The chemistry of interstellar argonium and other probes of the molecular fraction in diffuse clouds
We present a general parameter study in which the abundance of interstellar argonium (ArH{sup +}) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation field, cosmic-ray ionization rate, and cloud extinction. No single set of cloud parameters provides an acceptable fit to the typical ArH{sup +}, OH{sup +}, and H{sub 2}O{sup +} abundances observed in diffuse clouds within the Galactic disk. Instead, the observed abundances suggest that ArH{sup +} resides primarily in a separate population of small clouds of total visual extinction of at most 0.02 mag per cloud, within which the column-averaged molecular fraction is in the range 10{sup −5}--10{sup −2}, while OH{sup +} and H{sub 2}O{sup +} reside primarily in somewhat larger clouds with a column-averaged molecular fraction ∼0.2. This analysis confirms our previous suggestion that the argonium molecular ion is a unique tracer of almost purely atomic gas.