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Transition from wall modes to multimodality in liquid gallium magnetoconvection
Coupled laboratory-numerical experiments of Rayleigh-Bénard convection in liquid gallium subject to a vertical magnetic field are presented. The experiments are carried out in two cylindrical containers with diameter-to-height aspect ratio Γ = 1.0 and 2.0 at varying thermal forcing (Rayleigh numbers 10 5 ≲ Ra ≲ 10 8 ) and magnetic field strength (Chandrasekhar numbers 0 ≲ Ch ≲ 3 × 10 5 ). Laboratory measurements and numerical simulations confirm that magnetoconvection in our finite cylindrical tanks onsets via nondrifting wall-attached modes, in good agreement with asymptotic predictions for a semi-infinite domain. With increasing supercriticality, the experimental and numerical thermal measurements and the numerical velocity data reveal transitions between wall mode states with different azimuthal mode numbers and between wall-dominated convection to wall and interior multimodality. These transitions are also reflected in the heat transfer data, which combined with previous studies connect onset to supercritical turbulent behaviors in liquid metal magnetoconvection over a large parameter space. The gross heat transfer behaviors between magnetoconvection and rotating convection in liquid metals are compared and discussed.
Observation of the p η ' Cusp in the New Precise Beam Asymmetry Σ Data for γ p → p η
Data on the beam asymmetry Σ in the photoproduction of η mesons off protons are reported for tagged photon energies from 1130 to 1790 MeV (mass range from W = 1748 MeV to W = 2045 MeV). The data cover the full solid angle that allows for a precise moment analysis. For the first time, a strong cusp effect in a polarization observable has been observed that is an effect of a branch-point singularity at the pη' threshold [E γ = 1447 MeV (W = 1896 MeV)]. Here, the latest BnGa partial wave analysis includes the new beam asymmetry data and yields a strong indication for the N(1895)1/2 – nucleon resonance, demonstrating the importance of including all singularities for a correct determination of partial waves and resonance parameters.
All-XUV Pump-Probe Transient Absorption Spectroscopy of the Structural Molecular Dynamics of Di-iodomethane
Not Available
Quantum Tensor-Product Decomposition from Choi-State Tomography
The Schmidt decomposition is the go-to tool for measuring bipartite entanglement of pure quantum states. Similarly, it is possible to study the entangling features of a quantum operation using its operator-Schmidt or tensor-product decomposition. While quantum technological implementations of the former are thoroughly studied, entangling properties on the operator level are harder to extract in the quantum computational framework because of the exponential nature of sample complexity. Here, we present an algorithm for unbalanced partitions into a small subsystem and a large one (the environment) to compute the tensor-product decomposition of a unitary the effect of which on the small subsystem is captured in classical memory, while the effect on the environment is accessible as a quantum resource. This quantum algorithm may be used to make predictions about operator nonlocality and effective open quantum dynamics on a subsystem, as well as for finding low-rank approximations and low-depth compilations of quantum circuit unitaries. We demonstrate the method and its applications on a time-evolution unitary of an isotropic Heisenberg model in two dimensions. Published by the American Physical Society 2024
Tokamak level performance in the optimized stellarator Wendelstein 7-X with stable peaked density profiles
Progress towards achieving net gain from nuclear fusion is typically characterized by the triple product 𝑛𝑇𝜏. Although stellarators have several benefits for a reactor, such as the inherent steady-state capability and the lack of disruptions, the maximum achieved triple product has historically lagged behind that of tokamaks. In the large optimized stellarator Wendelstein 7-X, a triple product of (1.10 ± 0.15) × 10 20 m −3 keVs has recently been achieved and held stable for 1.9 s. This marks an important step in stellarator core plasma performance and puts it in line with 𝐻-mode performance in similar sized tokamaks. The progress in Wendelstein 7-X performance is due to the suppression of ion-temperature-gradient turbulence by strong density gradients. In the record case, these are maintained by a fine balance of the core particle transport and central fueling using neutral beam injection. The duration of the scenario was limited in time only by technical restrictions of the neutral beam injectors and control of the divertor heat loads. This paper presents the result in the context of the leading magnetic confinement devices along with details of the scenario.
High-resolution electron time-of-flight spectrometers for angle-resolved measurements at the SQS Instrument at the European XFEL
A set of electron time-of-flight spectrometers for high-resolution angle-resolved spectroscopy was developed for the Small Quantum Systems (SQS) instrument at the SASE3 soft X-ray branch of the European XFEL. The resolving power of this spectrometer design is demonstrated to exceed 10 000 (E/ΔE), using the well known Ne 1s –1 3p resonant Auger spectrum measured at a photon energy of 867.11 eV at a third-generation synchrotron radiation source. At the European XFEL, a width of ~0.5 eV full width at half-maximum for a kinetic energy of 800 eV was demonstrated. It is expected that this linewidth can be reached over a broad range of kinetic energies. An array of these spectrometers, with different angular orientations, is tailored for the Atomic-like Quantum Systems endstation for high-resolution angle-resolved spectroscopy of gaseous samples.
Additive Manufacturing of Coreless Flyback Transformers Using Aerosol Jet Printing and Electrochemical Deposition
An additive manufacturing approach combining aerosol jet printing (AJP) and electrodeposition opens a new pathway to the production of lightweight coreless flyback transformer devices for power electronics. AJP of seed layers with resolution on the order of 30 μm is combined with electrodeposition of Cu and Ni for decreased resistance. This combined approach addresses known shortcomings of AJP and electrodeposition. Nanoparticle inks used in AJP of metals have low conductivity versus bulk materials due to their high grain boundary resistance. There is a lack of readily available high-resolution patterning techniques for electrodeposition outside of expensive clean-room-based lithography techniques. Combining these two techniques enables the patterning of high-resolution, high-conductivity components. Here in this manuscript, we report on the construction of coreless flyback transformers consisting of two-layer primary and two-layer secondary spiral inductors separated by layers of a printed UV-curable dielectric. An input voltage of 17 V at 400 kHz was amplified to an output of 1250 V corresponding to a gain of 73.5. COMSOL modeling at the individual inductor level and at the transformer level was used to compare expected inductance, equivalent series resistance (ESR), and coupling with experimentally measured values.
Ecovoltaic solar energy development can promote grassland bird communities
Ecologically informed photovoltaic (PV) developments that co-prioritize PV electricity generation with ecosystem function (‘ecovoltaics’) have emerged as a promising land sharing strategy to minimize ecological conflicts associated with PV solar energy development. While habitat-focused ecovoltaic designs can conceptually benefit biodiversity by offsetting or enhancing impacts of PV development, foundational field research is needed to examine how wildlife respond to these novel ecosystems. We conducted passive acoustic monitoring (PAM) in 2023 and 2024 at 13 solar facilities and paired control sites to investigate avian community responses to ecovoltaic facilities in the Midwestern United States. Compared to control sites (row crop agricultural fields), we found that ecovoltaic sites supported more grassland bird species throughout a 17-week monitoring period between May and September. Grassland bird communities on ecovoltaic sites were also more stable than on agricultural controls, as measured by the Jaccard dissimilarity index. We also used PAM-based weekly species occurrences in an occupancy-modelling framework to investigate the influence of PV development and other landscape variables on grassland bird occupancy. 10 out of 13 modelled grassland bird species had greater predicted occupancy probabilities (ψ) on PV sites than control sites. Synthesis and applications. Our findings suggest that properly sited and developed ecovoltaic solar facilities in human altered landscapes can improve habitat for birds and other wildlife, but further research is needed to understand which species may benefit most from these novel ecosystems.
Phycocyanobilin biosynthesis in Galdieria sulphuraria requires isomerization of phycoerythrobilin synthesized by bilin reductases
Phycobiliproteins are essential components of the light-harvesting antennae in cyanobacteria and red algae, requiring covalently bound open-chain tetrapyrrole chromophores (bilins) for proper function. In the red alga Galdieria sulphuraria , the primary chromophore is phycocyanobilin (PCB), despite the apparent presence of only biosynthetic genes for phycoerythrobilin (PEB) biosynthesis (PEBA and PEBB). This observation suggests the presence of an alternative, atypical biosynthetic pathway for PCB. In this study, we confirmed the presence of PEB:PCB isomerase activity in an enriched protein fraction from G. sulphuraria . To further investigate this unusual pathway, we combined in silico analyses with biochemical assays. Phylogenetic analyses confirmed the placement of the G. sulphuraria ferredoxin-dependent bilin reductases within the PEBA and PEBB lineages, typically associated with PEB synthesis, whereas the related red alga Cyanidioschyzon merolae was found to contain only PCYA. This gene distribution presents a functional paradox. G. sulphuraria harbors PEB biosynthesis genes but no detectable PEB chromophores and lacks known PCB-synthesizing enzymes despite containing PCB. Functional characterization of recombinant GsPEBA (G. sulphuraria PEBA) and GsPEBB ( G. sulphuraria PEBB) confirmed their roles in PEB synthesis, demonstrating that these enzymes have not evolved to synthesize PCB or act as isomerases despite their phylogenetic placement. In contrast, Cm PCYA ( C. merolae PCYA) catalyzed direct PCB formation from biliverdin. Together, these findings reveal an atypical isomerase-based pathway for PCB biosynthesis in G. sulphuraria , expanding our understanding of bilin metabolism and providing new insight into the evolutionary flexibility of photosynthetic pigment biosynthesis in Rhodophyta.
All-sky Medium Energy Gamma-ray Observatory eXplorer mission concept
The All-sky Medium Energy Gamma-ray Observatory eXplorer (AMEGO-X) is designed to identify and characterize gamma rays from extreme explosions and accelerators. The main science themes include supermassive black holes and their connections to neutrinos and cosmic rays; binary neutron star mergers and the relativistic jets they produce; cosmic ray particle acceleration sources including galactic supernovae; continuous monitoring of other astrophysical events and sources over the full sky in this important energy range. AMEGO-X will probe the medium energy gamma-ray band using a single instrument with sensitivity up to an order of magnitude greater than previous telescopes in the energy range 100 keV to 1 GeV that can be only realized in space. Finally, during its 3-year baseline mission, AMEGO-X will observe nearly the entire sky every two orbits, building up a sensitive all-sky map of gamma-ray sources and emissions. AMEGO-X was submitted in the recent 2021 NASA MIDEX announcement of opportunity.
The Gamow Explorer: a Gamma-Ray Burst Observatory to study the high redshift universe and enable multi-messenger astrophysics
The Gamow Explorer will use Gamma Ray Bursts (GRBs) to: 1) probe the high redshift universe (z < 6) when the first stars were born, galaxies formed and Hydrogen was reionized; and 2) enable multi-messenger astrophysics by rapidly identifying Electro-Magnetic (IR/Optical/X-ray) counterparts to Gravitational Wave (GW) events. GRBs have been detected out to z ~ 9 and their afterglows are a bright beacon lasting a few days that can be used to observe the spectral fingerprints of the host galaxy and intergalactic medium to map the period of reionization and early metal enrichment. Gamow Explorer is optimized to quickly identify high-z events to trigger follow-up observations with JWST and large ground-based telescopes. A wide field of view Lobster Eye X-ray Telescope (LEXT) will search for GRBs and locate them with arc-minute precision. When a GRB is detected, the rapidly slewing spacecraft will point the 5 photometric channel Photo-z Infra-Red Telescope (PIRT) to identify high redshift (z < 6) long GRBs within 100s and send an alert within 1000s of the GRB trigger. An L2 orbit provides < 95% observing efficiency with pointing optimized for follow up by the James Webb Space Telescope (JWST) and ground observatories. The predicted Gamow Explorer high-z rate is <10 times that of the Neil Gehrels Swift Observatory. The instrument and mission capabilities also enable rapid identification of short GRBs and their afterglows associated with GW events. The Gamow Explorer will be proposed to the 2021 NASA MIDEX call and if approved, launched in 2028.
The 2.4 Å cryo-EM structure of a heptameric light-harvesting 2 complex reveals two carotenoid energy transfer pathways
The structure of a heptameric LH2 antenna complex reveals energy transfer pathways and basic assembly principles.
Fingerprinting diverse nanoporous materials for optimal hydrogen storage conditions using meta-learning
A meta-learning model predicts the optimal hydrogen storage conditions and selects from a diverse set of nanoporous materials.
The mole genome reveals regulatory rearrangements associated with adaptive intersexuality
Linking genomic variation to phenotypical traits remains a major challenge in evolutionary genetics. In this study, we use phylogenomic strategies to investigate a distinctive trait among mammals: the development of masculinizing ovotestes in female moles. By combining a chromosome-scale genome assembly of the Iberian mole, Talpa occidentalis, with transcriptomic, epigenetic, and chromatin interaction datasets, we identify rearrangements altering the regulatory landscape of genes with distinct gonadal expression patterns. These include a tandem triplication involving CYP17A1, a gene controlling androgen synthesis, and an intrachromosomal inversion involving the pro-testicular growth factor gene FGF9, which is heterochronically expressed in mole ovotestes. Transgenic mice with a knock-in mole CYP17A1 enhancer or overexpressing FGF9 showed phenotypes recapitulating mole sexual features. Our results highlight how integrative genomic approaches can reveal the phenotypic impact of noncoding sequence changes.
Mechanism and dynamics of fatty acid photodecarboxylase
Photoenzymes are rare biocatalysts driven by absorption of a photon at each catalytic cycle; they inspire development of artificial photoenzymes with valuable activities. Fatty acid photodecarboxylase (FAP) is a natural photoenzyme that has potential applications in the bio-based production of hydrocarbons, yet its mechanism is far from fully understood. RATIONALE To elucidate the mechanism of FAP, we studied the wild-type (WT) enzyme from Chlorella variabilis (CvFAP) and variants with altered active-site residues using a wealth of techniques, including static and time-resolved crystallography and spectroscopy, as well as biochemical and computational approaches. RESULTS A 1.8-Å-resolution CvFAP x-ray crystal structure revealed a dense hydrogen-bonding network positioning the fatty acid carboxyl group in the vicinity of the flavin adenine dinucleotide (FAD) cofactor. Structures solved from free electron laser and low-dose synchrotron x-ray crystal data further highlighted an unusual bent shape of the oxidized flavin chromophore, and showed that the bending angle (14°) did not change upon photon absorption (step 1) or throughout the photocycle. Calculations showed that bending substantially affected the energy levels of the flavin. Structural and spectroscopic analysis of WT and mutant proteins targeting two conserved active-site residues, R451 and C432, demonstrated that both residues were crucial for proper positioning of the substrate and water molecules and for oxidation of the fatty acid carboxylate by 1 FAD* (~300 ps in WT FAP) to form FAD ∙– (step 2). Time-resolved infrared spectroscopy demonstrated that decarboxylation occured quasi-instantaneously upon this forward electron transfer, consistent with barrierless bond cleavage predicted by quantum chemistry calculations and with snapshots obtained by time-resolved crystallography. Transient absorption spectroscopy in H 2 O and D 2 O buffers indicated that back electron transfer from FAD ∙– was coupled to and limited by transfer of an exchangeable proton or hydrogen atom (step 3). Unexpectedly, concomitant with FAD ∙– reoxidation (to a red-shifted form FAD RS ) in 100 ns, most of the CO 2 product was converted, most likely into bicarbonate (as inferred from FTIR spectra of the cryotrapped FAD RS intermediate). Calculations indicated that this catalytic transformation involved an active-site water molecule. Cryo-Fourier transform infrared spectroscopy studies suggested that bicarbonate formation (step 4) was preceded by deprotonation of an arginine residue (step 3). At room temperature, the remaining CO 2 left the protein in 1.5 μs (step 4'). The observation of residual electron density close to C432 in electron density maps derived from time-resolved and cryocrystallography data suggests that this residue may play a role in stabilizing CO 2 and/or bicarbonate. Three routes for alkane formation were identified by quantum chemistry calculations; the one shown in the figure is favored by the ensemble of experimental data. CONCLUSION Finally, we provide a detailed and comprehensive characterization of light-driven hydrocarbon formation by FAP, which uses a remarkably complex mechanism including unique catalytic steps. We anticipate that our results will help to expand the green chemistry toolkit.