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At least 271 records · Page 15

SECARB Report on Post-Injection In-Situ Monitoring

The Southeast Carbon Sequestration Partnership Phase III Anthropogenic Test at Citronelle Field is the United States’ largest prototype of commercial CO 2 capture from a coal-fired power station and transportation, injection, storage and monitoring. This report focuses on the results of the post-injection monitoring period for the Anthropogenic Test. Monitoring methods include both direct and indirect measurements. The Class V Experimental Permit requires extensive monitoring of injected CO 2 at the surface and at deep and shallow depths. The safety, integrity and information objectives of the CO 2 monitoring plan are in place to: (1) create and sustain wellbore integrity; (2) assure safe CO 2 injection operations; (3) verify the location and migration of the injected CO 2 plume; and (4) monitor for any CO 2 leakage. A robust suite of monitoring approaches is utilized for the in-situ monitoring and include, pressure monitoring, various seismic surveys, pulsed neutron logging, reservoir fluid sampling and injection surveys. Data and observations collected using these monitoring methods will be used in the numerical model to inform the post-injection site care monitoring plan. This report describes actions pertaining to in situ monitoring at the Anthropogenic Test Site that were undertaken during the period of September 2014 to May 2016. These monitoring techniques include the acquisition of pressure data, seismic data, pulsed neutron capture logs, reservoir fluid sampling, and tracer gas monitoring. CO 2 injection operations began on August 20, 2012 and terminated on September 1, 2014.

01 COAL, LIGNITE, AND PEAT↗

Characterization of Reactivity Controlled Compression Ignition (RCCI) Using Premixed Gasoline and Direct-Injected Gasoline with a Cetane Improver on a Multi-Cylinder Engine

The focus of the present paper was to characterize Reactivity Controlled Compression Ignition (RCCI) using a single-fuel approach of gasoline and gasoline mixed with a commercially available cetane improver on a multi-cylinder engine. RCCI was achieved by port-injecting a certification grade 96 research octane gasoline and direct-injecting the same gasoline mixed with various levels of a cetane improver, 2-ethylhexyl nitrate (EHN). The EHN volume percentages investigated in the direct-injected fuel were 10, 5, and 2.5%. The combustion phasing controllability and emissions of the different fueling combinations were characterized at 2300 rpm and 4.2 bar brake mean effective pressure over a variety of parametric investigations including direct injection timing, premixed gasoline percentage, and intake temperature. Comparisons were made to gasoline/diesel RCCI operation on the same engine platform at nominally the same operating condition. The experiments were conducted on a modern four cylinder light-duty diesel engine that was modified with a port-fuel injection system while maintaining the stock direct injection fuel system. The pistons were modified for highly premixed operation and feature an open shallow bowl design. The results indicate that the authority to control the combustion phasing through the fuel delivery strategy (e.g., direct injection timing or premixed gasoline percentage) is not a strong function of the EHN concentration in the direct-injected fuel. It was also observed that NOx emissions are a strong function of the global EHN concentration in-cylinder and the combustion phasing. Finally, in general, NOx emissions are significantly elevated for gasoline/gasoline+EHN operation compared with gasoline/diesel RCCI operation at a given operating condition.

33 ADVANCED PROPULSION SYSTEMS↗

Climate response to off-equatorial stratospheric sulfur injections in three Earth system models – Part 1: Experimental protocols and surface changes

There is now substantial literature on climate model studies of equatorial or tropical stratospheric SO 2 injections that aim to counteract the surface warming produced by rising concentrations of greenhouse gases. Here we present the results from the first systematic intercomparison of climate responses in three Earth system models wherein the injection of SO 2 occurs at different latitudes in the lower stratosphere: CESM2-WACCM6, UKESM1.0 and GISS-E2.1-G. The first two use a modal aerosol microphysics scheme, while two versions of GISS-E2.1-G use a bulk aerosol (One-Moment Aerosol, OMA) and a two-moment (Multiconfiguration Aerosol TRacker of mIXing state, MATRIX) microphysics approach, respectively. Our aim in this work is to determine commonalities and differences between the climate model responses in terms of the distribution of the optically reflective sulfate aerosols produced from the oxidation of SO 2 and in terms of the surface response to the resulting reduction in solar radiation. A focus on understanding the contribution of characteristics of models transport alongside their microphysical and chemical schemes, and on evaluating the resulting stratospheric responses in different models, is given in the companion paper (Bednarz et al., 2023). The goal of this exercise is not to evaluate these single-point injection simulations as stand-alone proposed strategies to counteract global warming; instead we determine sources and areas of agreement and uncertainty in the simulated responses and, ultimately, the possibility of designing a comprehensive intervention strategy capable of managing multiple simultaneous climate goals through the combination of different injection locations. We find large disagreements between GISS-E2.1-G and the CESM2-WACCM6 and UKESM1.0 models regarding the magnitude of cooling per unit of aerosol optical depth (AOD) produced, which varies from 4.7 K per unit of AOD in CESM2-WACCM6 to 16.7 K in the GISS-E2.1-G version with two-moment aerosol microphysics. By normalizing the results with the global mean response in each of the models and thus assuming that the amount of SO 2 injected is a free parameter that can be managed independently, we highlight some commonalities in the overall distributions of the aerosols, in the inter-hemispheric surface temperature response and in shifts to the Intertropical Convergence Zone, as well as some areas of disagreement, such as the extent of the aerosol confinement in the equatorial region and the efficiency of the transport to polar latitudes. In conclusion, we demonstrate that it is possible to use these simulations to produce more comprehensive injection strategies in multiple climate models. However, large differences in the injection magnitudes can be expected, potentially increasing inter-model spreads in some stratospheric quantities (such as aerosol distribution) while reducing the spread in the surface response in terms of temperature and precipitation; furthermore, the selection of the injection locations may be dependent on the models' specific stratospheric transport.

54 ENVIRONMENTAL SCIENCES↗

Skin friction reduction by slot injection at Mach 0.8

Surface skin friction, boundary layer profiles and turbulent intensity due to axially symmetric tangential slot injection into a transonic boundary layer were measured. Effects of slot height, multiple slot injection, and injection mass flow rate on the surface skin friction downstream of the the slot have been investigated. Surface skin friction was a function of the injection mass flow rate for x/s 40. Large normal pressure gradient and relatively large turbulent intensity were found near the slot with small injection mass flow rate; the region the high turbulent intensity moved downstream with increasing injection mass flow rate. The results with two slot injections indicated that the distance between slots should be less than 30 slot heights in order to achieve some benefits from the first slot. Of significant importance in the present investigation is that the skin friction reduction obtained at transonic speed is of the same order as obtained in the hypersonic regime. Additional work is required in order to formulate a correlation between the turbulent intensity and the injection mass flow rate that may be used in future analysis.

Zakkay, V.↗

Qualitative investigation of cryogenic fluid injection into a supersonic flow field

The behavior of liquid nitrogen injected into a supersonic nitrogen flow field was investigated using an experimental apparatus in which a Mach 2.7 2D gas nitrogen tunnel is coupled with a high-pressure cryogenic source. Observations were monitored and recorded via a video camera and a motion picture camera. It was found that the penetration of a supersonic flow field by injection of liquid nitrogen is strongly dependent on the flow Mach number, the cryogen injection pressure (Pi/Pc), the injector configuration, and the cryogen temperature. For a 2D gaseous N2, Mach 2.7 tunnel, with cryogen injection Pi/Pc approaching 2, the injected fluid penetration for the 1/8-in. injection port approached one half of the tunnel width at 90-deg injection, and one fourth of the tunnel width at 20-deg injection.

Hendricks, R. C.↗

Test results for rotordynamic coefficients of anti-swirl self-injection seals

Test results are presented for rotordynamic coefficients and leakage for three annular seals which use anti-swirl self-injection concept to yield significant improvement in whirl frequency ratios as compared to smooth and damper seals. A new anti-swirl self-inection mechanism is achieved by deliberately machining self-injection holes inside the seal stator mechanism which is used to achieve effective reduction of the tangential flow which is considered as a prime cause of rotor instability in high performance turbomachinery. Test results show that the self-injection mechanism significantly improves whirl frequency ratios; however, the leakage performance degrades due to the introduction of the self-injection mechanism. Through a series of the test program, an optimum anti-swirl self-injection seal which uses a labyrinth stator surface with anti-axial flow injections is selected to obtain a significant improvement in the whirl frequency ratio as compared to a damper seal, while showing moderate leakage performance. Best whirl frequency ratio is achieved by an anti-swirl self-injection seal of 12 holes anti-swirl and 6 degree anti-leakage injection with a labyrinth surface configuration. When compared to a damper seal, the optimum configuration outperforms the whirl frequency ratio by a factor of 2.

Kim, C. H.↗

Quantitative investigation of compressible mixing: Staged transverse injection into Mach 2 flow

Planar measurements of the injectant mole fraction distribution and the velocity field within a supersonic mixing flowfield have been made using laser-induced iodine fluorescence. The flowfield investigated in this work is staged transverse injection of air into a Mach 2 freestream. A complete three-dimensional survey of the injectant mole fraction distribution has been generated, and a single planar velocity measurement has been completed. The measurements reveal the dramatic effect of streamwise vortices on the mixing in the near field of the injectors, as well as the rapid mixing generated by staging two fuel injectors. Analysis of the downstream decay of the maximum injectant mole fraction in this and other supersonic mixing flowfields indicates that the relative rate of injectant mixing well downstream of the injectors is independent of injection geometry, freestream Mach number, and injectant molecular weight. Mixing within this region of the flowfield is dominated by small-scale turbulence within the injectant plume. The transition of the dominant mixing mechanism, from vortex-driven mixing in the near field to small-scale turbulent mixing in the far field, was found to occur in the region about 10 diameters downstream of the injectors.

Hollo, Steven D.↗

Experimental Investigation of Diffuser Hub Injection to Improve Centrifugal Compressor Stability

Results from a series of experiments to investigate whether centrifugal compressor stability could be improved by injecting air through the diffuser hub surface are reported. The research was conducted in a 4:1 pressure ratio centrifugal compressor configured with a vane-island diffuser. Injector nozzles were located just upstream of the leading edge of the diffuser vanes. Nozzle orientations were set to produce injected streams angled at 8, 0 and +8 degrees relative to the vane mean camber line. Several injection flow rates were tested using both an external air supply and recirculation from the diffuser exit. Compressor flow range did not improve at any injection flow rate that was tested. Compressor flow range did improve slightly at zero injection due to the flow resistance created by injector openings on the hub surface. Leading edge loading and semi-vaneless space diffusion showed trends similar to those reported earlier from shroud surface experiments that did improve compressor flow range. Opposite trends are seen for hub injection cases where compressor flow range decreased. The hub injection data further explain the range improvement provided by shroud-side injection and suggest that different hub-side techniques may produce range improvement in centrifugal compressors.

Skoch, Gary J.↗

Measurements of Skin Friction of the Compressible Turbulent Boundary Layer on a Cone with Foreign Gas Injection

Measurements of average skin friction of the turbulent boundary layer have been made on a 15deg total included angle cone with foreign gas injection. Measurements of total skin-friction drag were obtained at free-stream Mach numbers of 0.3, 0.7, 3.5, and 4.7 and within a Reynolds number range from 0.9 x 10(exp 6) to 5.9 x 10(exp 6) with injection of helium, air, and Freon-12 (CCl2F2) through the porous wall. Substantial reductions in skin friction are realized with gas injection within the range of Mach numbers of this test. The relative reduction in skin friction is in accordance with theory-that is, the light gases are most effective when compared on a mass flow basis. There is a marked effect of Mach number on the reduction of average skin friction; this effect is not shown by the available theories. Limited transition location measurements indicate that the boundary layer does not fully trip with gas injection but that the transition point approaches a forward limit with increasing injection. The variation of the skin-friction coefficient, for the lower injection rates with natural transition, is dependent on the flow Reynolds number and type of injected gas; and at the high injection rates the skin friction is in fair agreement with the turbulent boundary layer results.

Pappas, Constantine C.↗

Comparison of Oxygen Liquefaction Gaseous Oxygen Injection via Ullage and Dip Tube

The Cryogenic Fluid In-situ Liquefaction for Landers (CryoFILL) testing demonstrated constant and transient oxygen liquefaction in a scaled lander tank integrated with an industrial cryocooler. Early in the test series, two methods for injecting gaseous oxygen into the test tank were ran under similar constant liquefaction conditions for comparison. Gaseous oxygen was either injected directly from the lid into the ullage or bubbled up through the liquid using a dip tube that extends to the bottom of the test tank. The direct comparison of these gaseous oxygen injection methods for constant liquefaction indicated ullage injection provided a greater liquefaction rate than injection via a dip tube. Injection through the ullage was subsequently selected as the nominal injection method for the CryoFILL test series. The comparison of the two injection methods will be highlighted with a discussion of what may cause the variation in liquefaction rate.

Cryogenic Fluid Management↗

Finding Balance Between Biological Groundwater Treatment and Treated Injection Water

At the U.S. Department of Energy’s Hanford Site, CH2M HILL Plateau Remediation Company operates the 200 West Pump and Treat which was engineered to treat radiological and chemical contaminants in groundwater as a result of the site’s former plutonium production years. Fluidized bed bioreactors (FBRs) are used to remove nitrate, metals, and volatile organic compounds. Increasing nitrate concentrations in the treatment plant effluent and the presence of a slimy biomass (a typical microorganism response to stress) in the FBRs triggered an investigation of nutrient levels in the system. Little, if any, micronutrient feed was coming into the bioreactors. Additionally, carbon substrate (used to promote biological growth) was passing through to the injection wells, causing biological fouling of the wells and reduced specific injectivity. Adjustments to the micronutrient feed improved microorganism health, but the micronutrients were being overfed (particularly manganese) plugging the injection wells further. Injection well rehabilitation to restore specific injectivity required repeated treatments to remove the biological fouling and precipitated metal oxides. A combination of sulfamic and citric acids worked well to dissolve metal oxides and sodium hypochlorite effectively removed the biological growth. Intensive surging and development techniques successfully removed clogging material from the injection wells. Ultimately, the investigation and nutrient adjustments took months to restore proper balance to the microbial system and over a year to stabilize injection well capacities. Carefully tracking and managing the FBRs and well performance monitoring are critical to balancing the needs of the treatment system while reducing fouling mechanisms in the injection wells.

Carlson, Mark A.↗

Can strong substorm-associated MeV electron injections be an important cause of large radiation belt enhancements?

It has become well-established that strong outer radiation belt enhancements are due to wave-driven electron energization by whistler-mode chorus waves. However, in this study, we examine strong MeV electron injections on 10 July 2019 and find substantial evidence that such injections may be a crucial contributor to outer radiation belt enhancement events. For such an examination, it is essential to precisely separate temporal flux changes from spatial variations observed as Van Allen Probes move along their orbits. Employing a new “hourly snapshot” analysis approach, we discover unprecedented details of electron flux evolutions that suggest that for this event, the outer belt enhancement was not continuous but instead intermittent, mostly composed of 4 large discrete injection-driven flux increases. The injections appear as sharp flux increases when observed near apogee. Otherwise, by comparing hourly snapshots for different times, we infer injections and infer temporally stable fluxes between injections, despite strong and continuous chorus emission. The fast and intermittent electron flux growth successively extending earthwards implies cumulative outer belt enhancement via a series of repetitive inward transport associated with injection-induced electric fields.

79 ASTRONOMY AND ASTROPHYSICS↗

Investigating the Influence of the Initial Biomass Distribution and Injection Strategies on Biofilm-Mediated Calcite Precipitation in Porous Media

Attachment of bacteria in porous media is a complex mixture of processes resulting in the transfer and immobilization of suspended cells onto a solid surface within the porous medium. However, quantifying the rate of attachment is difficult due to the many simultaneous processes possibly involved in attachment, including straining, sorption, and sedimentation, and the difficulties in measuring metabolically active cells attached to porous media. Preliminary experiments confirmed the difficulty associated with measuring active Sporosarcina pasteurii cells attached to porous media. However, attachment is a key process in applications of biofilm-mediated reactions in the subsurface such as microbially induced calcite precipitation. Independent of the exact processes involved, attachment determines both the distribution and the initial amount of attached biomass and as such the initial reaction rate. As direct experimental investigations are difficult, this study is limited to a numerical investigation of the effect of various initial biomass distributions and initial amounts of attached biomass. This is performed for various injection strategies, changing the injection rate as well as alternating between continuous and pulsed injections. The results of this study indicate that, for the selected scenarios, both the initial amount and the distribution of attached biomass have minor influence on the Ca 2+ precipitation efficiency as well as the distribution of the precipitates compared to the influence of the injection strategy. The influence of the initial biomass distribution on the resulting final distribution of the precipitated calcite is limited, except for the continuous injection at intermediate injection rate. But even for this injection strategy, the Ca 2+ precipitation efficiency shows no significant dependence on the initial biomass distribution.

58 GEOSCIENCES↗

CO 2 zonal injection rate allocation and plume extent evaluation through wellbore temperature analysis

Temperature analysis during a pause in injection operations, known as warmback analysis, has been used in the petroleum industry for evaluating the injection conformance and estimating the location of the flooded front in applications, such as waterflooding oil reservoirs. Here in this work, methods are introduced to extend the application of temperature warmback analysis to estimate the zonal CO 2 injection rate and zonal CO 2 plume extent during geologic CO 2 storage in a saline aquifer. First, novel analytical solutions are developed to model transient temperature in the aquifer during the injection and subsequent shut-in periods considering two-phase flow (gaseous CO 2 and aqueous brine) conditions in the aquifer. The solution involves a discretization of the aquifer into regions; the energy and mass conservation equations for the regions are solved simultaneously considering appropriate boundary conditions at the interfaces. Two solutions techniques are presented: multi-region and three-region solutions. Inverse models are developed accordingly to evaluate the injection profile and estimate the extent of the plume front in the reservoir during the injection period. The multi-region solution results in an inversion approach that requires regression analysis. However, the three-region formulation results in a simple graphical technique for inverse modeling. The analytical solutions are validated against a thermally coupled reservoir simulation tool using different synthetic cases for CO 2 injection in deep saline aquifers. The results of the developed solutions provide a good match with numerical results during forward and inverse modeling.

54 ENVIRONMENTAL SCIENCES↗

A comparison of implantation methods for large PIT tags or injectable acoustic transmitters in juvenile Chinook salmon

The miniaturization of acoustic transmitters may allow greater flexibility in terms of the size and species of fish available to tag. New downsized injectable acoustic tags similar in shape to passive integrated transponder tags can be rapidly injected rather than surgically implanted through a sutured incision, as is current practice. Before wide-scale field use of these injectable transmitters, standard protocols to ensure the most effective and least damaging methods of implantation must be developed. Three implantation methods were tested in various sizes of juvenile Chinook salmon Oncorhynchus tschawytscha. Methods included a needle bevel-down injection, a needle bevel-up injection with a 90-degree rotation, and tag implantation through an unsutured incision. Tagged fish were compared to untagged control groups. Weight and wound area were measured at tagging and every week for 3 weeks; holding tanks were checked daily for mortalities and tag losses. No differences among treatments were found in growth, tag loss, or survival, but wound area was significantly reduced among incision-treated fish. The bevel-up injection had the worst results in terms of tag loss and wound area and also had high mortality. Implantation through an incision resulted in the lowest tag loss but the highest mortality. Fish from the bevel-down treatment group had the least mortality; wound areas also were smaller than the bevel-up treatment group. Cumulatively, the data suggest that the unsutured incision and bevel-down injection methods were the most effective; the drawbacks of both methods are described in detail. However, we further recommend larger and longer studies to find more robust thresholds for tagging size that include more sensitive measures.

injection↗

Prostate Hypofractionated Radiation Therapy With Injection of Hyaluronic Acid: Acute Toxicities in a Phase 2 Study

Purpose: Hypofractionated radiation therapy (RT) in prostate cancer can be developed only if the risk of rectal toxicity is controlled. In a multicenter phase 2 trial, hypofractionated irradiation was combined with an injection of hyaluronic acid (HA) to preserve the rectal wall. Tolerance of the injection and acute toxicity rates are reported. Methods and Materials: The study was designed to assess late grade 2 toxicity rates. The results described here correspond to the secondary objectives. Acute toxicity was defined as occurring during RT or within 3 months after RT and graded according to the Common Terminology Criteria for Adverse Events version 4.0. HA tolerance was evaluated with a visual analog scale during the injection and 30 minutes after injection and then by use of the Common Terminology Criteria at each visit. Results: From 2010 to 2012, 36 patients with low-risk to intermediate-risk prostate cancer were included. The HA injection induced a mean pain score of 4.6/10 ± 2.3. Thirty minutes after the injection, 2 patients still reported pain (2/10 and 3/10), which persisted after the intervention. Thirty-three patients experienced at least 1 acute genitourinary toxicity and 20 patients at least 1 acute gastrointestinal toxicity. Grade 2 toxicities were reported for 19 patients with urinary obstruction, frequency, or both and for 1 patient with proctitis. No grade 3 or 4 toxicities were reported. At the 3-month visit, 4 patients described grade 2 obstruction or frequency, and no patients had any grade 2 gastrointestinal toxicities. Conclusions: The injection of HA makes it possible to deliver hypofractionated irradiation over 4 weeks with a dose per fraction of > 3 Gy, with limited acute rectal toxicity.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Prospective Randomized Comparison of the Effectiveness of Radiation Therapy and Local Steroid Injection for the Treatment of Plantar Fasciitis

Purpose: The purpose of this study was to conduct a randomized trial of radiation therapy for plantar fasciitis and to compare radiation therapy with local steroid injections. Methods and Materials: Between March 2013 and April 2014, 128 patients with plantar fasciitis were randomized to receive radiation therapy (total dose of 6.0 Gy applied in 6 fractions of 1.0 Gy three times a week) or local corticosteroid injections a 1 ml injection of 40 mg methylprednisolone and 0.5 ml 1% lidocaine under the guidance of palpation. The results were measured using a visual analog scale, a modified von Pannewitz scale, and a 5-level function score. The fundamental phase of the study was 3 months, with a follow-up period of up to 6 months. Results: The median follow-up period for all patients was 12.5 months (range, 6.5-18.6 months). For the radiation therapy patients, the median follow-up period was 13 months (range, 6.5-18.5 months), whereas in the palpation-guided (PG) steroid injection arm, it was 12.1 months (range, 6.5-18.6 months). After 3 months, results in the radiation therapy arm were significantly superior to those in the PG steroid injection arm (visual analog scale, P<.001; modified von Pannewitz scale, P<.001; 5-level function score, P<.001). Requirements for a second treatment did not significantly differ between the 2 groups, but the time interval for the second treatment was significantly shorter in the PG steroid injection group (P=.045). Conclusion: This study confirms the superior analgesic effect of radiation therapy compared to mean PG steroid injection on plantar fasciitis for at least 6 months after treatment.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Modeling injection-induced fault slip using long short-term memory networks

Stress changes due to changes in fluid pressure and temperature in a faulted formation may lead to the opening/shearing of the fault. This can be due to subsurface (geo)engineering activities such as fluid injections and geologic disposal of nuclear waste. Such activities are expected to rise in the future making it necessary to assess their short- and long-term safety. Here, a new machine learning (ML) approach to model pore pressure and fault displacements in response to high-pressure fluid injection cycles is developed. The focus is on fault behavior near the injection borehole. To capture the temporal dependencies in the data, long short-term memory (LSTM) networks are utilized. To prevent error accumulation within the forecast window, four critical measures to train a robust LSTM model for predicting fault response are highlighted: (i) setting an appropriate value of LSTM lag, (ii) calibrating the LSTM cell dimension, (iii) learning rate reduction during weight optimization, and (iv) not adopting an independent injection cycle as a validation set. Several numerical experiments were conducted, which demonstrated that the ML model can capture peaks in pressure and associated fault displacement that accompany an increase in fluid injection. The model also captured the decay in pressure and displacement during the injection shut-in period. Further, the ability of an ML model to highlight key changes in fault hydromechanical activation processes was investigated, which shows that ML can be used to monitor risk of fault activation and leakage during high pressure fluid injections.

58 GEOSCIENCES↗