mars at low altitudes (e.g. 100-200 km) can be an interesting application of Mars Advance Radar for Subsurface and Ionospheric Sounder (MARSIS). Due to a low HF operation frequency, the radio wave propagating in the ionosphere of Mars, over the magnetic anomaly regions, will be affected and distorted by the localized magnetic field. This distortion in the sounder signal is due to the Faraday rotation and provides information about the strength of the magnetic field. MARSIS is especially sensitive to the radial magnetic field at altitudes where the electron density in the ionosphere peaks (i.e. 100-200 km). Consequently, MARSIS is potentially capable of providing measurements for the radial component of the magnetic field at altitudes between 100 to 200 km that are normally out of reach for orbital magnetometers (with the exception of the aero-braking phase). Such low-altitude measurements would be complementary to already existing measurements at 400 km by MAG-ER on Mars Global Surveyor. This paper will explain the sensitivity of MARSIS as a magnetometer and the method envisioned to measure the radial magnetic field component. MARSIS (Picardi et al.), the first major planetary radar sounder, is the result of an international collaboration between NASA, the Italian Space Agency (ASI), and European Space Agency (ESA), and will arrive at Mars in early 2004 for a two-year mission. MARSIS has a frequency range between 0.1-5.5 MHz and is designed to penetrate the subsurface to a depth of a few kilometers. MARSIS primary objective is to map and characterize the subsurface geological structure of Mars, and search for subsurface liquid water reservoirs. The secondary objective of MARSIS is to study the ionosphere of Mars providing the most extensive amount of data on Martian ionosphere to date. In addition to MARSIS, a second radar sounder named SHARAD (SHallow RADar) with operation frequency of 15-25 MHz is under development. SHARAD is an Italian instrument (Seu et. al) that will fly on NASA s Mars Reconnaissance orbiter in 2005. SHARAD can also provide magnetic measurements, however, it is not expected to be as sensitive as MARSIS to magnetic field variations.

A Safaeinili↗
DOE OSTI2023

Direct observation of 3D topological spin textures and their interactions using soft x-ray vector ptychography

Magnetic topological defects are energetically stable spin configurations characterized by symmetry breaking. Vortices and skyrmions are two well-known examples of 2D spin textures that have been actively studied for both fundamental interest and practical applications. However, experimental evidence of the 3D spin textures has been largely indirect or qualitative to date, due to the difficulty of quantitively characterizing them within nanoscale volumes. Here, we develop soft x-ray vector ptychography to quantitatively image the 3D magnetization vector field in a frustrated superlattice with 10 nm spatial resolution. By applying homotopy theory to the experimental data, we quantify the topological charge of hedgehogs and anti-hedgehogs as emergent magnetic monopoles and probe their interactions inside the frustrated superlattice. We also directly observe virtual hedgehogs and anti-hedgehogs created by magnetically inert voids. We expect that this new quantitative imaging method will open the door to study 3D topological spin textures in a broad class of magnetic materials. Our work also demonstrates that magnetically frustrated superlattices could be used as a new platform to investigate hedgehog interactions and dynamics and to exploit optimized geometries for information storage and transport applications.

Rana, A↗
DOE OSTI2022

Probing elemental speciation in hydrochar produced from hydrothermal liquefaction of anaerobic digestates using quantitative X-ray diffraction

Valorization of hydrochar, a solid byproduct from hydrothermal liquefaction (HTL) of anaerobically-digested agriculture wastes (digestates), requires fundamental knowledge of elemental speciation. This study investigated the effects of reaction temperatures (320–360 °C), digestate pH (3.5–8), and digestate cellulose-to-lignin ratios (0.2–1.8) on the speciation (chemical form) and composition of organics and inorganics in hydrochars produced during hydrothermal treatment. Quantitative X-ray diffraction (XRD) method was the primary technique used to characterize hydrochars. The comprehensive XRD pattern processing including the Rietveld refinement protocols demonstrated that the organic phase was comprised of mostly crystalline monocyclic, heterocyclic, and polycyclic aromatics with diverse aliphatic and aromatic substituents, while the inorganic mineral phase consisted of calcium-phosphates, magnesium-phosphates, calcium-carbonates, and magnesium-carbonates. Further, XRD results were validated by the elemental yields of products and the distribution of chemical functionalities measured using solid-state nuclear magnetic resonance (NMR) spectroscopy. The characterization data were used to evaluate proposed mechanistic pathways using compositional analysis of biocrude and aqueous-phase coproducts. Mechanistic pathways developed in the study suggested that benzoic acids, phenols, benzaldehydes, phenolic aldehydes, α-dicarbonyls, and α-hydroxycarbonyls were responsible for the precipitation of organics through various reactions depending on operating conditions. Meanwhile, the formation of inorganic compounds appeared to be consistently represented by reactions including dehydration, hydrolysis, endergonic reduction, and structure rearrangement of native minerals in the digestates. This study provides basic knowledge needed to create and assess potential elemental speciation pathways. In addition, the results of the study facilitate the specification of process conditions to optimize targeted utilization routes of hydrochar for more economically-feasible and sustainable HTL processing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1978

Imp 6 measurements in the distant polar cusp during substorms

High time-resolution data from the magnetic field, plasma, energetic particle, and VLF wave experiments performed aboard Imp 6 in a study of the distant dayside cusp during substorms are described. The cusp was studied when its location was slightly equatorward of its normal location and the geomagnetic dipole was tilted in the appropriate direction. The data support both reconnection and diffusion as methods of particle entry to the magnetosphere. The evidence (1) indicates an acceleration process to explain enhancements of 400 to 600-km/sec protons above their magnetosheath intensities, and (2) suggests convection of field lines over the polar cap as a means of explaining the lack of low-energy protons near the low-latitude boundary of the cusp. Magnetic field fluctuations, a perturbation vector, ion cyclotron waves, and an abrupt change in the intensity of both whistler waves and electrostatic waves are characterized.

Fairfield, D. H.↗
DOE OSTI2021

Proton-detected 15 N- 1 H dipolar coupling/ 1 H chemical shift correlation experiment for the measurement of NH distances in biological solids under fast MAS solid-state NMR

Measurement of distances from dipolar couplings is essential for structural characterization, refinement and validation using the solid-state nuclear magnetic resonance (ssNMR) spectroscopy. Particularly, knowledge about NH dipolar interactions in biological solids is important for understanding the hydrogen (H)-bonding interactions, molecular geometry and spin dynamics. In this regard, we have proposed a proton-detected two-dimensional (2D) 15 N- 1 H dipolar coupling/ 1 H chemical shift correlation experiment using the C-symmetry based windowless recoupling of chemical shift anisotropy (ROCSA) in combination with the DIPSHIFT pulse-based method for the measurement of short NH distances in the isotopically labeled and naturally abundant biological solids at fast magic angle spinning (MAS) rates (40–70 kHz). Our proposed method results in undistorted recoupled 15 N- 1 H dipolar coupling powder lineshapes that are free from the recoupled 1 H CSA contributions under the 15 N evolution, a feature that is essential for the measurement of NH distances with improved accuracy (± 500 Hz in terms of the NH dipolar couplings). The pulse sequence developed in the present study is also insensitive to the 1H–1H homonuclear dipolar interactions, relaxation effects owing to its constant-time implementation, and t1-noise from the fluctuations in the MAS.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Atomically Dispersed Copper Sites in a Metal–Organic Framework for Reduction of Nitrogen Dioxide

Metal-organic framework (MOF) materials provide an excellent platform to fabricate single-atom catalysts due to their structural diversity, intrinsic porosity, and designable functionality. However, the unambiguous identification of atomically dispersed metal sites and the elucidation of their role in catalysis are challenging due to limited methods of characterization and lack of direct structural information. Here, we report a comprehensive investigation of the structure and the role of atomically dispersed copper sites in UiO-66 for the catalytic reduction of NO 2 at ambient temperature. The atomic dispersion of copper sites on UiO-66 is confirmed by high-angle annular dark-field scanning transmission electron microscopy, electron paramagnetic resonance spectroscopy, and inelastic neutron scattering, and their location is identified by neutron powder diffraction and solid-state nuclear magnetic resonance spectroscopy. The Cu/UiO-66 catalyst exhibits superior catalytic performance for the reduction of NO 2 at 25 °C without the use of reductants. A selectivity of 88% for the formation of N2 at a 97% conversion of NO 2 with a lifetime of >50 h and an unprecedented turnover frequency of 6.1 h-1 is achieved under nonthermal plasma activation. In situ and operando infrared, solid-state NMR, and EPR spectroscopy reveal the critical role of copper sites in the adsorption and activation of NO 2 molecules, with the formation of {Cu(I)···NO} and {Cu···NO 2 } adducts promoting the conversion of NO 2 to N 2 . This study will inspire the further design and study of new efficient single-atom catalysts for NO 2 abatement via detailed unravelling of their role in catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Poplar lignin structural changes during extraction in γ-valerolactone (GVL)

In this paper, we describe an approach for producing both high quality and high quantity of lignin through studying the structural change of lignin during treatment of poplar wood in γ-valerolactone (GVL) for a range of temperatures (from 80 to 120 °C) and reaction time at temperature (from 1 to 24 h). Throughout the study, various techniques, including nuclear magnetic resonance (NMR) spectroscopies (solution- and gel-state 1 H –13 C 2D HSQC and 31 P) and gel-permeation chromatography (GPC) were applied to characterize the lignin structures. As the GVL-extracted lignin yield increases, the level of β-ether units decreases and the level of condensation products increases. The β-ether content, the aliphatic hydroxyl group content, and the molecular weight of the GVL-extracted lignin fractions were close to the poplar lignin from other preparation methods (e.g., enzyme lignin). A two-step hydrolytic process (120 °C, 2 × 15 min) gave a higher lignin yield (56.5% vs. 54.8%) with three times higher β-ether content (31.9% vs. 10.6%) than lignin extracted from a single-step process at 120 °C for 1 h. The results demonstrate that multiple-step cycling of cosolvent-assisted hydrolysis can help preserve more of the virgin ether-bond structures of GVL-extracted poplar lignin. Such a strategy can also be applied to a fully continuous-flow reactor system in future research to further improve both the productivity and quality of GVL-extracted lignin.

2D HSQC NMR↗
NASA NTRS1973

Growth of a single crystal ribbon in space

Three critical technological areas associated with adapting the method of pulling signal crystal silicon ribbon to a space environment were investigated. Basic parameters such as the magnitude of the forces required and the coupling between thermal and force are discussed. The design of a ribbon puller is described, and the problems encountered are also discussed. The force fields in the vicinity of a coil were characterized and results of attempts to pull ribbon are described. The results of the one experiment to grow a conventional float zone crystal in an external static magnetic field are presented.

Padovani, F. A.↗
NASA NTRS1975

SUMMA hot-ion plasma heating research at NASA Lewis Research Center

The SUMMA superconducting magnetic mirror facility and the associated hot-ion plasma research were described. SUMMA is characterized by intense magnetic fields and a large-diameter working bore (41 cm diameter) with room-temperature access. The goal of the plasma research program is to produce steady-state plasmas of fusion reactor densities and temperatures (but not confinement times). The program includes electrode development to produce a hot, dense, large-volume, steady-state plasma and diagnostics development to document the plasma properties. SUMMA and its hot-ion plasma are ideally suited to develop advanced plasma diagnostics methods. Two such methods whose requirements are well matched to SUMMA are: (1) heavy ion beam probing to measure plasma space potential; and (2) submillimeter wavelength laser Thomson scattering to measure local ion temperature.

Reinmann, J. J.↗
NASA NTRS1991

Development of a high-efficiency motor/generator for flywheel energy storage

This study addresses the design changes and extensions necessary to construct and test a working prototype of a motor/generator for a magnetically suspended flywheel energy storage system. The brushless motor controller for the motor was specified and the electronic commutation arrangement designed. The laminations were redesigned and fabricated using laser machining. Flux density measurements were made and the results used to redesign the armature windings. A test rig was designed and built, and the motor/generator was installed and speed tested to 9000 rpm. Experimental methods of obtaining the machine voltage and torque constants Kv and Kt, obtaining the useful air-gap flux density, and characterizing the motor and other system components are described. The measured Kv and Kt were approximately 40 percent greater than predicted by theory and initial experiment.

Lashley, Christopher↗
NASA NTRS1982

The cometary atmosphere and its interaction with the solar wind

The present state of knowledge of cometary atmospheres and their interaction with the solar winds is assessed. Current models of the magnetospheres and ionospheres of comets are based on either an atmospheric chemistry approach, minimizing the effects of atmospheric dynamics and thermodynamics, while the other method takes the exact opposite viewpoint and roles and significance are reversed. A major difficulty in completing the models is a lack of data on the chemical composition of the cometary nucleus, although UV observations have revealed the H, C, O, and S elemental abundance ratios. It is suggested that further studies of collisional ionization by energetic electrons be performed to characterize processes in the cometary atmosphere. Hydronium may be the dominat molecule in the inner coma, if the assumption that the ionosphere is a magnetic field-free cavity separated from the solar wind by an unyielding tangential discontinuity surface is accurate. Particular observations and theoretical attention are recommended for the solar wind interaction in the intermediate range, i.e., 2.5-5 AU, when the cometary atmosphere develops.

Mendis, D. A.↗